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Title: Electro-chemo-mechanical evolution of sulfide solid electrolyte/Li metal interfaces: operando analysis and ALD interlayer effects

Abstract

Investigation of interfacial degradation of Li 10 GeP 2 S 12 (LGPS) electrolytes and the effect of ALD artificial SEI interlayers in lithium metal solid state batteries using a suite of operando microscopy and spectroscopy techniques.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [1];  [2];  [4];  [5]; ORCiD logo [1]
  1. Department of Mechanical Engineering, University of Michigan, Ann Arbor, USA
  2. Department of Materials Science and Engineering, University of Michigan, Ann Arbor, USA
  3. Materials Science Center, National Renewable Energy Laboratory, USA, Department of Mechanical Engineering, San Diego State University
  4. Materials Science Center, National Renewable Energy Laboratory, USA
  5. Department of Mechanical Engineering, University of Michigan, Ann Arbor, USA, Department of Materials Science and Engineering
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1605610
Grant/Contract Number:  
AC36-08GO28308
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 13; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Davis, Andrew L., Garcia-Mendez, Regina, Wood, Kevin N., Kazyak, Eric, Chen, Kuan-Hung, Teeter, Glenn, Sakamoto, Jeff, and Dasgupta, Neil P. Electro-chemo-mechanical evolution of sulfide solid electrolyte/Li metal interfaces: operando analysis and ALD interlayer effects. United Kingdom: N. p., 2020. Web. doi:10.1039/C9TA11508K.
Davis, Andrew L., Garcia-Mendez, Regina, Wood, Kevin N., Kazyak, Eric, Chen, Kuan-Hung, Teeter, Glenn, Sakamoto, Jeff, & Dasgupta, Neil P. Electro-chemo-mechanical evolution of sulfide solid electrolyte/Li metal interfaces: operando analysis and ALD interlayer effects. United Kingdom. doi:10.1039/C9TA11508K.
Davis, Andrew L., Garcia-Mendez, Regina, Wood, Kevin N., Kazyak, Eric, Chen, Kuan-Hung, Teeter, Glenn, Sakamoto, Jeff, and Dasgupta, Neil P. Tue . "Electro-chemo-mechanical evolution of sulfide solid electrolyte/Li metal interfaces: operando analysis and ALD interlayer effects". United Kingdom. doi:10.1039/C9TA11508K.
@article{osti_1605610,
title = {Electro-chemo-mechanical evolution of sulfide solid electrolyte/Li metal interfaces: operando analysis and ALD interlayer effects},
author = {Davis, Andrew L. and Garcia-Mendez, Regina and Wood, Kevin N. and Kazyak, Eric and Chen, Kuan-Hung and Teeter, Glenn and Sakamoto, Jeff and Dasgupta, Neil P.},
abstractNote = {Investigation of interfacial degradation of Li 10 GeP 2 S 12 (LGPS) electrolytes and the effect of ALD artificial SEI interlayers in lithium metal solid state batteries using a suite of operando microscopy and spectroscopy techniques.},
doi = {10.1039/C9TA11508K},
journal = {Journal of Materials Chemistry. A},
number = 13,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {3}
}

Journal Article:
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Works referenced in this record:

Negating interfacial impedance in garnet-based solid-state Li metal batteries
journal, December 2016

  • Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin)
  • Nature Materials, Vol. 16, Issue 5
  • DOI: 10.1038/nmat4821

Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li7P3S11 solid electrolyte
journal, March 2016


Lithium Mechanics: Roles of Strain Rate and Temperature and Implications for Lithium Metal Batteries
journal, January 2019

  • LePage, William S.; Chen, Yuxin; Kazyak, Eric
  • Journal of The Electrochemical Society, Vol. 166, Issue 2
  • DOI: 10.1149/2.0221902jes

A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries
journal, January 2014

  • Seino, Yoshikatsu; Ota, Tsuyoshi; Takada, Kazunori
  • Energy Environ. Sci., Vol. 7, Issue 2
  • DOI: 10.1039/C3EE41655K

Atomic to Nanoscale Investigation of Functionalities of an Al 2 O 3 Coating Layer on a Cathode for Enhanced Battery Performance
journal, January 2016


New horizons for inorganic solid state ion conductors
journal, January 2018

  • Zhang, Zhizhen; Shao, Yuanjun; Lotsch, Bettina
  • Energy & Environmental Science, Vol. 11, Issue 8
  • DOI: 10.1039/C8EE01053F

ALD Protection of Li-Metal Anode Surfaces - Quantifying and Preventing Chemical and Electrochemical Corrosion in Organic Solvent
journal, August 2016

  • Lin, Chuan-Fu; Kozen, Alexander C.; Noked, Malachi
  • Advanced Materials Interfaces, Vol. 3, Issue 21
  • DOI: 10.1002/admi.201600426

Understanding the Effect of Interlayers at the Thiophosphate Solid Electrolyte/Lithium Interface for All-Solid-State Li Batteries
journal, November 2018


Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations
journal, October 2015

