Roles of humidity and cathodic current in chromium poisoning of Sr-doped LaMnO3-based cathodes in solid oxide fuel cells

Wang, Ruofan; Würth, Manuel; Pal, Uday B.; Gopalan, Srikanth; Basu, Soumendra N.

doi:10.1016/j.jpowsour.2017.06.005

Title: Roles of humidity and cathodic current in chromium poisoning of Sr-doped LaMnO3-based cathodes in solid oxide fuel cells

Authors:

; Würth, Manuel; Pal, Uday B.; Gopalan, Srikanth; Basu, Soumendra N.

Publication Date:: Tue Aug 01 00:00:00 EDT 2017

Sponsoring Org.:: USDOE Office of Fossil Energy and Carbon Management (FECM)

OSTI Identifier:: 1550133

Grant/Contract Number:: FE0023325

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Name: Journal of Power Sources Journal Volume: 360 Journal Issue: C; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Wang, Ruofan, Würth, Manuel, Pal, Uday B., Gopalan, Srikanth, and Basu, Soumendra N. Roles of humidity and cathodic current in chromium poisoning of Sr-doped LaMnO3-based cathodes in solid oxide fuel cells.  Netherlands: N. p., 2017. 
Web.  doi:10.1016/j.jpowsour.2017.06.005.

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                    Wang, Ruofan, Würth, Manuel, Pal, Uday B., Gopalan, Srikanth, & Basu, Soumendra N. Roles of humidity and cathodic current in chromium poisoning of Sr-doped LaMnO3-based cathodes in solid oxide fuel cells.  Netherlands.  https://doi.org/10.1016/j.jpowsour.2017.06.005

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                    Wang, Ruofan, Würth, Manuel, Pal, Uday B., Gopalan, Srikanth, and Basu, Soumendra N. Tue .  
"Roles of humidity and cathodic current in chromium poisoning of Sr-doped LaMnO3-based cathodes in solid oxide fuel cells".  Netherlands.  https://doi.org/10.1016/j.jpowsour.2017.06.005.

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@article{osti_1550133,

  title        = {Roles of humidity and cathodic current in chromium poisoning of Sr-doped LaMnO3-based cathodes in solid oxide fuel cells},

  author       = {Wang, Ruofan and Würth, Manuel and Pal, Uday B. and Gopalan, Srikanth and Basu, Soumendra N.},

  abstractNote = {},

  doi          = {10.1016/j.jpowsour.2017.06.005},

  journal      = {Journal of Power Sources},

  number       = C,

  volume       = 360,

  place        = {Netherlands},

  year         = {Tue Aug 01 00:00:00 EDT 2017},

  month        = {Tue Aug 01 00:00:00 EDT 2017}

}

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https://doi.org/10.1016/j.jpowsour.2017.06.005

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Title: Roles of humidity and cathodic current in chromium poisoning of Sr-doped LaMnO3-based cathodes in solid oxide fuel cells

Citation Formats

Chromium Poisoning of LaMnO3-Based Cathode within Generalized Approach journal, February 2013

A mechanistic study on the activation process of (La, Sr)MnO3 electrodes of solid oxide fuel cells journal, June 2006

Chromium Volatilization Rates from Cr2O3 Scales into Flowing Gases Containing Water Vapor journal, November 2006

Effect of Polarization on and Implications for Characterization of LSM-YSZ Composite Cathodes journal, January 2004

Running on natural gas journal, August 1999

A comparative investigation of chromium deposition at air electrodes of solid oxide fuel cells journal, March 2002

Density functional theory studies of methyl dissociation on a Ni(111) surface in the presence of an external electric field journal, January 2014

Analysis of Electrochemical Performance of SOFCs Using Polarization Modeling and Impedance Measurements journal, January 2009

Evaluation of fuel cell system efficiency and degradation at development and during commercialization journal, September 2006

Comparison of chromium poisoning among solid oxide fuel cell cathode materials journal, September 2014

The effect of temperature on chromium vaporization and oxide scale growth on interconnect steels for Solid Oxide Fuel Cells journal, August 2015

