Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media

Volia, M. F.; Tereshatov, E. E.; Boltoeva, M.; Folden, C. M.

doi:10.1039/C9NJ04879K

Title: Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media

Journal Article · 20 January 2020 · New Journal of Chemistry

DOI: https://doi.org/10.1039/C9NJ04879K · OSTI ID:1597480

^[1];

^[2];

^[3];

^[2]

Texas A & M Univ., College Station, TX (United States). Cyclotron Inst.; Texas A&M University
Texas A & M Univ., College Station, TX (United States). Cyclotron Inst.
Université de Strasbourg (France)

The partitioning behavior of indium and thallium ions between aqueous hydrochloric acid solutions and hydrophobic betainium bis(trifluoromethylsulfonyl)imide ionic liquid was studied using a standard liquid–liquid extraction technique. The experiments were mainly carried out by means of a radiochemical method, using ¹¹¹In and ²⁰¹Tl medical radionuclides at an ultra-trace concentration. Both mono- and trivalent thallium were utilized and the highest oxidation state (3+) was produced by adding either chlorine or bromine water to the aqueous phase prior to extraction. The metal ion transfer was optimized by varying the aqueous concentration of hydrochloric acid and by introducing zwitterionic betaine as an extracting agent into the aqueous phase. It was found that the highest D values of In(III), Tl(III) and Tl(I) in the investigated chemical systems were up to 200, 70, and 1, respectively. The influence of the addition of lithium salt, having common with the ionic liquid counterion, and the variation of mixing time on the distribution ratio of the metal ions were also studied. Finally, to understand the underlying extraction mechanism of the metal ions and to propose the predominant extracted species, mathematical models based on ion pair formation and ion exchange were developed.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Nuclear Physics (NP) (SC-26); USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: FG02-93ER40773; NA0003180

OSTI ID:: 1597480

Journal Information:: New Journal of Chemistry, Journal Name: New Journal of Chemistry Journal Issue: 6 Vol. 44; ISSN NJCHE5; ISSN 1144-0546

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (61)

