Magnetocaloric effect near room temperature in quintenary and sextenary Heusler alloys
Abstract
An inverse magnetocaloric effect is studied in Ni2Mn1+xX1-x-type Heusler alloys. Principally known for their shape-memory properties, these alloys also exhibit significant entropy and temperature changes (ΔS and ΔTAd, respectively) under adiabatic conditions when a modest magnetic field is applied. We investigated the impact on magnetocaloric properties of introducing substantial chemical disorder on the X-site (X=Si,Ga,In), of replacing Ni with nonmagnetic Ag, and of replacing a small amount of Mn with Gd. While a reduction in ΔS is observed in the first two cases, we observe a significant enhancement of ΔS when a small amount of Gd is substituted for Mn. A thermodynamic analysis was conducted using magnetization and heat capacity data to estimate adiabatic temperature changes in the range of ΔTAd≃ -1 to -3 K for a 5 T magnetic field. Several alloys characterized in this study exhibit these respectable ΔTAd values near room temperature, making them potentially viable candidates for magnetic refrigeration applications.
- Authors:
-
[2];
- Central Washington University, Ellensburg, WA (United States)
- Univ. of Tennessee, Knoxville, TN (United States)
- Salk Institute for Biological Studies, La Jolla, CA (United States)
- Univ. of California, San Diego, CA (United States)
- Publication Date:
- Research Org.:
- Univ. of California, San Diego, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1800179
- Alternate Identifier(s):
- OSTI ID: 1571336
- Grant/Contract Number:
- FG02-04ER46105; FG02-04-ER46105
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 126; Journal Issue: 16; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Physics; Thermodynamic properties; Calorimetry; Alloys; Entropy; Magnetism; X-ray diffraction; Polycrystalline material; Refrigerators; Phase transitions
Citation Formats
White, B. D., Barabash, R. I., Barabash, O. M., Jeon, I., and Maple, M. B. Magnetocaloric effect near room temperature in quintenary and sextenary Heusler alloys. United States: N. p., 2019.
Web. doi:10.1063/1.5120819.
White, B. D., Barabash, R. I., Barabash, O. M., Jeon, I., & Maple, M. B. Magnetocaloric effect near room temperature in quintenary and sextenary Heusler alloys. United States. https://doi.org/10.1063/1.5120819
White, B. D., Barabash, R. I., Barabash, O. M., Jeon, I., and Maple, M. B. Mon .
"Magnetocaloric effect near room temperature in quintenary and sextenary Heusler alloys". United States. https://doi.org/10.1063/1.5120819. https://www.osti.gov/servlets/purl/1800179.
@article{osti_1800179,
title = {Magnetocaloric effect near room temperature in quintenary and sextenary Heusler alloys},
author = {White, B. D. and Barabash, R. I. and Barabash, O. M. and Jeon, I. and Maple, M. B.},
abstractNote = {An inverse magnetocaloric effect is studied in Ni2Mn1+xX1-x-type Heusler alloys. Principally known for their shape-memory properties, these alloys also exhibit significant entropy and temperature changes (ΔS and ΔTAd, respectively) under adiabatic conditions when a modest magnetic field is applied. We investigated the impact on magnetocaloric properties of introducing substantial chemical disorder on the X-site (X=Si,Ga,In), of replacing Ni with nonmagnetic Ag, and of replacing a small amount of Mn with Gd. While a reduction in ΔS is observed in the first two cases, we observe a significant enhancement of ΔS when a small amount of Gd is substituted for Mn. A thermodynamic analysis was conducted using magnetization and heat capacity data to estimate adiabatic temperature changes in the range of ΔTAd≃ -1 to -3 K for a 5 T magnetic field. Several alloys characterized in this study exhibit these respectable ΔTAd values near room temperature, making them potentially viable candidates for magnetic refrigeration applications.},
doi = {10.1063/1.5120819},
journal = {Journal of Applied Physics},
number = 16,
volume = 126,
place = {United States},
year = {Mon Oct 28 00:00:00 EDT 2019},
month = {Mon Oct 28 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 11 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Giant inverse magnetocaloric effect near room temperature in Co substituted NiMnSb Heusler alloys
journal, January 2009
- Nayak, Ajaya K.; Suresh, K. G.; Nigam, A. K.
