Understanding How Structure and Crystallinity Affect Performance in Solid-State Batteries Using a Glass Ceramic LiV3O8 Cathode
Abstract
The rate-limiting step in lithiation/delithiation of solid-state cathode materials is not well understood. Phase-transformation reaction rate, lithium ion diffusion coefficient, and lithium ion concentration have all been shown to affect the discharge and charge performance. All three parameters are affected by the crystal structure and crystallinity of the cathode. In this paper, lithium trivanadate (LiV3O8) is selected as a representative cathode for all solid-state thin-film batteries because of its glass ceramic properties at different annealing temperatures, where the crystallinity and preferred orientation vary. The intermediate temperature-treated thin films outperform both the amorphous and the most crystalline thin films. By correlating the cell polarization with both the diffusion coefficient and the lithium ion concentration at different states of charge, we gain insights into the electrochemical performance of the glass ceramic LiV3O8 cathode.
- Authors:
-
[1];
[2];
[3];
[1];
[2];
[1]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Stony Brook Univ., Stony Brook, NY (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1560476
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry of Materials
- Additional Journal Information:
- Journal Volume: 31; Journal Issue: 16; Journal ID: ISSN 0897-4756
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Zhang, Yiman, Marschilok, Amy C., Takeuchi, Kenneth J., Kercher, Andrew K., Takeuchi, Esther S., and Dudney, Nancy J. Understanding How Structure and Crystallinity Affect Performance in Solid-State Batteries Using a Glass Ceramic LiV3O8 Cathode. United States: N. p., 2019.
Web. doi:10.1021/acs.chemmater.9b01571.
Zhang, Yiman, Marschilok, Amy C., Takeuchi, Kenneth J., Kercher, Andrew K., Takeuchi, Esther S., & Dudney, Nancy J. Understanding How Structure and Crystallinity Affect Performance in Solid-State Batteries Using a Glass Ceramic LiV3O8 Cathode. United States. https://doi.org/10.1021/acs.chemmater.9b01571
Zhang, Yiman, Marschilok, Amy C., Takeuchi, Kenneth J., Kercher, Andrew K., Takeuchi, Esther S., and Dudney, Nancy J. Tue .
"Understanding How Structure and Crystallinity Affect Performance in Solid-State Batteries Using a Glass Ceramic LiV3O8 Cathode". United States. https://doi.org/10.1021/acs.chemmater.9b01571. https://www.osti.gov/servlets/purl/1560476.
@article{osti_1560476,
title = {Understanding How Structure and Crystallinity Affect Performance in Solid-State Batteries Using a Glass Ceramic LiV3O8 Cathode},
author = {Zhang, Yiman and Marschilok, Amy C. and Takeuchi, Kenneth J. and Kercher, Andrew K. and Takeuchi, Esther S. and Dudney, Nancy J.},
abstractNote = {The rate-limiting step in lithiation/delithiation of solid-state cathode materials is not well understood. Phase-transformation reaction rate, lithium ion diffusion coefficient, and lithium ion concentration have all been shown to affect the discharge and charge performance. All three parameters are affected by the crystal structure and crystallinity of the cathode. In this paper, lithium trivanadate (LiV3O8) is selected as a representative cathode for all solid-state thin-film batteries because of its glass ceramic properties at different annealing temperatures, where the crystallinity and preferred orientation vary. The intermediate temperature-treated thin films outperform both the amorphous and the most crystalline thin films. By correlating the cell polarization with both the diffusion coefficient and the lithium ion concentration at different states of charge, we gain insights into the electrochemical performance of the glass ceramic LiV3O8 cathode.},
doi = {10.1021/acs.chemmater.9b01571},
journal = {Chemistry of Materials},
number = 16,
volume = 31,
place = {United States},
year = {Tue Jul 23 00:00:00 EDT 2019},
month = {Tue Jul 23 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 9 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:
Figure 1: (a) The circuit used for the EIS fitting (b) Nyquist plot of LVO260 at 2.7 V for test T = 25, 45 and 60°C, where the end point is at 0.1 mHz (c) Zoom in to 1400 Ohm for axis. The frequency of last point in the graphmore »
All figures and tables
(8 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
The quenching and electrochemical behavior of Li2OV2O5 glasses
journal, June 1981
- Nassau, K.; Murphy, D. W.
