Atomic interface effect of a single atom copper catalyst for enhanced oxygen reduction reactions
Abstract
The regulation of catalytic activity in the oxygen reduction reaction (ORR) is significant to the development of metal–air batteries and other oxygen involving energy conversion devices. Herein, we propose an atomic interface strategy to construct a single atom copper catalyst (denoted as Cu-SA/SNC) which exhibits enhanced ORR activity with a half-wave potential of 0.893 V vs. RHE in alkaline media. Moreover, synchrotron-radiation-based X-ray absorption fine structure (XAFS) investigations together with density functional theory (DFT) calculations reveal that the isolated bond-shrinking low-valence Cu (+1)–N4–C8S2 atomic interface moiety serves as an active site during the ORR process, and the synergistic mechanism between the Cu species and the carbon matrix at the atomic interface plays a critical role in boosting the ORR efficiency, by adjusting the reaction free energy of intermediate adsorption. Furthermore, this atomic interface concept may provide an alternative methodology for the rational design of advanced oxygen electrode materials and new probability to improve their catalytic performance.
- Authors:
-
- Beijing Inst. of Technology, Beijing (China)
- China Agricultural Univ., Beijing (China)
- Univ. of Science and Technology Beijing, Beijing (China)
- Chinese Academy of Sciences (CAS), Beijing (China)
- Chinese Academy of Sciences (CAS), Shanghai (China)
- Tsinghua Univ., Beijing (China)
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Univ. of Science and Technology of China, Hefei (China)
- Department of Chemistry; Tsinghua University; Beijing 100084; China
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1595249
- Grant/Contract Number:
- AC02-76SF00515; 21643003; 21671117; 21703219; 21801015; 21871159; 51501010; 51631001; 51702016; 51872030
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 12; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Jiang, Zhuoli, Sun, Wenming, Shang, Huishan, Chen, Wenxing, Sun, Tingting, Li, Haijing, Dong, Juncai, Zhou, Jing, Li, Zhi, Wang, Yu, Cao, Rui, Sarangi, Ritimukta, Yang, Zhengkun, Wang, Dingsheng, Zhang, Jiatao, and Li, Yadong. Atomic interface effect of a single atom copper catalyst for enhanced oxygen reduction reactions. United States: N. p., 2019.
Web. doi:10.1039/c9ee02974e.
Jiang, Zhuoli, Sun, Wenming, Shang, Huishan, Chen, Wenxing, Sun, Tingting, Li, Haijing, Dong, Juncai, Zhou, Jing, Li, Zhi, Wang, Yu, Cao, Rui, Sarangi, Ritimukta, Yang, Zhengkun, Wang, Dingsheng, Zhang, Jiatao, & Li, Yadong. Atomic interface effect of a single atom copper catalyst for enhanced oxygen reduction reactions. United States. https://doi.org/10.1039/c9ee02974e
Jiang, Zhuoli, Sun, Wenming, Shang, Huishan, Chen, Wenxing, Sun, Tingting, Li, Haijing, Dong, Juncai, Zhou, Jing, Li, Zhi, Wang, Yu, Cao, Rui, Sarangi, Ritimukta, Yang, Zhengkun, Wang, Dingsheng, Zhang, Jiatao, and Li, Yadong. Fri .
"Atomic interface effect of a single atom copper catalyst for enhanced oxygen reduction reactions". United States. https://doi.org/10.1039/c9ee02974e. https://www.osti.gov/servlets/purl/1595249.
