DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Factors Controlling Short-Range Methane Migration of Gas Hydrate Accumulations in Thin Coarse-Grained Layers

Abstract

Natural gas hydrate is often found in marine sediment in heterogeneous distributions in different sediment types. Diffusion may be a dominant mechanism for methane migration and affect hydrate distribution. We use a 1–D advection–diffusion–reaction model to understand hydrate distribution in and surrounding thin coarse–grained layers to examine the sensitivity of four controlling factors in a diffusion–dominant gas hydrate system. These factors are the particulate organic carbon content at seafloor, the microbial reaction rate constant, the sediment grading pattern, and the cementation factor of the coarse–grained layer. We use available data at Walker Ridge 313 in the northern Gulf of Mexico where two ~3–m–thick hydrate–bearing coarse–grained layers were observed at different depths. The results show that the hydrate volume and the total amount of methane within thin, coarse–grained layers are most sensitive to the particulate organic carbon of fine–grained sediments when deposited at the seafloor. The thickness of fine–grained hydrate free zones surrounding the coarse–grained layers is most sensitive to the microbial reaction rate constant. Furthermore, it may be possible to estimate microbial reaction rate constants at other locations by studying the thickness of the hydrate free zones using the Damköhler number. In addition, we note that sediment grading patterns havemore » a strong influence on gas hydrate occurrence within coarse–grained layers.« less

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [2]
  1. The Ohio State Univ., Columbus, OH (United States)
  2. Univ. of Texas at Austin, Austin, TX (United States)
  3. Columbia Univ., Palisades, NY (United States)
  4. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1559497
Alternate Identifier(s):
OSTI ID: 1548017
Report Number(s):
SAND-2019-8736J
Journal ID: ISSN 1525-2027; 677864
Grant/Contract Number:  
AC04-94AL85000; FE0013919; FE0023919
Resource Type:
Accepted Manuscript
Journal Name:
Geochemistry, Geophysics, Geosystems
Additional Journal Information:
Journal Volume: 20; Journal Issue: 8; Journal ID: ISSN 1525-2027
Publisher:
American Geophysical Union
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES

Citation Formats

Wei, Li, Cook, Ann, Daigle, Hugh, Malinverno, Alberto, Nole, Michael, and You, Kehua. Factors Controlling Short-Range Methane Migration of Gas Hydrate Accumulations in Thin Coarse-Grained Layers. United States: N. p., 2019. Web. doi:10.1029/2019GC008405.
Wei, Li, Cook, Ann, Daigle, Hugh, Malinverno, Alberto, Nole, Michael, & You, Kehua. Factors Controlling Short-Range Methane Migration of Gas Hydrate Accumulations in Thin Coarse-Grained Layers. United States. https://doi.org/10.1029/2019GC008405
Wei, Li, Cook, Ann, Daigle, Hugh, Malinverno, Alberto, Nole, Michael, and You, Kehua. Mon . "Factors Controlling Short-Range Methane Migration of Gas Hydrate Accumulations in Thin Coarse-Grained Layers". United States. https://doi.org/10.1029/2019GC008405. https://www.osti.gov/servlets/purl/1559497.
@article{osti_1559497,
title = {Factors Controlling Short-Range Methane Migration of Gas Hydrate Accumulations in Thin Coarse-Grained Layers},
author = {Wei, Li and Cook, Ann and Daigle, Hugh and Malinverno, Alberto and Nole, Michael and You, Kehua},
abstractNote = {Natural gas hydrate is often found in marine sediment in heterogeneous distributions in different sediment types. Diffusion may be a dominant mechanism for methane migration and affect hydrate distribution. We use a 1–D advection–diffusion–reaction model to understand hydrate distribution in and surrounding thin coarse–grained layers to examine the sensitivity of four controlling factors in a diffusion–dominant gas hydrate system. These factors are the particulate organic carbon content at seafloor, the microbial reaction rate constant, the sediment grading pattern, and the cementation factor of the coarse–grained layer. We use available data at Walker Ridge 313 in the northern Gulf of Mexico where two ~3–m–thick hydrate–bearing coarse–grained layers were observed at different depths. The results show that the hydrate volume and the total amount of methane within thin, coarse–grained layers are most sensitive to the particulate organic carbon of fine–grained sediments when deposited at the seafloor. The thickness of fine–grained hydrate free zones surrounding the coarse–grained layers is most sensitive to the microbial reaction rate constant. Furthermore, it may be possible to estimate microbial reaction rate constants at other locations by studying the thickness of the hydrate free zones using the Damköhler number. In addition, we note that sediment grading patterns have a strong influence on gas hydrate occurrence within coarse–grained layers.},
doi = {10.1029/2019GC008405},
journal = {Geochemistry, Geophysics, Geosystems},
number = 8,
volume = 20,
place = {United States},
year = {Mon Jul 29 00:00:00 EDT 2019},
month = {Mon Jul 29 00:00:00 EDT 2019}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 12 works
Citation information provided by
Web of Science