- Journal of Physics D: Applied Physics, Vol. 42, Issue 3
Improved magnetostructural and magnetocaloric reversibility in magnetic Ni-Mn-In shape-memory Heusler alloy by optimizing the geometric compatibility condition
journal, June 2019
- Devi, P.; Mejía, C. Salazar; Zavareh, M. Ghorbani
- Physical Review Materials, Vol. 3, Issue 6
Caloric and Multicaloric Effects in Shape Memory Alloys
journal, January 2015
- Planes, A.; Stern-Taulats, E.; Castán, T.
- Materials Today: Proceedings, Vol. 2
Implicit measurement of the latent heat in a magnetocaloric NiMnIn Heusler alloy
journal, May 2013
- Ghahremani, Mohammadreza; ElBidweihy, Hatem; Bennett, Lawrence H.
- Journal of Applied Physics, Vol. 113, Issue 17
Giant magnetocaloric effect driven by structural transitions
journal, May 2012
- Liu, Jian; Gottschall, Tino; Skokov, Konstantin P.
- Nature Materials, Vol. 11, Issue 7
Large inverse magnetocaloric effect in Ni48.5−Co Mn37Sn14.5 (x= 0, 1 and 2) with negligible hysteresis
journal, December 2013
- Ghosh, Arup; Mandal, Kalyan
- Journal of Alloys and Compounds, Vol. 579
Correlation between microstructure and martensitic transformation, mechanical properties and elastocaloric effect in Ni–Mn-based alloys
journal, October 2019
- Huang, Xiao-Ming; Wang, Lu-Da; Liu, Hao-Xuan
- Intermetallics, Vol. 113
Influence of Sb on the magnetic and magnetocaloric properties of ferromagnetic shape memory alloy NiMnIn
journal, February 2009
- Liu, Z. H.; Aksoy, S.; Acet, M.
- Journal of Applied Physics, Vol. 105, Issue 3
Martensitic transition near room temperature and the temperature- and magnetic-field-induced multifunctional properties of alloy
journal, November 2010
- Sharma, V. K.; Chattopadhyay, M. K.; Khandelwal, A.
- Physical Review B, Vol. 82, Issue 17
Role of Ge in Bridging Ferromagnetism in the Giant Magnetocaloric Alloys
journal, June 2007
- Haskel, D.; Lee, Y. B.; Harmon, B. N.
- Physical Review Letters, Vol. 98, Issue 24
Martensitic Transformation and Shape Memory Effect of NiCoMnSn High Temperature Shape Memory Alloy
journal, September 2012
- Chen, F.; Tong, Y. X.; Lu, X. L.
- Journal of Materials Engineering and Performance, Vol. 21, Issue 12
Magnetic properties and martensitic transformation in quaternary Heusler alloy of NiMnFeGa
journal, November 2002
- Liu, Z. H.; Zhang, M.; Wang, W. Q.
- Journal of Applied Physics, Vol. 92, Issue 9
Direct measurements of the magnetocaloric effect in pulsed magnetic fields: The example of the Heusler alloy Ni 50 Mn 35 In 15
journal, February 2015
- Ghorbani Zavareh, M.; Salazar Mejía, C.; Nayak, A. K.
- Applied Physics Letters, Vol. 106, Issue 7
The magnetocaloric effect in Fe49Rh51 compound
journal, August 1990
- Nikitin, S. A.; Myalikgulyev, G.; Tishin, A. M.
- Physics Letters A, Vol. 148, Issue 6-7
The effect of partial substitution of In by X = Si, Ge and Al on the crystal structure, magnetic properties and resistivity of Ni 50 Mn 35 In 15 Heusler alloys
journal, January 2009
- Pathak, Arjun Kumar; Dubenko, Igor; Mabon, James C.