Calculation of Reactive-evaporation Rates of Chromia journal, February 2008

Fundamental mechanisms limiting solid oxide fuel cell durability journal, August 2008

The Effect of Chromium Oxyhydroxide on Solid Oxide Fuel Cells journal, January 2010

Formation of chromium containing impurities in (La,Sr)MnO 3 solid-oxide-fuel-cell cathodes under stack operating conditions and its effect on performance journal, June 2016

Vaporisation of chromia in humid air journal, February 2005

Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers journal, January 2016

Evaluation of the oxidation and Cr evaporation properties of selected FeCr alloys used as SOFC interconnects journal, November 2013

Comprehensive review of methane conversion in solid oxide fuel cells: Prospects for efficient electricity generation from natural gas journal, May 2016

Recent results in Jülich solid oxide fuel cell technology development journal, November 2013

Chromium deposition and poisoning of cathodes of solid oxide fuel cells – A review journal, January 2014

Degradation of anode supported cell (ASC) performance by Cr-poisoning journal, September 2011

Worldwide SOFC Technology Overview and Benchmark journal, November 2005

Chromium Poisoning and Degradation at (La,Sr)MnO[sub 3] and (La,Sr)FeO[sub 3] Cathodes for Solid Oxide Fuel Cells journal, January 2010

Degradation phenomena in the cathode of a solid oxide fuel cell with an alloy separator journal, May 1995

Polarization measurements on single-step co-fired solid oxide fuel cells (SOFCs) journal, October 2007

A fundamental study of chromium deposition and poisoning at (La0.8Sr0.2)0.95(Mn1−xCox)O3 ± δ (0.0≤ x ≤1.0) cathodes of solid oxide fuel cells journal, January 2011

Solid oxide fuel cells (SOFCs): a review of an environmentally clean and efficient source of energy journal, October 2002

Chromium Poisoning of LSM/YSZ and LSCF/CGO Composite Cathodes journal, December 2009

Chromium Vapor Species over Solid Oxide Fuel Cell Interconnect Materials and Their Potential for Degradation Processes journal, January 1996

Interaction between chromia forming alloy interconnects and air electrode of solid oxide fuel cells journal, August 1997

Effect of Fuel Composition on Performance of Single-Step Cofired SOFCs journal, January 2007

Dependence of SOFC Cathode Degradation by Chromium-Containing Alloy on Compositions of Electrodes and Electrolytes journal, January 2001

Chromium vaporization of bare and of coated iron–chromium alloys at 1073 K journal, February 2007

Chromium Vaporization from High-Temperature Alloys journal, January 2007

A fundamental study of chromium deposition on solid oxide fuel cell cathode materials journal, September 2006

Microstructural Degradation of (La,Sr)MnO[sub 3]∕YSZ Cathodes in Solid Oxide Fuel Cells with Uncoated E-Brite Interconnects journal, January 2011

Thermodynamics of gas phase chromium species: The chromium oxides, the chromium oxyhydroxides, and volatility calculations in waste incineration processes journal, April 1993

Chromium deposition and poisoning in dry and humidified air at (La0.8Sr0.2)0.9MnO3+δ cathodes of solid oxide fuel cells journal, March 2010

Electrochemical Performance of Solid Oxide Fuel Cells Manufactured by Single Step Co-firing Process journal, January 2007

Cathode materials for solid oxide fuel cells: a review journal, October 2009

Chromium Poisoning of LaMnO₃-Based Cathode within Generalized Approach
journal, February 2013

A mechanistic study on the activation process of (La, Sr)MnO3 electrodes of solid oxide fuel cells
journal, June 2006

Chromium Volatilization Rates from Cr2O3 Scales into Flowing Gases Containing Water Vapor
journal, November 2006

Effect of Polarization on and Implications for Characterization of LSM-YSZ Composite Cathodes
journal, January 2004

Running on natural gas
journal, August 1999

A comparative investigation of chromium deposition at air electrodes of solid oxide fuel cells
journal, March 2002

