Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic

van Genuchten, C. M.; Behrends, T.; Dideriksen, K.

doi:10.1039/C9EM00267G

Title: Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic

Abstract

Structural transformations of green rust and the partitioning of arsenic were tracked during aging for up to a year.

Authors:

^[1]; Behrends, T. ^[2]; Dideriksen, K. ^[3]

Geological Survey of Denmark and Greenland (GEUS), Copenhagen, Denmark, Department of Earth Sciences – Geochemistry, Faculty of Geosciences, Utrecht University, Utrecht, The Netherlands
Department of Earth Sciences – Geochemistry, Faculty of Geosciences, Utrecht University, Utrecht, The Netherlands
Geological Survey of Denmark and Greenland (GEUS), Copenhagen, Denmark

Publication Date:: Wed Sep 18 00:00:00 EDT 2019

Sponsoring Org.:: USDOE

OSTI Identifier:: 1832515

Alternate Identifier(s):: OSTI ID: 1545397

Grant/Contract Number:: AC02-76SF00515

Resource Type:: Published Article

Journal Name:: Environmental Science: Processes & Impacts

Additional Journal Information:: Journal Name: Environmental Science: Processes & Impacts Journal Volume: 21 Journal Issue: 9; Journal ID: ISSN 2050-7887

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    van Genuchten, C. M., Behrends, T., and Dideriksen, K. Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9EM00267G.

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                    van Genuchten, C. M., Behrends, T., & Dideriksen, K. Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic.  United Kingdom.  https://doi.org/10.1039/C9EM00267G

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                    van Genuchten, C. M., Behrends, T., and Dideriksen, K. Wed .  
"Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic".  United Kingdom.  https://doi.org/10.1039/C9EM00267G.

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@article{osti_1832515,

  title        = {Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic},

  author       = {van Genuchten, C. M. and Behrends, T. and Dideriksen, K.},

  abstractNote = {Structural transformations of green rust and the partitioning of arsenic were tracked during aging for up to a year.},

  doi          = {10.1039/C9EM00267G},

  journal      = {Environmental Science: Processes & Impacts},

  number       = 9,

  volume       = 21,

  place        = {United Kingdom},

  year         = {Wed Sep 18 00:00:00 EDT 2019},

  month        = {Wed Sep 18 00:00:00 EDT 2019}

}

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Works referenced in this record:

Iron-Catalyzed Oxidation of Arsenic(III) by Oxygen and by Hydrogen Peroxide: pH-Dependent Formation of Oxidants in the Fenton Reaction
journal, June 2003

Hug, Stephan J.; Leupin, Olivier
Environmental Science & Technology, Vol. 37, Issue 12
DOI: 10.1021/es026208x

Arsenic(III) and Arsenic(V) Speciation during Transformation of Lepidocrocite to Magnetite
journal, November 2014

Wang, Yuheng; Morin, Guillaume; Ona-Nguema, Georges
Environmental Science & Technology, Vol. 48, Issue 24
DOI: 10.1021/es5033629

Transformation of hydroxycarbonate green rust into crystalline iron (hydr)oxides: Influences of reaction conditions and underlying mechanisms
journal, August 2013

Wang, Xiaoming; Liu, Fan; Tan, Wenfeng
Chemical Geology, Vol. 351
DOI: 10.1016/j.chemgeo.2013.05.003

Ferrate(VI)-Induced Arsenite and Arsenate Removal by In Situ Structural Incorporation into Magnetic Iron(III) Oxide Nanoparticles
journal, March 2013

Prucek, Robert; Tuček, Jiří; Kolařík, Jan
Environmental Science & Technology, Vol. 47, Issue 7
DOI: 10.1021/es3042719

Effect of phosphate, silicate, and Ca on Fe(III)-precipitates formed in aerated Fe(II)- and As(III)-containing water studied by X-ray absorption spectroscopy
journal, January 2010

Voegelin, Andreas; Kaegi, Ralf; Frommer, Jakob
Geochimica et Cosmochimica Acta, Vol. 74, Issue 1
DOI: 10.1016/j.gca.2009.09.020