- Journal of Physics D: Applied Physics, Vol. 42, Issue 4
Effect of partial substitution of In with Mn on the structural, magnetic, and magnetocaloric properties of Ni 2 Mn 1+ x In 1− x Heusler alloys
journal, August 2019
- Dahal, Bishnu; Huber, Carter; Zhang, Wenyong
- Journal of Physics D: Applied Physics, Vol. 52, Issue 42
Magnetocaloric effect: From materials research to refrigeration devices
journal, April 2018
- Franco, V.; Blázquez, J. S.; Ipus, J. J.
- Progress in Materials Science, Vol. 93
Nonvolatile manipulation of the magnetocaloric effect in Ni43Co7Mn39Sn11/(011)PMN-PT composite by electric fields
journal, July 2019
- Zhao, Xiaoyu; Wen, Jiahong; Gong, Yuanyuan
- Scripta Materialia, Vol. 167
Experimental Study of Magnetocaloric Effect in Ni-Fe-Mn-Ga and Ni-Co-Mn-Ga Heusler Alloys
journal, January 2013
- Fayzullin, Rafael; Buchelnikov, Vasiliy D.; Taskaev, Sergey
- Materials Science Forum, Vol. 738-739
Inverse magnetocaloric effect in ferromagnetic Ni50Mn37+xSb13−x Heusler alloys
journal, March 2007
- Khan, Mahmud; Ali, Naushad; Stadler, Shane
- Journal of Applied Physics, Vol. 101, Issue 5
Magnetic field-induced martensite–austenite transformation in Fe-substituted NiMnGa ribbons
journal, June 2011
- Yu, S. Y.; Yan, S. S.; Kang, S. S.
- Scripta Materialia, Vol. 65, Issue 1
Improved magnetostructural and magnetocaloric reversibility in magnetic Ni-Mn-In shape-memory Heusler alloy by optimizing the geometric compatibility condition
text, January 2019
- Devi, P.; Mejía, C. Salazar; Zavareh, M. Ghorbani
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Kinetic arrest behavior in martensitic transformation of NiCoMnSn metamagnetic shape memory alloy
journal, February 2011
- Umetsu, R. Y.; Ito, K.; Ito, W.
- Journal of Alloys and Compounds, Vol. 509, Issue 5
Giant Magnetoresistance and Magnetocaloric Effects of the Mn1.82V0.18Sb Compound.
journal, March 2005
- Zhang, Yu Qin; Zhang, Zhi Dong
- ChemInform, Vol. 36, Issue 10
NiMn-based Heusler magnetic shape memory alloys: a review
journal, April 2019
- Bachaga, T.; Zhang, J.; Khitouni, M.
- The International Journal of Advanced Manufacturing Technology, Vol. 103, Issue 5-8
Platinum as a Thermal Conductivity Standard
journal, February 1964
- Slack, Glen A.
- Journal of Applied Physics, Vol. 35, Issue 2
Direct measurements of the magnetocaloric effect in pulsed magnetic fields: The example of the Heusler alloy Ni$_{50}$Mn$_{35}$In$_{15}$
text, January 2015
- Zavareh, M. Ghorbani; Mejía, C. Salazar; Nayak, A. K.
- arXiv
The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models
journal, August 2012
- Franco, V.; Blázquez, J. S.; Ingale, B.
- Annual Review of Materials Research, Vol. 42, Issue 1
Martensitic transformations and magnetocaloric effect in Sn-doped NiMnIn shape memory alloy
journal, November 2012
- Dwevedi, Sandhya; Tiwari, Brajesh
- Journal of Alloys and Compounds, Vol. 540
Outstanding role of the magnetic entropy in arrested austenite in an ordered Ni45Mn36.7In13.3Co5 metamagnetic shape memory alloy
journal, July 2019
- Pérez-Landazábal, J. I.; Recarte, V.; Sánchez-Alarcos, V.
- Scripta Materialia, Vol. 168
Giant magnetoresistance and magnetocaloric effects of the Mn1.82V0.18Sb compound
journal, February 2004
- Zhang, Yu Qin; Zhang, Zhi Dong
- Journal of Alloys and Compounds, Vol. 365, Issue 1-2
Caloric Effects in Ferroic Materials: New Concepts for Cooling
journal, November 2011
- Fähler, Sebastian; Rößler, Ulrich K.; Kastner, Oliver
- Advanced Engineering Materials, Vol. 14, Issue 1-2
Giant magnetocaloric effect from reverse martensitic transformation in Ni–Mn–Ga–Cu ferromagnetic shape memory alloys
journal, June 2016
- Sarkar, Sudip Kumar; Babu, P. D.