Figures / Tables:

Figure 1 Figure 1: Illustration of five gas hydrate reservoirs that are A.) fractures in fine-grained sediment; B.) a thin (and sometimes patchy) coarse-grained layer surrounded by fine-grained sediment; C.) a thin coarse-grained layer (possibly connected to deep methane sources) surrounded by fine-grained sediment; D.) a thick coarse-grained layer connected to themore » base of GHSZ; E.) a thick coarse-grained layer with connection to deep hydrocarbon reservoirs. Three gas migration mechanisms are shown: short-range migration, long-range migration, and methane recycling. Within GHSZ, gas hydrate is formed, while below GHSZ, methane is free gas or dissolved phase.« less

Save / Share:

Works referenced in this record:

Clathrate Hydrates of Natural Gases
book, September 2007


On the Importance of Advective Versus Diffusive Transport in Controlling the Distribution of Methane Hydrate in Heterogeneous Marine Sediments
journal, July 2018

  • VanderBeek, Brandon P.; Rempel, Alan W.
  • Journal of Geophysical Research: Solid Earth, Vol. 123, Issue 7
  • DOI: 10.1029/2017JB015298

Gulf of Mexico Gas Hydrate Joint Industry Project Leg II logging-while-drilling data acquisition and analysis
journal, June 2012


Gas hydrate resource potential in the Terrebonne Basin, Northern Gulf of Mexico
journal, June 2012


Productivity, sedimentation rate, and sedimentary organic matter in the oceans—I. Organic carbon preservation
journal, December 1979


Archie's Saturation Exponent for Natural Gas Hydrate in Coarse-Grained Reservoirs
journal, March 2018

  • Cook, Ann E.; Waite, William F.
  • Journal of Geophysical Research: Solid Earth, Vol. 123, Issue 3
  • DOI: 10.1002/2017JB015138

Dynamic multiphase flow model of hydrate formation in marine sediments
journal, January 2007

  • Liu, Xiaoli; Flemings, Peter B.
  • Journal of Geophysical Research, Vol. 112, Issue B3
  • DOI: 10.1029/2005JB004227

The cementation factor of Archie's equation for shaly sandstone reservoirs
journal, August 1999


Bacterial populations and processes in sediments containing gas hydrates (ODP Leg 146: Cascadia Margin)
journal, April 1996


Burial-driven methane recycling in marine gas hydrate systems
journal, October 2018


Short-range, overpressure-driven methane migration in coarse-grained gas hydrate reservoirs: Short Advection in Gas Hydrate Systems
journal, September 2016

  • Nole, Michael; Daigle, Hugh; Cook, Ann E.
  • Geophysical Research Letters, Vol. 43, Issue 18
  • DOI: 10.1002/2016GL070096

Methane and other Hydrocarbon Gases in Marine Sediment
journal, May 1983


The interaction of climate change and methane hydrates: Climate-Hydrates Interactions
journal, February 2017

  • Ruppel, Carolyn D.; Kessler, John D.
  • Reviews of Geophysics, Vol. 55, Issue 1
  • DOI: 10.1002/2016RG000534

The sources and deposition of organic matter in the Late Quaternary Pigmy Basin, Gulf of Mexico
journal, April 1990


Linking basin-scale and pore-scale gas hydrate distribution patterns in diffusion-dominated marine hydrate systems: DIFFUSION-DRIVEN HYDRATE GROWTH IN SANDS
journal, February 2017

  • Nole, Michael; Daigle, Hugh; Cook, Ann E.
  • Geochemistry, Geophysics, Geosystems, Vol. 18, Issue 2
  • DOI: 10.1002/2016GC006662

Methane hydrate formation in thick sand reservoirs: 1. Short-range methane diffusion
journal, January 2018


The effect of temperature on organic carbon degradation in marine sediments
journal, December 2015

  • Malinverno, Alberto; Martinez, Ernesto A.
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep17861

Architecture of gas-hydrate-bearing sands from Walker Ridge 313, Green Canyon 955, and Alaminos Canyon 21: Northern deepwater Gulf of Mexico
journal, June 2012


Methane solubility in marine hydrate environments
journal, January 2004


Formation of natural gas hydrates in marine sediments: 2. Thermodynamic calculations of stability conditions in porous sediments
journal, October 1999

  • Henry, Pierre; Thomas, Michel; Clennell, M. Ben
  • Journal of Geophysical Research: Solid Earth, Vol. 104, Issue B10
  • DOI: 10.1029/1999JB900167

Abundant Early Palaeogene marine gas hydrates despite warm deep-ocean temperatures
journal, November 2011

