This content will become publicly available on January 21, 2021
Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media
Abstract
The partitioning behavior of indium and thallium ions between aqueous hydrochloric acid solutions and hydrophobic betainium bis(trifluoromethylsulfonyl)imide ionic liquid was studied using a standard liquid–liquid extraction technique. The experiments were mainly carried out by means of a radiochemical method, using 111In and 201Tl medical radionuclides at an ultra-trace concentration. Both mono- and trivalent thallium were utilized and the highest oxidation state (3+) was produced by adding either chlorine or bromine water to the aqueous phase prior to extraction. The metal ion transfer was optimized by varying the aqueous concentration of hydrochloric acid and by introducing zwitterionic betaine as an extracting agent into the aqueous phase. It was found that the highest D values of In(III), Tl(III) and Tl(I) in the investigated chemical systems were up to 200, 70, and 1, respectively. The influence of the addition of lithium salt, having common with the ionic liquid counterion, and the variation of mixing time on the distribution ratio of the metal ions were also studied. Finally, to understand the underlying extraction mechanism of the metal ions and to propose the predominant extracted species, mathematical models based on ion pair formation and ion exchange were developed.
- Authors:
-
[1];
[1];
[2];
[1]
- Texas A & M Univ., College Station, TX (United States). Cyclotron Inst.
- Université de Strasbourg (France)
- Publication Date:
- Research Org.:
- Texas A & M Univ., College Station, TX (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Nuclear Physics (NP) (SC-26); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1597480
- Alternate Identifier(s):
- OSTI ID: 1596156
- Grant/Contract Number:
- [FG02-93ER40773; NA0003180]
- Resource Type:
- Accepted Manuscript
- Journal Name:
- New Journal of Chemistry
- Additional Journal Information:
- [ Journal Volume: 44; Journal Issue: 6]; Journal ID: ISSN 1144-0546
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Indium; thallium; ionic liquid; betainium bis(trifluoromethylsulfonyl)imide; zwitterion; liquid-liquid extraction
Citation Formats
Volia, M. F., Tereshatov, E. E., Boltoeva, M., and Folden, C. M. Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media. United States: N. p., 2020.
Web. doi:10.1039/C9NJ04879K.
Volia, M. F., Tereshatov, E. E., Boltoeva, M., & Folden, C. M. Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media. United States. doi:10.1039/C9NJ04879K.
Volia, M. F., Tereshatov, E. E., Boltoeva, M., and Folden, C. M. Tue .
"Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media". United States. doi:10.1039/C9NJ04879K.
@article{osti_1597480,
title = {Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media},
author = {Volia, M. F. and Tereshatov, E. E. and Boltoeva, M. and Folden, C. M.},
abstractNote = {The partitioning behavior of indium and thallium ions between aqueous hydrochloric acid solutions and hydrophobic betainium bis(trifluoromethylsulfonyl)imide ionic liquid was studied using a standard liquid–liquid extraction technique. The experiments were mainly carried out by means of a radiochemical method, using 111In and 201Tl medical radionuclides at an ultra-trace concentration. Both mono- and trivalent thallium were utilized and the highest oxidation state (3+) was produced by adding either chlorine or bromine water to the aqueous phase prior to extraction. The metal ion transfer was optimized by varying the aqueous concentration of hydrochloric acid and by introducing zwitterionic betaine as an extracting agent into the aqueous phase. It was found that the highest D values of In(III), Tl(III) and Tl(I) in the investigated chemical systems were up to 200, 70, and 1, respectively. The influence of the addition of lithium salt, having common with the ionic liquid counterion, and the variation of mixing time on the distribution ratio of the metal ions were also studied. Finally, to understand the underlying extraction mechanism of the metal ions and to propose the predominant extracted species, mathematical models based on ion pair formation and ion exchange were developed.},
doi = {10.1039/C9NJ04879K},
journal = {New Journal of Chemistry},
number = [6],
volume = [44],
place = {United States},
year = {2020},
month = {1}
}
Free Publicly Available Full Text
This content will become publicly available on January 21, 2021
Publisher's Version of Record
DOI: 10.1039/C9NJ04879K
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Liquid–liquid extraction of actinides, lanthanides, and fission products by use of ionic liquids: from discovery to understanding
journal, January 2011
- Billard, Isabelle; Ouadi, Ali; Gaillard, Clotilde
- Analytical and Bioanalytical Chemistry, Vol. 400, Issue 6
From Molten Salts to Ionic Liquids: A “Nano” Journey
journal, November 2011
- Dupont, Jairton
- Accounts of Chemical Research, Vol. 44, Issue 11
Green and Sustainable Solvents in Chemical Processes
journal, January 2018
- Clarke, Coby J.; Tu, Wei-Chien; Levers, Oliver
- Chemical Reviews, Vol. 118, Issue 2
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
journal, August 1999
- Welton, Thomas
- Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084
Ionic liquids: solvent properties and organic reactivity
journal, January 2005
- Chiappe, Cinzia; Pieraccini, Daniela
- Journal of Physical Organic Chemistry, Vol. 18, Issue 4
Amineborane-Based Chemical Hydrogen Storage: Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids
journal, June 2006
- Bluhm, Martin E.; Bradley, Mark G.; Butterick, Robert
- Journal of the American Chemical Society, Vol. 128, Issue 24
Preparation and Applications of Room Temperature Ionic Liquids in Organic Synthesis: A Review on Recent Efforts
journal, April 2015
- Jindal, Rani; Sablok, Anju
- Current Green Chemistry, Vol. 2, Issue 2
New developments in catalysis using ionic liquids
journal, December 2001
- Gordon, Charles M.
