Spatial quantification of dynamic inter and intra particle crystallographic heterogeneities within lithium ion electrodes
Abstract
The performance of lithium ion electrodes is hindered by unfavorable chemical heterogeneities that pre-exist or develop during operation. Time-resolved spatial descriptions are needed to understand the link between such heterogeneities and a cell's performance. Here, operando high-resolution X-ray diffraction-computed tomography is used to spatially and temporally quantify crystallographic heterogeneities within and between particles throughout both fresh and degraded LixMn2O4 electrodes. This imaging technique facilitates identification of stoichiometric differences between particles and stoichiometric gradients and phase heterogeneities within particles. Through radial quantification of phase fractions, the response of distinct particles to lithiation is found to vary; most particles contain localized regions that transition to rock salt LiMnO2 within the first cycle. Other particles contain monoclinic Li2MnO3 near the surface and almost pure spinel LixMn2O4 near the core. Following 150 cycles, concentrations of LiMnO2 and Li2MnO3 significantly increase and widely vary between particles.
- Authors:
-
[1];
[2];
[3];
[8];
[1]
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- European Synchrotron Radiation Facility (ESRF), Grenoble (France); Finden Limited, Abingdon (United Kingdom); Univ. College London (United Kingdom)
- Univ. College London (United Kingdom); The Faraday Inst. (United Kingdom)
- Univ. College London (United Kingdom)
- National Renewable Energy Lab. (NREL), Golden, CO (United States); Colorado School of Mines, Golden, CO (United States)
- European Synchrotron Radiation Facility (ESRF), Grenoble (France)
- Finden Limited, Abingdon (United Kingdom)
- Finden Limited, Abingdon (United Kingdom); Univ. College London (United Kingdom); Science and Technology Facilities Council (STFC), Oxford (United Kingdom). Rutherford Appleton Lab. (RAL)
- Publication Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); European Union Horizon 2020 Research and Innovation Program; Royal Academy of Engineering; The Faraday Institution
- OSTI Identifier:
- 1601577
- Report Number(s):
- NREL/JA-5400-75809
Journal ID: ISSN 2041-1723
- Grant/Contract Number:
- AC36-08GO28308; 679933; EP/S003053/1
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; lithium ion batteries; x-ray diffraction; computed tomography; crystallography
Citation Formats
Finegan, Donal P., Vamvakeros, Antonis, Tan, Chun, Heenan, Thomas M. M., Daemi, Sohrab R., Seitzman, Natalie, Di Michiel, Marco, Jacques, Simon, Beale, Andrew M., Brett, Dan J. L., Shearing, Paul R., and Smith, Kandler. Spatial quantification of dynamic inter and intra particle crystallographic heterogeneities within lithium ion electrodes. United States: N. p., 2020.
Web. doi:10.1038/s41467-020-14467-x.
Finegan, Donal P., Vamvakeros, Antonis, Tan, Chun, Heenan, Thomas M. M., Daemi, Sohrab R., Seitzman, Natalie, Di Michiel, Marco, Jacques, Simon, Beale, Andrew M., Brett, Dan J. L., Shearing, Paul R., & Smith, Kandler. Spatial quantification of dynamic inter and intra particle crystallographic heterogeneities within lithium ion electrodes. United States. https://doi.org/10.1038/s41467-020-14467-x
Finegan, Donal P., Vamvakeros, Antonis, Tan, Chun, Heenan, Thomas M. M., Daemi, Sohrab R., Seitzman, Natalie, Di Michiel, Marco, Jacques, Simon, Beale, Andrew M., Brett, Dan J. L., Shearing, Paul R., and Smith, Kandler. Fri .
"Spatial quantification of dynamic inter and intra particle crystallographic heterogeneities within lithium ion electrodes". United States. https://doi.org/10.1038/s41467-020-14467-x. https://www.osti.gov/servlets/purl/1601577.