Ionic Liquids—New “Solutions” for Transition Metal Catalysis Wasserscheid, Peter; Keim, Wilhelm Angewandte Chemie, Vol. 39, Issue 21 https://doi.org/10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO;2-5	journal	November 2000
Ionic Liquids: Solvent Properties and Organic Reactivity Chiappe, Cinzia; Pieraccini, Daniela ChemInform, Vol. 36, Issue 33 https://doi.org/10.1002/chin.200533313	journal	August 2005
Ionic liquids: solvents and sorbents in sample preparation Clark, Kevin D.; Emaus, Miranda N.; Varona, Marcelino Journal of Separation Science, Vol. 41, Issue 1 https://doi.org/10.1002/jssc.201700864	journal	October 2017
Ionic liquids: solvent properties and organic reactivity Chiappe, Cinzia; Pieraccini, Daniela Journal of Physical Organic Chemistry, Vol. 18, Issue 4 https://doi.org/10.1002/poc.863	journal	January 2005
Metal Complexes in Aqueous Solutions Martell, Arthur E.; Hancock, Robert D. Modern Inorganic Chemistry (MICE) https://doi.org/10.1007/978-1-4899-1486-6	book	January 1996
Thallous chloride complexes in 0 to 6 molal sodium chloride at 25°C Read, A. J.; Aldridge, L. P. Journal of Solution Chemistry, Vol. 21, Issue 12 https://doi.org/10.1007/BF00667219	journal	December 1992
Liquid–liquid extraction of actinides, lanthanides, and fission products by use of ionic liquids: from discovery to understanding Billard, Isabelle; Ouadi, Ali; Gaillard, Clotilde Analytical and Bioanalytical Chemistry, Vol. 400, Issue 6 https://doi.org/10.1007/s00216-010-4478-x	journal	January 2011
Preparation of 111In using irradiated natural cadmium target for medical applications with a simple ion exchange method Yavari, Ramin; Khanchi, Ali Reza Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 1 https://doi.org/10.1007/s10967-015-4280-5	journal	July 2015
Extraction of thallium and indium isotopes as the homologues of nihonium into the ionic liquids Cubova, Katerina; Semelova, Miroslava; Nemec, Mojmir Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 3 https://doi.org/10.1007/s10967-018-6270-x	journal	October 2018
Hydrometallurgical Recovery of Indium from Flat-Panel Displays of Spent Liquid Crystal Televisions Inoue, Katsutoshi; Alam, Shafiq JOM, Vol. 67, Issue 2 https://doi.org/10.1007/s11837-014-1287-2	journal	January 2015
U.V.-absorptionsspektren von Tl(III)-halogenidkomplexen in Wässeriger Lösung Schmidt, K. Journal of Inorganic and Nuclear Chemistry, Vol. 32, Issue 11 https://doi.org/10.1016/0022-1902(70)80164-6	journal	November 1970
Liquid-liquid extraction of indium (III) from aqueous acid solutions by acid organophosphorus compounds Sato, Taichi; Sato, Keiichi Hydrometallurgy, Vol. 30, Issue 1-3 https://doi.org/10.1016/0304-386X(92)90094-G	journal	June 1992
The coordination chemistry of thallium(I) Lee, A. G. Coordination Chemistry Reviews, Vol. 8, Issue 4 https://doi.org/10.1016/S0010-8545(00)80001-6	journal	November 1972
New developments in catalysis using ionic liquids Gordon, Charles M. Applied Catalysis A: General, Vol. 222, Issue 1-2 https://doi.org/10.1016/S0926-860X(01)00834-1	journal	December 2001
SILCA—Supported ionic liquid catalysts for fine chemicals Mikkola, Jyri-Pekka T.; Virtanen, Pasi P.; Kordás, Krisztian Applied Catalysis A: General, Vol. 328, Issue 1 https://doi.org/10.1016/j.apcata.2007.05.030	journal	August 2007
Thallium in the environment: A critical review focused on natural waters, soils, sediments and airborne particles Belzile, Nelson; Chen, Yu-Wei Applied Geochemistry, Vol. 84 https://doi.org/10.1016/j.apgeochem.2017.06.013	journal	September 2017
Ionic Liquid-Modified Electrocatalysts: The Interaction of [C 1 C 2 Im][OTf] with Pt(1 1 1) and its Influence on Methanol Oxidation Studied by Electrochemical IR Spectroscopy Brummel, Olaf; Faisal, Firas; Bauer, Tanja Electrochimica Acta, Vol. 188 https://doi.org/10.1016/j.electacta.2015.12.006	journal	January 2016
Fractionation and mobility of thallium in areas impacted by mining-metallurgical activities: Identification of a water-soluble Tl(I) fraction Cruz-Hernández, Yusniel; Ruiz-García, Mismel; Villalobos, Mario Environmental Pollution, Vol. 237 https://doi.org/10.1016/j.envpol.2018.02.031	journal	June 2018