- Journal of Non-Crystalline Solids, Vol. 44, Issue 2-3
A large capacity of LiV3O8 cathode material for rechargeable lithium-based batteries
journal, January 2011
- Liu, Haimei; Wang, Yonggang; Yang, Wensheng
- Electrochimica Acta, Vol. 56, Issue 3
LiV 3 O 8 nanorods as cathode materials for high-power and long-life rechargeable lithium-ion batteries
journal, January 2014
- Mei, Peng; Wu, Xing-Long; Xie, Haiming
- RSC Adv., Vol. 4, Issue 49
High capacity lithium-ion battery cathode using LiV3O8 nanorods
journal, June 2013
- Sarkar, Sudeep; Banda, Harish; Mitra, Sagar
- Electrochimica Acta, Vol. 99
Phase Transition, Electrochemistry, and Structural Studies of High Rate Li x V 3 O 8 Cathode with Nanoplate Morphology
journal, October 2013
- Sarkar, S.; Bhowmik, Arghya; Dixit Bharadwaj, Mridula
- Journal of The Electrochemical Society, Vol. 161, Issue 1
Nanosheet-structured LiV3O8 with high capacity and excellent stability for high energy lithium batteries
journal, January 2011
- Pan, Anqiang; Zhang, Ji-Guang; Cao, Guozhong
- Journal of Materials Chemistry, Vol. 21, Issue 27
An amorphous wrapped nanorod LiV3O8 electrode with enhanced performance for lithium ion batteries
journal, January 2012
- Shi, Qian; Liu, Jiangwen; Hu, Renzong
- RSC Advances, Vol. 2, Issue 18
Li x V 2 O 5 /LiV 3 O 8 nanoflakes with significantly improved electrochemical performance for Li-ion batteries
journal, January 2014
- Sun, Dan; Jin, Guanhua; Wang, Haiyan
- J. Mater. Chem. A, Vol. 2, Issue 21
High Rate and Stable Li-Ion Insertion in Oxygen-Deficient LiV 3 O 8 Nanosheets as a Cathode Material for Lithium-Ion Battery
journal, January 2017
- Song, Huanqiao; Luo, Mingsheng; Wang, Aimei
- ACS Applied Materials & Interfaces, Vol. 9, Issue 3
A combined X-ray and neutron Rietveld study of the chemically lithiated electrode materials Li2.7V3O8 and Li4.8V3O8
journal, January 2005
- Jouanneau, S.; Verbaere, A.; Guyomard, D.
- Journal of Solid State Chemistry, Vol. 178, Issue 1
Investigation of Structural Evolution of Li 1.1 V 3 O 8 by In Situ X-ray Diffraction and Density Functional Theory Calculations
journal, February 2017
- Zhang, Qing; Brady, Alexander B.; Pelliccione, Christopher J.
- Chemistry of Materials, Vol. 29, Issue 5
Discharge, Relaxation, and Charge Model for the Lithium Trivanadate Electrode: Reactions, Phase Change, and Transport
journal, January 2016
- Brady, Nicholas W.; Zhang, Qing; Knehr, K. W.
- Journal of The Electrochemical Society, Vol. 163, Issue 14
Operando Study of LiV 3 O 8 Cathode: Coupling EDXRD Measurements to Simulations
journal, January 2018
- Brady, Nicholas W.; Zhang, Qing; Bruck, Andrea
- Journal of The Electrochemical Society, Vol. 165, Issue 2
Impact of Synthesis Method on Phase Transformations of Layered Lithium Vanadium Oxide upon Electrochemical (De)lithiation
journal, January 2019
- Zhang, Qing; Yue, Shiyu; Quilty, Calvin D.
- Journal of The Electrochemical Society, Vol. 166, Issue 4
Lattice orientation control of lithium cobalt oxide cathode film for all-solid-state thin film batteries
journal, March 2013
- Yoon, Yongsub; Park, Chanhwi; Kim, Junghoon
- Journal of Power Sources, Vol. 226
A diffusion kinetics study of Li-ion in LiV3O8 thin film electrode
journal, September 2010
- Shi, Qian; Hu, Renzong; Zeng, Meiqin
- Electrochimica Acta, Vol. 55, Issue 22
The cycle performance and capacity fading mechanism of a LiV3O8 thin-film electrode with a mixed amorphous-nanocrystalline microstructure
journal, October 2011
- Shi, Qian; Hu, Renzong; Zeng, Meiqin
- Electrochimica Acta, Vol. 56, Issue 25
Sol–gel fabrication and lithium insertion kinetics of the Mo-doped lithium vanadium oxide thin films Li1+xMoyV3−yO8
journal, November 2002
- Pouchko, S.
- Solid State Ionics, Vol. 151, Issue 1-4
The fluctuation-dissipation theorem
journal, January 1966
- Kubo, R.
- Reports on Progress in Physics, Vol. 29, Issue 1
Designing the next generation high capacity battery electrodes
journal, January 2014
- Yu, H. -C.; Ling, C.; Bhattacharya, J.
- Energy & Environmental Science, Vol. 7, Issue 5
Structural properties of Li1+xV3O8 upon lithium insertion at ambient and high temperature
journal, March 1998
- Kawakita, J.