@article{osti_1595249,
title = {Atomic interface effect of a single atom copper catalyst for enhanced oxygen reduction reactions},
author = {Jiang, Zhuoli and Sun, Wenming and Shang, Huishan and Chen, Wenxing and Sun, Tingting and Li, Haijing and Dong, Juncai and Zhou, Jing and Li, Zhi and Wang, Yu and Cao, Rui and Sarangi, Ritimukta and Yang, Zhengkun and Wang, Dingsheng and Zhang, Jiatao and Li, Yadong},
abstractNote = {The regulation of catalytic activity in the oxygen reduction reaction (ORR) is significant to the development of metal–air batteries and other oxygen involving energy conversion devices. Herein, we propose an atomic interface strategy to construct a single atom copper catalyst (denoted as Cu-SA/SNC) which exhibits enhanced ORR activity with a half-wave potential of 0.893 V vs. RHE in alkaline media. Moreover, synchrotron-radiation-based X-ray absorption fine structure (XAFS) investigations together with density functional theory (DFT) calculations reveal that the isolated bond-shrinking low-valence Cu (+1)–N4–C8S2 atomic interface moiety serves as an active site during the ORR process, and the synergistic mechanism between the Cu species and the carbon matrix at the atomic interface plays a critical role in boosting the ORR efficiency, by adjusting the reaction free energy of intermediate adsorption. Furthermore, this atomic interface concept may provide an alternative methodology for the rational design of advanced oxygen electrode materials and new probability to improve their catalytic performance.},
doi = {10.1039/c9ee02974e},
journal = {Energy & Environmental Science},
number = 12,
volume = 12,
place = {United States},
year = {Fri Nov 15 00:00:00 EST 2019},
month = {Fri Nov 15 00:00:00 EST 2019}
}
Web of Science
Works referenced in this record:
Surface and Interface Engineering of Noble-Metal-Free Electrocatalysts for Efficient Energy Conversion Processes
journal, February 2017
- Zhu, Yun Pei; Guo, Chunxian; Zheng, Yao
- Accounts of Chemical Research, Vol. 50, Issue 4
Bottom-up precise synthesis of stable platinum dimers on graphene
journal, October 2017
- Yan, Huan; Lin, Yue; Wu, Hong
- Nature Communications, Vol. 8, Issue 1
Atomic cobalt on nitrogen-doped graphene for hydrogen generation
journal, October 2015
- Fei, Huilong; Dong, Juncai; Arellano-Jiménez, M. Josefina
- Nature Communications, Vol. 6, Issue 1
Interfacial engineering of cobalt sulfide/graphene hybrids for highly efficient ammonia electrosynthesis
journal, March 2019
- Chen, Pengzuo; Zhang, Nan; Wang, Sibo
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 14
Defect engineering in earth-abundant electrocatalysts for CO 2 and N 2 reduction
journal, January 2019
- Wang, Qichen; Lei, Yongpeng; Wang, Dingsheng
- Energy & Environmental Science, Vol. 12, Issue 6
Efficient alkaline hydrogen evolution on atomically dispersed Ni–N x Species anchored porous carbon with embedded Ni nanoparticles by accelerating water dissociation kinetics
journal, January 2019
- Lei, Chaojun; Wang, Yu; Hou, Yang
- Energy & Environmental Science, Vol. 12, Issue 1
A metal–organic framework-derived bifunctional oxygen electrocatalyst
journal, January 2016
- Xia, Bao Yu; Yan, Ya; Li, Nan
- Nature Energy, Vol. 1, Issue 1
Uncoordinated Amine Groups of Metal–Organic Frameworks to Anchor Single Ru Sites as Chemoselective Catalysts toward the Hydrogenation of Quinoline
journal, July 2017
- Wang, Xin; Chen, Wenxing; Zhang, Lei
- Journal of the American Chemical Society, Vol. 139, Issue 28
A Bifunctional Hybrid Electrocatalyst for Oxygen Reduction and Evolution: Cobalt Oxide Nanoparticles Strongly Coupled to B,N-Decorated Graphene
journal, May 2017
- Tong, Yun; Chen, Pengzuo; Zhou, Tianpei
- Angewandte Chemie International Edition, Vol. 56, Issue 25
Single-atom catalysts by the atomic layer deposition technique
journal, May 2018
- Zhang, Lei; Banis, Mohammad Norouzi; Sun, Xueliang
- National Science Review, Vol. 5, Issue 5
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017
- Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
- Angewandte Chemie International Edition, Vol. 56, Issue 24
Oxygen Reduction Electrocatalyst Based on Strongly Coupled Cobalt Oxide Nanocrystals and Carbon Nanotubes
journal, September 2012
- Liang, Yongye; Wang, Hailiang; Diao, Peng
- Journal of the American Chemical Society, Vol. 134, Issue 38
Heterogeneous nanocarbon materials for oxygen reduction reaction
journal, January 2014
- Wang, Da-Wei; Su, Dangsheng
- Energy & Environmental Science, Vol. 7, Issue 2
Fe Isolated Single Atoms on S, N Codoped Carbon by Copolymer Pyrolysis Strategy for Highly Efficient Oxygen Reduction Reaction
journal, May 2018
- Li, Qiheng; Chen, Wenxing; Xiao, Hai
- Advanced Materials, Vol. 30, Issue 25
Transition metal–nitrogen–carbon nanostructured catalysts for the oxygen reduction reaction: From mechanistic insights to structural optimization
journal, January 2017
- Shen, Mengxia; Wei, Changting; Ai, Kelong
- Nano Research, Vol. 10, Issue 5
The application of graphene and its composites in oxygen reduction electrocatalysis: a perspective and review of recent progress
journal, January 2016
- Higgins, Drew; Zamani, Pouyan; Yu, Aiping
- Energy & Environmental Science, Vol. 9, Issue 2
Copper-Modified Covalent Triazine Frameworks as Non-Noble-Metal Electrocatalysts for Oxygen Reduction
journal, July 2015
- Iwase, Kazuyuki; Yoshioka, Tatsuro; Nakanishi, Shuji
- Angewandte Chemie International Edition, Vol. 54, Issue 38
Sulfur K- and L-edge X-ray absorption spectroscopy of sphalerite, chalcopyrite and stannite
journal, January 1994
- Li, Dien; Bancroft, G. M.; Kasrai, M.
