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Title: Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid

Abstract

Oxygen evolution reaction (OER) catalysts that are earth-abundant and are active and stable in acid are unknown. Active catalysts derived from Co and Ni oxides dissolve at low pH, whereas acid stable systems such as Mn oxides (MnOx) display poor OER activity. We now demonstrate a rational approach for the design of earth-abundant catalysts that are stable and active in acid by treating activity and stability as decoupled elements of mixed metal oxides. Manganese serves as a stabilizing structural element for catalytically active Co centers in CoMnOx films. In acidic solutions (pH 2.5), CoMnOx exhibits the OER activity of electrodeposited Co oxide (CoOx) with a Tafel slope of 70–80 mV per decade while also retaining the long-term acid stability of MnOx films for OER at 0.1 mA cm-2. Driving OER at greater current densities in this system is not viable because at high anodic potentials, Mn oxides convert to and dissolve as permanganate. However, by exploiting the decoupled design of the catalyst, the stabilizing structural element may be optimized independently of the Co active sites. By screening potential–pH diagrams, we replaced Mn with Pb to prepare CoFePbOx films that maintained the high OER activity of CoOx at pH 2.5 whilemore » exhibiting long-term acid stability at higher current densities (at 1 mA cm-2 for over 50 h at pH 2.0). Under these acidic conditions, CoFePbOx exhibits OER activity that approaches noble metal oxides, thus establishing the viability of decoupling functionality in mixed metal catalysts for designing active, acid-stable, and earth-abundant OER catalysts.« less

Authors:
 [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
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  1. Harvard Univ., Cambridge, MA (United States)
Publication Date:
Research Org.:
Harvard Univ., Cambridge, MA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Science Foundation (NSF)
OSTI Identifier:
1599222
Grant/Contract Number:  
SC0017619; ECS-0335765
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 8; Journal Issue: 7; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Huynh, Michael, Ozel, Tuncay, Liu, Chong, Lau, Eric C., and Nocera, Daniel G. Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid. United States: N. p., 2017. Web. doi:10.1039/C7SC01239J.
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Huynh, Michael, Ozel, Tuncay, Liu, Chong, Lau, Eric C., & Nocera, Daniel G. Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid. United States. https://doi.org/10.1039/C7SC01239J
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Huynh, Michael, Ozel, Tuncay, Liu, Chong, Lau, Eric C., and Nocera, Daniel G. Fri . "Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid". United States. https://doi.org/10.1039/C7SC01239J. https://www.osti.gov/servlets/purl/1599222.
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@article{osti_1599222,
title = {Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid},
author = {Huynh, Michael and Ozel, Tuncay and Liu, Chong and Lau, Eric C. and Nocera, Daniel G.},
abstractNote = {Oxygen evolution reaction (OER) catalysts that are earth-abundant and are active and stable in acid are unknown. Active catalysts derived from Co and Ni oxides dissolve at low pH, whereas acid stable systems such as Mn oxides (MnOx) display poor OER activity. We now demonstrate a rational approach for the design of earth-abundant catalysts that are stable and active in acid by treating activity and stability as decoupled elements of mixed metal oxides. Manganese serves as a stabilizing structural element for catalytically active Co centers in CoMnOx films. In acidic solutions (pH 2.5), CoMnOx exhibits the OER activity of electrodeposited Co oxide (CoOx) with a Tafel slope of 70–80 mV per decade while also retaining the long-term acid stability of MnOx films for OER at 0.1 mA cm-2. Driving OER at greater current densities in this system is not viable because at high anodic potentials, Mn oxides convert to and dissolve as permanganate. However, by exploiting the decoupled design of the catalyst, the stabilizing structural element may be optimized independently of the Co active sites. By screening potential–pH diagrams, we replaced Mn with Pb to prepare CoFePbOx films that maintained the high OER activity of CoOx at pH 2.5 while exhibiting long-term acid stability at higher current densities (at 1 mA cm-2 for over 50 h at pH 2.0). Under these acidic conditions, CoFePbOx exhibits OER activity that approaches noble metal oxides, thus establishing the viability of decoupling functionality in mixed metal catalysts for designing active, acid-stable, and earth-abundant OER catalysts.},
doi = {10.1039/C7SC01239J},
journal = {Chemical Science},
number = 7,
volume = 8,
place = {United States},
year = {Fri May 05 00:00:00 EDT 2017},
month = {Fri May 05 00:00:00 EDT 2017}
}
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Works referenced in this record:

On the future of global energy
journal, October 2006

Keeping the Energy Debate Clean: How Do We Supply the World's Energy Needs?
journal, January 2010

“Fast food” energy
journal, January 2010

  • Nocera, Daniel G.
  • Energy & Environmental Science, Vol. 3, Issue 8
  • DOI: 10.1039/c003891c

Opportunities and challenges for a sustainable energy future
journal, August 2012

  • Chu, Steven; Majumdar, Arun
  • Nature, Vol. 488, Issue 7411, p. 294-303
  • DOI: 10.1038/nature11475

Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

  • Lewis, N. S.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
  • DOI: 10.1073/pnas.0603395103

Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
journal, November 2010

  • Cook, Timothy R.; Dogutan, Dilek K.; Reece, Steven Y.
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr100246c

Solar Fuels and Solar Chemicals Industry
journal, March 2017

Catalysis Research of Relevance to Carbon Management:  Progress, Challenges, and Opportunities
journal, April 2001

  • Arakawa, Hironori; Aresta, Michele; Armor, John N.
  • Chemical Reviews, Vol. 101, Issue 4
  • DOI: 10.1021/cr000018s

Water splitting–biosynthetic system with CO 2 reduction efficiencies exceeding photosynthesis
journal, June 2016

Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II
journal, March 2008

  • Liu, Feng; Concepcion, Javier J.; Jurss, Jonah W.
  • Inorganic Chemistry, Vol. 47, Issue 6
  • DOI: 10.1021/ic701249s

The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
journal, June 2010

In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+
journal, August 2008

Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH
journal, November 2010

  • Surendranath, Yogesh; Kanan, Matthew W.; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 132, Issue 46
  • DOI: 10.1021/ja106102b

Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0–14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity
journal, August 2011

  • Gerken, James B.; McAlpin, J. Gregory; Chen, Jamie Y. C.
  • Journal of the American Chemical Society, Vol. 133, Issue 36
  • DOI: 10.1021/ja205647m

Water Oxidation by Amorphous Cobalt-Based Oxides: Volume Activity and Proton Transfer to Electrolyte Bases
journal, January 2014

  • Klingan, Katharina; Ringleb, Franziska; Zaharieva, Ivelina
  • ChemSusChem, Vol. 7, Issue 5
  • DOI: 10.1002/cssc.201301019

The Catalysis of the Oxygen Evolution Reaction by Iron Impurities in Thin Film Nickel Oxide Electrodes
journal, January 1987

  • Corrigan, Dennis A.
  • Journal of The Electrochemical Society, Vol. 134, Issue 2
  • DOI: 10.1149/1.2100463

Nickel-borate oxygen-evolving catalyst that functions under benign conditions
journal, May 2010

  • Dinca, M.; Surendranath, Y.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 23
  • DOI: 10.1073/pnas.1001859107

Mechanistic Studies of the Oxygen Evolution Reaction Mediated by a Nickel–Borate Thin Film Electrocatalyst
journal, February 2013

  • Bediako, D. Kwabena; Surendranath, Yogesh; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 135, Issue 9
  • DOI: 10.1021/ja3126432

Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation
journal, April 2014

  • Trotochaud, Lena; Young, Samantha L.; Ranney, James K.
  • Journal of the American Chemical Society, Vol. 136, Issue 18
  • DOI: 10.1021/ja502379c