@article{osti_1601577,
title = {Spatial quantification of dynamic inter and intra particle crystallographic heterogeneities within lithium ion electrodes},
author = {Finegan, Donal P. and Vamvakeros, Antonis and Tan, Chun and Heenan, Thomas M. M. and Daemi, Sohrab R. and Seitzman, Natalie and Di Michiel, Marco and Jacques, Simon and Beale, Andrew M. and Brett, Dan J. L. and Shearing, Paul R. and Smith, Kandler},
abstractNote = {The performance of lithium ion electrodes is hindered by unfavorable chemical heterogeneities that pre-exist or develop during operation. Time-resolved spatial descriptions are needed to understand the link between such heterogeneities and a cell's performance. Here, operando high-resolution X-ray diffraction-computed tomography is used to spatially and temporally quantify crystallographic heterogeneities within and between particles throughout both fresh and degraded LixMn2O4 electrodes. This imaging technique facilitates identification of stoichiometric differences between particles and stoichiometric gradients and phase heterogeneities within particles. Through radial quantification of phase fractions, the response of distinct particles to lithiation is found to vary; most particles contain localized regions that transition to rock salt LiMnO2 within the first cycle. Other particles contain monoclinic Li2MnO3 near the surface and almost pure spinel LixMn2O4 near the core. Following 150 cycles, concentrations of LiMnO2 and Li2MnO3 significantly increase and widely vary between particles.},
doi = {10.1038/s41467-020-14467-x},
journal = {Nature Communications},
number = 1,
volume = 11,
place = {United States},
year = {Fri Jan 31 00:00:00 EST 2020},
month = {Fri Jan 31 00:00:00 EST 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 96 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Electrochemical extraction of lithium from LiMn2O4
journal, February 1984
- Thackeray, M. M.; Johnson, P. J.; de Picciotto, L. A.
- Materials Research Bulletin, Vol. 19, Issue 2
Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells
journal, April 1994
- Gummow, R. J.; de Kock, A.; Thackeray, M. M.
- Solid State Ionics, Vol. 69, Issue 1, p. 59-67
Numerical Simulation of the Effect of the Dissolution of LiMn[sub 2]O[sub 4] Particles on Li-Ion Battery Performance
journal, January 2011
- Park, Jonghyun; Seo, Jeong Hun; Plett, Gregory
- Electrochemical and Solid-State Letters, Vol. 14, Issue 2
Probing the structure of heterogeneous diluted materials by diffraction tomography
journal, April 2008
- Bleuet, Pierre; Welcomme, Eléonore; Dooryhée, Eric
- Nature Materials, Vol. 7, Issue 6
“Electrochemical Shock” of Intercalation Electrodes: A Fracture Mechanics Analysis
journal, January 2010
- Woodford, William H.; Chiang, Yet-Ming; Carter, W. Craig
- Journal of The Electrochemical Society, Vol. 157, Issue 10
Homogeneity of lithium distribution in cylinder-type Li-ion batteries
journal, December 2015
- Senyshyn, A.; Mühlbauer, M. J.; Dolotko, O.
- Scientific Reports, Vol. 5, Issue 1
Spinel materials for Li-ion batteries: new insights obtained by operando neutron and synchrotron X-ray diffraction
journal, November 2015
- Bianchini, Matteo; Fauth, François; Suard, Emmanuelle
- Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 71, Issue 6
Quantification of Heterogeneous Degradation in Li‐Ion Batteries
journal, May 2019
- Yang, Yang; Xu, Rong; Zhang, Kai
- Advanced Energy Materials, Vol. 9, Issue 25
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems
journal, September 2013
- Zhan, Chun; Lu, Jun; Jeremy Kropf, A.
- Nature Communications, Vol. 4, Issue 1
5D operando tomographic diffraction imaging of a catalyst bed
journal, November 2018
- Vamvakeros, A.; Jacques, S. D. M.; Di Michiel, M.
- Nature Communications, Vol. 9, Issue 1
The LiMn2O4 to λ-MnO2 phase transition studied by in situ neutron diffraction
journal, September 2001
- Berg, H.