Effect of aqueous hydrochloric acid and zwitterionic betaine on the mutual solubility between a protic betainium-based ionic liquid and water Volia, Merinda F.; Tereshatov, Evgeny E.; Mazan, Valérie Journal of Molecular Liquids, Vol. 276 https://doi.org/10.1016/j.molliq.2018.11.136	journal	February 2019
A review on the efficacy of the application of myriad carbonaceous materials for the removal of toxic trace elements in the environment Dimpe, K. Mogolodi; Nomngongo, Philiswa N. Trends in Environmental Analytical Chemistry, Vol. 16 https://doi.org/10.1016/j.teac.2017.10.001	journal	October 2017
Ionic-Liquid-Mediated Extraction and Separation Processes for Bioactive Compounds: Past, Present, and Future Trends Ventura, Sónia P. M.; e. Silva, Francisca A.; Quental, Maria V. Chemical Reviews, Vol. 117, Issue 10 https://doi.org/10.1021/acs.chemrev.6b00550	journal	February 2017
Multiscale Studies on Ionic Liquids Dong, Kun; Liu, Xiaomin; Dong, Haifeng Chemical Reviews, Vol. 117, Issue 10 https://doi.org/10.1021/acs.chemrev.6b00776	journal	February 2017
Green and Sustainable Solvents in Chemical Processes Clarke, Coby J.; Tu, Wei-Chien; Levers, Oliver Chemical Reviews, Vol. 118, Issue 2 https://doi.org/10.1021/acs.chemrev.7b00571	journal	January 2018
Highly Efficient and Selective Dissolution Separation of Fission Products by an Ionic Liquid [Hbet][Tf 2 N]: A New Approach to Spent Nuclear Fuel Recycling Fan, Fang-Li; Qin, Zhi; Cao, Shi-Wei Inorganic Chemistry, Vol. 58, Issue 1 https://doi.org/10.1021/acs.inorgchem.8b02783	journal	December 2018
Overview of the Effect of Salts on Biphasic Ionic Liquid/Water Solvent Extraction Systems: Anion Exchange, Mutual Solubility, and Thermomorphic Properties Dupont, David; Depuydt, Daphne; Binnemans, Koen The Journal of Physical Chemistry B, Vol. 119, Issue 22 https://doi.org/10.1021/acs.jpcb.5b02980	journal	April 2015
Thallium Transfer from Hydrochloric Acid Media into Pure Ionic Liquids Tereshatov, Evgeny E.; Boltoeva, Maria Yu.; Mazan, Valerie The Journal of Physical Chemistry B, Vol. 120, Issue 9 https://doi.org/10.1021/acs.jpcb.5b08924	journal	February 2016
Pd Nanoparticle Formation in Ionic Liquid Thin Films Monitored by in situ Vibrational Spectroscopy Mehl, Sascha; Toghan, Arafat; Bauer, Tanja Langmuir, Vol. 31, Issue 44 https://doi.org/10.1021/acs.langmuir.5b03386	journal	October 2015
Microwave-Assisted Solvent Extraction of Inert Platinum Group Metals from HNO 3 (aq) to Betainium-Based Thermomorphic Ionic Liquid Ikeda, Saki; Mori, Takahiro; Ikeda, Yasuhisa ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 5 https://doi.org/10.1021/acssuschemeng.6b00186	journal	March 2016
Significant Acceleration of PGMs Extraction with UCST-Type Thermomorphic Ionic Liquid at Elevated Temperature Kono, Soma; Kazama, Hiroyuki; Mori, Takahiro ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 2 https://doi.org/10.1021/acssuschemeng.7b04447	journal	December 2017
From Molten Salts to Ionic Liquids: A “Nano” Journey Dupont, Jairton Accounts of Chemical Research, Vol. 44, Issue 11 https://doi.org/10.1021/ar2000937	journal	November 2011
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis Welton, Thomas Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084 https://doi.org/10.1021/cr980032t	journal	August 1999
A Raman Study of Thallium(III) Chloride Complexes in Aqueous Solution Spiro, Thomas G. Inorganic Chemistry, Vol. 4, Issue 5 https://doi.org/10.1021/ic50027a029	journal	May 1965
Ionic Liquid Based Separations of Trivalent Lanthanide and Actinide Ions. Shkrob, Ilya A.; Marin, Timothy W.; Jensen, Mark P. Industrial & Engineering Chemistry Research, Vol. 53, Issue 9 https://doi.org/10.1021/ie4036719	journal	February 2014
Recovery of Scandium(III) from Aqueous Solutions by Solvent Extraction with the Functionalized Ionic Liquid Betainium Bis(trifluoromethylsulfonyl)imide Onghena, Bieke; Binnemans, Koen Industrial & Engineering Chemistry Research, Vol. 54, Issue 6 https://doi.org/10.1021/ie504765v	journal	February 2015
