Progress in development of electrolytes for magnesium batteries

Deivanayagam, Ramasubramonian; Ingram, Brian J.; Shahbazian-Yassar, Reza

doi:10.1016/j.ensm.2019.05.028

Title: Progress in development of electrolytes for magnesium batteries

Journal Article · Tue May 21 20:00:00 EDT 2019 · Energy Storage Materials

DOI: https://doi.org/10.1016/j.ensm.2019.05.028 · OSTI ID:1572939

Deivanayagam, Ramasubramonian ^[1]; Ingram, Brian J. ^[2]; Shahbazian-Yassar, Reza ^[1]

Univ. of Illinois at Chicago, Chicago, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Over the last few years, there has been an increased interest in developing safe, next-generation battery systems that offer energy densities higher than those of lithium-based batteries. In this context, batteries based on multivalent-ions (Mg²⁺, Zn²⁺, Ca²⁺, and Al³⁺) have developed their own niche with their capability to achieve at least twice the energy density of monovalent-ion systems such as Li-ion and Na-ion batteries. Among the multivalent-ion battery candidates, magnesium (Mg) batteries appear to be the most viable choice to eventually replace the Li-ion technology because of the high electrode potential, superior safety, and high abundance of Mg-metal. However, the limited development in electrolytes and cathodes has prevented their commercialization to date. There is a lack of suitable electrolytes that can be used at high voltages required for Mg²⁺ insertion into cathode hosts. The limited compatibility of organic electrolytes with Mg-metal anode is also a challenge, which requires extensive studies of the metal/electrolyte interactions. Such studies over the last two decades were critical in developing state-of-the-art Mg electrolytes that possess voltage windows of >4.0 V and simultaneously be compatible with Mg-metal anodes. Here, we present a review on the development of Mg battery electrolytes, challenges that impede their performance, and promising strategies that have been adopted to address them. As a result, we believe that this comprehensive review covering all three categories of Mg electrolytes (liquids, polymers, and solids) would enable researchers to get a quick grasp of the prevailing challenges, and consequently motivate them to develop novel electrolyte candidates.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Joint Center for Energy Storage Research (JCESR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1572939

Journal Information:: Energy Storage Materials, Journal Name: Energy Storage Materials Journal Issue: C Vol. 21; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries Doe, Robert E.; Han, Ruoban; Hwang, Jaehee Chemical Communications, Vol. 50, Issue 2, p. 243-245 https://doi.org/10.1039/C3CC47896C	journal	January 2014
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Spinel compounds as multivalent battery cathodes: a systematic evaluation based on ab initio calculations Liu, Miao; Rong, Ziqin; Malik, Rahul Energy & Environmental Science, Vol. 8, Issue 3 https://doi.org/10.1039/C4EE03389B	journal	January 2015
A Lewis acid-free and phenolate-based magnesium electrolyte for rechargeable magnesium batteries Pan, Baofei; Zhang, Junjie; Huang, Jinhua Chemical Communications, Vol. 51, Issue 28 https://doi.org/10.1039/C5CC01225B	journal	January 2015
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Ionic liquid electrolytes for reversible magnesium electrochemistry Kar, Mega; Ma, Zheng; Azofra, Luis Miguel Chemical Communications, Vol. 52, Issue 21 https://doi.org/10.1039/C5CC09324D	journal	January 2016
Impact of intermediate sites on bulk diffusion barriers: Mg intercalation in Mg ₂ Mo ₃ O ₈ Gautam, Gopalakrishnan Sai; Sun, Xiaoqi; Duffort, Victor Journal of Materials Chemistry A, Vol. 4, Issue 45 https://doi.org/10.1039/C6TA07804D	journal	January 2016
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Magnesium Borohydride-Based Electrolytes Containing 1-butyl-1-methylpiperidinium bis(trifluoromethyl sulfonyl)imide Ionic Liquid for Rechargeable Magnesium Batteries Su, Shuojian; NuLi, Yanna; Wang, Nan Journal of The Electrochemical Society, Vol. 163, Issue 13 https://doi.org/10.1149/2.0631613jes	journal	January 2016
Theoretical Analysis on De-Solvation of Lithium, Sodium, and Magnesium Cations to Organic Electrolyte Solvents Okoshi, Masaki; Yamada, Yuki; Yamada, Atsuo Journal of The Electrochemical Society, Vol. 160, Issue 11 https://doi.org/10.1149/2.074311jes	journal	January 2013
MgCl ₂ : The Key Ingredient to Improve Chloride Containing Electrolytes for Rechargeable Magnesium-Ion Batteries Pan, Baofei; Huang, Jinhua; Sa, Niya Journal of The Electrochemical Society, Vol. 163, Issue 8 https://doi.org/10.1149/2.0821608jes	journal	January 2016
Communication—A Composite Polymer Electrolyte for Safer Mg Batteries Song, Shufeng; Kotobuki, Masashi; Zheng, Feng Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.1171704jes	journal	January 2017
Ionic Liquid as an Effective Additive for Rechargeable Magnesium Batteries Pan, Baofei; Lau, Ka-Cheong; Vaughey, John T. Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.1551704jes	journal	January 2017
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Beyond Intercalation Chemistry for Rechargeable Mg Batteries: A Short Review and Perspective Zhao-Karger, Zhirong; Fichtner, Maximilian Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00656	journal	January 2019

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Recent Development of Mg Ion Solid Electrolyte Zhan, Yi; Zhang, Wei; Lei, Bing Frontiers in Chemistry, Vol. 8 https://doi.org/10.3389/fchem.2020.00125	journal	February 2020
A high-voltage concept with sodium-ion conducting β-alumina for magnesium-sodium dual-ion batteries Kravchyk, Kostiantyn V.; Walter, Marc; Kovalenko, Maksym V. Communications Chemistry, Vol. 2, Issue 1 https://doi.org/10.1038/s42004-019-0186-4	journal	July 2019
Challenges and benefits of post-lithium-ion batteries Walter, Marc; Kovalenko, Maksym V.; Kravchyk, Kostiantyn V. New Journal of Chemistry, Vol. 44, Issue 5 https://doi.org/10.1039/c9nj05682c	journal	January 2020
Synthesis of ternary metal oxides as positive electrodes for Mg–Li hybrid ion batteries Asif, Muhammad; Rashad, Muhammad; Ali, Zeeshan Nanoscale, Vol. 12, Issue 2 https://doi.org/10.1039/c9nr08758c	journal	January 2020
A high-voltage concept with sodium-ion conducting β-alumina for magnesium-sodium dual-ion batteries Kravchyk, Kostiantyn V.; Walter, Marc; Kovalenko, Maksym V. ETH Zurich https://doi.org/10.3929/ethz-b-000361670	text	January 2019
Challenges and benefits of post-lithium-ion batteries Marc, Walter,; V., Kovalenko, Maksym; V., Kravchyk, Kostiantyn ETH Zurich https://doi.org/10.3929/ethz-b-000401213	text	January 2020

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