Dark air–liquid interfacial chemistry of glyoxal and hydrogen peroxide
Abstract
The air-liquid (a-l) interfacial chemistry of glyoxal is of great interest in atmospheric chemistry. We present molecular imaging of glyoxal and hydrogen peroxide (H2O2) dark aging using in situ time-of-flight secondary ion mass spectrometry (ToF-SIMS). More organic peroxides and cluster ions are observed at the a-l interface in dark aging compared to UV aging. Cluster ions formed with more water molecules in dark aging indicate that aqueous secondary organic aerosols (aqSOA) could form hydrogen bond with water molecules, suggesting that aqSOA at the aqueous phase are more hydrophilic. Thus the interfacial aqSOA in dark aging could increase hygroscopic growth. Strong contribution of cluster ions and large water clusters in dark aging indicates change of solvation shells at the a-l interface. The observation of organic peroxides and cluster ions indicates that the aqueous surface could be a reservoir of organic peroxides and odd hydrogen radicals at night. Our findings provide new understandings of glyoxal a-l interfacial chemistry and fill in the gap between field measurements and the climate model simulation of SOA.
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1619820
- Alternate Identifier(s):
- OSTI ID: 1605900
- Report Number(s):
- PNNL-SA-146695
Journal ID: ISSN 2397-3722; 28; PII: 85
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Published Article
- Journal Name:
- npj Climate and Atmospheric Science
- Additional Journal Information:
- Journal Name: npj Climate and Atmospheric Science Journal Volume: 2 Journal Issue: 1; Journal ID: ISSN 2397-3722
- Publisher:
- Springer Nature
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES; glyoxal; H2O2; dark aging; liquid SIMS; aqSOA; organic peroxides; water clusters; cluster ions
Citation Formats
Zhang, Fei, Yu, Xiaofei, Chen, Jianmin, Zhu, Zihua, and Yu, Xiao-Ying. Dark air–liquid interfacial chemistry of glyoxal and hydrogen peroxide. United Kingdom: N. p., 2019.
Web. doi:10.1038/s41612-019-0085-5.
Zhang, Fei, Yu, Xiaofei, Chen, Jianmin, Zhu, Zihua, & Yu, Xiao-Ying. Dark air–liquid interfacial chemistry of glyoxal and hydrogen peroxide. United Kingdom. https://doi.org/10.1038/s41612-019-0085-5
Zhang, Fei, Yu, Xiaofei, Chen, Jianmin, Zhu, Zihua, and Yu, Xiao-Ying. Thu .
"Dark air–liquid interfacial chemistry of glyoxal and hydrogen peroxide". United Kingdom. https://doi.org/10.1038/s41612-019-0085-5.
@article{osti_1619820,
title = {Dark air–liquid interfacial chemistry of glyoxal and hydrogen peroxide},
author = {Zhang, Fei and Yu, Xiaofei and Chen, Jianmin and Zhu, Zihua and Yu, Xiao-Ying},
abstractNote = {The air-liquid (a-l) interfacial chemistry of glyoxal is of great interest in atmospheric chemistry. We present molecular imaging of glyoxal and hydrogen peroxide (H2O2) dark aging using in situ time-of-flight secondary ion mass spectrometry (ToF-SIMS). More organic peroxides and cluster ions are observed at the a-l interface in dark aging compared to UV aging. Cluster ions formed with more water molecules in dark aging indicate that aqueous secondary organic aerosols (aqSOA) could form hydrogen bond with water molecules, suggesting that aqSOA at the aqueous phase are more hydrophilic. Thus the interfacial aqSOA in dark aging could increase hygroscopic growth. Strong contribution of cluster ions and large water clusters in dark aging indicates change of solvation shells at the a-l interface. The observation of organic peroxides and cluster ions indicates that the aqueous surface could be a reservoir of organic peroxides and odd hydrogen radicals at night. Our findings provide new understandings of glyoxal a-l interfacial chemistry and fill in the gap between field measurements and the climate model simulation of SOA.},
doi = {10.1038/s41612-019-0085-5},
journal = {npj Climate and Atmospheric Science},
number = 1,
volume = 2,
place = {United Kingdom},
year = {Thu Aug 15 00:00:00 EDT 2019},
month = {Thu Aug 15 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1038/s41612-019-0085-5
https://doi.org/10.1038/s41612-019-0085-5
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 13 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Impact of mixing state and hygroscopicity on CCN activity of biomass burning aerosol in Amazonia
journal, January 2017
- Sánchez Gácita, Madeleine; Longo, Karla M.; Freire, Julliana L. M.