Density functional theory studies of methyl dissociation on a Ni(111) surface in the presence of an external electric field
journal, January 2014

Analysis of Electrochemical Performance of SOFCs Using Polarization Modeling and Impedance Measurements
journal, January 2009

Evaluation of fuel cell system efficiency and degradation at development and during commercialization
journal, September 2006

Comparison of chromium poisoning among solid oxide fuel cell cathode materials
journal, September 2014

The effect of temperature on chromium vaporization and oxide scale growth on interconnect steels for Solid Oxide Fuel Cells
journal, August 2015

Calculation of Reactive-evaporation Rates of Chromia
journal, February 2008

Fundamental mechanisms limiting solid oxide fuel cell durability
journal, August 2008

The Effect of Chromium Oxyhydroxide on Solid Oxide Fuel Cells
journal, January 2010

Formation of chromium containing impurities in (La,Sr)MnO 3 solid-oxide-fuel-cell cathodes under stack operating conditions and its effect on performance
journal, June 2016

Vaporisation of chromia in humid air
journal, February 2005

Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers
journal, January 2016

Evaluation of the oxidation and Cr evaporation properties of selected FeCr alloys used as SOFC interconnects
journal, November 2013

Comprehensive review of methane conversion in solid oxide fuel cells: Prospects for efficient electricity generation from natural gas
journal, May 2016

Recent results in Jülich solid oxide fuel cell technology development
journal, November 2013

Chromium deposition and poisoning of cathodes of solid oxide fuel cells – A review
journal, January 2014

Degradation of anode supported cell (ASC) performance by Cr-poisoning
journal, September 2011

Worldwide SOFC Technology Overview and Benchmark
journal, November 2005

Chromium Poisoning and Degradation at (La,Sr)MnO[sub 3] and (La,Sr)FeO[sub 3] Cathodes for Solid Oxide Fuel Cells
journal, January 2010

Degradation phenomena in the cathode of a solid oxide fuel cell with an alloy separator
journal, May 1995

Polarization measurements on single-step co-fired solid oxide fuel cells (SOFCs)
journal, October 2007

A fundamental study of chromium deposition and poisoning at (La0.8Sr0.2)0.95(Mn1−xCox)O3 ± δ (0.0≤ x ≤1.0) cathodes of solid oxide fuel cells
journal, January 2011

Solid oxide fuel cells (SOFCs): a review of an environmentally clean and efficient source of energy
journal, October 2002

Chromium Poisoning of LSM/YSZ and LSCF/CGO Composite Cathodes
journal, December 2009

Chromium Vapor Species over Solid Oxide Fuel Cell Interconnect Materials and Their Potential for Degradation Processes
journal, January 1996

Interaction between chromia forming alloy interconnects and air electrode of solid oxide fuel cells
journal, August 1997

Effect of Fuel Composition on Performance of Single-Step Cofired SOFCs
journal, January 2007

Dependence of SOFC Cathode Degradation by Chromium-Containing Alloy on Compositions of Electrodes and Electrolytes
journal, January 2001

Chromium vaporization of bare and of coated iron–chromium alloys at 1073 K
journal, February 2007

Chromium Vaporization from High-Temperature Alloys
journal, January 2007

A fundamental study of chromium deposition on solid oxide fuel cell cathode materials
journal, September 2006

Microstructural Degradation of (La,Sr)MnO[sub 3]∕YSZ Cathodes in Solid Oxide Fuel Cells with Uncoated E-Brite Interconnects
journal, January 2011

Thermodynamics of gas phase chromium species: The chromium oxides, the chromium oxyhydroxides, and volatility calculations in waste incineration processes
journal, April 1993

Chromium deposition and poisoning in dry and humidified air at (La0.8Sr0.2)0.9MnO3+δ cathodes of solid oxide fuel cells
journal, March 2010

Electrochemical Performance of Solid Oxide Fuel Cells Manufactured by Single Step Co-firing Process
journal, January 2007

Cathode materials for solid oxide fuel cells: a review
journal, October 2009