- Solid State Ionics, Vol. 144, Issue 1-2
Dynamic X-Ray Diffraction Computed Tomography Reveals Real-Time Insight into Catalyst Active Phase Evolution
journal, September 2011
- Jacques, Simon D. M.; Di Michiel, Marco; Beale, Andrew M.
- Angewandte Chemie International Edition, Vol. 50, Issue 43
Real-time diffraction computed tomography data reduction
journal, February 2018
- Kieffer, J.; Petitdemange, S.; Vincent, T.
- Journal of Synchrotron Radiation, Vol. 25, Issue 2
Propagation topography of redox phase transformations in heterogeneous layered oxide cathode materials
journal, July 2018
- Mu, Linqin; Yuan, Qingxi; Tian, Chixia
- Nature Communications, Vol. 9, Issue 1
Progress towards five dimensional diffraction imaging of functional materials under process conditions
journal, October 2014
- Beale, Andrew M.; Jacques, Simon D. M.; Gibson, Emma K.
- Coordination Chemistry Reviews, Vol. 277-278
Connecting Particle Fracture with Electrochemical Impedance in Li X Mn 2 O 4
journal, January 2017
- McGrogan, Frank P.; Bishop, Sean R.; Chiang, Yet-Ming
- Journal of The Electrochemical Society, Vol. 164, Issue 14
Li-Rich Li 1+ x Mn 2– x O 4 Spinel Electrode Materials: An Operando Neutron Diffraction Study during Li + Extraction/Insertion
journal, October 2014
- Bianchini, Matteo; Suard, Emmanuelle; Croguennec, Laurence
- The Journal of Physical Chemistry C, Vol. 118, Issue 45
Design and performance of an electrochemical in-situ cell for high resolution full-pattern X-ray powder diffraction
journal, May 2005
- Baehtz, C.; Buhrmester, Th.; Bramnik, N. N.
- Solid State Ionics, Vol. 176, Issue 17-18
Spatially Resolving Lithiation in Silicon–Graphite Composite Electrodes via in Situ High-Energy X-ray Diffraction Computed Tomography
journal, April 2019
- Finegan, Donal P.; Vamvakeros, Antonis; Cao, Lei
- Nano Letters, Vol. 19, Issue 6
Quantifying lithium concentration gradients in the graphite electrode of Li-ion cells using operando energy dispersive X-ray diffraction
journal, January 2019
- Yao, Koffi P. C.; Okasinski, John S.; Kalaga, Kaushik
- Energy & Environmental Science, Vol. 12, Issue 2
Feasibility study of x-ray diffraction computed tomography for medical imaging
journal, October 1998
- Kleuker, U.; Suortti, P.; Weyrich, W.
- Physics in Medicine and Biology, Vol. 43, Issue 10
Developments in X-ray tomography characterization for electrochemical devices
journal, December 2019
- Heenan, Thomas M. M.; Tan, Chun; Hack, Jennifer
- Materials Today, Vol. 31
The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior
journal, January 2018
- Thackeray, M. M.; Croy, J. R.; Lee, Eungje
- Sustainable Energy & Fuels, Vol. 2, Issue 7
High‐Voltage Charging‐Induced Strain, Heterogeneity, and Micro‐Cracks in Secondary Particles of a Nickel‐Rich Layered Cathode Material
journal, March 2019
- Mao, Yuwei; Wang, Xuelong; Xia, Sihao
- Advanced Functional Materials, Vol. 29, Issue 18
Design of next-generation ceramic fuel cells and real-time characterization with synchrotron X-ray diffraction computed tomography
journal, April 2019
- Li, Tao; Heenan, Thomas M. M.; Rabuni, Mohamad F.
- Nature Communications, Vol. 10, Issue 1
X-ray diffraction study on phase transition of orthorhombic LiMnO2 in electrochemical conversions
journal, July 2007
- Tu, X. Y.; Shu, K. Y.