- Atmospheric Chemistry and Physics, Vol. 17, Issue 3
Real-time observational evidence of changing Asian dust morphology with the mixing of heavy anthropogenic pollution
journal, March 2017
- Pan, Xiaole; Uno, Itsushi; Wang, Zhe
- Scientific Reports, Vol. 7, Issue 1
Henry's Law Constant Determinations for Hydrogen Peroxide, Methyl Hydroperoxide, Hydroxymethyl Hydroperoxide, Ethyl Hydroperoxide, and Peroxyacetic Acid
journal, January 1996
- O'Sullivan, Daniel W.; Lee, Meehye; Noone, Birgitta C.
- The Journal of Physical Chemistry, Vol. 100, Issue 8
Photosensitized Production of Atmospherically Reactive Organic Compounds at the Air/Aqueous Interface
journal, June 2015
- Fu, Hongbo; Ciuraru, Raluca; Dupart, Yoan
- Journal of the American Chemical Society, Vol. 137, Issue 26
An investigation of the beam damage effect on in situ liquid secondary ion mass spectrometry analysis
journal, October 2017
- Yu, Xiaofei; Yu, Jiachao; Zhou, Yufan
- Rapid Communications in Mass Spectrometry, Vol. 31, Issue 23
Insights into the formation of secondary organic carbon in the summertime in urban Shanghai
journal, October 2018
- Zhang, Ci; Lu, Xiaohui; Zhai, Jinghao
- Journal of Environmental Sciences, Vol. 72
Organosulfates in cloud water above the Ozarks' isoprene source region
journal, October 2013
- Pratt, Kerri A.; Fiddler, Marc N.; Shepson, Paul B.
- Atmospheric Environment, Vol. 77
Atmospheric oxalic acid and SOA production from glyoxal: Results of aqueous photooxidation experiments
journal, November 2007
- Carlton, Annmarie G.; Turpin, Barbara J.; Altieri, Katye E.
- Atmospheric Environment, Vol. 41, Issue 35
Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation
journal, July 2015
- Krechmer, Jordan E.; Coggon, Matthew M.; Massoli, Paola
- Environmental Science & Technology, Vol. 49, Issue 17
Low Temperature Kinetics of the First Steps of Water Cluster Formation
journal, March 2016
- Bourgalais, J.; Roussel, V.; Capron, M.
- Physical Review Letters, Vol. 116, Issue 11
A missing sink for gas-phase glyoxal in Mexico City: Formation of secondary organic aerosol
journal, January 2007
- Volkamer, Rainer; San Martini, Federico; Molina, Luisa T.
- Geophysical Research Letters, Vol. 34, Issue 19
Does interfacial photochemistry play a role in the photolysis of pyruvic acid in water?
journal, October 2018
- Fu, Yao; Zhang, Yanyan; Zhang, Fei
- Atmospheric Environment, Vol. 191
Making a hybrid microfluidic platform compatible for in situ imaging by vacuum-based techniques
journal, November 2011
- Yang, Li; Yu, Xiao-Ying; Zhu, Zihua
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 29, Issue 6
Direct observation of aqueous secondary organic aerosol from biomass-burning emissions
journal, August 2016
- Gilardoni, Stefania; Massoli, Paola; Paglione, Marco
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 36
Chemical Analysis of Complex Organic Mixtures Using Reactive Nanospray Desorption Electrospray Ionization Mass Spectrometry
journal, July 2012
- Laskin, Julia; Eckert, Peter A.; Roach, Patrick J.
- Analytical Chemistry, Vol. 84, Issue 16
Understanding the aqueous phase ozonolysis of isoprene: distinct product distribution and mechanism from the gas phase reaction
journal, January 2012
- Wang, H. L.; Huang, D.; Zhang, X.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 15
Heterogeneous Ozonolysis of Endocyclic Unsaturated Organic Aerosol Proxies: Implications for Criegee Intermediate Dynamics and Later-Generation Reactions
journal, January 2019
- Zhao, Zixu; Xu, Qi; Yang, Xiaoyan
- ACS Earth and Space Chemistry, Vol. 3, Issue 3
Effective Henry’s Law Partitioning and the Salting Constant of Glyoxal in Aerosols Containing Sulfate
journal, April 2013
- Kampf, Christopher J.; Waxman, Eleanor M.; Slowik, Jay G.