Sorption of As(III) and As(V) to siderite, green rust (fougerite) and magnetite: Implications for arsenic release in anoxic groundwaters
journal, September 2008

Jönsson, Jörgen; Sherman, David M.
Chemical Geology, Vol. 255, Issue 1-2
DOI: 10.1016/j.chemgeo.2008.06.036

Iron(II,III) Hydroxycarbonate Green Rust Formation and Stabilization from Lepidocrocite Bioreduction
journal, January 2002

Ona-Nguema, Georges; Abdelmoula, Mustapha; Jorand, Frédéric
Environmental Science & Technology, Vol. 36, Issue 1
DOI: 10.1021/es0020456

Effect of citrate on the local Fe coordination in ferrihydrite, arsenate binding, and ternary arsenate complex formation
journal, October 2010

Mikutta, Christian; Frommer, Jakob; Voegelin, Andreas
Geochimica et Cosmochimica Acta, Vol. 74, Issue 19
DOI: 10.1016/j.gca.2010.06.024

Multi-competitive interaction of As(III) and As(V) oxyanions with Ca2+, Mg2+, PO3−4, and CO2−3 ions on goethite
journal, April 2008

Stachowicz, Monika; Hiemstra, Tjisse; van Riemsdijk, Willem H.
Journal of Colloid and Interface Science, Vol. 320, Issue 2
DOI: 10.1016/j.jcis.2008.01.007

Secondary mineralization pathways induced by dissimilatory iron reduction of ferrihydrite under advective flow
journal, August 2003

Hansel, Colleen M.; Benner, Shawn G.; Neiss, Jim
Geochimica et Cosmochimica Acta, Vol. 67, Issue 16
DOI: 10.1016/S0016-7037(03)00276-X

Effect of orthophosphate on the oxidation products of Fe(II)-Fe(III) hydroxycarbonate: the transformation of green rust to ferrihydrite
journal, June 2001

Benali, Omar; Abdelmoula, Mustapha; Refait, Philippe
Geochimica et Cosmochimica Acta, Vol. 65, Issue 11
DOI: 10.1016/S0016-7037(01)00556-7

Distinctive Arsenic(V) Trapping Modes by Magnetite Nanoparticles Induced by Different Sorption Processes
journal, September 2011

Wang, Yuheng; Morin, Guillaume; Ona-Nguema, Georges
Environmental Science & Technology, Vol. 45, Issue 17
DOI: 10.1021/es200299f

Dynamic Fe-precipitate formation induced by Fe(II) oxidation in aerated phosphate-containing water
journal, September 2013

Voegelin, Andreas; Senn, Anna-Caterina; Kaegi, Ralf
Geochimica et Cosmochimica Acta, Vol. 117
DOI: 10.1016/j.gca.2013.04.022

Identification of Uranyl Surface Complexes on Ferrihydrite: Advanced EXAFS Data Analysis and CD-MUSIC Modeling
journal, March 2009

Rossberg, André; Ulrich, Kai-Uwe; Weiss, Stephan
Environmental Science & Technology, Vol. 43, Issue 5
DOI: 10.1021/es801727w

Magnetite and Green Rust: Synthesis, Properties, and Environmental Applications of Mixed-Valent Iron Minerals
journal, February 2018

Usman, M.; Byrne, J. M.; Chaudhary, A.
Chemical Reviews, Vol. 118, Issue 7
DOI: 10.1021/acs.chemrev.7b00224

Removal of arsenic from drinking water by the electrocoagulation using Fe and Al electrodes
journal, May 2011

Kobya, M.; Gebologlu, U.; Ulu, F.
Electrochimica Acta, Vol. 56, Issue 14
DOI: 10.1016/j.electacta.2011.03.086

Complexation of uranium(VI) with protocatechuic acid?application of iterative transformation factor analysis to EXAFS spectroscopy
journal, July 2003