  • Zhu, Yizhou; He, Xingfeng; Mo, Yifei
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 42
  • DOI: 10.1021/acsami.5b07517

Atomic Layer Deposition of Li x Al y S Solid-State Electrolytes for Stabilizing Lithium-Metal Anodes
journal, April 2016


Interface Re-Engineering of Li 10 GeP 2 S 12 Electrolyte and Lithium anode for All-Solid-State Lithium Batteries with Ultralong Cycle Life
journal, January 2018

  • Zhang, Zhihua; Chen, Shaojie; Yang, Jing
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 3
  • DOI: 10.1021/acsami.7b16176

Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All-Solid-State Batteries
journal, April 2018

  • Park, Kern Ho; Bai, Qiang; Kim, Dong Hyeon
  • Advanced Energy Materials, Vol. 8, Issue 18
  • DOI: 10.1002/aenm.201800035

Influence of Coating Protocols on Alumina-Coated Cathode Material: Atomic Layer Deposition versus Wet-Chemical Coating
journal, January 2019

  • Han, Binghong; Key, Baris; Lipton, Andrew S.
  • Journal of The Electrochemical Society, Vol. 166, Issue 15
  • DOI: 10.1149/2.0681915jes

Impedance characterization reveals mixed conducting interphases between sulfidic superionic conductors and lithium metal electrodes
journal, June 2017


Enhanced Stability of LiCoO2 Cathodes in Lithium-Ion Batteries Using Surface Modification by Atomic Layer Deposition
journal, January 2010

  • Jung, Yoon Seok; Cavanagh, Andrew S.; Dillon, Anne C.
  • Journal of The Electrochemical Society, Vol. 157, Issue 1, p. A75-A81
  • DOI: 10.1149/1.3258274

A lithium superionic conductor
journal, July 2011

  • Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
  • Nature Materials, Vol. 10, Issue 9, p. 682-686
  • DOI: 10.1038/nmat3066

“Lithium-Free” Thin-Film Battery with In Situ Plated Li Anode
journal, January 2000

  • Neudecker, B. J.; Dudney, N. J.; Bates, J. B.
  • Journal of The Electrochemical Society, Vol. 147, Issue 2
  • DOI: 10.1149/1.1393226

Solid‐State Plastic Crystal Electrolytes: Effective Protection Interlayers for Sulfide‐Based All‐Solid‐State Lithium Metal Batteries
journal, March 2019

  • Wang, Changhong; Adair, Keegan R.; Liang, Jianwen
  • Advanced Functional Materials, Vol. 29, Issue 26
  • DOI: 10.1002/adfm.201900392

Recent Advances in Atomic Layer Deposition
journal, March 2016


Stable Cycling Lithium–Sulfur Solid Batteries with Enhanced Li/Li 10 GeP 2 S 12 Solid Electrolyte Interface Stability
journal, April 2019

  • Umeshbabu, Ediga; Zheng, Bizhu; Zhu, Jianping
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 20
  • DOI: 10.1021/acsami.9b03726

First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material
journal, December 2011

  • Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand
  • Chemistry of Materials, Vol. 24, Issue 1, p. 15-17
  • DOI: 10.1021/cm203303y

Structural absorption by barbule microstructures of super black bird of paradise feathers
journal, January 2018


High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016


Lithium metal protected by atomic layer deposition metal oxide for high performance anodes
journal, January 2017

  • Chen, Lin; Connell, Justin G.; Nie, Anmin
  • Journal of Materials Chemistry A, Vol. 5, Issue 24
  • DOI: 10.1039/C7TA03116E

First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries
journal, January 2016

  • Zhu, Yizhou; He, Xingfeng; Mo, Yifei
  • Journal of Materials Chemistry A, Vol. 4, Issue 9
  • DOI: 10.1039/C5TA08574H

Li Distribution Heterogeneity in Solid Electrolyte Li 10 GeP 2 S 12 upon Electrochemical Cycling Probed by 7 Li MRI
journal, March 2018

  • Chien, Po-Hsiu; Feng, Xuyong; Tang, Mingxue
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 8
  • DOI: 10.1021/acs.jpclett.8b00240

XPS on Li-Battery-Related Compounds: Analysis of Inorganic SEI Phases and a Methodology for Charge Correction
journal, August 2018


Lithium Metal Anodes: Toward an Improved Understanding of Coupled Morphological, Electrochemical, and Mechanical Behavior
journal, February 2017


Dendrites and Pits: Untangling the Complex Behavior of Lithium Metal Anodes through Operando Video Microscopy
journal, October 2016


Solid-state thin-film rechargeable batteries
journal, February 2005


Electrochemical Stability of Li 10 GeP 2 S 12 and Li 7 La 3 Zr 2 O 12 Solid Electrolytes
journal, January 2016

  • Han, Fudong; Zhu, Yizhou; He, Xingfeng
  • Advanced Energy Materials, Vol. 6, Issue 8
  • DOI: 10.1002/aenm.201501590