- Environmental Science & Technology, Vol. 47, Issue 9
Kinetic measurements of the reactivity of hydrogen peroxide and ozone towards small atmospherically relevant aldehydes, ketones and organic acids in aqueous solutions
journal, January 2014
- Schöne, L.; Herrmann, H.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 9
Probing liquid surfaces under vacuum using SEM and ToF-SIMS
journal, January 2011
- Yang, Li; Yu, Xiao-Ying; Zhu, Zihua
- Lab on a Chip, Vol. 11, Issue 15
Comparison of aerosol hygroscopicity and mixing state between winter and summer seasons in Pearl River Delta region, China
journal, March 2016
- Jiang, Rongxin; Tan, Haobo; Tang, Lili
- Atmospheric Research, Vol. 169
The Hydrated Proton at the Water Liquid/Vapor Interface
journal, September 2004
- Petersen, Matt K.; Iyengar, Srinivasan S.; Day, Tyler J. F.
- The Journal of Physical Chemistry B, Vol. 108, Issue 39
Tropospheric Aqueous-Phase Chemistry: Kinetics, Mechanisms, and Its Coupling to a Changing Gas Phase
journal, February 2015
- Herrmann, Hartmut; Schaefer, Thomas; Tilgner, Andreas
- Chemical Reviews, Vol. 115, Issue 10
Oxidation Products of Biogenic Emissions Contribute to Nucleation of Atmospheric Particles
journal, May 2014
- Riccobono, F.; Schobesberger, S.; Scott, C. E.
- Science, Vol. 344, Issue 6185
Formation of aqueous-phase α-hydroxyhydroperoxides (α-HHP): potential atmospheric impacts
journal, January 2013
- Zhao, R.; Lee, A. K. Y.; Soong, R.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 12
Hygroscopic growth of water soluble organic carbon isolated from atmospheric aerosol collected at US national parks and Storm Peak Laboratory
journal, January 2017
- Taylor, Nathan F.; Collins, Don R.; Lowenthal, Douglas H.
- Atmospheric Chemistry and Physics, Vol. 17, Issue 4
Perspective: Water cluster mediated atmospheric chemistry
journal, July 2011
- Vaida, Veronica
- The Journal of Chemical Physics, Vol. 135, Issue 2
Ultrafast photochemistry of methyl hydroperoxide on ice particles
journal, October 2009
- Kamboures, M. A.; Nizkorodov, S. A.; Gerber, R. B.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 15
Deciphering the aqueous chemistry of glyoxal oxidation with hydrogen peroxide using molecular imaging
journal, January 2017
- Sui, Xiao; Zhou, Yufan; Zhang, Fei
- Physical Chemistry Chemical Physics, Vol. 19, Issue 31
Computational Studies of Atmospherically-Relevant Chemical Reactions in Water Clusters and on Liquid Water and Ice Surfaces
journal, January 2015
- Gerber, R. Benny; Varner, Mychel E.; Hammerich, Audrey D.
- Accounts of Chemical Research, Vol. 48, Issue 2
Nuclear magnetic resonance spectroscopy for determining the functional content of organic aerosols: A review
journal, August 2014
- Chalbot, Marie-Cecile G.; Kavouras, Ilias G.
- Environmental Pollution, Vol. 191
Two coexisting liquid phases in switchable ionic liquids
journal, January 2017
- Yao, Juan; Lao, David B.; Sui, Xiao
- Physical Chemistry Chemical Physics, Vol. 19, Issue 34
Formation of secondary organic aerosols from isoprene and its gas-phase oxidation products through reaction with hydrogen peroxide
journal, August 2004
- Claeys, Magda; Wang, Wu; Ion, Alina C.
- Atmospheric Environment, Vol. 38, Issue 25
Direct Photolysis of α-Pinene Ozonolysis Secondary Organic Aerosol: Effect on Particle Mass and Peroxide Content
journal, September 2014
- Epstein, Scott A.; Blair, Sandra L.; Nizkorodov, Sergey A.
- Environmental Science & Technology, Vol. 48, Issue 19
The impact of interactions between algal organic matter and humic substances on coagulation
journal, November 2015
- Pivokonsky, Martin; Naceradska, Jana; Brabenec, Tomas
- Water Research, Vol. 84
Kinetics of the Baeyer-Villiger reaction of aromatic ketones with perbenzoic acid
journal, September 1972
- Ogata, Yoshiro.; Sawaki, Yasuhiko.
- The Journal of Organic Chemistry, Vol. 37, Issue 19
Photooxidation of methylhydroperoxide and ethylhydroperoxide in the aqueous phase under simulated cloud droplet conditions
journal, April 2007
- Monod, A.; Chevallier, E.; Durandjolibois, R.
- Atmospheric Environment, Vol. 41, Issue 11
Ion-water clusters, bulk medium effects, and ion hydration
journal, August 2011
- Merchant, Safir; Dixit, Purushottam D.; Dean, Kelsey R.