- Solid State Ionics, Vol. 107, Issue 1-2
Lithium insertion and extraction kinetics of Li1+xV3O8
journal, October 1999
- Kawakita, Jin; Miura, Takashi; Kishi, Tomiya
- Journal of Power Sources, Vol. 83, Issue 1-2
Electrode kinetics in poly(ethylene oxide)-based electrolytes
journal, July 1987
- Bonino, F.; Ottaviani, M.; Scrosati, B.
- Journal of Power Sources, Vol. 20, Issue 3-4
A Polymeric Electrolyte Rechargeable Lithium Battery
journal, January 1988
- Bonino, F.; Ottaviani, M.; Scrosati, B.
- Journal of The Electrochemical Society, Vol. 135, Issue 1
The Li/LiV3O8 polymer electrolyte lithium battery III. Investigation of the electrode interfaces
journal, November 1988
- Scrosati, Bruno; Selvaggi, Alessandro; Croce, Fausto
- Journal of Power Sources, Vol. 24, Issue 4
All solid state Li-Li1+x V3O8 secondary batteries
journal, December 1988
- Hammou, A.; Hammouche, A.
- Electrochimica Acta, Vol. 33, Issue 12
A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride
journal, January 1997
- Yu, Xiaohua; Bates, J. B.; Jellison, G. E.
- Journal of The Electrochemical Society, Vol. 144, Issue 2, p. 524-532
Resolving the Amorphous Structure of Lithium Phosphorus Oxynitride (Lipon)
journal, July 2018
- Lacivita, Valentina; Westover, Andrew S.; Kercher, Andrew
- Journal of the American Chemical Society, Vol. 140, Issue 35
Structural and Compositional Factors That Control the Li-Ion Conductivity in LiPON Electrolytes
journal, September 2018
- Lacivita, Valentina; Artrith, Nongnuch; Ceder, Gerbrand
- Chemistry of Materials, Vol. 30, Issue 20
Rechargeable thin-film lithium batteries
journal, May 1994
- Bates, J.; Gruzalski, G.; Dudney, N.
- Solid State Ionics, Vol. 70-71
Thin Film Rechargeable Lithium Batteries for Implantable Devices
journal, January 1997
- Bates, John B.; Dudney, Nancy J.
- ASAIO Journal, Vol. 43, Issue 5
Nanocrystalline Li[sub x]Mn[sub 2−y]O[sub 4] Cathodes for Solid-State Thin-Film Rechargeable Lithium Batteries
journal, January 1999
- Dudney, N. J.
- Journal of The Electrochemical Society, Vol. 146, Issue 7
Nano-sized copper tungstate thin films as positive electrodes for rechargeable Li batteries
journal, May 2008
- Li, Chi-Lin; Fu, Zheng-Wen
- Electrochimica Acta, Vol. 53, Issue 12
Sputter deposited LiPON thin films from powder target as electrolyte for thin film battery applications
journal, March 2011
- Nimisha, C. S.; Rao, K. Yellareswar; Venkatesh, G.
- Thin Solid Films, Vol. 519, Issue 10
High-Voltage Cycling Behavior of Thin-Film LiCoO[sub 2] Cathodes
journal, January 2002
- Jang, Young-Il; Dudney, Nancy J.; Blom, Douglas A.
- Journal of The Electrochemical Society, Vol. 149, Issue 11
Synthesis of Ni-Rich Thin-Film Cathode as Model System for Lithium Ion Batteries
journal, January 2019
- Phillip, Nathan D.; Ruther, Rose E.; Sang, Xiahan
- ACS Applied Energy Materials, Vol. 2, Issue 2
High temperature property of all-solid-state thin film lithium battery using LiPON electrolyte
journal, November 2014
- Li, Dezhan; Ma, Zhongyun; Xu, Jing
- Materials Letters, Vol. 134
Preferred Orientation of Polycrystalline LiCoO[sub 2] Films
journal, January 2000
- Bates, J. B.; Dudney, N. J.; Neudecker, B. J.
- Journal of The Electrochemical Society, Vol. 147, Issue 1
Application of A-C Techniques to the Study of Lithium Diffusion in Tungsten Trioxide Thin Films
journal, January 1980
- Ho, C.
- Journal of The Electrochemical Society, Vol. 127, Issue 2
Electrochemically Induced Phase Evolution of Lithium Vanadium Oxide: Complementary Insights Gained via Ex-Situ , In-Situ , and Operando Experiments and Density Functional Theory
journal, January 2018
- Yin, Jiefu; Li, Wenzao; Dunkin, Mikaela
- MRS Advances, Vol. 3, Issue 22
Size-dependent kinetics during non-equilibrium lithiation of nano-sized zinc ferrite
journal, January 2019
- Li, Jing; Meng, Qingping; Zhang, Yiman
- Nature Communications, Vol. 10, Issue 1
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.