- Journal of Solid State Electrochemistry, Vol. 12, Issue 3
Chemomechanical fatigue of LiMn1.95Al0.05O4 electrodes for lithium-ion batteries
journal, January 2018
- Chen, Di; Kramer, Dominik; Mönig, Reiner
- Electrochimica Acta, Vol. 259
Technological, economic and environmental prospects of all-electric aircraft
journal, December 2018
- Schäfer, Andreas W.; Barrett, Steven R. H.; Doyme, Khan
- Nature Energy, Vol. 4, Issue 2
Effectively suppressing dissolution of manganese from spinel lithium manganate via a nanoscale surface-doping approach
journal, December 2014
- Lu, Jun; Zhan, Chun; Wu, Tianpin
- Nature Communications, Vol. 5, Issue 1
The fast azimuthal integration Python library: pyFAI
journal, March 2015
- Ashiotis, Giannis; Deschildre, Aurore; Nawaz, Zubair
- Journal of Applied Crystallography, Vol. 48, Issue 2
Effects of Inhomogeneities—Nanoscale to Mesoscale—on the Durability of Li-Ion Batteries
journal, February 2013
- Harris, Stephen J.; Lu, Peng
- The Journal of Physical Chemistry C, Vol. 117, Issue 13
Charge Heterogeneity and Surface Chemistry in Polycrystalline Cathode Materials
journal, March 2018
- Tian, Chixia; Xu, Yahong; Nordlund, Dennis
- Joule, Vol. 2, Issue 3
Emerging In Situ and Operando Nanoscale X-Ray Imaging Techniques for Energy Storage Materials
journal, February 2015
- Nelson Weker, Johanna; Toney, Michael F.
- Advanced Functional Materials, Vol. 25, Issue 11
Rapidly falling costs of battery packs for electric vehicles
journal, March 2015
- Nykvist, Björn; Nilsson, Måns
- Nature Climate Change, Vol. 5, Issue 4
Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells
journal, December 2016
- Gilbert, James A.; Shkrob, Ilya A.; Abraham, Daniel P.
- Journal of The Electrochemical Society, Vol. 164, Issue 2
Nano-structural changes in Li-ion battery cathodes during cycling revealed by FIB-SEM serial sectioning tomography
journal, January 2015
- Song, Bohang; Sui, Tan; Ying, Siqi
- Journal of Materials Chemistry A, Vol. 3, Issue 35
Structural Fatigue in Spinel Electrodes in High Voltage (4 V) Li/Li[sub x]Mn[sub 2]O[sub 4] Cells
journal, January 1999
- Thackeray, Michael M.
- Electrochemical and Solid-State Letters, Vol. 1, Issue 1
Electrochemical kinetics of the 0.5Li2MnO3·0.5LiMn0.42Ni0.42Co0.16O2 ‘composite’ layered cathode material for lithium-ion batteries
journal, January 2012
- Yu, Haijun; Wang, Yarong; Asakura, Daisuke
- RSC Advances, Vol. 2, Issue 23
Structural Changes of LiMn[sub 2]O[sub 4] Spinel Electrodes during Electrochemical Cycling
journal, January 1999
- Choa, Jaephil
- Journal of The Electrochemical Society, Vol. 146, Issue 10
Quantifying Reaction and Rate Heterogeneity in Battery Electrodes in 3D through Operando X-ray Diffraction Computed Tomography
journal, April 2019
- Liu, Hao; Kazemiabnavi, Saeed; Grenier, Antonin
- ACS Applied Materials & Interfaces, Vol. 11, Issue 20
TOPAS and TOPAS-Academic : an optimization program integrating computer algebra and crystallographic objects written in C++
journal, February 2018
- Coelho, Alan A.
- Journal of Applied Crystallography, Vol. 51, Issue 1
Removing multiple outliers and single-crystal artefacts from X-ray diffraction computed tomography data
journal, November 2015
- Vamvakeros, Antonios; Jacques, Simon D. M.; Di Michiel, Marco
- Journal of Applied Crystallography, Vol. 48, Issue 6
On the fragmentation of active material secondary particles in lithium ion battery cathodes induced by charge cycling
journal, December 2016
- Sun, Guanhua; Sui, Tan; Song, Bohang
- Extreme Mechanics Letters, Vol. 9
Lithium insertion into manganese spinels
journal, April 1983
- Thackeray, M. M.; David, W. I. F.; Bruce, P. G.