Ro�berg, A.; Reich, T.; Bernhard, G.
Analytical and Bioanalytical Chemistry, Vol. 376, Issue 5
DOI: 10.1007/s00216-003-1963-5

The Dutch–Belgian beamline at the ESRF
journal, May 1998

Borsboom, M.; Bras, W.; Cerjak, I.
Journal of Synchrotron Radiation, Vol. 5, Issue 3
DOI: 10.1107/S0909049597013484

High-order multiple-scattering calculations of x-ray-absorption fine structure
journal, December 1992

Rehr, J. J.; Albers, R. C.; Zabinsky, S. I.
Physical Review Letters, Vol. 69, Issue 23
DOI: 10.1103/PhysRevLett.69.3397

Evidence for Different Surface Speciation of Arsenite and Arsenate on Green Rust: An EXAFS and XANES Study
journal, January 2010

Wang, Yuheng; Morin, Guillaume; Ona-Nguema, Georges
Environmental Science & Technology, Vol. 44, Issue 1
DOI: 10.1021/es901627e

Implementation of a combined SAXS/WAXS/QEXAFS set-up for time-resolved in situ experiments
journal, October 2008

Nikitenko, Sergey; Beale, Andrew M.; van der Eerden, Ad M. J.
Journal of Synchrotron Radiation, Vol. 15, Issue 6
DOI: 10.1107/S0909049508023327

Controls on the formation of Fe(II,III) (hydr)oxides by Fe(0) electrolysis
journal, October 2018

van Genuchten, C. M.; Behrends, T.; Kraal, P.
Electrochimica Acta, Vol. 286
DOI: 10.1016/j.electacta.2018.08.031

Oxidation modes and thermodynamics of FeII–III oxyhydroxycarbonate green rust: Dissolution–precipitation versus in situ deprotonation
journal, February 2010

Ruby, Christian; Abdelmoula, Mustapha; Naille, Sébastien
Geochimica et Cosmochimica Acta, Vol. 74, Issue 3
DOI: 10.1016/j.gca.2009.10.030

Surface speciation of As(III) and As(V) in relation to charge distribution
journal, October 2006

Stachowicz, Monika; Hiemstra, Tjisse; van Riemsdijk, Willem H.
Journal of Colloid and Interface Science, Vol. 302, Issue 1
DOI: 10.1016/j.jcis.2006.06.030

Electrochemical formation of a new Fe(II)Fe(III) hydroxy-carbonate green rust: characterisation and morphology
journal, March 2001

Legrand, L.; Abdelmoula, M.; Géhin, A.
Electrochimica Acta, Vol. 46, Issue 12
DOI: 10.1016/S0013-4686(00)00728-3

Iron control by equilibria between hydroxy-Green Rusts and solutions in hydromorphic soils
journal, October 1999

Bourrié, Guilhem; Trolard, Fabienne; Jaffrezic, Jean-Marie Robert GéninAnne
Geochimica et Cosmochimica Acta, Vol. 63, Issue 19-20
DOI: 10.1016/S0016-7037(99)00262-8

Surface complexation of arsenic(V) to iron(III) (hydr)oxides: structural mechanism from ab initio molecular geometries and EXAFS spectroscopy
journal, November 2003

Sherman, David M.; Randall, Simon R.
Geochimica et Cosmochimica Acta, Vol. 67, Issue 22
DOI: 10.1016/S0016-7037(03)00237-0

Identification of Green Rust in Groundwater
journal, May 2009

Christiansen, B. C.; Balic-Zunic, T.; Dideriksen, K.
Environmental Science & Technology, Vol. 43, Issue 10
DOI: 10.1021/es8011047

SIXPack a Graphical User Interface for XAS Analysis Using IFEFFIT
journal, January 2005

Webb, S. M.
Physica Scripta
DOI: 10.1238/Physica.Topical.115a01011

Remarkable efficiency of phosphate removal: Ferrate(VI)-induced in situ sorption on core-shell nanoparticles
journal, October 2016

Kralchevska, Radina P.; Prucek, Robert; Kolařík, Jan
Water Research, Vol. 103
DOI: 10.1016/j.watres.2016.07.021