- The Journal of Chemical Physics, Vol. 135, Issue 5
Functional waters in intraprotein proton transfer monitored by FTIR difference spectroscopy
journal, November 2005
- Garczarek, Florian; Gerwert, Klaus
- Nature, Vol. 439, Issue 7072
Observational constraints on glyoxal production from isoprene oxidation and its contribution to organic aerosol over the Southeast United States: GLYOXAL PRODUCTION FROM ISOPRENE
journal, August 2016
- Li, Jingyi; Mao, Jingqiu; Min, Kyung-Eun
- Journal of Geophysical Research: Atmospheres, Vol. 121, Issue 16
Atmospheric photochemistry at a fatty acid-coated air-water interface
journal, August 2016
- Rossignol, S.; Tinel, L.; Bianco, A.
- Science, Vol. 353, Issue 6300
Submicrometer Particles Are in the Liquid State during Heavy Haze Episodes in the Urban Atmosphere of Beijing, China
journal, September 2017
- Liu, Yuechen; Wu, Zhijun; Wang, Yu
- Environmental Science & Technology Letters, Vol. 4, Issue 10
Simulation of semi-explicit mechanisms of SOA formation from glyoxal in aerosol in a 3-D model
journal, January 2014
- Knote, C.; Hodzic, A.; Jimenez, J. L.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 12
Secondary Organic Aerosol Formation from Low-NO x Photooxidation of Dodecane: Evolution of Multigeneration Gas-Phase Chemistry and Aerosol Composition
journal, February 2012
- Yee, Lindsay D.; Craven, Jill S.; Loza, Christine L.
- The Journal of Physical Chemistry A, Vol. 116, Issue 24
In Situ Characterization of Hydrated Proteins in Water by SALVI and ToF-SIMS
journal, January 2016
- Yu, Jiachao; Zhou, Yufan; Hua, Xin
- Journal of Visualized Experiments, Issue 108
Uptake Rate Measurements of Methanesulfonic Acid and Glyoxal by Aqueous Droplets
journal, January 1998
- Schweitzer, Francis; Magi, Laurent; Mirabel, Philippe
- The Journal of Physical Chemistry A, Vol. 102, Issue 3
Atmospheric radical chemistry revisited
journal, August 2016
- Vaida, V.
- Science, Vol. 353, Issue 6300
Two-stroke scooters are a dominant source of air pollution in many cities
journal, May 2014
- Platt, S. M.; Haddad, I. El.; Pieber, S. M.
- Nature Communications, Vol. 5, Issue 1
Mesoscopic Structure Facilitates Rapid CO 2 Transport and Reactivity in CO 2 Capture Solvents
journal, September 2018
- Yu, Xiao-Ying; Yao, Juan; Lao, David B.
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 19
Two-dimensional and three-dimensional dynamic imaging of live biofilms in a microchannel by time-of-flight secondary ion mass spectrometry
journal, May 2015
- Hua, Xin; Marshall, Matthew J.; Xiong, Yijia
- Biomicrofluidics, Vol. 9, Issue 3
Hygroscopic behavior of water-soluble matter in marine aerosols over the East China Sea
journal, February 2017
- Yan, Yu; Fu, Pingqing; Jing, Bo
- Science of The Total Environment, Vol. 578
Transition Metal Catalysis in the Baeyer-Villiger Oxidation of Ketones
journal, May 1998
- Strukul, Giorgio
- Angewandte Chemie International Edition, Vol. 37, Issue 9
Secondary Organic Aerosol Formation from Acetylene (C 2 H 2 ): seed effect on SOA yields due to organic photochemistry in the aerosol aqueous phase
journal, January 2009
- Volkamer, R.; Ziemann, P. J.; Molina, M. J.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 6
Aqueous-Phase OH Oxidation of Glyoxal: Application of a Novel Analytical Approach Employing Aerosol Mass Spectrometry and Complementary Off-Line Techniques
journal, September 2011
- Lee, Alex K. Y.; Zhao, R.; Gao, S. S.
- The Journal of Physical Chemistry A, Vol. 115, Issue 38
Formation of hydroxyl radicals from photolysis of secondary organic aerosol material
journal, January 2015
- Badali, K. M.; Zhou, S.; Aljawhary, D.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 14
The Influence of Organic Films at the Air−Aqueous Boundary on Atmospheric Processes
journal, April 2006
- Donaldson, D. J.; Vaida, Veronica
- Chemical Reviews, Vol. 106, Issue 4
Improving the Molecular Ion Signal Intensity for In Situ Liquid SIMS Analysis
journal, September 2016
- Zhou, Yufan; Yao, Juan; Ding, Yuanzhao
- Journal of The American Society for Mass Spectrometry, Vol. 27, Issue 12
Uptake of Gas-Phase Formaldehyde by Aqueous Acid Surfaces
journal, January 1996
- Jayne, J. T.; Worsnop, D. R.; Kolb, C. E.