- Materials Research Bulletin, Vol. 18, Issue 4, p. 461-472
Review—Manganese Dissolution from Spinel Cathode: Few Unanswered Questions
journal, December 2016
- Bhandari, Arihant; Bhattacharya, Jishnu
- Journal of The Electrochemical Society, Vol. 164, Issue 2
Chemical Structures of Specific Sodium Ion Battery Components Determined by Operando Pair Distribution Function and X-ray Diffraction Computed Tomography
journal, August 2017
- Sottmann, Jonas; Di Michiel, Marco; Fjellvåg, Helmer
- Angewandte Chemie International Edition, Vol. 56, Issue 38
In situ Visualization of State-of-Charge Heterogeneity within a LiCoO 2 Particle that Evolves upon Cycling at Different Rates
journal, April 2017
- Xu, Yahong; Hu, Enyuan; Zhang, Kai
- ACS Energy Letters, Vol. 2, Issue 5
X-ray diffraction computed tomography: X-ray diffraction computed tomography
journal, July 1987
- Harding, G.; Kosanetzky, J.; Neitzel, U.
- Medical Physics, Vol. 14, Issue 4
Evolution of Electrochemical Cell Designs for In-Situ and Operando 3D Characterization
journal, November 2018
- Tan, Chun; Daemi, Sohrab; Taiwo, Oluwadamilola
- Materials, Vol. 11, Issue 11
In situ neutron powder diffraction studies of lithium-ion batteries
journal, October 2011
- Sharma, Neeraj; Peterson, Vanessa K.
- Journal of Solid State Electrochemistry, Vol. 16, Issue 5
X-Ray Diffraction Computed Tomography for Structural Analysis of Electrode Materials in Batteries
journal, January 2015
- Jensen, Kirsten M. Ø.; Yang, Xiaohao; Laveda, Josefa Vidal
- Journal of The Electrochemical Society, Vol. 162, Issue 7
Development of manganese-rich cathodes as alternatives to nickel-rich chemistries
journal, September 2019
- Croy, Jason R.; Gutierrez, Arturo; He, Meinan
- Journal of Power Sources, Vol. 434
Preparation of a new crystal form of manganese dioxide: λ-MnO2
journal, September 1981
- Hunter, James C.
- Journal of Solid State Chemistry, Vol. 39, Issue 2, p. 142-147
Structural Evolution of Li[sub x]Mn[sub 2]O[sub 4] in Lithium-Ion Battery Cells Measured In Situ Using Synchrotron X-Ray Diffraction Techniques
journal, January 1998
- Mukerjee, S.
- Journal of The Electrochemical Society, Vol. 145, Issue 2
Topotactic Reactions, Structural Studies, and Lithium Intercalation in Cation-Deficient Spinels with Formula Close to Li2Mn4O9
journal, August 2001
- Palos, A. Ibarra; Anne, M.; Strobel, P.
- Journal of Solid State Chemistry, Vol. 160, Issue 1
Surface-to-Bulk Redox Coupling through Thermally Driven Li Redistribution in Li- and Mn-Rich Layered Cathode Materials
journal, July 2019
- Li, Shaofeng; Lee, Sang-Jun; Wang, Xuelong
- Journal of the American Chemical Society, Vol. 141, Issue 30
Quantifying Bulk Electrode Strain and Material Displacement within Lithium Batteries via High-Speed Operando Tomography and Digital Volume Correlation
journal, December 2015
- Finegan, Donal P.; Tudisco, Erika; Scheel, Mario
- Advanced Science, Vol. 3, Issue 3
Visualization of Electrochemical Reactions in Battery Materials with X-ray Microscopy and Mapping
journal, April 2017
- Wolf, Mark; May, Brian M.; Cabana, Jordi
- Chemistry of Materials, Vol. 29, Issue 8
Dynamic X-Ray Diffraction Computed Tomography Reveals Real-Time Insight into Catalyst Active Phase Evolution
journal, September 2011
- Jacques, Simon D. M.; Di Michiel, Marco; Beale, Andrew M.