  • Gu, Guangsheng; Dickens, Gerald R.; Bhatnagar, Gaurav
  • Nature Geoscience, Vol. 4, Issue 12
  • DOI: 10.1038/ngeo1301

Oceanic Methane Biogeochemistry
journal, February 2007


Thermogenic vent gas and gas hydrate in the Gulf of Mexico slope: Is gas hydrate decomposition significant?
journal, January 2001


Capillary controls on methane hydrate distribution and fracturing in advective systems: CAPILLARY CONTROLS ON HYDRATES
journal, January 2011

  • Daigle, Hugh; Dugan, Brandon
  • Geochemistry, Geophysics, Geosystems, Vol. 12, Issue 1
  • DOI: 10.1029/2010GC003392

Diffusion coefficients in nearshore marine sediments1
journal, May 1982


Natural gas hydrates occupying fractures: A focus on non-vent sites on the Indian continental margin and the northern Gulf of Mexico
journal, December 2014


Fabric of gas hydrate in sediments from Hydrate Ridge—results from ODP Leg 204 samples
journal, April 2007


Topography- and fracture-driven fluid focusing in layered ocean sediments: FLUID FOCUSING IN LAYERED SEDIMENTS
journal, April 2011

  • Frederick, Jennifer M.; Buffett, Bruce A.
  • Geophysical Research Letters, Vol. 38, Issue 8
  • DOI: 10.1029/2010GL046027

Gas hydrate reservoirs and gas migration mechanisms in the Terrebonne Basin, Gulf of Mexico
journal, September 2017


A numerical model for the formation of gas hydrate below the seafloor
journal, January 2001

  • Davie, Matthew K.; Buffett, Bruce A.
  • Journal of Geophysical Research: Solid Earth, Vol. 106, Issue B1
  • DOI: 10.1029/2000JB900363

Formation of natural gas hydrates in marine sediments: 1. Conceptual model of gas hydrate growth conditioned by host sediment properties
journal, October 1999

  • Clennell, M. Ben; Hovland, Martin; Booth, James S.
  • Journal of Geophysical Research: Solid Earth, Vol. 104, Issue B10
  • DOI: 10.1029/1999JB900175

Effect of hydrostatic pressure and salinity on the stability of gas hydrates
journal, March 1990


A semi-Lagrangian Crank-Nicolson algorithm for the numerical solution of advection-diffusion problems: SLCN ALGORITHM
journal, April 2006

  • Spiegelman, Marc; Katz, Richard F.
  • Geochemistry, Geophysics, Geosystems, Vol. 7, Issue 4
  • DOI: 10.1029/2005GC001073

Capillary effects on hydrate stability in marine sediments
journal, January 2011

  • Liu, Xiaoli; Flemings, Peter B.
  • Journal of Geophysical Research, Vol. 116, Issue B7
  • DOI: 10.1029/2010JB008143

Rising methane gas bubbles form massive hydrate layers at the seafloor
journal, November 2004

  • Haeckel, Matthias; Suess, Erwin; Wallmann, Klaus
  • Geochimica et Cosmochimica Acta, Vol. 68, Issue 21
  • DOI: 10.1016/j.gca.2004.01.018

A model for the diffusive growth of hydrate saturation anomalies in layered sediments
journal, January 2011


Methane Hydrate Formation in Thick Sandstones by Free Gas Flow
journal, June 2018

  • You, Kehua; Flemings, Peter B.
  • Journal of Geophysical Research: Solid Earth, Vol. 123, Issue 6
  • DOI: 10.1029/2018JB015683

A steady state model for marine hydrate formation: Constraints on methane supply from pore water sulfate profiles: STEADY STATE HYDRATE MODEL
journal, October 2003

  • Davie, M. K.; Buffett, B. A.
  • Journal of Geophysical Research: Solid Earth, Vol. 108, Issue B10
  • DOI: 10.1029/2002JB002300

A review of the geochemistry of methane in natural gas hydrate
journal, November 1995


Diffusion coefficients of sulfate and methane in marine sediments: Influence of porosity
journal, February 1993


Short migration of methane into a gas hydrate-bearing sand layer at Walker Ridge, Gulf of Mexico: SHORT MIGRATION OF METHANE
journal, February 2013

  • Cook, Ann E.; Malinverno, Alberto
  • Geochemistry, Geophysics, Geosystems, Vol. 14, Issue 2
  • DOI: 10.1002/ggge.20040

Marine gas hydrates in thin sand layers that soak up microbial methane
journal, April 2010


Methane hydrate formation in turbidite sediments of northern Cascadia, IODP Expedition 311
journal, July 2008

  • Torres, M. E.; Tréhu, A. M.; Cespedes, N.
  • Earth and Planetary Science Letters, Vol. 271, Issue 1-4
  • DOI: 10.1016/j.epsl.2008.03.061

Oceanic Methane Biogeochemistry
journal, May 2007