- Applied Catalysis A: General, Vol. 222, Issue 1-2
Ionic Liquids—New “Solutions” for Transition Metal Catalysis
journal, November 2000
- Wasserscheid, Peter; Keim, Wilhelm
- Angewandte Chemie, Vol. 39, Issue 21
SILCA—Supported ionic liquid catalysts for fine chemicals
journal, August 2007
- Mikkola, Jyri-Pekka T.; Virtanen, Pasi P.; Kordás, Krisztian
- Applied Catalysis A: General, Vol. 328, Issue 1
Ionic Liquid-Modified Electrocatalysts: The Interaction of [C 1 C 2 Im][OTf] with Pt(1 1 1) and its Influence on Methanol Oxidation Studied by Electrochemical IR Spectroscopy
journal, January 2016
- Brummel, Olaf; Faisal, Firas; Bauer, Tanja
- Electrochimica Acta, Vol. 188
Reactivities of Some Electrogenerated Organic Cation Radicals in Room-Temperature Ionic Liquids: Toward an Alternative to Volatile Organic Solvents?
journal, February 2003
- Lagrost, C.; Carrié,, D.; Vaultier, M.
- The Journal of Physical Chemistry A, Vol. 107, Issue 5
Pd Nanoparticle Formation in Ionic Liquid Thin Films Monitored by in situ Vibrational Spectroscopy
journal, October 2015
- Mehl, Sascha; Toghan, Arafat; Bauer, Tanja
- Langmuir, Vol. 31, Issue 44
Ionic liquids: solvents and sorbents in sample preparation
journal, October 2017
- Clark, Kevin D.; Emaus, Miranda N.; Varona, Marcelino
- Journal of Separation Science, Vol. 41, Issue 1
Ionic-Liquid-Mediated Extraction and Separation Processes for Bioactive Compounds: Past, Present, and Future Trends
journal, February 2017
- Ventura, Sónia P. M.; e. Silva, Francisca A.; Quental, Maria V.
- Chemical Reviews, Vol. 117, Issue 10
Actinide ion extraction using room temperature ionic liquids: opportunities and challenges for nuclear fuel cycle applications
journal, January 2017
- Mohapatra, Prasanta Kumar
- Dalton Transactions, Vol. 46, Issue 6
Ionic Liquids as Extraction Solvents: Where do We Stand?
journal, June 2006
- Dietz, Mark L.
- Separation Science and Technology, Vol. 41, Issue 10
Multiscale Studies on Ionic Liquids
journal, February 2017
- Dong, Kun; Liu, Xiaomin; Dong, Haifeng
- Chemical Reviews, Vol. 117, Issue 10
Task-Specific Ionic Liquid for Solubilizing Metal Oxides
journal, October 2006
- Nockemann, Peter; Thijs, Ben; Pittois, Stijn
- The Journal of Physical Chemistry B, Vol. 110, Issue 42
Extraction Behavior of U(VI) Using Novel Betainium-Type Ionic Liquids: More Hydrophobic Cations Enhance Extractability, Selectivity, and Recyclability
journal, November 2016
- Mori, Takahiro; Ikeda, Yasuhisa; Takao, Koichiro
- Bulletin of the Chemical Society of Japan, Vol. 89, Issue 11
Recovery of Scandium(III) from Aqueous Solutions by Solvent Extraction with the Functionalized Ionic Liquid Betainium Bis(trifluoromethylsulfonyl)imide
journal, February 2015
- Onghena, Bieke; Binnemans, Koen
- Industrial & Engineering Chemistry Research, Vol. 54, Issue 6
Homogeneous Liquid–Liquid Extraction of Metal Ions with a Functionalized Ionic Liquid
journal, May 2013
- Vander Hoogerstraete, Tom; Onghena, Bieke; Binnemans, Koen
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 10
Ionic Liquid Based Separations of Trivalent Lanthanide and Actinide Ions.
journal, February 2014
- Shkrob, Ilya A.; Marin, Timothy W.; Jensen, Mark P.