Structure of Thallium(III) Chloride, Bromide, and Cyanide Complexes in Aqueous Solution Blixt, Johan; Glaser, Julius; Mink, Janos Journal of the American Chemical Society, Vol. 117, Issue 18 https://doi.org/10.1021/ja00123a011	journal	May 1995
Equilibrium dynamics in the thallium(III)-chloride system in acidic aqueous solution Banyai, Istvan; Glaser, Julius Journal of the American Chemical Society, Vol. 111, Issue 9 https://doi.org/10.1021/ja00191a013	journal	April 1989
Amineborane-Based Chemical Hydrogen Storage: Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids Bluhm, Martin E.; Bradley, Mark G.; Butterick, Robert Journal of the American Chemical Society, Vol. 128, Issue 24 https://doi.org/10.1021/ja062085v	journal	June 2006
Reactivities of Some Electrogenerated Organic Cation Radicals in Room-Temperature Ionic Liquids: Toward an Alternative to Volatile Organic Solvents? Lagrost, C.; Carrié,, D.; Vaultier, M. The Journal of Physical Chemistry A, Vol. 107, Issue 5 https://doi.org/10.1021/jp026907w	journal	February 2003
Task-Specific Ionic Liquid for Solubilizing Metal Oxides Nockemann, Peter; Thijs, Ben; Pittois, Stijn The Journal of Physical Chemistry B, Vol. 110, Issue 42 https://doi.org/10.1021/jp0642995	journal	October 2006
Determination of Single-Ion Activities of H + and Cl – in Aqueous Hydrochloric Acid Solutions by Use of an Ionic Liquid Salt Bridge Sakaida, Hideaki; Kakiuchi, Takashi The Journal of Physical Chemistry B, Vol. 115, Issue 45 https://doi.org/10.1021/jp2052079	journal	November 2011
Homogeneous Liquid–Liquid Extraction of Metal Ions with a Functionalized Ionic Liquid Vander Hoogerstraete, Tom; Onghena, Bieke; Binnemans, Koen The Journal of Physical Chemistry Letters, Vol. 4, Issue 10 https://doi.org/10.1021/jz4005366	journal	May 2013
Determination of Hydrogen Single Ion Activity Coefficients in Aqueous HCl Solutions at 25°C Schneider, Armin C.; Pasel, Christoph; Luckas, Michael Journal of Solution Chemistry, Vol. 33, Issue 3 https://doi.org/10.1023/B:JOSL.0000035359.00943.14	journal	March 2004
Structural properties of the inner coordination sphere of indium chloride complexes in organic and aqueous solutions Narita, Hirokazu; Tanaka, Mikiya; Shiwaku, Hideaki Dalton Trans., Vol. 43, Issue 4 https://doi.org/10.1039/C3DT52474D	journal	January 2014
Unusual redox stability of neptunium in the ionic liquid [Hbet][Tf ₂ N] Long, Kristy; Goff, George; Runde, Wolfgang Chem. Commun., Vol. 50, Issue 58 https://doi.org/10.1039/C4CC01835D	journal	January 2014
Extraction of Pd( ii ), Rh( iii ) and Ru( iii ) from HNO 3 aqueous solution to betainium bis(trifluoromethanesulfonyl)imide ionic liquid Sasaki, Kotoe; Takao, Koichiro; Suzuki, Tomoya Dalton Trans., Vol. 43, Issue 15 https://doi.org/10.1039/C4DT00091A	journal	January 2014
Actinide ion extraction using room temperature ionic liquids: opportunities and challenges for nuclear fuel cycle applications Mohapatra, Prasanta Kumar Dalton Transactions, Vol. 46, Issue 6 https://doi.org/10.1039/C6DT04898F	journal	January 2017
Speciation of indium( iii ) chloro complexes in the solvent extraction process from chloride aqueous solutions to ionic liquids Deferm, Clio; Onghena, Bieke; Vander Hoogerstraete, Tom Dalton Transactions, Vol. 46, Issue 13 https://doi.org/10.1039/C7DT00618G	journal	January 2017
Hydrophobic polymerized ionic liquids for trace metal solid phase extraction: thallium transfer from hydrochloric acid media Tereshatov, Evgeny E.; Boltoeva, Maria; Mazan, Valérie New Journal of Chemistry, Vol. 43, Issue 23 https://doi.org/10.1039/C9NJ00689C	journal	January 2019
Removal of transition metals from rare earths by solvent extraction with an undiluted phosphonium ionic liquid: separations relevant to rare-earth magnet recycling Vander Hoogerstraete, Tom; Wellens, Sil; Verachtert, Katrien Green Chemistry, Vol. 15, Issue 4 https://doi.org/10.1039/c3gc40198g	journal	January 2013
