High Energy Density CNT/NaI Composite Cathodes for Sodium-Ion Batteries
Abstract
The Na-iodine system has potential as a positive electrode in sodium-ion batteries due to its fast reaction kinetics and high energy density. Here, the fabrication of a NaI-loaded carbon nanotube (CNT) mat cathode is presented and the use of NaI as a Na-ion battery cathode is reported for the first time. Freestanding electrodes show a capacity retention of 92% after 100 cycles at 100 mA h g-1 and a high specific energy density (≈473 W h kg-1, second discharge basis vs Na metal) and small hysteresis (0.03 V). Adding a CNT mat interlayer between the NaI composite cathode and the separator, and fluoroethylene carbonate to the electrolyte significantly suppresses shuttling of active materials during cycling. Using ex situ X-ray photoelectron spectroscopy and Raman data, an understanding of the relevant processes occurring during cycling of the CNT/NaI cathode is developed.
- Authors:
-
[1]
- Univ. of Illinois at Urbana-Champaign, IL (United States). Frederick Seitz Materials Research Lab., Beckman Inst.
- Univ. of Illinois at Urbana-Champaign, IL (United States). Frederick Seitz Materials Research Lab.
- Kangwon National Univ., Samcheok (South Korea)
- Publication Date:
- Research Org.:
- Univ. of Illinois at Urbana-Champaign, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; Kwanjeong Educational Foundation
- OSTI Identifier:
- 1606382
- Alternate Identifier(s):
- OSTI ID: 1479522
- Grant/Contract Number:
- FG02-07ER46471
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials Interfaces
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 23; Journal ID: ISSN 2196-7350
- Publisher:
- Wiley-VCH
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Na-ion batteries; carbon nanotubes; high energy density cathodes; shuttling; sodium iodide
Citation Formats
Kim, Sanghyeon, Li, Xiangming, Sang, Lingzi, Yun, Young Soo, Nuzzo, Ralph G., Gewirth, Andrew A., and Braun, Paul V. High Energy Density CNT/NaI Composite Cathodes for Sodium-Ion Batteries. United States: N. p., 2018.
Web. doi:10.1002/admi.201801342.
Kim, Sanghyeon, Li, Xiangming, Sang, Lingzi, Yun, Young Soo, Nuzzo, Ralph G., Gewirth, Andrew A., & Braun, Paul V. High Energy Density CNT/NaI Composite Cathodes for Sodium-Ion Batteries. United States. https://doi.org/10.1002/admi.201801342
Kim, Sanghyeon, Li, Xiangming, Sang, Lingzi, Yun, Young Soo, Nuzzo, Ralph G., Gewirth, Andrew A., and Braun, Paul V. Mon .
"High Energy Density CNT/NaI Composite Cathodes for Sodium-Ion Batteries". United States. https://doi.org/10.1002/admi.201801342. https://www.osti.gov/servlets/purl/1606382.
@article{osti_1606382,
title = {High Energy Density CNT/NaI Composite Cathodes for Sodium-Ion Batteries},
author = {Kim, Sanghyeon and Li, Xiangming and Sang, Lingzi and Yun, Young Soo and Nuzzo, Ralph G. and Gewirth, Andrew A. and Braun, Paul V.},
abstractNote = {The Na-iodine system has potential as a positive electrode in sodium-ion batteries due to its fast reaction kinetics and high energy density. Here, the fabrication of a NaI-loaded carbon nanotube (CNT) mat cathode is presented and the use of NaI as a Na-ion battery cathode is reported for the first time. Freestanding electrodes show a capacity retention of 92% after 100 cycles at 100 mA h g-1 and a high specific energy density (≈473 W h kg-1, second discharge basis vs Na metal) and small hysteresis (0.03 V). Adding a CNT mat interlayer between the NaI composite cathode and the separator, and fluoroethylene carbonate to the electrolyte significantly suppresses shuttling of active materials during cycling. Using ex situ X-ray photoelectron spectroscopy and Raman data, an understanding of the relevant processes occurring during cycling of the CNT/NaI cathode is developed.},
doi = {10.1002/admi.201801342},
journal = {Advanced Materials Interfaces},
number = 23,
volume = 5,
place = {United States},
year = {Mon Aug 20 00:00:00 EDT 2018},
month = {Mon Aug 20 00:00:00 EDT 2018}
}
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