Formation of green rust and elemental sulfur in an analogue for oxygenated ferro-euxinic transition zones of Precambrian oceans
journal, January 2019

Koeksoy, E.; Sundman, A.; Byrne, J. M.
Geology, Vol. 47, Issue 3
DOI: 10.1130/G45501.1

Composition and structure of Fe(III)-precipitates formed by Fe(II) oxidation in water at near-neutral pH: Interdependent effects of phosphate, silicate and Ca
journal, August 2015

Senn, Anna-Caterina; Kaegi, Ralf; Hug, Stephan J.
Geochimica et Cosmochimica Acta, Vol. 162
DOI: 10.1016/j.gca.2015.04.032

Fe(III) Nucleation in the Presence of Bivalent Cations and Oxyanions Leads to Subnanoscale 7 Å Polymers
journal, October 2014

van Genuchten, Case M.; Gadgil, Ashok J.; Peña, Jasquelin
Environmental Science & Technology, Vol. 48, Issue 20
DOI: 10.1021/es503281a

Production and Transformation of Mixed-Valent Nanoparticles Generated by Fe(0) Electrocoagulation
journal, February 2015

Dubrawski, Kristian L.; van Genuchten, Case M.; Delaire, Caroline
Environmental Science & Technology, Vol. 49, Issue 4
DOI: 10.1021/es505059d

A key role for green rust in the Precambrian oceans and the genesis of iron formations
journal, January 2017

Halevy, I.; Alesker, M.; Schuster, E. M.
Nature Geoscience, Vol. 10, Issue 2
DOI: 10.1038/ngeo2878

Formation of single domain magnetite by green rust oxidation promoted by microbial anaerobic nitrate-dependent iron oxidation
journal, August 2014

Miot, Jennyfer; Li, Jinhua; Benzerara, Karim
Geochimica et Cosmochimica Acta, Vol. 139
DOI: 10.1016/j.gca.2014.04.047

Potential indicators for the assessment of arsenic natural attenuation in the subsurface
journal, June 2003

Lin, Zhixun; Puls, Robert W.
Advances in Environmental Research, Vol. 7, Issue 4
DOI: 10.1016/S1093-0191(02)00056-4

Chemical stability of hydroxysulphate green rust synthetised in the presence of foreign anions: carbonate, phosphate and silicate
journal, November 2006

Ruby, C.; Géhin, A.; Aissa, R.
Hyperfine Interactions, Vol. 167, Issue 1-3
DOI: 10.1007/s10751-006-9361-y

Reactivity of Fe(II)-Bearing Minerals toward Reductive Transformation of Organic Contaminants
journal, February 2004

Elsner, Martin; Schwarzenbach, René P.; Haderlein, Stefan B.
Environmental Science & Technology, Vol. 38, Issue 3
DOI: 10.1021/es0345569

Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy
journal, May 2012

Manceau, A.; Marcus, M. A.; Grangeon, S.
American Mineralogist, Vol. 97, Issue 5-6
DOI: 10.2138/am.2012.3903

Reduction of SeO ₄ ² ^- Anions and Anoxic Formation of Iron(II)−Iron(III) Hydroxy-Selenate Green Rust
journal, March 2000

Refait, Philippe; Simon, Lilian; Génin, Jean-Marie R.
Environmental Science & Technology, Vol. 34, Issue 5
DOI: 10.1021/es990376g

Thermodynamic Studies of the Arsenic Adsorption on Iron Species Generated by Electrocoagulation
journal, November 2009

Parga, J. R.; Vazquez, V.; Moreno, H.
Journal of Metallurgy, Vol. 2009
DOI: 10.1155/2009/286971

Effects of silicate, sulfate, and carbonate on arsenic removal by ferric chloride
journal, March 2000

Meng, X.
Water Research, Vol. 34, Issue 4
DOI: 10.1016/S0043-1354(99)00272-9

Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate
journal, May 1993

Waychunas, G. A.; Rea, B. A.; Fuller, C. C.
Geochimica et Cosmochimica Acta, Vol. 57, Issue 10
DOI: 10.1016/0016-7037(93)90567-G