Electrochemical Synthesis of Photoelectrodes and Catalysts for Use in Solar Water Splitting
journal, August 2015

First row transition metal catalysts for solar-driven water oxidation produced by electrodeposition
journal, January 2016

  • Roger, Isolda; Symes, Mark D.
  • Journal of Materials Chemistry A, Vol. 4, Issue 18
  • DOI: 10.1039/C5TA09423B

A Functionally Stable Manganese Oxide Oxygen Evolution Catalyst in Acid
journal, April 2014

  • Huynh, Michael; Bediako, D. Kwabena; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 136, Issue 16
  • DOI: 10.1021/ja413147e

Nucleation and Growth Mechanisms of an Electrodeposited Manganese Oxide Oxygen Evolution Catalyst
journal, April 2014

  • Huynh, Michael; Bediako, D. Kwabena; Liu, Yi
  • The Journal of Physical Chemistry C, Vol. 118, Issue 30
  • DOI: 10.1021/jp501768n

Nature of Activated Manganese Oxide for Oxygen Evolution
journal, November 2015

  • Huynh, Michael; Shi, Chenyang; Billinge, Simon J. L.
  • Journal of the American Chemical Society, Vol. 137, Issue 47
  • DOI: 10.1021/jacs.5b06382

Low pH Electrolytic Water Splitting Using Earth-Abundant Metastable Catalysts That Self-Assemble in Situ
journal, February 2014

  • Bloor, Leanne G.; Molina, Pedro I.; Symes, Mark D.
  • Journal of the American Chemical Society, Vol. 136, Issue 8
  • DOI: 10.1021/ja5003197

Toward an Active and Stable Catalyst for Oxygen Evolution in Acidic Media: Ti-Stabilized MnO 2
journal, August 2015

  • Frydendal, Rasmus; Paoli, Elisa A.; Chorkendorff, Ib
  • Advanced Energy Materials, Vol. 5, Issue 22
  • DOI: 10.1002/aenm.201500991

Parallel Electrochemical Treatment System and Application for Identifying Acid-Stable Oxygen Evolution Electrocatalysts
journal, January 2015

  • Jones, Ryan J. R.; Shinde, Aniketa; Guevarra, Dan
  • ACS Combinatorial Science, Vol. 17, Issue 2
  • DOI: 10.1021/co500148p

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013

  • McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja407115p

Will Solar-Driven Water-Splitting Devices See the Light of Day?
journal, September 2013

  • McKone, James R.; Lewis, Nathan S.; Gray, Harry B.
  • Chemistry of Materials, Vol. 26, Issue 1
  • DOI: 10.1021/cm4021518

A comprehensive review on PEM water electrolysis
journal, April 2013

  • Carmo, Marcelo; Fritz, David L.; Mergel, Jürgen
  • International Journal of Hydrogen Energy, Vol. 38, Issue 12, p. 4901-4934
  • DOI: 10.1016/j.ijhydene.2013.01.151

Solar Water Splitting Cells
journal, November 2010

  • Walter, Michael G.; Warren, Emily L.; McKone, James R.
  • Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
  • DOI: 10.1021/cr1002326

Proton Activity in Nafion Films:  Probing Exchangeable Protons with Methylene Blue
journal, May 2007

  • Seger, Brian; Vinodgopal, K.; Kamat, Prashant V.
  • Langmuir, Vol. 23, Issue 10
  • DOI: 10.1021/la0636816

Interfaces between water splitting catalysts and buried silicon junctions
journal, January 2013

  • Cox, Casandra R.; Winkler, Mark T.; Pijpers, Joep J. H.
  • Energy Environ. Sci., Vol. 6, Issue 2
  • DOI: 10.1039/C2EE23932A

Stabilized CdSe-CoPi Composite Photoanode for Light-Assisted Water Oxidation by Transformation of a CdSe/Cobalt Metal Thin Film
journal, March 2013

  • Costi, Ronny; Young, Elizabeth R.; Bulović, Vladimir
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 7
  • DOI: 10.1021/am400364u