- Angewandte Chemie, Vol. 123, Issue 43
Chemical Structures of Specific Sodium Ion Battery Components Determined by Operando Pair Distribution Function and X-ray Diffraction Computed Tomography
journal, August 2017
- Sottmann, Jonas; Di Michiel, Marco; Fjellvåg, Helmer
- Angewandte Chemie, Vol. 129, Issue 38
Probing the structure of heterogeneous diluted materials by diffraction tomography
journal, August 2008
- Hodeau, J. -L.; Bleuet, P.; Welcomme, E.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue a1
Homogeneity of lithium distribution in cylinder-type Li-ion batteries
text, January 2015
- Senyshyn, A.; Mühlbauer, M. J.; Dolotko, O.
- Karlsruhe
X-Ray Diffraction Computed Tomography for Structural Analysis of Electrode Materials in Batteries
text, January 2015
- Jensen, Kirsten M. Ø.; Yang, Xiaohao; Laveda, Josefa Vidal
- Columbia University
Quantifying Bulk Electrode Strain and Material Displacement within Lithium Batteries via High-Speed Operando Tomography and Digital Volume Correlation
journal, December 2015
- Finegan, Donal P.; Tudisco, Erika; Scheel, Mario
- Advanced Science, Vol. 3, Issue 3
Quantification of Heterogeneous Degradation in Li‐Ion Batteries
journal, May 2019
- Yang, Yang; Xu, Rong; Zhang, Kai
- Advanced Energy Materials, Vol. 9, Issue 25
Topotactic Reactions, Structural Studies, and Lithium Intercalation in Cation-Deficient Spinels with Formula Close to Li2Mn4O9
journal, August 2001
- Palos, A. Ibarra; Anne, M.; Strobel, P.
- Journal of Solid State Chemistry, Vol. 160, Issue 1
In situ neutron powder diffraction studies of lithium-ion batteries
journal, October 2011
- Sharma, Neeraj; Peterson, Vanessa K.
- Journal of Solid State Electrochemistry, Vol. 16, Issue 5
Preparation of a new crystal form of manganese dioxide: λ-MnO2
journal, September 1981
- Hunter, James C.
- Journal of Solid State Chemistry, Vol. 39, Issue 2, p. 142-147
Lithium insertion into manganese spinels
journal, April 1983
- Thackeray, M. M.; David, W. I. F.; Bruce, P. G.
- Materials Research Bulletin, Vol. 18, Issue 4, p. 461-472
Electrochemical extraction of lithium from LiMn2O4
journal, February 1984
- Thackeray, M. M.; Johnson, P. J.; de Picciotto, L. A.
- Materials Research Bulletin, Vol. 19, Issue 2
Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells
journal, April 1994
- Gummow, R. J.; de Kock, A.; Thackeray, M. M.
- Solid State Ionics, Vol. 69, Issue 1, p. 59-67
Progress towards five dimensional diffraction imaging of functional materials under process conditions
journal, October 2014
- Beale, Andrew M.; Jacques, Simon D. M.; Gibson, Emma K.
- Coordination Chemistry Reviews, Vol. 277-278
Chemomechanical fatigue of LiMn1.95Al0.05O4 electrodes for lithium-ion batteries
journal, January 2018
- Chen, Di; Kramer, Dominik; Mönig, Reiner
- Electrochimica Acta, Vol. 259
Charge Heterogeneity and Surface Chemistry in Polycrystalline Cathode Materials
journal, March 2018
- Tian, Chixia; Xu, Yahong; Nordlund, Dennis
- Joule, Vol. 2, Issue 3
Development of manganese-rich cathodes as alternatives to nickel-rich chemistries
journal, September 2019
- Croy, Jason R.; Gutierrez, Arturo; He, Meinan
- Journal of Power Sources, Vol. 434
Manganese oxides for lithium batteries
journal, January 1997
- Thackeray, Michael M.