- The Journal of Physical Chemistry, Vol. 100, Issue 19
ToF-SIMS characterization of glyoxal surface oxidation products by hydrogen peroxide: A comparison between dry and liquid samples: SIMS characterization of glyoxal surface oxidation by hydrogen peroxide
journal, November 2017
- Sui, Xiao; Zhou, Yufan; Zhang, Fei
- Surface and Interface Analysis, Vol. 50, Issue 10
Identification of organic hydroperoxides and peroxy acids using atmospheric pressure chemical ionization–tandem mass spectrometry (APCI-MS/MS): application to secondary organic aerosol
journal, January 2018
- Zhou, Shouming; Rivera-Rios, Jean C.; Keutsch, Frank N.
- Atmospheric Measurement Techniques, Vol. 11, Issue 5
Mechanistic Insights on the Photosensitized Chemistry of a Fatty Acid at the Air/Water Interface
journal, September 2016
- Tinel, Liselotte; Rossignol, Stéphanie; Bianco, Angelica
- Environmental Science & Technology, Vol. 50, Issue 20
Laboratory evidence of organic peroxide and peroxyhemiacetal formation in the aqueous phase and implications for aqueous OH
journal, January 2015
- Lim, Y. B.; Turpin, B. J.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 22
Atmospheric hydrogen peroxide and organic hydroperoxides during PRIDE-PRD'06, China: their concentration, formation mechanism and contribution to secondary aerosols
journal, January 2008
- Hua, W.; Chen, Z. M.; Jie, C. Y.
- Atmospheric Chemistry and Physics, Vol. 8, Issue 22
Near-UV photolysis cross sections of CH<sub>3</sub>OOH and HOCH<sub>2</sub>OOH determined via action spectroscopy
journal, January 2007
- Roehl, C. M.; Marka, Z.; Fry, J. L.
- Atmospheric Chemistry and Physics, Vol. 7, Issue 3
Photochemistry of the glyoxal–hydrogen peroxide complexes in solid argon: Formation of 2-hydroxy-2-hydroperoxyethanal
journal, November 2009
- Mucha, Małgorzata; Mielke, Zofia
- Chemical Physics Letters, Vol. 482, Issue 1-3
Ion-induced nucleation of pure biogenic particles
journal, May 2016
- Kirkby, Jasper; Duplissy, Jonathan; Sengupta, Kamalika
- Nature, Vol. 533, Issue 7604
Development of a sensitive long path absorption photometer to quantify peroxides in aerosol particles (Peroxide-LOPAP)
journal, January 2012
- Mertes, P.; Pfaffenberger, L.; Dommen, J.
- Atmospheric Measurement Techniques, Vol. 5, Issue 10
Formation of alkyl and hydroxyalkyl hydroperoxides on ozonolysis in water and in air
journal, September 1995
- Gäb, Siegmar; Turner, Walter V.; Wolff, Silke
- Atmospheric Environment, Vol. 29, Issue 18
Photosensitized Formation of Secondary Organic Aerosols above the Air/Water Interface
journal, August 2016
- Bernard, F.; Ciuraru, R.; Boréave, A.
- Environmental Science & Technology, Vol. 50, Issue 16
Investigation of Aqueous-Phase Photooxidation of Glyoxal and Methylglyoxal by Aerosol Chemical Ionization Mass Spectrometry: Observation of Hydroxyhydroperoxide Formation
journal, February 2012
- Zhao, R.; Lee, A. K. Y.; Abbatt, J. P. D.
- The Journal of Physical Chemistry A, Vol. 116, Issue 24
Identification of water-soluble organic carbon in non-urban aerosols using ultrahigh-resolution FT-ICR mass spectrometry: organic anions
journal, January 2012
- Mazzoleni, Lynn R.; Saranjampour, Parichehr; Dalbec, Megan M.
- Environmental Chemistry, Vol. 9, Issue 3
Oligomer Formation Pathways in Secondary Organic Aerosol from MS and MS/MS Measurements with High Mass Accuracy and Resolving Power
journal, April 2012
- Hall, Wiley A.; Johnston, Murray V.
- Journal of The American Society for Mass Spectrometry, Vol. 23, Issue 6