High-Performance Silicon Photoanodes Passivated with Ultrathin Nickel Films for Water Oxidation
journal, November 2013

Protection of inorganic semiconductors for sustained, efficient photoelectrochemical water oxidation
journal, March 2016

Chemistry of Personalized Solar Energy
journal, November 2009

Photocatalytic hydrogen production
journal, January 2011

  • Teets, Thomas S.; Nocera, Daniel G.
  • Chemical Communications, Vol. 47, Issue 33
  • DOI: 10.1039/c1cc12390d

Halide-Bridged Binuclear HX-Splitting Catalysts
journal, August 2014

  • Powers, David C.; Hwang, Seung Jun; Zheng, Shao-Liang
  • Inorganic Chemistry, Vol. 53, Issue 17
  • DOI: 10.1021/ic501136m

Electroreduction of Dioxygen for Fuel-Cell Applications: Materials and Challenges
journal, April 2010

  • Gewirth, Andrew A.; Thorum, Matthew S.
  • Inorganic Chemistry, Vol. 49, Issue 8
  • DOI: 10.1021/ic9022486

Nucleation, Growth, and Repair of a Cobalt-Based Oxygen Evolving Catalyst
journal, March 2012

  • Surendranath, Yogesh; Lutterman, Daniel A.; Liu, Yi
  • Journal of the American Chemical Society, Vol. 134, Issue 14
  • DOI: 10.1021/ja3000084

Electrodeposited lead dioxide coatings
journal, January 2011

  • Li, Xiaohong; Pletcher, Derek; Walsh, Frank C.
  • Chemical Society Reviews, Vol. 40, Issue 7
  • DOI: 10.1039/c0cs00213e

Photoactivity of Transparent Nanocrystalline Fe 2 O 3 Electrodes Prepared via Anodic Electrodeposition
journal, August 2009

  • Spray, Ryan L.; Choi, Kyoung-Shin
  • Chemistry of Materials, Vol. 21, Issue 15
  • DOI: 10.1021/cm803099k

Anodic electrodeposition of iridium oxide films
journal, March 1998

Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution
journal, October 2012

  • Trotochaud, Lena; Ranney, James K.; Williams, Kerisha N.
  • Journal of the American Chemical Society, Vol. 134, Issue 41
  • DOI: 10.1021/ja307507a

Anodic Deposition of Colloidal Iridium Oxide Thin Films from Hexahydroxyiridate(IV) Solutions
journal, June 2011

  • Zhao, Yixin; Vargas-Barbosa, Nella M.; Hernandez-Pagan, Emil A.
  • Small, Vol. 7, Issue 14
  • DOI: 10.1002/smll.201100485

Cobalt–Iron (Oxy)hydroxide Oxygen Evolution Electrocatalysts: The Role of Structure and Composition on Activity, Stability, and Mechanism
journal, March 2015

  • Burke, Michaela S.; Kast, Matthew G.; Trotochaud, Lena
  • Journal of the American Chemical Society, Vol. 137, Issue 10
  • DOI: 10.1021/jacs.5b00281

Effects of Fe Electrolyte Impurities on Ni(OH) 2 /NiOOH Structure and Oxygen Evolution Activity
journal, March 2015

  • Klaus, Shannon; Cai, Yun; Louie, Mary W.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 13
  • DOI: 10.1021/acs.jpcc.5b00105

Electrocatalytic effect of metal ions on lead and lead dioxide electrode reactions
journal, September 1991

  • Sánchez, H.; Meas, Y.
  • Reaction Kinetics & Catalysis Letters, Vol. 45, Issue 1
  • DOI: 10.1007/BF02078610

Nature of the use of adventitious carbon as a binding energy standard
journal, May 1995

  • Barr, Tery L.; Seal, Sudipta
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 13, Issue 3
  • DOI: 10.1116/1.579868

