Influence of temperature on gas transport properties of tetraaminodiphenylsulfone (TADPS) based polybenzimidazoles

doi:10.1016/j.memsci.2019.117427

Title: Influence of temperature on gas transport properties of tetraaminodiphenylsulfone (TADPS) based polybenzimidazoles

Full Record
Other Related Research

Authors:: Stevens, Kevin A.; Moon, Joshua D.; Borjigin, Hailun; Liu, Ran; Joseph, Ronald M.; Riffle, Judy S.; Freeman, Benny D.

Publication Date:: 2020-01-01

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1560328

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Membrane Science

Additional Journal Information:: Journal Name: Journal of Membrane Science Journal Volume: 593 Journal Issue: C; Journal ID: ISSN 0376-7388

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Stevens, Kevin A., Moon, Joshua D., Borjigin, Hailun, Liu, Ran, Joseph, Ronald M., Riffle, Judy S., and Freeman, Benny D. Influence of temperature on gas transport properties of tetraaminodiphenylsulfone (TADPS) based polybenzimidazoles.  Netherlands: N. p., 2020. 
        Web.  doi:10.1016/j.memsci.2019.117427.

Copy to clipboard


                    Stevens, Kevin A., Moon, Joshua D., Borjigin, Hailun, Liu, Ran, Joseph, Ronald M., Riffle, Judy S., & Freeman, Benny D. Influence of temperature on gas transport properties of tetraaminodiphenylsulfone (TADPS) based polybenzimidazoles.  Netherlands.  doi:10.1016/j.memsci.2019.117427.

Copy to clipboard


                    Stevens, Kevin A., Moon, Joshua D., Borjigin, Hailun, Liu, Ran, Joseph, Ronald M., Riffle, Judy S., and Freeman, Benny D. Wed .  
        "Influence of temperature on gas transport properties of tetraaminodiphenylsulfone (TADPS) based polybenzimidazoles".  Netherlands.  doi:10.1016/j.memsci.2019.117427.

Copy to clipboard


                    
@article{osti_1560328,

  title        = {Influence of temperature on gas transport properties of tetraaminodiphenylsulfone (TADPS) based polybenzimidazoles},

  author       = {Stevens, Kevin A. and Moon, Joshua D. and Borjigin, Hailun and Liu, Ran and Joseph, Ronald M. and Riffle, Judy S. and Freeman, Benny D.},

  abstractNote = {},

  doi          = {10.1016/j.memsci.2019.117427},

  journal      = {Journal of Membrane Science},

  number       = C,

  volume       = 593,

  place        = {Netherlands},

  year         = {2020},

  month        = {1}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: 10.1016/j.memsci.2019.117427

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 6 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Prediction of Performance Variation Caused by Manufacturing Tolerances and Defects in Gas Diffusion Electrodes of Phosphoric Acid (PA)–Doped Polybenzimidazole (PBI)-Based High-Temperature Proton Exchange Membrane Fuel Cells

Journal Article Gurau, Vladimir ; De Castro, Emory - Energies (Basel)

The automated process of coating catalyst layers on gas diffusion electrodes (GDEs) for high-temperature proton exchange membrane fuel cells results inherently into a number of defects. These defects consist of agglomerates in which the platinum sites cannot be accessed by phosphoric acid and which are the consequence of an inconsistent coating, uncoated regions, scratches, knots, blemishes, folds, or attached fine particles—all ranging from μm to mm size. These electrochemically inactive spots cause a reduction of the effective catalyst area per unit volume (cm2/cm3) and determine a drop in fuel cell performance. A computational fluid dynamics (CFD) model is presented thatmore »« less
Cited by 1
DOI: 10.3390/en13061345
Polybenzimidazole based random copolymers containing hexafluoroisopropylidene functional groups for gas separations at elevated temperatures

Journal Article Singh, Rajinder Pal ; Li, Xin ; Dudeck, Kevin Wade ; ... - Polymer

Polybenzimidazoles (PBIs) are attractive membrane materials for H₂/CO₂ separation at hydrocarbon fuel derived synthesis gas operating conditions due to their exceptional physicochemical stability and promising permselectivity character. PBI molecular structure modification is a viable approach to disrupt chain packing altering the free-volume architecture which results in improved gas transport characteristics. This work is focused on the synthesis and characterization of novel PBI random copolymers for application as elevated temperature H₂/CO₂ membranes. The co-polymerization route is expected to result in tailorable permeability and selectivity by combining the high H₂ permeability aspect of the highly disrupted loosely packed hexafluoroisopropylidene diphenyl group containingmore »« less
Cited by 6
DOI: 10.1016/j.polymer.2017.04.075

Full Text Available
Influence of toluene on CO2 and CH4 gas transport properties in thermally rearranged (TR) polymers based on 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA)

Journal Article Liu, Qiang ; Galizia, Michele ; Gleason, Kristofer L. ; ... - Journal of Membrane Science
Cited by 5
DOI: 10.1016/j.memsci.2016.04.043
Development of Polybenzimidazole-Based High-Temperature Membrane and Electrode Assemblies for Stationary and Automotive Applications

Technical Report Vogel, John A

The program began on August 1, 2003 and ended on July 31, 2007. The goal of the project was to optimize a high-temperature polybenzimidazole (PBI) membrane to meet the performance, durability, and cost targets required for stationary fuel cell applications. These targets were identified in the Fuel Cell section (3.4) of DOE’s Hydrogen, Fuel Cells and Infrastructure Technologies Program Multi-Year Research, Development and Demonstration Plan. A membrane that operates at high temperatures is important to the fuel cell industry because it is insensitive to carbon monoxide (a poison to low-temperature fuel cells), and does not require complex water management strategies.more »« less
DOI: 10.2172/936594

Full Text Available
Polybenzimidazole (PBI)-Based Membrane Materials for High Temperature H2/CO2 Separation

Conference Li, Xi ; Singh, Rajinder P ; Dudeck, Kevin Wade ; ...
Full Text Available

Similar Records