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Title: Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries

Abstract

A novel strategy is designed to stabilize atomic Pt catalysts in alloyed platinum cobalt nanosheets with trapped interstitial fluorine (SA-PtCoF) for zinc-air batteries.

Authors:
 [1]; ORCiD logo [2]; ORCiD logo [3];  [4];  [5];  [5];  [4]; ORCiD logo [5];  [5];  [6]; ORCiD logo [7];  [7]; ORCiD logo [5];  [3]; ORCiD logo [1]
  1. Department of Materials Science and Engineering, University of Central Florida, Orlando, USA, NanoScience Technology Center
  2. NanoScience Technology Center, University of Central Florida, Orlando, USA
  3. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, USA
  4. Department of Physics, University of Central Florida, Orlando, USA
  5. School of Chemical, Biological, and Environmental Engineering, Oregon State University, Corvallis, USA
  6. Materials Science Division, Argonne National Laboratory, Lemont, USA
  7. X-ray Science Division, Argonne National Laboratory, Lemont, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1577910
Grant/Contract Number:  
68278; AC02-06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Li, Zhao, Niu, Wenhan, Yang, Zhenzhong, Zaman, Nusaiba, Samarakoon, Widitha, Wang, Maoyu, Kara, Abdelkader, Lucero, Marcos, Vyas, Manasi V., Cao, Hui, Zhou, Hua, Sterbinsky, George E., Feng, Zhenxing, Du, Yingge, and Yang, Yang. Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries. United Kingdom: N. p., 2020. Web. doi:10.1039/C9EE02657F.
Li, Zhao, Niu, Wenhan, Yang, Zhenzhong, Zaman, Nusaiba, Samarakoon, Widitha, Wang, Maoyu, Kara, Abdelkader, Lucero, Marcos, Vyas, Manasi V., Cao, Hui, Zhou, Hua, Sterbinsky, George E., Feng, Zhenxing, Du, Yingge, & Yang, Yang. Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries. United Kingdom. doi:10.1039/C9EE02657F.
Li, Zhao, Niu, Wenhan, Yang, Zhenzhong, Zaman, Nusaiba, Samarakoon, Widitha, Wang, Maoyu, Kara, Abdelkader, Lucero, Marcos, Vyas, Manasi V., Cao, Hui, Zhou, Hua, Sterbinsky, George E., Feng, Zhenxing, Du, Yingge, and Yang, Yang. Wed . "Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries". United Kingdom. doi:10.1039/C9EE02657F.
@article{osti_1577910,
title = {Stabilizing atomic Pt with trapped interstitial F in alloyed PtCo nanosheets for high-performance zinc-air batteries},
author = {Li, Zhao and Niu, Wenhan and Yang, Zhenzhong and Zaman, Nusaiba and Samarakoon, Widitha and Wang, Maoyu and Kara, Abdelkader and Lucero, Marcos and Vyas, Manasi V. and Cao, Hui and Zhou, Hua and Sterbinsky, George E. and Feng, Zhenxing and Du, Yingge and Yang, Yang},
abstractNote = {A novel strategy is designed to stabilize atomic Pt catalysts in alloyed platinum cobalt nanosheets with trapped interstitial fluorine (SA-PtCoF) for zinc-air batteries.},
doi = {10.1039/C9EE02657F},
journal = {Energy & Environmental Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
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This content will become publicly available on November 22, 2020
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Works referenced in this record:

Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
journal, October 2012

  • Wang, Deli; Xin, Huolin L.; Hovden, Robert
  • Nature Materials, Vol. 12, Issue 1, p. 81-87
  • DOI: 10.1038/nmat3458

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Projector augmented-wave method
journal, December 1994


Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
journal, January 2015

  • Nie, Yao; Li, Li; Wei, Zidong
  • Chemical Society Reviews, Vol. 44, Issue 8
  • DOI: 10.1039/C4CS00484A

Non defect-stabilized thermally stable single-atom catalyst
journal, January 2019


The Power of Single-Atom Catalysis
journal, August 2015


Advanced Architectures and Relatives of Air Electrodes in Zn-Air Batteries
journal, January 2018


An Investigation of Structure−Catalytic Activity Relationship for Pt−Co/C Bimetallic Nanoparticles toward the Oxygen Reduction Reaction
journal, October 2007

  • Hwang, Bing Joe; Kumar, Sakkarapalayam Murugesan Senthil; Chen, Ching-Hsiang
  • The Journal of Physical Chemistry C, Vol. 111, Issue 42
  • DOI: 10.1021/jp072681r

Scalable 3-D Carbon Nitride Sponge as an Efficient Metal-Free Bifunctional Oxygen Electrocatalyst for Rechargeable Zn–Air Batteries
journal, December 2016


Pt Skin on AuCu Intermetallic Substrate: A Strategy to Maximize Pt Utilization for Fuel Cells
journal, June 2014

  • Wang, Gongwei; Huang, Bing; Xiao, Li
  • Journal of the American Chemical Society, Vol. 136, Issue 27
  • DOI: 10.1021/ja503315s