- Physics and Chemistry of Minerals, Vol. 20, Issue 7
Understanding the High Activity of Fe–N–C Electrocatalysts in Oxygen Reduction: Fe/Fe 3 C Nanoparticles Boost the Activity of Fe–N x
journal, March 2016
- Jiang, Wen-Jie; Gu, Lin; Li, Li
- Journal of the American Chemical Society, Vol. 138, Issue 10
Metal-Organic-Framework-Derived Hybrid Carbon Nanocages as a Bifunctional Electrocatalyst for Oxygen Reduction and Evolution
journal, June 2017
- Liu, Shaohong; Wang, Zhiyu; Zhou, Si
- Advanced Materials, Vol. 29, Issue 31
Opportunities and challenges for a sustainable energy future
journal, August 2012
- Chu, Steven; Majumdar, Arun
- Nature, Vol. 488, Issue 7411, p. 294-303
Atomically dispersed nickel–nitrogen–sulfur species anchored on porous carbon nanosheets for efficient water oxidation
journal, March 2019
- Hou, Yang; Qiu, Ming; Kim, Min Gyu
- Nature Communications, Vol. 10, Issue 1
An Isolated Zinc-Cobalt Atomic Pair for Highly Active and Durable Oxygen Reduction
journal, February 2019
- Lu, Ziyang; Wang, Bo; Hu, Yongfeng
- Angewandte Chemie International Edition, Vol. 58, Issue 9
Lattice-strained metal–organic-framework arrays for bifunctional oxygen electrocatalysis
journal, January 2019
- Cheng, Weiren; Zhao, Xu; Su, Hui
- Nature Energy, Vol. 4, Issue 2
Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst
journal, April 2016
- Yang, Hong Bin; Miao, Jianwei; Hung, Sung-Fu
- Science Advances, Vol. 2, Issue 4
Efficient and Robust Carbon Dioxide Electroreduction Enabled by Atomically Dispersed Sn δ + Sites
journal, February 2019
- Zu, Xiaolong; Li, Xiaodong; Liu, Wei
- Advanced Materials, Vol. 31, Issue 15
3D Nitrogen-Doped Graphene Aerogel-Supported Fe 3 O 4 Nanoparticles as Efficient Electrocatalysts for the Oxygen Reduction Reaction
journal, May 2012
- Wu, Zhong-Shuai; Yang, Shubin; Sun, Yi
- Journal of the American Chemical Society, Vol. 134, Issue 22
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
journal, February 2016
- Shao, Minhua; Chang, Qiaowan; Dodelet, Jean-Pol
- Chemical Reviews, Vol. 116, Issue 6
Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction
journal, November 2017
- Chen, Wenxing; Pei, Jiajing; He, Chun-Ting
- Angewandte Chemie International Edition, Vol. 56, Issue 50
Wavelet analysis of extended x-ray absorption fine structure data
journal, March 2005
- Funke, H.; Scheinost, A. C.; Chukalina, M.
- Physical Review B, Vol. 71, Issue 9
Recent Advances on Non-precious Metal Porous Carbon-based Electrocatalysts for Oxygen Reduction Reaction
journal, March 2018
- Liu, Dongdong; Tao, Li; Yan, Dafeng
- ChemElectroChem, Vol. 5, Issue 14
Single-Atom Catalysts: Synthetic Strategies and Electrochemical Applications
journal, July 2018
- Chen, Yuanjun; Ji, Shufang; Chen, Chen
- Joule, Vol. 2, Issue 7
Direct observation of the oxygenated species during oxygen reduction on a platinum fuel cell cathode
journal, December 2013
- Casalongue, Hernan Sanchez; Kaya, Sarp; Viswanathan, Venkatasubramanian
- Nature Communications, Vol. 4, Issue 1
X-ray absorption spectroscopy in coordination chemistry
journal, September 1999
- Penner-Hahn, James E.
- Coordination Chemistry Reviews, Vol. 190-192
Single-Atom Electrocatalysts
journal, October 2017
- Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong
- Angewandte Chemie International Edition, Vol. 56, Issue 45
Inner shell excitation of thiophene and thiolane: Gas, solid, and monolayer states
journal, November 1986
- Hitchcock, A. P.; Horsley, J. A.; Stöhr, J.
