Enhancing thermochemical energy storage density of magnesium‐manganese oxides

doi:10.1002/est2.83

This content will become publicly available on August 25, 2020

Title: Enhancing thermochemical energy storage density of magnesium‐manganese oxides

Authors:

^[1]; Randhir, Kelvin ^[1]; Petrasch, Joerg ^[1]; Klausner, James ^[1]

Department of Mechanical EngineeringMichigan State University East Lansing Michigan

Publication Date:: 2019-08-26

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1558808

Grant/Contract Number:: DE‐AR0000991

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Energy Storage

Additional Journal Information:: Journal Name: Energy Storage Journal Volume: 1 Journal Issue: 5; Journal ID: ISSN 2578-4862

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Country unknown/Code not available

Language:: English

Citation Formats


                    King, Keith, Randhir, Kelvin, Petrasch, Joerg, and Klausner, James. Enhancing thermochemical energy storage density of magnesium‐manganese oxides.  Country unknown/Code not available: N. p., 2019. 
        Web.  doi:10.1002/est2.83.

Copy to clipboard


                    King, Keith, Randhir, Kelvin, Petrasch, Joerg, & Klausner, James. Enhancing thermochemical energy storage density of magnesium‐manganese oxides.  Country unknown/Code not available.  doi:10.1002/est2.83.

Copy to clipboard


                    King, Keith, Randhir, Kelvin, Petrasch, Joerg, and Klausner, James. Mon .  
        "Enhancing thermochemical energy storage density of magnesium‐manganese oxides".  Country unknown/Code not available.  doi:10.1002/est2.83.

Copy to clipboard


                    
@article{osti_1558808,

  title        = {Enhancing thermochemical energy storage density of magnesium‐manganese oxides},

  author       = {King, Keith and Randhir, Kelvin and Petrasch, Joerg and Klausner, James},

  abstractNote = {},

  doi          = {10.1002/est2.83},

  journal      = {Energy Storage},

  number       = 5,

  volume       = 1,

  place        = {Country unknown/Code not available},

  year         = {2019},

  month        = {8}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

This content will become publicly available on August 25, 2020

Publisher's Version of Record

DOI: 10.1002/est2.83

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Thermochemical Heat Storage at High Temperatures using Mn2O3/Mn3O4 System: Narrowing the Redox Hysteresis by Metal Co-doping
journal, June 2015

Carrillo, Alfonso J.; Serrano, David P.; Pizarro, Patricia
Energy Procedia, Vol. 73
DOI: 10.1016/j.egypro.2015.07.686

Screening of thermochemical systems based on solid-gas reversible reactions for high temperature solar thermal energy storage
journal, October 2016

André, Laurie; Abanades, Stéphane; Flamant, Gilles
Renewable and Sustainable Energy Reviews, Vol. 64
DOI: 10.1016/j.rser.2016.06.043

Improving the Thermochemical Energy Storage Performance of the Mn ₂ O ₃ /Mn ₃ O ₄ Redox Couple by the Incorporation of Iron
journal, April 2015

Carrillo, Alfonso J.; Serrano, David P.; Pizarro, Patricia
ChemSusChem, Vol. 8, Issue 11
DOI: 10.1002/cssc.201500148

Thermodynamics of the Mg-Mn-O system-modeling and heat capacity measurements
journal, January 2017

Dilner, David; Pavlyuchkov, Dmytro; Zienert, Tilo
Journal of the American Ceramic Society, Vol. 100, Issue 4
DOI: 10.1111/jace.14686

Lithium manganese oxides as high-temperature thermal energy storage system
journal, September 2016

Varsano, Francesca; Alvani, Carlo; La Barbera, Aurelio
Thermochimica Acta, Vol. 640
DOI: 10.1016/j.tca.2016.07.018

Application of Neumann–Kopp rule for the estimation of heat capacity of mixed oxides
journal, January 2010

Leitner, J.; Voňka, P.; Sedmidubský, D.
Thermochimica Acta, Vol. 497, Issue 1-2
DOI: 10.1016/j.tca.2009.08.002

Magnesium-manganese oxides for high temperature thermochemical energy storage
journal, February 2019