Production and Clinical Applications of Radiopharmaceuticals and Medical Radioisotopes in Iran Jalilian, Amir Reza; Beiki, Davood; Hassanzadeh-Rad, Arman Seminars in Nuclear Medicine, Vol. 46, Issue 4 https://doi.org/10.1053/j.semnuclmed.2016.01.006	journal	July 2016
Ionic Liquids as Extraction Solvents: Where do We Stand? Dietz, Mark L. Separation Science and Technology, Vol. 41, Issue 10 https://doi.org/10.1080/01496390600743144	journal	June 2006
Resin Ion Exchange and Liquid-Liquid Extraction of Indium and Thallium from Chloride Media Tereshatov, E. E.; Boltoeva, M. Yu.; Folden, C. M. Solvent Extraction and Ion Exchange, Vol. 33, Issue 6 https://doi.org/10.1080/07366299.2015.1080529	journal	July 2015
Recent advances in indium metallurgy: A review Pradhan, Debabrata; Panda, Sandeep; Sukla, Lala Behari Mineral Processing and Extractive Metallurgy Review, Vol. 39, Issue 3 https://doi.org/10.1080/08827508.2017.1399887	journal	November 2017
Extraction Behavior of U(VI) Using Novel Betainium-Type Ionic Liquids: More Hydrophobic Cations Enhance Extractability, Selectivity, and Recyclability Mori, Takahiro; Ikeda, Yasuhisa; Takao, Koichiro Bulletin of the Chemical Society of Japan, Vol. 89, Issue 11 https://doi.org/10.1246/bcsj.20160210	journal	November 2016
Selective Liquid–Liquid Extraction of Uranyl Species Using Task-specific Ionic Liquid, Betainium Bis(trifluoromethylsulfonyl)imide Sasaki, Kotoe; Suzuki, Tomoya; Mori, Takahiro Chemistry Letters, Vol. 43, Issue 6 https://doi.org/10.1246/cl.140048	journal	June 2014
Preparation and Applications of Room Temperature Ionic Liquids in Organic Synthesis: A Review on Recent Efforts Jindal, Rani; Sablok, Anju Current Green Chemistry, Vol. 2, Issue 2 https://doi.org/10.2174/2213346101666140915212515	journal	April 2015
Liquid-Liquid Extraction of Trivalent Gallium, Indium and Thallium from Hydrochloric Acid Solutions by Trioctyl Phosphine Oxide. Sato, Taichi Shigen-to-Sozai, Vol. 112, Issue 2 https://doi.org/10.2473/shigentosozai.112.123	journal	January 1996
Homogeneous Liquid–Liquid Extraction of Rare Earths with the Betaine—Betainium Bis(trifluoromethylsulfonyl)imide Ionic Liquid System Vander Hoogerstraete, Tom; Onghena, Bieke; Binnemans, Koen International Journal of Molecular Sciences, Vol. 14, Issue 11 https://doi.org/10.3390/ijms141121353	journal	October 2013
Europium, Yttrium, and Indium Recovery from Electronic Wastes de la Torre, Ernesto; Vargas, Estefanía; Ron, César Metals, Vol. 8, Issue 10 https://doi.org/10.3390/met8100777	journal	September 2018
Germanium and Indium Recovery from Zinc Metallurgy by-Products—Dross Leaching in Sulphuric and Oxalic Acids Drzazga, Michał; Prajsnar, Ryszard; Chmielarz, Andrzej Metals, Vol. 8, Issue 12 https://doi.org/10.3390/met8121041	journal	December 2018
The Stability of Metal Halide Complexes in Aqueous Solution. V. The Chloride and Bromide Complexes of Thallium(III). Ahrland, Sten; Grenthe, Ingmar; Johansson, Lars Acta Chemica Scandinavica, Vol. 17 https://doi.org/10.3891/acta.chem.scand.17-1567	journal	January 1963

Similar Records

Effect of aqueous hydrochloric acid and zwitterionic betaine on the mutual solubility between a protic betainium-based ionic liquid and water

Journal Article · 2018 · Journal of Molecular Liquids · OSTI ID:1496879

Volia, Merinda F.; Tereshatov, Evgeny E.; Mazan, Valérie; +2 more

Quantification of zwitterion betaine in betaine bis(trifluoromethylsulfonyl)imide and its influence on liquid–liquid equilibrium with water

Journal Article · 2023 · ChemComm · OSTI ID:2377311

Lee, Jaeseong; Fairley, Melissa; Goff, George S.; +1 more

Effect of hydrophobic ionic liquids aqueous solubility on metal extraction from hydrochloric acid media: Mathematical modelling and trivalent thallium behavior

Journal Article · 2020 · Separation and Purification Technology · OSTI ID:1668865

Tereshatov, Evgeny E.; Mazan, Valérie; Boltoeva, Maria; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Indium
betainium bis(trifluoromethylsulfonyl)imide
ionic liquid
liquid-liquid extraction
thallium
zwitterion

Title: Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media

Citation Formats

References (61)

Similar Records

Related Subjects