Evolution at the Solid Electrolyte/Gold Electrode Interface during Lithium Deposition and Stripping
journal, March 2017


Operando X-ray photoelectron spectroscopy of solid electrolyte interphase formation and evolution in Li2S-P2S5 solid-state electrolytes
journal, June 2018


How Do Li Atoms Pass through the Al 2 O 3 Coating Layer during Lithiation in Li-ion Batteries?
journal, July 2013

  • Jung, Sung Chul; Han, Young-Kyu
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 16
  • DOI: 10.1021/jz401231e

Improved Cycle Life and Stability of Lithium Metal Anodes through Ultrathin Atomic Layer Deposition Surface Treatments
journal, September 2015


Exploring interfacial stability of solid-state electrolytes at the lithium-metal anode surface
journal, August 2018


An insight into intrinsic interfacial properties between Li metals and Li 10 GeP 2 S 12 solid electrolytes
journal, January 2017

  • Chen, Bingbing; Ju, Jiangwei; Ma, Jun
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 46
  • DOI: 10.1039/C7CP05253G

Demonstration of high current densities and extended cycling in the garnet Li7La3Zr2O12 solid electrolyte
journal, August 2018


Evaluating the Effects of Temperature and Pressure on Li/PEO-LiTFSI Interfacial Stability and Kinetics
journal, January 2018

  • Gupta, A.; Kazyak, E.; Craig, N.
  • Journal of The Electrochemical Society, Vol. 165, Issue 11
  • DOI: 10.1149/2.0901811jes

Stabilizing interface between Li10SnP2S12 and Li metal by molecular layer deposition
journal, November 2018


Interfacial Stability of Li Metal–Solid Electrolyte Elucidated via in Situ Electron Microscopy
journal, October 2016


Dead lithium: mass transport effects on voltage, capacity, and failure of lithium metal anodes
journal, January 2017

  • Chen, Kuan-Hung; Wood, Kevin N.; Kazyak, Eric
  • Journal of Materials Chemistry A, Vol. 5, Issue 23
  • DOI: 10.1039/C7TA00371D

Direct Observation of the Interfacial Instability of the Fast Ionic Conductor Li 10 GeP 2 S 12 at the Lithium Metal Anode
journal, March 2016


Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013

  • Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
  • APL Materials, Vol. 1, Issue 1
  • DOI: 10.1063/1.4812323

Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery
journal, July 2013

  • Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02261

Sulfide solid electrolytes for all-solid-state lithium batteries: Structure, conductivity, stability and application
journal, September 2018


A new asymmetric Pseudo-Voigt function for more efficient fitting of XPS lines: New asymmetric Pseudo-Voigt function for efficient XPS line fitting
journal, June 2014

  • Schmid, Martin; Steinrück, Hans-Peter; Gottfried, J. Michael
  • Surface and Interface Analysis, Vol. 46, Issue 8
  • DOI: 10.1002/sia.5521

ALD for clean energy conversion, utilization, and storage
journal, November 2011

  • Elam, Jeffrey W.; Dasgupta, Neil P.; Prinz, Fritz B.
  • MRS Bulletin, Vol. 36, Issue 11, p. 899-906
  • DOI: 10.1557/mrs.2011.265

Atomic Layer Deposition: An Overview
journal, January 2010

  • George, Steven M.
  • Chemical Reviews, Vol. 110, Issue 1, p. 111-131
  • DOI: 10.1021/cr900056b

Lithium Transport in Amorphous Al 2 O 3 and AlF 3 for Discovery of Battery Coatings
journal, April 2013

  • Hao, Shiqiang; Wolverton, C.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 16
  • DOI: 10.1021/jp311982d

Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries
journal, February 2018


Interface Stability in Solid-State Batteries
journal, December 2015


Emerging Applications of Atomic Layer Deposition for Lithium-Ion Battery Studies
journal, June 2012

  • Meng, Xiangbo; Yang, Xiao-Qing; Sun, Xueliang
  • Advanced Materials, Vol. 24, Issue 27
  • DOI: 10.1002/adma.201200397

Interfacial behaviours between lithium ion conductors and electrode materials in various battery systems
journal, January 2016

  • Wu, Bingbin; Wang, Shanyu; Evans IV, Willie J.
  • Journal of Materials Chemistry A, Vol. 4, Issue 40
  • DOI: 10.1039/C6TA05439K

Salt-Based Organic-Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li 10 GeP 2 S 12 Solid Electrolyte Interface
journal, September 2018

  • Gao, Yue; Wang, Daiwei; Li, Yuguang C.
  • Angewandte Chemie International Edition, Vol. 57, Issue 41
  • DOI: 10.1002/anie.201807304

Ultrathin Lithium-Ion Conducting Coatings for Increased Interfacial Stability in High Voltage Lithium-Ion Batteries
journal, May 2014

  • Park, Joong Sun; Meng, Xiangbo; Elam, Jeffrey W.
  • Chemistry of Materials, Vol. 26, Issue 10
  • DOI: 10.1021/cm500512n