Randhir, Kelvin; King, Keith; Rhodes, Nathan
Journal of Energy Storage, Vol. 21
DOI: 10.1016/j.est.2018.11.024

Critical Evaluation and Thermodynamic Modeling of the Mg-Mn-O (MgO-MnO-MnO ₂ ) System
journal, July 2014

Panda, Sourav Kumar; Jung, In-Ho
Journal of the American Ceramic Society, Vol. 97, Issue 10
DOI: 10.1111/jace.13106

A review on high-temperature thermochemical energy storage based on metal oxides redox cycle
journal, July 2018

Wu, Sike; Zhou, Cheng; Doroodchi, Elham
Energy Conversion and Management, Vol. 168
DOI: 10.1016/j.enconman.2018.05.017

High-temperature thermochemical energy storage based on redox reactions using Co-Fe and Mn-Fe mixed metal oxides
journal, September 2017

André, Laurie; Abanades, Stéphane; Cassayre, Laurent
Journal of Solid State Chemistry, Vol. 253
DOI: 10.1016/j.jssc.2017.05.015

Metal oxides for thermochemical energy storage: A comparison of several metal oxide systems
journal, March 2016

Block, Tina; Schmücker, Martin
Solar Energy, Vol. 126
DOI: 10.1016/j.solener.2015.12.032

Calorimetric method for determining the thermochemical energy storage capacities of redox metal oxides
journal, March 2019

King, Keith; Randhir, Kelvin; Klausner, James
Thermochimica Acta, Vol. 673
DOI: 10.1016/j.tca.2019.01.008

Similar records in OSTI.GOV collections:

THERMOCHEMICAL HEAT STORAGE FOR CONCENTRATED SOLAR POWER

Technical Report PROJECT STAFF

Thermal energy storage (TES) is an integral part of a concentrated solar power (CSP) system. It enables plant operators to generate electricity beyond on sun hours and supply power to the grid to meet peak demand. Current CSP sensible heat storage systems employ molten salts as both the heat transfer fluid and the heat storage media. These systems have an upper operating temperature limit of around 400 C. Future TES systems are expected to operate at temperatures between 600 C to 1000 C for higher thermal efficiencies which should result in lower electricity cost. To meet future operating temperature andmore »« less
DOI: 10.2172/1039304

Full Text Available
High-temperature thermochemical energy storage based on redox reactions using Co-Fe and Mn-Fe mixed metal oxides

Journal Article André, Laurie ; Abanades, Stéphane ; Cassayre, Laurent - Journal of Solid State Chemistry

Metal oxides are potential materials for thermochemical heat storage via reversible endothermal/exothermal redox reactions, and among them, cobalt oxide and manganese oxide are attracting attention. The synthesis of mixed oxides is considered as a way to answer the drawbacks of pure metal oxides, such as slow reaction kinetics, loss-in-capacity over cycles or sintering issues, and the materials potential for thermochemical heat storage application needs to be assessed. This work proposes a study combining thermodynamic calculations and experimental measurements by simultaneous thermogravimetric analysis and calorimetry, in order to identify the impact of iron oxide addition to Co and Mn-based oxides. Femore »« less
DOI: 10.1016/J.JSSC.2017.05.015
Efficient Oxygen Electrocatalysis by Nanostructured Mixed-Metal Oxides

Journal Article Gu, Xiang -Kui ; Carneiro, Juliana S. A. ; Samira, Samji ; ... - Journal of the American Chemical Society

Oxygen electrocatalysis plays a critical role in the efficiency of important energy conversion and storage systems. While many efforts have focused on designing efficient electrocatalysts for these processes, optimal catalysts that are inexpensive, active, selective, and stable are still being searched. Nonstoichiometric, mixed-metal oxides present a promising group of electrocatalysts for these processes due to the versatility of the surface composition and fast oxygen conducting properties. Herein, we demonstrate, using a combination of theoretical and experimental studies, the ability to develop design principles that can be used to engineer oxygen electrocatalysis activity of layered, mixed ionic-electronic conducting Ruddlesden– Popper (R–P)more »« less
Cited by 10
DOI: 10.1021/jacs.7b11138