Surface composition and structure of Co3O4(110) and the effect of impurity segregation
journal, July 2004

  • Petitto, S. C.; Langell, M. A.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 22, Issue 4
  • DOI: 10.1116/1.1763899

Investigation of the oxidation of polycrystalline lead by XPS and SIMS
journal, November 1978

On the relative dissolution rates of some oxide and orthosilicate minerals
journal, October 1991

Reactivity at the mineral-water interface: dissolution and inhibition
journal, February 1997

Electrochemical investigation of electrocatalysts for the oxygen evolution reaction in PEM water electrolyzers
journal, October 2008

Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials
journal, July 2012

  • Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter
  • ACS Catalysis, Vol. 2, Issue 8
  • DOI: 10.1021/cs3003098

Combinatorial Search for Improved Metal Oxide Oxygen Evolution Electrocatalysts in Acidic Electrolytes
journal, January 2013

  • Seley, David; Ayers, Katherine; Parkinson, B. A.
  • ACS Combinatorial Science, Vol. 15, Issue 2
  • DOI: 10.1021/co300086h

Efficient multi-metallic anode catalysts in a PEM water electrolyzer
journal, February 2014

Ir-Surface Enriched Porous Ir–Co Oxide Hierarchical Architecture for High Performance Water Oxidation in Acidic Media
journal, July 2014

  • Hu, Wei; Zhong, Huawei; Liang, Wei
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 15
  • DOI: 10.1021/am5027192

Influence of iron doping on tetravalent nickel content in catalytic oxygen evolving films
journal, January 2017

  • Li, Nancy; Bediako, D. Kwabena; Hadt, Ryan G.
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 7
  • DOI: 10.1073/pnas.1620787114

Combinatorial Discovery and Optimization of a Complex Oxide with Water Photoelectrolysis Activity
journal, April 2008

  • Woodhouse, Michael; Parkinson, B. A.
  • Chemistry of Materials, Vol. 20, Issue 7
  • DOI: 10.1021/cm703099j

Development of an O 2 -Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation
journal, May 2012

  • Gerken, James B.; Chen, Jamie Y. C.; Massé, Robert C.
  • Angewandte Chemie International Edition, Vol. 51, Issue 27
  • DOI: 10.1002/anie.201201999

Ordered Mesoporous Cobalt Oxide as Highly Efficient Oxygen Evolution Catalyst
journal, March 2013

  • Rosen, Jonathan; Hutchings, Gregory S.; Jiao, Feng
  • Journal of the American Chemical Society, Vol. 135, Issue 11
  • DOI: 10.1021/ja400555q

Catalytic Oxygen Evolution by Cobalt Oxido Thin Films
book, January 2015

  • Bediako, D. Kwabena; Ullman, Andrew M.; Nocera, Daniel G.
  • Topics in Current Chemistry
  • DOI: 10.1007/128_2015_649

A Self-Healing Oxygen-Evolving Catalyst
journal, March 2009

  • Lutterman, Daniel A.; Surendranath, Yogesh; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 131, Issue 11
  • DOI: 10.1021/ja900023k

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices
journal, March 2015

  • McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M.
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/ja510442p

High-Throughput Screening for Acid-Stable Oxygen Evolution Electrocatalysts in the (Mn–Co–Ta–Sb)O x Composition Space
journal, November 2014

Real surface area measurements in electrochemistry
journal, June 1992

Electrosynthesis, functional, and structural characterization of a water-oxidizing manganese oxide
journal, January 2012

  • Zaharieva, Ivelina; Chernev, Petko; Risch, Marcel
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21191b

Photochemical Water Oxidation by Crystalline Polymorphs of Manganese Oxides: Structural Requirements for Catalysis
journal, February 2013

  • Robinson, David M.; Go, Yong Bok; Mui, Michelle
  • Journal of the American Chemical Society, Vol. 135, Issue 9
  • DOI: 10.1021/ja310286h