- The Journal of Chemical Physics, Vol. 85, Issue 9
Recent advances in zinc–air batteries
journal, January 2014
- Li, Yanguang; Dai, Hongjie
- Chem. Soc. Rev., Vol. 43, Issue 15
Highly stable single Pt atomic sites anchored on aniline-stacked graphene for hydrogen evolution reaction
journal, January 2019
- Ye, Shenghua; Luo, Feiyan; Zhang, Qianling
- Energy & Environmental Science, Vol. 12, Issue 3
Electrocatalytic O 2 Reduction at a Bio-inspired Mononuclear Copper Phenolato Complex Immobilized on a Carbon Nanotube Electrode
journal, January 2016
- Gentil, Solène; Serre, Doti; Philouze, Christian
- Angewandte Chemie International Edition, Vol. 55, Issue 7
Highly efficient nonprecious metal catalysts towards oxygen reduction reaction based on three-dimensional porous carbon nanostructures
journal, January 2016
- Zhu, Chengzhou; Li, He; Fu, Shaofang
- Chemical Society Reviews, Vol. 45, Issue 3
Versatile Strategy for Tuning ORR Activity of a Single Fe-N 4 Site by Controlling Electron-Withdrawing/Donating Properties of a Carbon Plane
journal, March 2019
- Mun, Yeongdong; Lee, Seonggyu; Kim, Kyeounghak
- Journal of the American Chemical Society, Vol. 141, Issue 15
Inner-shell excitation of gas-phase and polymer thin-film 3-alkylthiophenes by electron energy loss and x-ray photoabsorption spectroscopy
journal, March 1990
- Hitchcock, A. P.; Tourillon, G.; Garrett, R.
- The Journal of Physical Chemistry, Vol. 94, Issue 6
Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions
journal, December 2016
- Chen, Pengzuo; Zhou, Tianpei; Xing, Lili
- Angewandte Chemie International Edition, Vol. 56, Issue 2
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
journal, February 2018
- Yang, Hong Bin; Hung, Sung-Fu; Liu, Song
- Nature Energy, Vol. 3, Issue 2
XAFS investigation of polyamidoxime-bound uranyl contests the paradigm from small molecule studies
journal, January 2016
- Abney, C. W.; Mayes, R. T.; Piechowicz, M.
- Energy & Environmental Science, Vol. 9, Issue 2
Synergistic Effects between Atomically Dispersed Fe−N−C and C−S−C for the Oxygen Reduction Reaction in Acidic Media
journal, September 2017
- Shen, Hangjia; Gracia-Espino, Eduardo; Ma, Jingyuan
- Angewandte Chemie International Edition, Vol. 56, Issue 44
Metal organic frameworks derived single atom catalysts for electrocatalytic energy conversion
journal, March 2019
- Sun, Tingting; Xu, Lianbin; Wang, Dingsheng
- Nano Research, Vol. 12, Issue 9
Earth-Abundant Nanomaterials for Oxygen Reduction
journal, December 2015
- Xia, Wei; Mahmood, Asif; Liang, Zibin
- Angewandte Chemie International Edition, Vol. 55, Issue 8
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016
- Yin, Peiqun; Yao, Tao; Wu, Yuen
- Angewandte Chemie International Edition, Vol. 55, Issue 36
Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts
journal, March 2019
- Zhao, Lu; Zhang, Yun; Huang, Lin-Bo
- Nature Communications, Vol. 10, Issue 1
Copper-Modified Covalent Triazine Frameworks as Non-Noble-Metal Electrocatalysts for Oxygen Reduction
journal, July 2015
- Iwase, Kazuyuki; Yoshioka, Tatsuro; Nakanishi, Shuji
- Angewandte Chemie, Vol. 127, Issue 38
A Bifunctional Hybrid Electrocatalyst for Oxygen Reduction and Evolution: Cobalt Oxide Nanoparticles Strongly Coupled to B,N-Decorated Graphene
journal, May 2017
- Tong, Yun; Chen, Pengzuo; Zhou, Tianpei
- Angewandte Chemie, Vol. 129, Issue 25
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017
- Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
- Angewandte Chemie, Vol. 129, Issue 24
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016
- Yin, Peiqun; Yao, Tao; Wu, Yuen
- Angewandte Chemie, Vol. 128, Issue 36
Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction
journal, November 2017
- Chen, Wenxing; Pei, Jiajing; He, Chun-Ting
- Angewandte Chemie, Vol. 129, Issue 50
Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions
journal, December 2016
- Chen, Pengzuo; Zhou, Tianpei; Xing, Lili
- Angewandte Chemie, Vol. 129, Issue 2
Synergistic Effects between Atomically Dispersed Fe−N−C and C−S−C for the Oxygen Reduction Reaction in Acidic Media
journal, September 2017
- Shen, Hangjia; Gracia-Espino, Eduardo; Ma, Jingyuan
- Angewandte Chemie, Vol. 129, Issue 44