Full Text Available
Coordination Chemistry in magnesium battery electrolytes: how ligands affect their performance

Journal Article Shao, Yuyan ; Liu, Tianbiao L. ; Li, Guosheng ; ... - Scientific Reports

Magnesium battery is potentially a safe, cost-effective, and high energy density technology for large scale energy storage. However, the development of magnesium battery has been hindered by the limited performance and the lack of fundamental understandings of electrolytes. Here, we present a coordination chemistry study of Mg(BH ₄) ₂ in ethereal solvents. The O donor denticity, i.e. ligand strength of the ethereal solvents which act as ligands to form solvated Mg complexes, plays a significant role in enhancing coulombic efficiency of the corresponding solvated Mg complex electrolytes. A new and safer electrolyte is developed based on Mg(BH4)2, diglyme and optimizedmore »« less
Cited by 62
DOI: 10.1038/srep03130

Full Text Available
Chemical Hydride Slurry for Hydrogen Production and Storage

Technical Report McClaine, Andrew W

The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH ₂ slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at amore »« less
DOI: 10.2172/940573

Full Text Available

Similar Records

This content will become publicly available on August 25, 2020

Title: Enhancing thermochemical energy storage density of magnesium‐manganese oxides

Citation Formats

Thermochemical Heat Storage at High Temperatures using Mn2O3/Mn3O4 System: Narrowing the Redox Hysteresis by Metal Co-doping journal, June 2015

Screening of thermochemical systems based on solid-gas reversible reactions for high temperature solar thermal energy storage journal, October 2016

Improving the Thermochemical Energy Storage Performance of the Mn 2 O 3 /Mn 3 O 4 Redox Couple by the Incorporation of Iron journal, April 2015

Thermodynamics of the Mg-Mn-O system-modeling and heat capacity measurements journal, January 2017

Lithium manganese oxides as high-temperature thermal energy storage system journal, September 2016

Application of Neumann–Kopp rule for the estimation of heat capacity of mixed oxides journal, January 2010

Magnesium-manganese oxides for high temperature thermochemical energy storage journal, February 2019

Critical Evaluation and Thermodynamic Modeling of the Mg-Mn-O (MgO-MnO-MnO 2 ) System journal, July 2014

A review on high-temperature thermochemical energy storage based on metal oxides redox cycle journal, July 2018

High-temperature thermochemical energy storage based on redox reactions using Co-Fe and Mn-Fe mixed metal oxides journal, September 2017

Metal oxides for thermochemical energy storage: A comparison of several metal oxide systems journal, March 2016

Calorimetric method for determining the thermochemical energy storage capacities of redox metal oxides journal, March 2019

Thermochemical Heat Storage at High Temperatures using Mn2O3/Mn3O4 System: Narrowing the Redox Hysteresis by Metal Co-doping
journal, June 2015

Screening of thermochemical systems based on solid-gas reversible reactions for high temperature solar thermal energy storage
journal, October 2016

Improving the Thermochemical Energy Storage Performance of the Mn ₂ O ₃ /Mn ₃ O ₄ Redox Couple by the Incorporation of Iron
journal, April 2015

Thermodynamics of the Mg-Mn-O system-modeling and heat capacity measurements
journal, January 2017

Lithium manganese oxides as high-temperature thermal energy storage system
journal, September 2016

Application of Neumann–Kopp rule for the estimation of heat capacity of mixed oxides
journal, January 2010

Magnesium-manganese oxides for high temperature thermochemical energy storage
journal, February 2019

Critical Evaluation and Thermodynamic Modeling of the Mg-Mn-O (MgO-MnO-MnO ₂ ) System
journal, July 2014

A review on high-temperature thermochemical energy storage based on metal oxides redox cycle
journal, July 2018

High-temperature thermochemical energy storage based on redox reactions using Co-Fe and Mn-Fe mixed metal oxides
journal, September 2017

Metal oxides for thermochemical energy storage: A comparison of several metal oxide systems
journal, March 2016

Calorimetric method for determining the thermochemical energy storage capacities of redox metal oxides
journal, March 2019