Growth and structural studies of In/Au(111) alloys and InOx/Au(111) inverse oxide/metal model catalysts
Abstract
Indium oxide has received attention as an exciting candidate for catalyzing the CO2 hydrogenation to methanol due to its high selectivity (>80%). Compared to the extent of research on the activity of indium oxide-based powder catalysts, very little is known about the phenomena associated with the formation of surface alloys involving indium or the growth mechanism for indium oxide nanoparticles. In this report, scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS) were employed to elucidate the growth mode, structure, and chemical state of In/Au(111) alloys and InOx/Au(111) inverse model catalysts. Here, our study reveals distinct morphological differences between In/Au(111) and InOx/Au(111), and the InOx structure also depends strongly on the preparation conditions. In/Au surface alloy systems with extremely low coverage (0.02 ML) form islands preferentially on the elbow sites of reconstructed Au(111) herringbone, regardless of hcp and fcc stacking. At higher coverage (0.1 ML), the In islands expand over the herringbone in the <110> direction and create two dimensional domain structures over the entire surfaces. Moreover, this 2D domain structure is disturbed by temperature with high dispersion of indium atoms observed during the annealing process. Oxidation of the In/Au(111) surface alloys with O2 at 550 K produces InOx/Au(111) systemsmore »
- Authors:
-
- State Univ. of New York (SUNY), Stony Brook, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- State Univ. of New York (SUNY), Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1633598
- Alternate Identifier(s):
- OSTI ID: 1596892
- Report Number(s):
- BNL-216032-2020-JAAM
Journal ID: ISSN 0021-9606; TRN: US2201384
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Chemical Physics
- Additional Journal Information:
- Journal Volume: 152; Journal Issue: 5; Journal ID: ISSN 0021-9606
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; Indium oxide; gold; catalysis; oxide chemistry and catalysis; scanning tunneling microscopy; hydrogenation process; catalysts and catalysis; hydrogen energy; vapor deposition; biofuels; x-ray photoelectron spectroscopy; nanoparticles; Auger electron spectroscopy
Citation Formats
Kang, Jindong, Mahapatra, Mausumi, Rui, Ning, Orozco, Ivan, Shi, Rui, Senanayake, Sanjaya D., and Rodriguez, José A. Growth and structural studies of In/Au(111) alloys and InOx/Au(111) inverse oxide/metal model catalysts. United States: N. p., 2020.
Web. doi:10.1063/1.5139237.
Kang, Jindong, Mahapatra, Mausumi, Rui, Ning, Orozco, Ivan, Shi, Rui, Senanayake, Sanjaya D., & Rodriguez, José A. Growth and structural studies of In/Au(111) alloys and InOx/Au(111) inverse oxide/metal model catalysts. United States. https://doi.org/10.1063/1.5139237
Kang, Jindong, Mahapatra, Mausumi, Rui, Ning, Orozco, Ivan, Shi, Rui, Senanayake, Sanjaya D., and Rodriguez, José A. Mon .
"Growth and structural studies of In/Au(111) alloys and InOx/Au(111) inverse oxide/metal model catalysts". United States. https://doi.org/10.1063/1.5139237. https://www.osti.gov/servlets/purl/1633598.
@article{osti_1633598,
title = {Growth and structural studies of In/Au(111) alloys and InOx/Au(111) inverse oxide/metal model catalysts},
author = {Kang, Jindong and Mahapatra, Mausumi and Rui, Ning and Orozco, Ivan and Shi, Rui and Senanayake, Sanjaya D. and Rodriguez, José A.},
abstractNote = {Indium oxide has received attention as an exciting candidate for catalyzing the CO2 hydrogenation to methanol due to its high selectivity (>80%). Compared to the extent of research on the activity of indium oxide-based powder catalysts, very little is known about the phenomena associated with the formation of surface alloys involving indium or the growth mechanism for indium oxide nanoparticles. In this report, scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS) were employed to elucidate the growth mode, structure, and chemical state of In/Au(111) alloys and InOx/Au(111) inverse model catalysts. Here, our study reveals distinct morphological differences between In/Au(111) and InOx/Au(111), and the InOx structure also depends strongly on the preparation conditions. In/Au surface alloy systems with extremely low coverage (0.02 ML) form islands preferentially on the elbow sites of reconstructed Au(111) herringbone, regardless of hcp and fcc stacking. At higher coverage (0.1 ML), the In islands expand over the herringbone in the <110> direction and create two dimensional domain structures over the entire surfaces. Moreover, this 2D domain structure is disturbed by temperature with high dispersion of indium atoms observed during the annealing process. Oxidation of the In/Au(111) surface alloys with O2 at 550 K produces InOx/Au(111) systems which contain various sizes of InOx aggregates (from 0.7 to 10 nm). On the other hand, InOx/Au(111) surfaces prepared by vapor deposition of In at 550 K in an O2 background exhibit highly dispersed and uniformly small InOx particles (~1 nm). Both InOx systems were confirmed to be partially oxidized by XPS.},
doi = {10.1063/1.5139237},
journal = {Journal of Chemical Physics},
number = 5,
volume = 152,
place = {United States},
year = {Mon Feb 03 00:00:00 EST 2020},
month = {Mon Feb 03 00:00:00 EST 2020}
}
Web of Science
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