- Journal of Alloys and Compounds, Vol. 670
Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys
journal, May 2005
- Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet
- Nature Materials, Vol. 4, Issue 6
Recent developments in magnetocaloric materials
journal, May 2005
- Gschneidner, K. A.; Pecharsky, V. K.; Tsokol, A. O.
- Reports on Progress in Physics, Vol. 68, Issue 6, p. 1479-1539
Tuning the magnetic and magnetocaloric properties of austenitic Ni-Mn-(In,Sn) Heuslers
journal, September 2019
- Cavazzini, G.; Cugini, F.; Gruner, M. E.
- Scripta Materialia, Vol. 170
Large magnetoresistance associated with large inverse magnetocaloric effect in Ni-Co-Mn-Sn alloys
journal, September 2013
- Ghosh, Arup; Mandal, Kalyan
- The European Physical Journal B, Vol. 86, Issue 9
Ambient pressure colossal magnetocaloric effect tuned by composition in Mn1−xFe x As
journal, September 2006
- de Campos, Ariana; Rocco, Daniel L.; Carvalho, Alexandre Magnus G.
- Nature Materials, Vol. 5, Issue 10
Direct and inverse magnetocaloric effect in Ni1.81Mn1.64In0.55, Ni1.73Mn1.80In0.47, and Ni1.72Mn1.51In0.49Co0.28 Heusler alloys
journal, October 2016
- Fayzullin, R. R.; Mashirov, A. V.; Buchelnikov, V. D.
- Journal of Communications Technology and Electronics, Vol. 61, Issue 10
Martensitic transformation in Cu-doped NiMnGa magnetic shape memory alloys
journal, February 2011
- Li, Pan-Pan; Wang, Jing-Min; Jiang, Cheng-Bao
- Chinese Physics B, Vol. 20, Issue 2
Field and Temperature Induced Magnetic Transition in : A Giant Magnetocaloric Material
journal, March 2003
- Ryan, D. H.; Elouneg-Jamróz, Miryam; van Lierop, J.
- Physical Review Letters, Vol. 90, Issue 11
Tunable magnetic regenerator alloys with a giant magnetocaloric effect for magnetic refrigeration from ∼20 to ∼290 K
journal, June 1997
- Pecharsky, V. K.; Gschneidner, K. A.
- Applied Physics Letters, Vol. 70, Issue 24
Large reversible magnetocaloric effect in Ni-Mn-In-Co
journal, January 2015
- Gottschall, Tino; Skokov, Konstantin P.; Frincu, Bianca
- Applied Physics Letters, Vol. 106, Issue 2
Pressure induced martensitic transition, magnetocaloric and magneto-transport properties in Mn-Ni-Sn Heusler alloy
journal, October 2019
- Sharma, Jyoti; Coelho, A. A.; Repaka, D. V. M.
- Journal of Magnetism and Magnetic Materials, Vol. 487
Magnetic-phase transitions and magnetocaloric effects
journal, July 2002
- Tegus, O.; Brück, E.; Zhang, L.
- Physica B: Condensed Matter, Vol. 319, Issue 1-4
On the S(T) diagram of magnetocaloric materials with first-order transition: Kinetic and cyclic effects of Heusler alloys
journal, April 2016
- Gottschall, Tino; Skokov, Konstantin P.; Burriel, Ramon
- Acta Materialia, Vol. 107
First principles approach to the magneto caloric effect: Application toNi 2 MnGa
journal, April 2011
- Nicholson, D. M.; Odbadrakh, Kh.; Rusanu, A.
- Journal of Applied Physics, Vol. 109, Issue 7
Magnetostructural transition and magnetocaloric effect in single crystals
journal, September 2005
- Pasquale, M.; Sasso, C. P.; Lewis, L. H.