- Progress in Solid State Chemistry, Vol. 25, Issue 1-2
Spatially Resolving Lithiation in Silicon–Graphite Composite Electrodes via in Situ High-Energy X-ray Diffraction Computed Tomography
journal, April 2019
- Finegan, Donal P.; Vamvakeros, Antonis; Cao, Lei
- Nano Letters, Vol. 19, Issue 6
In situ Visualization of State-of-Charge Heterogeneity within a LiCoO 2 Particle that Evolves upon Cycling at Different Rates
journal, April 2017
- Xu, Yahong; Hu, Enyuan; Zhang, Kai
- ACS Energy Letters, Vol. 2, Issue 5
Surface-to-Bulk Redox Coupling through Thermally Driven Li Redistribution in Li- and Mn-Rich Layered Cathode Materials
journal, July 2019
- Li, Shaofeng; Lee, Sang-Jun; Wang, Xuelong
- Journal of the American Chemical Society, Vol. 141, Issue 30
Li-Rich Li 1+ x Mn 2– x O 4 Spinel Electrode Materials: An Operando Neutron Diffraction Study during Li + Extraction/Insertion
journal, October 2014
- Bianchini, Matteo; Suard, Emmanuelle; Croguennec, Laurence
- The Journal of Physical Chemistry C, Vol. 118, Issue 45
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems
journal, September 2013
- Zhan, Chun; Lu, Jun; Jeremy Kropf, A.
- Nature Communications, Vol. 4, Issue 1
Effectively suppressing dissolution of manganese from spinel lithium manganate via a nanoscale surface-doping approach
journal, December 2014
- Lu, Jun; Zhan, Chun; Wu, Tianpin
- Nature Communications, Vol. 5, Issue 1
Feasibility study of x-ray diffraction computed tomography for medical imaging
journal, October 1998
- Kleuker, U.; Suortti, P.; Weyrich, W.
- Physics in Medicine and Biology, Vol. 43, Issue 10
X-ray diffraction computed tomography: X-ray diffraction computed tomography
journal, July 1987
- Harding, G.; Kosanetzky, J.; Neitzel, U.
- Medical Physics, Vol. 14, Issue 4
Structural Evolution of Li[sub x]Mn[sub 2]O[sub 4] in Lithium-Ion Battery Cells Measured In Situ Using Synchrotron X-Ray Diffraction Techniques
journal, January 1998
- Mukerjee, S.
- Journal of The Electrochemical Society, Vol. 145, Issue 2
“Electrochemical Shock” of Intercalation Electrodes: A Fracture Mechanics Analysis
journal, January 2010
- Woodford, William H.; Chiang, Yet-Ming; Carter, W. Craig
- Journal of The Electrochemical Society, Vol. 157, Issue 10
Review—Manganese Dissolution from Spinel Cathode: Few Unanswered Questions
journal, December 2016
- Bhandari, Arihant; Bhattacharya, Jishnu
- Journal of The Electrochemical Society, Vol. 164, Issue 2
Connecting Particle Fracture with Electrochemical Impedance in Li X Mn 2 O 4
journal, January 2017
- McGrogan, Frank P.; Bishop, Sean R.; Chiang, Yet-Ming
- Journal of The Electrochemical Society, Vol. 164, Issue 14
Mesopores inside electrode particles can change the Li-ion transport mechanism and diffusion-induced stress
journal, August 2010
- Harris, Stephen J.; Deshpande, Rutooj D.; Qi, Yue
- Journal of Materials Research, Vol. 25, Issue 8
Homogeneity of lithium distribution in cylinder-type Li-ion batteries
preprint, January 2015
- Senyshyn, A.; Mühlbauer, M. J.; Dolotko, O.
- arXiv
X-Ray Diffraction Computed Tomography for Structural Analysis of Electrode Materials in Batteries
text, January 2015
- Jensen, Kirsten M. Ø.; Yang, Xiaohao; Laveda, Josefa Vidal
- Columbia University