The mechanisms of reduction of hexavalent chromium by green rust sodium sulphate: Formation of Cr-goethite
journal, July 2006

Skovbjerg, L. L.; Stipp, S. L. S.; Utsunomiya, S.
Geochimica et Cosmochimica Acta, Vol. 70, Issue 14
DOI: 10.1016/j.gca.2006.02.017

The Structure of Magnetite and the Spinels
journal, July 1915

Bragg, W. H.
Nature, Vol. 95, Issue 2386
DOI: 10.1038/095561a0

Removing Arsenic from Synthetic Groundwater with Iron Electrocoagulation: An Fe and As K-Edge EXAFS Study
journal, December 2011

van Genuchten, Case M.; Addy, Susan E. A.; Peña, Jasquelin
Environmental Science & Technology, Vol. 46, Issue 2
DOI: 10.1021/es201913a

Fougerite, a new mineral of the pyroaurite-iowaite group: description and crystal structure
journal, June 2007

Trolard, Fabienne; Bourrié, Guilhem; Abdelmoula, Mustapha
Clays and Clay Minerals, Vol. 55, Issue 3
DOI: 10.1346/CCMN.2007.0550308

Effects of phosphate and silicate on the transformation of hydroxycarbonate green rust to ferric oxyhydroxides
journal, December 2015

Feng, Xionghan; Wang, Xiaoming; Zhu, Mengqiang
Geochimica et Cosmochimica Acta, Vol. 171
DOI: 10.1016/j.gca.2015.08.020

Quantitative antimony speciation in shooting-range soils by EXAFS spectroscopy
journal, July 2006

Scheinost, Andreas C.; Rossberg, Andre; Vantelon, Delphine
Geochimica et Cosmochimica Acta, Vol. 70, Issue 13
DOI: 10.1016/j.gca.2006.03.020

Significance of Iron(II,III) Hydroxycarbonate Green Rust in Arsenic Remediation Using Zerovalent Iron in Laboratory Column Tests
journal, October 2004

Su, Chunming; Puls, Robert W.
Environmental Science & Technology, Vol. 38, Issue 19
DOI: 10.1021/es0495462

Structure and stability of the Fe(II)–Fe(III) green rust “fougerite” mineral and its potential for reducing pollutants in soil solutions
journal, April 2001

Génin, Jean-Marie R.; Refait, Philippe; Bourrié, Guilhem
Applied Geochemistry, Vol. 16, Issue 5
DOI: 10.1016/S0883-2927(00)00043-3

Arsenic(III, V) adsorption on a goethite-based adsorbent in the presence of major co-existing ions: Modeling competitive adsorption consistent with spectroscopic and molecular evidence
journal, April 2013

Kanematsu, Masakazu; Young, Thomas M.; Fukushi, Keisuke
Geochimica et Cosmochimica Acta, Vol. 106
DOI: 10.1016/j.gca.2012.09.055

Refinement of the crystal structure of scorodite
journal, January 1975

Kitahama, K.; Kiriyama, R.; Baba, Y.
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 31, Issue 1
DOI: 10.1107/S056774087500266X

Green rust as a precursor for magnetite: an in situ synchrotron based study
journal, February 2008

Sumoondur, A.; Shaw, S.; Ahmed, I.
Mineralogical Magazine, Vol. 72, Issue 1
DOI: 10.1180/minmag.2008.072.1.201

Modeling As(III) Oxidation and Removal with Iron Electrocoagulation in Groundwater
journal, October 2012

Li, Lei; van Genuchten, Case M.; Addy, Susan E. A.
Environmental Science & Technology, Vol. 46, Issue 21
DOI: 10.1021/es302456b

Biogenic iron oxyhydroxide formation at mid-ocean ridge hydrothermal vents: Juan de Fuca Ridge
journal, January 2009