Advanced zinc-air batteries based on high-performance hybrid electrocatalysts
journal, May 2013

  • Li, Yanguang; Gong, Ming; Liang, Yongye
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2812

Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction
journal, January 2018


Single-Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis
journal, September 2017


Defect-enriched iron fluoride-oxide nanoporous thin films bifunctional catalyst for water splitting
journal, May 2018


Single-Site Active Iron-Based Bifunctional Oxygen Catalyst for a Compressible and Rechargeable Zinc–Air Battery
journal, January 2018


Multicomponent electrocatalyst with ultralow Pt loading and high hydrogen evolution activity
journal, July 2018


Atomically Dispersed Copper-Platinum Dual Sites Alloyed with Palladium Nanorings Catalyze the Hydrogen Evolution Reaction
journal, November 2017

  • Chao, Tingting; Luo, Xuan; Chen, Wenxing
  • Angewandte Chemie International Edition, Vol. 56, Issue 50
  • DOI: 10.1002/anie.201709803

Influence of Fe Substitution into LaCoO 3 Electrocatalysts on Oxygen-Reduction Activity
journal, January 2019

  • Wang, Maoyu; Han, Binghong; Deng, Junjing
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 6
  • DOI: 10.1021/acsami.8b20780

Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials
journal, July 2012

  • Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter
  • ACS Catalysis, Vol. 2, Issue 8
  • DOI: 10.1021/cs3003098

Design Principles for Heteroatom-Doped Carbon Nanomaterials as Highly Efficient Catalysts for Fuel Cells and Metal-Air Batteries
journal, September 2015

  • Zhao, Zhenghang; Li, Mingtao; Zhang, Lipeng
  • Advanced Materials, Vol. 27, Issue 43
  • DOI: 10.1002/adma.201503211

Advanced hybrid Li–air batteries with high-performance mesoporous nanocatalysts
journal, January 2014

  • Li, Longjun; Chai, Song-Hai; Dai, Sheng
  • Energy & Environmental Science, Vol. 7, Issue 8
  • DOI: 10.1039/C4EE00814F

Atomic-scale cation dynamics in a monolayer VO X /α-Fe 2 O 3 catalyst
journal, January 2015


Metallic Co 4 N Porous Nanowire Arrays Activated by Surface Oxidation as Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2015

  • Chen, Pengzuo; Xu, Kun; Fang, Zhiwei
  • Angewandte Chemie International Edition, Vol. 54, Issue 49
  • DOI: 10.1002/anie.201506480

Retaining the 3D Framework of Zinc Sponge Anodes upon Deep Discharge in Zn–Air Cells
journal, October 2014

  • Parker, Joseph F.; Nelson, Eric S.; Wattendorf, Matthew D.
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 22
  • DOI: 10.1021/am505266c

Nanostructured Ti 0.7 Mo 0.3 O 2 Support Enhances Electron Transfer to Pt: High-Performance Catalyst for Oxygen Reduction Reaction
journal, August 2011

  • Ho, Van Thi Thanh; Pan, Chun-Jern; Rick, John
  • Journal of the American Chemical Society, Vol. 133, Issue 30
  • DOI: 10.1021/ja2039562

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts
journal, June 2019


Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions
journal, December 2016

  • Chen, Pengzuo; Zhou, Tianpei; Xing, Lili
  • Angewandte Chemie International Edition, Vol. 56, Issue 2
  • DOI: 10.1002/anie.201610119

3D Aluminum Hybrid Plasmonic Nanostructures with Large Areas of Dense Hot Spots and Long-Term Stability
journal, January 2017

  • Li, Xi-Mei; Bi, Ming-Hai; Cui, Lan
  • Advanced Functional Materials, Vol. 27, Issue 10
  • DOI: 10.1002/adfm.201605703

Apically Dominant Mechanism for Improving Catalytic Activities of N-Doped Carbon Nanotube Arrays in Rechargeable Zinc-Air Battery
journal, April 2018

  • Niu, Wenhan; Pakhira, Srimanta; Marcus, Kyle
  • Advanced Energy Materials, Vol. 8, Issue 20
  • DOI: 10.1002/aenm.201800480

Water splitting by electrolysis at high current densities under 1.6 volts
journal, January 2018

  • Zhou, Haiqing; Yu, Fang; Zhu, Qing
  • Energy & Environmental Science, Vol. 11, Issue 10
  • DOI: 10.1039/C8EE00927A

Competing orders and spin-density-wave instability in La(O 1−x F x )FeAs
journal, June 2008


Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics
journal, May 2017

  • Zhang, Jian; Wang, Tao; Liu, Pan
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15437

A first principles study of oxygen reduction reaction on a Pt(111) surface modified by a subsurface transition metal M (M = Ni, Co, or Fe)
journal, January 2011

  • Duan, Zhiyao; Wang, Guofeng
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 45
  • DOI: 10.1039/c1cp21687b

Enhanced electrochemical activity of Pt nanowire network electrocatalysts for methanol oxidation reaction of fuel cells
journal, January 2011