The role of an interface in stabilizing reaction intermediates for hydrogen evolution in aprotic electrolytes

Castelli, Ivano E.; Zorko, Milena; Østergaard, Thomas M.; Martins, Pedro F.  B.  D.; Lopes, Pietro P.; Antonopoulos, Byron K.; Maglia, Filippo; Markovic, Nenad M.; Strmcnik, Dusan; Rossmeisl, Jan

doi:10.1039/C9SC05768D

Title: The role of an interface in stabilizing reaction intermediates for hydrogen evolution in aprotic electrolytes

Journal Article · Wed Jan 01 00:00:00 UTC 2020 · Chemical Science

DOI: https://doi.org/10.1039/C9SC05768D · OSTI ID:1607944

^[1]; Zorko, Milena ^[2]; Østergaard, Thomas M. ^[1]; Martins, Pedro F. B. D. ^[2];

^[2]; Antonopoulos, Byron K. ^[3];

^[4]; Markovic, Nenad M. ^[2]; Strmcnik, Dusan ^[2];

^[1]

Nano-Science Center; Department of Chemistry; University of Copenhagen; Copenhagen Ø; Denmark
Materials Science Division; Argonne National Laboratory; Argonne; USA
Battery Cell Technology; BMW Group; München; Germany
Battery Cell Technology; BMW Group; München; Germany; Institute for Advanced Study

By combining idealized experiments with realistic quantum mechanical simulations of an interface, we investigate electroreduction reactions of HF, water and methanesulfonic acid on the single crystal (111) facets of Au, Pt, Ir and Cu in a variety of aprotic electrolytes.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: BMW Technology Corporation; Technical University of Munich; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1607944

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 15 Vol. 11; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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