- Industrial & Engineering Chemistry Research, Vol. 53, Issue 9
Microwave-Assisted Solvent Extraction of Inert Platinum Group Metals from HNO 3 (aq) to Betainium-Based Thermomorphic Ionic Liquid
journal, March 2016
- Ikeda, Saki; Mori, Takahiro; Ikeda, Yasuhisa
- ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 5
Extraction of Pd( ii ), Rh( iii ) and Ru( iii ) from HNO 3 aqueous solution to betainium bis(trifluoromethanesulfonyl)imide ionic liquid
journal, January 2014
- Sasaki, Kotoe; Takao, Koichiro; Suzuki, Tomoya
- Dalton Trans., Vol. 43, Issue 15
Significant Acceleration of PGMs Extraction with UCST-Type Thermomorphic Ionic Liquid at Elevated Temperature
journal, December 2017
- Kono, Soma; Kazama, Hiroyuki; Mori, Takahiro
- ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 2
Selective Liquid–Liquid Extraction of Uranyl Species Using Task-specific Ionic Liquid, Betainium Bis(trifluoromethylsulfonyl)imide
journal, June 2014
- Sasaki, Kotoe; Suzuki, Tomoya; Mori, Takahiro
- Chemistry Letters, Vol. 43, Issue 6
Unusual redox stability of neptunium in the ionic liquid [Hbet][Tf 2 N]
journal, January 2014
- Long, Kristy; Goff, George; Runde, Wolfgang
- Chem. Commun., Vol. 50, Issue 58
Highly Efficient and Selective Dissolution Separation of Fission Products by an Ionic Liquid [Hbet][Tf 2 N]: A New Approach to Spent Nuclear Fuel Recycling
journal, December 2018
- Fan, Fang-Li; Qin, Zhi; Cao, Shi-Wei
- Inorganic Chemistry, Vol. 58, Issue 1
Preparation of 111In using irradiated natural cadmium target for medical applications with a simple ion exchange method
journal, July 2015
- Yavari, Ramin; Khanchi, Ali Reza
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 1
Production and Clinical Applications of Radiopharmaceuticals and Medical Radioisotopes in Iran
journal, July 2016
- Jalilian, Amir Reza; Beiki, Davood; Hassanzadeh-Rad, Arman
- Seminars in Nuclear Medicine, Vol. 46, Issue 4
Germanium and Indium Recovery from Zinc Metallurgy by-Products—Dross Leaching in Sulphuric and Oxalic Acids
journal, December 2018
- Drzazga, Michał; Prajsnar, Ryszard; Chmielarz, Andrzej
- Metals, Vol. 8, Issue 12
Europium, Yttrium, and Indium Recovery from Electronic Wastes
journal, September 2018
- de la Torre, Ernesto; Vargas, Estefanía; Ron, César
- Metals, Vol. 8, Issue 10
Recent advances in indium metallurgy: A review
journal, November 2017
- Pradhan, Debabrata; Panda, Sandeep; Sukla, Lala Behari
- Mineral Processing and Extractive Metallurgy Review, Vol. 39, Issue 3
Fractionation and mobility of thallium in areas impacted by mining-metallurgical activities: Identification of a water-soluble Tl(I) fraction
journal, June 2018
- Cruz-Hernández, Yusniel; Ruiz-García, Mismel; Villalobos, Mario
- Environmental Pollution, Vol. 237
A review on the efficacy of the application of myriad carbonaceous materials for the removal of toxic trace elements in the environment
journal, October 2017
- Dimpe, K. Mogolodi; Nomngongo, Philiswa N.
- Trends in Environmental Analytical Chemistry, Vol. 16
Thallium in the environment: A critical review focused on natural waters, soils, sediments and airborne particles
journal, September 2017
- Belzile, Nelson; Chen, Yu-Wei
- Applied Geochemistry, Vol. 84
Extraction of thallium and indium isotopes as the homologues of nihonium into the ionic liquids
journal, October 2018
- Cubova, Katerina; Semelova, Miroslava; Nemec, Mojmir
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 3
Resin Ion Exchange and Liquid-Liquid Extraction of Indium and Thallium from Chloride Media
journal, July 2015
- Tereshatov, E. E.; Boltoeva, M. Yu.; Folden, C. M.