In Situ X-ray Absorption Spectroscopy Investigation of a Bifunctional Manganese Oxide Catalyst with High Activity for Electrochemical Water Oxidation and Oxygen Reduction
journal, June 2013

  • Gorlin, Yelena; Lassalle-Kaiser, Benedikt; Benck, Jesse D.
  • Journal of the American Chemical Society, Vol. 135, Issue 23
  • DOI: 10.1021/ja3104632

Electrolyte-Dependent Electrosynthesis and Activity of Cobalt-Based Water Oxidation Catalysts
journal, February 2009

  • Surendranath, Yogesh; Dincǎ, Mircea; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 131, Issue 7
  • DOI: 10.1021/ja807769r

The electrochemical characteristics of binary manganese–cobalt oxides prepared by anodic deposition
journal, July 2005

Sol–gel preparation of cobalt manganese mixed oxides for their use as electrode materials in lithium cells
journal, November 2007

Ultrathin Cobalt–Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst
journal, November 2014

  • Song, Fang; Hu, Xile
  • Journal of the American Chemical Society, Vol. 136, Issue 47
  • DOI: 10.1021/ja5096733

High Surface Area Metal Carbide and Metal Nitride Electrodes
journal, January 1997

A review of gas diffusion layer in PEM fuel cells: Materials and designs
journal, April 2012

High Surface Area Transparent Conducting Oxide Electrodes with a Customizable Device Architecture
journal, December 2013

  • Forman, Arnold J.; Chen, Zhebo; Chakthranont, Pongkarn
  • Chemistry of Materials, Vol. 26, Issue 2
  • DOI: 10.1021/cm402551m

Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013

  • Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
  • APL Materials, Vol. 1, Issue 1
  • DOI: 10.1063/1.4812323

Why is lead dioxide metallic?
journal, August 2005

Nature of the Band Gap and Origin of the Conductivity of PbO 2 Revealed by Theory and Experiment
journal, December 2011

The behaviour of the lead dioxide electrode. Part 3.—Overvoltage during oxygen evolution in H 2 SO 4
journal, January 1954

  • Jones, P.; Lind, R.; Wynne-Jones, W. F. K.
  • Trans. Faraday Soc., Vol. 50, Issue 0
  • DOI: 10.1039/TF9545000972

Electrodeposition of Co-doped lead dioxide and its physicochemical properties
journal, May 2002

  • Velichenko, A. B.; Amadelli, R.; Baranova, E. A.
  • Journal of Electroanalytical Chemistry, Vol. 527, Issue 1-2
  • DOI: 10.1016/S0022-0728(02)00828-8

The influence of alloying elements on the electrochemistry of lead anodes for electrowinning of metals: A review
journal, January 2013

Lead dioxide electrode
journal, December 1972

The electronic conductivity of compact lead dioxide samples with various stoichiometric compositions
journal, December 1981

Synthesis and Characterization of Co3O4 Thin Film
journal, January 2012

  • Patil, Vikas; Joshi, Pradeep; Chougule, Manik
  • Soft Nanoscience Letters, Vol. 02, Issue 01
  • DOI: 10.4236/snl.2012.21001

Electrical Resistivity Measurements on Manganese Oxides with Layer and Tunnel Structures: Birnessites, Todorokites, and Cryptomelanes
journal, July 1995

  • De Guzman, Roberto N.; Awaluddin, Amir; Shen, Yan-Fei
  • Chemistry of Materials, Vol. 7, Issue 7
  • DOI: 10.1021/cm00055a003

Electrical conductivity as a defect property of γ-FeOOH
journal, January 1976

  • Kaneko, Katsumi; Inouye, Katsuya
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 72, Issue 0
  • DOI: 10.1039/f19767201258

A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites
journal, October 2007

  • Betley, Theodore A.; Surendranath, Yogesh; Childress, Montana V.
  • Philosophical Transactions of the Royal Society B: Biological Sciences, Vol. 363, Issue 1494
  • DOI: 10.1098/rstb.2007.2226

