Superconductivity in the superhard boride WB4.2
Abstract
Here, we show that the superhard boride WB4.2 is a superconductor with a Tc of 2.05(5) K. Temperature-dependent magnetic susceptibility, electrical resistivity, and specific heat measurements were used to characterize the superconducting transition. The Sommerfeld constant gamma for WB4.2 is 2.07(3) mJ mol(-1) K-2 and the ΔC/γ Tc = 1.56, which is somewhat higher than what is expected for weakly coupled Bardeen-Cooper-Schrieffer type superconductors. The H c2 versus T plot is linear over a wide temperature range but does show signs of flattening by the lowest temperatures studied and therefore the zero temperature upper critical field (μ 0H c2(0)) for WB4.2 lies somewhere between the linear extrapolation of μ 0H c2(T) to 0 K and expectations based on the Werthamer-Helfand-Hohenberg model.
- Authors:
-
- Princeton Univ., NJ (United States)
- Gdansk Univ. of Technology (Poland)
- Polish Academy of Sciences, Wroclaw (Poland)
- Louisiana State Univ., Baton Rouge, LA (United States)
- Publication Date:
- Research Org.:
- Princeton Univ., NJ (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1595074
- Grant/Contract Number:
- FG02-98ER45706; SC0012432; GBMF-4412; UMO-2016/22/M/ST5/00435
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Superconductor Science and Technology
- Additional Journal Information:
- Journal Volume: 31; Journal Issue: 11; Journal ID: ISSN 0953-2048
- Publisher:
- IOP Publishing
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; superconductivity; superhard; tungsten deficient; boride
Citation Formats
Carnicom, Elizabeth M., Strychalska-Nowak, Judyta, Wiśniewski, P., Kaczorowski, D., Xie, W., Klimczuk, T., and Cava, R. J. Superconductivity in the superhard boride WB4.2. United States: N. p., 2018.
Web. doi:10.1088/1361-6668/aade5a.
Carnicom, Elizabeth M., Strychalska-Nowak, Judyta, Wiśniewski, P., Kaczorowski, D., Xie, W., Klimczuk, T., & Cava, R. J. Superconductivity in the superhard boride WB4.2. United States. https://doi.org/10.1088/1361-6668/aade5a
Carnicom, Elizabeth M., Strychalska-Nowak, Judyta, Wiśniewski, P., Kaczorowski, D., Xie, W., Klimczuk, T., and Cava, R. J. Thu .
"Superconductivity in the superhard boride WB4.2". United States. https://doi.org/10.1088/1361-6668/aade5a. https://www.osti.gov/servlets/purl/1595074.
@article{osti_1595074,
title = {Superconductivity in the superhard boride WB4.2},
author = {Carnicom, Elizabeth M. and Strychalska-Nowak, Judyta and Wiśniewski, P. and Kaczorowski, D. and Xie, W. and Klimczuk, T. and Cava, R. J.},
abstractNote = {Here, we show that the superhard boride WB4.2 is a superconductor with a Tc of 2.05(5) K. Temperature-dependent magnetic susceptibility, electrical resistivity, and specific heat measurements were used to characterize the superconducting transition. The Sommerfeld constant gamma for WB4.2 is 2.07(3) mJ mol(-1) K-2 and the ΔC/γ Tc = 1.56, which is somewhat higher than what is expected for weakly coupled Bardeen-Cooper-Schrieffer type superconductors. The H c2 versus T plot is linear over a wide temperature range but does show signs of flattening by the lowest temperatures studied and therefore the zero temperature upper critical field (μ 0H c2(0)) for WB4.2 lies somewhere between the linear extrapolation of μ 0H c2(T) to 0 K and expectations based on the Werthamer-Helfand-Hohenberg model.},
doi = {10.1088/1361-6668/aade5a},
journal = {Superconductor Science and Technology},
number = 11,
volume = 31,
place = {United States},
year = {Thu Sep 27 00:00:00 EDT 2018},
month = {Thu Sep 27 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Structure and superconductivity in Zr-stabilized, nonstoichiometric molybdenum diboride
journal, November 2002
- Muzzy, L. E.; Avdeev, M.; Lawes, G.
- Physica C: Superconductivity, Vol. 382, Issue 2-3
Synthesis of superhard cubic BC2N
journal, March 2001
- Solozhenko, Vladimir L.; Andrault, Denis; Fiquet, Guillaume
- Applied Physics Letters, Vol. 78, Issue 10
Superconductivity at 39 K in magnesium diboride
journal, March 2001
- Nagamatsu, Jun; Nakagawa, Norimasa; Muranaka, Takahiro
- Nature, Vol. 410, Issue 6824
Superconductivity with extremely large upper critical fields in Nb2Pd0.81S5
journal, March 2013
- Zhang, Q.; Li, G.; Rhodes, D.