- Solvent Extraction and Ion Exchange, Vol. 33, Issue 6
Removal of transition metals from rare earths by solvent extraction with an undiluted phosphonium ionic liquid: separations relevant to rare-earth magnet recycling
journal, January 2013
- Vander Hoogerstraete, Tom; Wellens, Sil; Verachtert, Katrien
- Green Chemistry, Vol. 15, Issue 4
Effect of aqueous hydrochloric acid and zwitterionic betaine on the mutual solubility between a protic betainium-based ionic liquid and water
journal, February 2019
- Volia, Merinda F.; Tereshatov, Evgeny E.; Mazan, Valérie
- Journal of Molecular Liquids, Vol. 276
Homogeneous Liquid–Liquid Extraction of Rare Earths with the Betaine—Betainium Bis(trifluoromethylsulfonyl)imide Ionic Liquid System
journal, October 2013
- Vander Hoogerstraete, Tom; Onghena, Bieke; Binnemans, Koen
- International Journal of Molecular Sciences, Vol. 14, Issue 11
Liquid-Liquid Extraction of Trivalent Gallium, Indium and Thallium from Hydrochloric Acid Solutions by Trioctyl Phosphine Oxide.
journal, January 1996
- Sato, Taichi
- Shigen-to-Sozai, Vol. 112, Issue 2
Thallium Transfer from Hydrochloric Acid Media into Pure Ionic Liquids
journal, February 2016
- Tereshatov, Evgeny E.; Boltoeva, Maria Yu.; Mazan, Valerie
- The Journal of Physical Chemistry B, Vol. 120, Issue 9
The Stability of Metal Halide Complexes in Aqueous Solution. V. The Chloride and Bromide Complexes of Thallium(III).
journal, January 1963
- Ahrland, Sten; Grenthe, Ingmar; Johansson, Lars
- Acta Chemica Scandinavica, Vol. 17
Speciation of indium( iii ) chloro complexes in the solvent extraction process from chloride aqueous solutions to ionic liquids
journal, January 2017
- Deferm, Clio; Onghena, Bieke; Vander Hoogerstraete, Tom
- Dalton Transactions, Vol. 46, Issue 13
Overview of the Effect of Salts on Biphasic Ionic Liquid/Water Solvent Extraction Systems: Anion Exchange, Mutual Solubility, and Thermomorphic Properties
journal, April 2015
- Dupont, David; Depuydt, Daphne; Binnemans, Koen
- The Journal of Physical Chemistry B, Vol. 119, Issue 22
Hydrometallurgical Recovery of Indium from Flat-Panel Displays of Spent Liquid Crystal Televisions
journal, January 2015
- Inoue, Katsutoshi; Alam, Shafiq
- JOM, Vol. 67, Issue 2
Equilibrium dynamics in the thallium(III)-chloride system in acidic aqueous solution
journal, April 1989
- Banyai, Istvan; Glaser, Julius
- Journal of the American Chemical Society, Vol. 111, Issue 9
Structure of Thallium(III) Chloride, Bromide, and Cyanide Complexes in Aqueous Solution
journal, May 1995
- Blixt, Johan; Glaser, Julius; Mink, Janos
- Journal of the American Chemical Society, Vol. 117, Issue 18
Determination of Hydrogen Single Ion Activity Coefficients in Aqueous HCl Solutions at 25°C
journal, March 2004
- Schneider, Armin C.; Pasel, Christoph; Luckas, Michael
- Journal of Solution Chemistry, Vol. 33, Issue 3
Determination of Single-Ion Activities of H + and Cl – in Aqueous Hydrochloric Acid Solutions by Use of an Ionic Liquid Salt Bridge
journal, November 2011
- Sakaida, Hideaki; Kakiuchi, Takashi
- The Journal of Physical Chemistry B, Vol. 115, Issue 45
The coordination chemistry of thallium(I)
journal, November 1972
- Lee, A. G.
- Coordination Chemistry Reviews, Vol. 8, Issue 4
A Raman Study of Thallium(III) Chloride Complexes in Aqueous Solution
journal, May 1965
- Spiro, Thomas G.
- Inorganic Chemistry, Vol. 4, Issue 5
Liquid-liquid extraction of indium (III) from aqueous acid solutions by acid organophosphorus compounds
journal, June 1992
- Sato, Taichi; Sato, Keiichi
- Hydrometallurgy, Vol. 30, Issue 1-3
Structural properties of the inner coordination sphere of indium chloride complexes in organic and aqueous solutions
journal, January 2014
- Narita, Hirokazu; Tanaka, Mikiya; Shiwaku, Hideaki
- Dalton Trans., Vol. 43, Issue 4
U.V.-absorptionsspektren von Tl(III)-halogenidkomplexen in Wässeriger Lösung
journal, November 1970
- Schmidt, K.
- Journal of Inorganic and Nuclear Chemistry, Vol. 32, Issue 11
Hydrophobic polymerized ionic liquids for trace metal solid phase extraction: thallium transfer from hydrochloric acid media
journal, January 2019
- Tereshatov, Evgeny E.; Boltoeva, Maria; Mazan, Valérie
- New Journal of Chemistry, Vol. 43, Issue 23
Thallous chloride complexes in 0 to 6 molal sodium chloride at 25°C
journal, December 1992
- Read, A. J.; Aldridge, L. P.
- Journal of Solution Chemistry, Vol. 21, Issue 12