- Physical Review B, Vol. 72, Issue 9
Fe substitution induced intermartensitic transition and its internal stress dependent transforming behavior in Ni–Mn–Ga based alloy
journal, December 2013
- Huang, Chonghui; Wang, Yu; Wu, Haijun
- Journal of Alloys and Compounds, Vol. 581
On the nature of the magnetocaloric effect of the first-order magnetostructural transition
journal, September 2012
- Gschneidner, K. A.; Mudryk, Y.; Pecharsky, V. K.
- Scripta Materialia, Vol. 67, Issue 6
Multiscale twin hierarchy in NiMnGa shape memory alloys with Fe and Cu
journal, April 2015
- Barabash, Rozaliya I.; Barabash, Oleg M.; Popov, Dmitry
- Acta Materialia, Vol. 87
Elevating the temperature regime of the large magnetocaloric effect in a Ni–Mn–In alloy towards room temperature
journal, March 2011
- Sharma, V. K.; Chattopadhyay, M. K.; Sharath Chandra, L. S.
- Journal of Physics D: Applied Physics, Vol. 44, Issue 14
Giant Magnetocaloric Effect in
journal, June 1997
- Pecharsky, V. K.; Gschneidner, Jr., K. A.
- Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497
Giant solid-state barocaloric effect in the Ni–Mn–In magnetic shape-memory alloy
journal, April 2010
- Mañosa, Lluís; González-Alonso, David; Planes, Antoni
- Nature Materials, Vol. 9, Issue 6
Giant low-field magnetocaloric effect in a textured Ni45.3Co5.1Mn36.1In13.5 alloy
journal, July 2018
- Li, Zhenzhuang; Li, Zongbin; Yang, Bo
- Scripta Materialia, Vol. 151
Multiscale origin of the magnetocaloric effect in Ni-Mn-Ga shape-memory alloys
journal, September 2003
- Marcos, Jordi; Mañosa, Lluís; Planes, Antoni
- Physical Review B, Vol. 68, Issue 9
Exchange Bias and Inverse Magnetocaloric Effect in Co and Mn Co-Doped Ni2MnGa Shape Memory Alloy
journal, January 2013
- Wang, Baomin; Liu, Yong
- Metals, Vol. 3, Issue 1
Low-field-actuated giant magnetocaloric effect and excellent mechanical properties in a NiMn-based multiferroic alloy
journal, March 2018
- Cong, D. Y.; Huang, L.; Hardy, V.
- Acta Materialia, Vol. 146
Hysteresis effects in the inverse magnetocaloric effect in martensitic Ni-Mn-In and Ni-Mn-Sn
journal, October 2012
- Titov, I.; Acet, M.; Farle, M.
- Journal of Applied Physics, Vol. 112, Issue 7
Critical examination of heat capacity measurements made on a Quantum Design physical property measurement system
journal, June 2003
- Lashley, J. C.; Hundley, M. F.; Migliori, A.
- Cryogenics, Vol. 43, Issue 6
Enhanced magnetocaloric effect in Ni-Mn-Sn-Co alloys with two successive magnetostructural transformations
journal, May 2018
- Zhang, Xuexi; Zhang, Hehe; Qian, Mingfang
- Scientific Reports, Vol. 8, Issue 1
Caloric Effects in Ferroic Materials: New Concepts for Cooling
journal, February 2012
- Fähler, Sebastian; Rößler, Ulrich K.; Kastner, Oliver
- Advanced Engineering Materials, Vol. 14, Issue 1-2
Giant reversible magnetocaloric effect in MnNiGe-based materials: Minimizing thermal hysteresis via crystallographic compatibility modulation
journal, August 2019
- Liu, Jun; Gong, Yuanyuan; You, Yurong
- Acta Materialia, Vol. 174
Massive Magnetic-Field-Induced Structural Transformation in and the Nature of the Giant Magnetocaloric Effect
journal, November 2003
- Pecharsky, V. K.; Holm, A. P.; Gschneidner, K. A.
- Physical Review Letters, Vol. 91, Issue 19
Pressure-Induced Colossal Magnetocaloric Effect in MnAs
journal, November 2004
- Gama, Sergio; Coelho, Adelino A.; de Campos, Ariana
- Physical Review Letters, Vol. 93, Issue 23