- Scientific Reports, Vol. 3, Issue 1
Synthesis of Ultra-Incompressible Superhard Rhenium Diboride at Ambient Pressure
journal, April 2007
- Chung, H. -Y.; Weinberger, M. B.; Levine, J. B.
- Science, Vol. 316, Issue 5823
Mechanical Properties of Polycrystalline Translucent Cubic Boron Nitride as Characterized by the Vickers Indentation Method
journal, February 1996
- Taniguchi, Takashi; Akaishi, Minoru; Yamaoka, Shinobu
- Journal of the American Ceramic Society, Vol. 79, Issue 2
A short history of SHELX
journal, December 2007
- Sheldrick, George M.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
Temperature and Purity Dependence of the Superconducting Critical Field, . III. Electron Spin and Spin-Orbit Effects
journal, July 1966
- Werthamer, N. R.; Helfand, E.; Hohenberg, P. C.
- Physical Review, Vol. 147, Issue 1
MATERIALS SCIENCE: Designing Superhard Materials
journal, May 2005
- Kaner, R. B.
- Science, Vol. 308, Issue 5726
Crystalline structure and the superconducting properties of NbB 2+ x
journal, August 2004
- Escamilla, R.; Lovera, O.; Akachi, T.
- Journal of Physics: Condensed Matter, Vol. 16, Issue 32
Anisotropic mechanical properties of ultra-incompressible, hard osmium diboride
journal, June 2008
- Chung, Hsiu-Ying; Yang, J-M.; Tolbert, S. H.
- Journal of Materials Research, Vol. 23, Issue 6
Anisotropy of hardness from first principles: The cases of ReB 2 and OsB 2
journal, August 2009
- Šimůnek, Antonín
- Physical Review B, Vol. 80, Issue 6
Clean surface reactions between diamond and steel
journal, August 1978
- Thornton, A. G.; Wilks, J.
- Nature, Vol. 274, Issue 5673
Wear of synthetic diamond when grinding ferrous metals
journal, May 1975
- Komanduri, R.; Shaw, M. C.
- Nature, Vol. 255, Issue 5505
High-pressure synthesis of superconducting Nb1−xB2 (x=0–0.48) with the maximum Tc=9.2 K
journal, December 2002
- Yamamoto, Ayako; Takao, Chigaku; Masui, Takahiko
- Physica C: Superconductivity, Vol. 383, Issue 3
Advancements in the Search for Superhard Ultra-Incompressible Metal Borides
journal, November 2009
- Levine, Jonathan B.; Tolbert, Sarah H.; Kaner, Richard B.
- Advanced Functional Materials, Vol. 19, Issue 22
Formation process of tungsten borides by solid state reaction between tungsten and amorphous boron
journal, August 1987
- Itoh, H.; Matsudaira, T.; Naka, S.
- Journal of Materials Science, Vol. 22, Issue 8
Structure of superhard tungsten tetraboride: A missing link between MB 2 and MB 12 higher borides
journal, March 2015
- Lech, Andrew T.; Turner, Christopher L.; Mohammadi, Reza
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 11
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011
- Momma, Koichi; Izumi, Fujio
- Journal of Applied Crystallography, Vol. 44, Issue 6
Nearly isotropic superconductivity in (Ba,K)Fe2As2
journal, January 2009
- Yuan, H. Q.; Singleton, J.; Balakirev, F. F.
- Nature, Vol. 457, Issue 7229
Neutron diffraction and observation of superconductivity for tungsten borides, WB and W2B4
journal, November 2012
- Kayhan, Mehmet; Hildebrandt, Erwin; Frotscher, Michael
- Solid State Sciences, Vol. 14, Issue 11-12
Superhard materials with low elastic moduli: Three-dimensional covalent bonding as the origin of superhardness in O
journal, March 2011
- Zhang, R. F.; Lin, Z. J.; Zhao, Y. S.
- Physical Review B, Vol. 83, Issue 9
Origin of hardness in WB4 and its implications for ReB4, TaB4, MoB4, TcB4, and OsB4
journal, September 2008
- Wang, Mei; Li, Yinwei; Cui, Tian
- Applied Physics Letters, Vol. 93, Issue 10
Preparation and characterization of superhard AlB 2 -type WB 2 nanocomposite coatings : Superhard AlB
journal, March 2013
- Jiang, Chunlei; Pei, Zhiliang; Liu, Yanming
- physica status solidi (a), Vol. 210, Issue 6
Small anisotropy, weak thermal fluctuations, and high field superconductivity in Co-doped iron pnictide Ba(Fe1−xCox)2As2
journal, February 2009
- Yamamoto, A.; Jaroszynski, J.; Tarantini, C.