An Introduction to Surface Analysis by XPS and AES
book, March 2003

Photocatalytic Hydrogen Production
journal, November 2010

Real surface area measurements in electrochemistry
journal, January 1991

An Introduction to Surface Analysis by XPS and AES
journal, January 2019

Development of an O 2 -Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation
journal, May 2012

  • Gerken, James B.; Chen, Jamie Y. C.; Massé, Robert C.
  • Angewandte Chemie, Vol. 124, Issue 27
  • DOI: 10.1002/ange.201201999
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    • DOI: 10.1002/aenm.201801912

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    • DOI: 10.1002/anie.201813361

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    • DOI: 10.1002/chem.201704512

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    Intrinsically stable in situ generated electrocatalyst for long-term oxidation of acidic water at up to 80 °C
    journal, May 2019

    Nickel oxide–polypyrrole nanocomposite electrode materials for electrocatalytic water oxidation
    journal, January 2018

    • Morales, Daniela V.; Astudillo, Catalina N.; Lattach, Youssef
    • Catalysis Science & Technology, Vol. 8, Issue 16
    • DOI: 10.1039/c7cy01949a

    Trends in activity for the oxygen evolution reaction on transition metal (M = Fe, Co, Ni) phosphide pre-catalysts
    journal, January 2018

    • Xu, Junyuan; Li, Junjie; Xiong, Dehua
    • Chemical Science, Vol. 9, Issue 14
    • DOI: 10.1039/c7sc05033j

    Quasi-single-crystalline CoO hexagrams with abundant defects for highly efficient electrocatalytic water oxidation
    journal, January 2018

    • Liang, Zuozhong; Huang, Zhehao; Yuan, Haitao
    • Chemical Science, Vol. 9, Issue 34
    • DOI: 10.1039/c8sc02294a

    Cobalt-doped hematite thin films for electrocatalytic water oxidation in highly acidic media
    journal, January 2019

    • Kwong, Wai Ling; Lee, Cheng Choo; Shchukarev, Andrey
    • Chemical Communications, Vol. 55, Issue 34
    • DOI: 10.1039/c9cc01369e

    Photoelectrochemical cell for P–H/C–H cross-coupling with hydrogen evolution
    journal, January 2019

    • Wang, Jing-Hao; Li, Xu-Bing; Li, Jian
    • Chemical Communications, Vol. 55, Issue 70
    • DOI: 10.1039/c9cc05375a

    Fabricating Cu, Cu 2 O and hybrid Cu-Cu 2 O nanoparticles in carbon matrix and exploring catalytic activity of oxygen and hydrogen evolution and green A 3 -coupling reaction
    journal, November 2018

    • Muthukumar, Pandi; Kumar, P. Suresh; Anthony, Savarimuthu Philip
    • Materials Research Express, Vol. 6, Issue 2
    • DOI: 10.1088/2053-1591/aaf204

    Electrochemical characterization of manganese oxides as a water oxidation catalyst in proton exchange membrane electrolysers
    journal, May 2019

    • Hayashi, Toru; Bonnet-Mercier, Nadège; Yamaguchi, Akira
    • Royal Society Open Science, Vol. 6, Issue 5
    • DOI: 10.1098/rsos.190122

    Design of Multi‐Metallic‐Based Electrocatalysts for Enhanced Water Oxidation
    journal, May 2019

    Efficient oxygen evolution electrocatalysis in acid by a perovskite with face-sharing IrO6 octahedral dimers
    journal, December 2018

    Stable Potential Windows for Long‐Term Electrocatalysis by Manganese Oxides Under Acidic Conditions
    journal, March 2019

    • Li, Ailong; Ooka, Hideshi; Bonnet, Nadège
    • Angewandte Chemie, Vol. 131, Issue 15
    • DOI: 10.1002/ange.201813361

    Noble-Metal-Free Electrocatalysts for Oxygen Evolution
    journal, November 2018

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