- Applied Physics Letters, Vol. 94, Issue 6
Carbon nitride and other speculative superhard materials
journal, January 1996
- Sung, Chien-Min; Sung, Michael
- Materials Chemistry and Physics, Vol. 43, Issue 1
The NbB2-phase revisited: Homogeneity range, defect structure, superconductivity
journal, August 2005
- Nunes, Carlos Angelo; Kaczorowski, Dariusz; Rogl, Peter
- Acta Materialia, Vol. 53, Issue 13
Exploring the high-pressure behavior of superhard tungsten tetraboride
journal, February 2012
- Xie, Miao; Mohammadi, Reza; Mao, Zhu
- Physical Review B, Vol. 85, Issue 6
Crystal Structure of W1−x B3 and Phase Equilibria in the Boron-Rich Part of the Systems Mo-Rh-B and W-{Ru,Os,Rh,Ir,Ni,Pd,Pt}-B
journal, March 2014
- Zeiringer, I.; Rogl, P.; Grytsiv, A.
- Journal of Phase Equilibria and Diffusion, Vol. 35, Issue 4
Discovery of a Superhard Iron Tetraboride Superconductor
journal, October 2013
- Gou, Huiyang; Dubrovinskaia, Natalia; Bykova, Elena
- Physical Review Letters, Vol. 111, Issue 15
Bor-reiche Wolframboride
journal, May 1967
- Nowotny, H.; Haschke, H.; Benesovsky, F.
- Monatshefte für Chemie - Chemical Monthly, Vol. 98, Issue 3
Correlation between hardness and elastic moduli of the ultraincompressible transition metal diborides RuB2, OsB2, and ReB2
journal, June 2008
- Chung, Hsiu-Ying; Weinberger, Michelle B.; Yang, Jenn-Ming
- Applied Physics Letters, Vol. 92, Issue 26
TaRh 2 B 2 and NbRh 2 B 2 : Superconductors with a chiral noncentrosymmetric crystal structure
journal, May 2018
- Carnicom, Elizabeth M.; Xie, Weiwei; Klimczuk, Tomasz
- Science Advances, Vol. 4, Issue 5
Is Rhenium Diboride a Superhard Material?
journal, December 2008
- Qin, Jiaqian; He, Duanwei; Wang, Jianghua
- Advanced Materials, Vol. 20, Issue 24
Hardness and elastic moduli of high pressure synthesized MoB 2 and WB 2 compacts
journal, June 2013
- Yin, Shuai; He, Duanwei; Xu, Chao
- High Pressure Research, Vol. 33, Issue 2
Fragment-Based Design of NbRuB as a New Metal-Rich Boride Superconductor
journal, February 2015
- Xie, Weiwei; Luo, Huixia; Baroudi, Kristen
- Chemistry of Materials, Vol. 27, Issue 4
Transition Metal Borides: Superhard versus Ultra-incompressible
journal, October 2008
- Gu, Qinfen; Krauss, Günter; Steurer, Walter
- Advanced Materials, Vol. 20, Issue 19
Osmium Diboride, An Ultra-Incompressible, Hard Material
journal, May 2005
- Cumberland, Robert W.; Weinberger, Michelle B.; Gilman, John J.
- Journal of the American Chemical Society, Vol. 127, Issue 20
Composition and crystallographic data for the highest boride of tungsten
journal, February 1966
- Romans, P. A.; Krug, M. P.
- Acta Crystallographica, Vol. 20, Issue 2
Transition Temperature of Strong-Coupled Superconductors
journal, March 1968
- McMillan, W. L.
- Physical Review, Vol. 167, Issue 2
Osmium Diboride, an Ultra-Incompressible, Hard Material.
journal, August 2005
- Cumberland, Robert W.; Weinberger, Michelle B.; Gilman, John J.
- ChemInform, Vol. 36, Issue 34
Lead palladium titanate: A room temperature nanoscale multiferroic thin film
journal, February 2020
- Mishra, K. K.; Instan, Alvaro A.; Kumari, Shalini
- Scientific Reports, Vol. 10, Issue 1
Superconductivity with extremely large upper critical fields in Nb2Pd0.81S5
text, January 2013
- Zhang, Q.; Li, G.; Rhodes, D.
- arXiv
Structure and Superconductivity in Zr-Stabilized, Nonstoichiometric Molybdenum Diboride
text, January 2002
- Muzzy, L. E.; Avdeev, M.; Lawes, G.
- arXiv
Works referencing / citing this record:
Superconductivity with high hardness in Mo 3 C 2
journal, January 2019
- Ge, Yufei; Ma, Shuailing; Bao, Kuo
- Inorganic Chemistry Frontiers, Vol. 6, Issue 5
Unravelling the structure and strength of the highest boride of tungsten
journal, December 2019
- Gong, Weiguang; Liu, Chang; Song, Xianqi
- Physical Review B, Vol. 100, Issue 22