Toner, Brandy M.; Santelli, Cara M.; Marcus, Matthew A.
Geochimica et Cosmochimica Acta, Vol. 73, Issue 2
DOI: 10.1016/j.gca.2008.09.035

Mn(II) Oxidation in Fenton and Fenton Type Systems: Identification of Reaction Efficiency and Reaction Products
journal, February 2017

van Genuchten, Case M.; Peña, Jasquelin
Environmental Science & Technology, Vol. 51, Issue 5
DOI: 10.1021/acs.est.6b05584

Reduction of Halogenated Ethanes by Green rust
journal, January 2004

O'Loughlin, Edward J.; Burris, David R.
Environmental Toxicology and Chemistry, Vol. 23, Issue 1
DOI: 10.1897/03-45

The oxidation of carbonate green rust into ferric phases:solid-state reaction or transformation via solution
journal, September 2004

Legrand, Ludovic; Mazerolles, Léo; Chaussé, Annie
Geochimica et Cosmochimica Acta, Vol. 68, Issue 17
DOI: 10.1016/j.gca.2004.02.019

Arsenite sorption at the magnetite–water interface during aqueous precipitation of magnetite: EXAFS evidence for a new arsenite surface complex
journal, June 2008

Wang, Yuheng; Morin, Guillaume; Ona-Nguema, Georges
Geochimica et Cosmochimica Acta, Vol. 72, Issue 11
DOI: 10.1016/j.gca.2008.03.011

Arsenic Removal with Iron(II) and Iron(III) in Waters with High Silicate and Phosphate Concentrations
journal, January 2004

Roberts, Linda C.; Hug, Stephan J.; Ruettimann, Thomas
Environmental Science & Technology, Vol. 38, Issue 1
DOI: 10.1021/es0343205

The interfacial reactivity of arsenic species with green rust sulfate (GRSO4)
journal, January 2019

Perez, Jeffrey Paulo H.; Freeman, Helen M.; Schuessler, Jan A.
Science of The Total Environment, Vol. 648
DOI: 10.1016/j.scitotenv.2018.08.163

IFEFFIT : interactive XAFS analysis and FEFF fitting
journal, March 2001

Newville, Matthew
Journal of Synchrotron Radiation, Vol. 8, Issue 2
DOI: 10.1107/S0909049500016964

Synthesis and phase transformations involving scorodite, ferric arsenate and arsenical ferrihydrite: Implications for arsenic mobility
journal, June 2008

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Geochimica et Cosmochimica Acta, Vol. 72, Issue 11
DOI: 10.1016/j.gca.2008.03.012

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Title: Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic

Abstract

Citation Formats

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Secondary mineralization pathways induced by dissimilatory iron reduction of ferrihydrite under advective flow journal, August 2003

Effect of orthophosphate on the oxidation products of Fe(II)-Fe(III) hydroxycarbonate: the transformation of green rust to ferrihydrite journal, June 2001

Distinctive Arsenic(V) Trapping Modes by Magnetite Nanoparticles Induced by Different Sorption Processes journal, September 2011

Dynamic Fe-precipitate formation induced by Fe(II) oxidation in aerated phosphate-containing water journal, September 2013

Identification of Uranyl Surface Complexes on Ferrihydrite: Advanced EXAFS Data Analysis and CD-MUSIC Modeling journal, March 2009

Magnetite and Green Rust: Synthesis, Properties, and Environmental Applications of Mixed-Valent Iron Minerals journal, February 2018

Removal of arsenic from drinking water by the electrocoagulation using Fe and Al electrodes journal, May 2011

Complexation of uranium(VI) with protocatechuic acid?application of iterative transformation factor analysis to EXAFS spectroscopy journal, July 2003

The Dutch–Belgian beamline at the ESRF journal, May 1998

High-order multiple-scattering calculations of x-ray-absorption fine structure journal, December 1992

Evidence for Different Surface Speciation of Arsenite and Arsenate on Green Rust: An EXAFS and XANES Study journal, January 2010

Implementation of a combined SAXS/WAXS/QEXAFS set-up for time-resolved in situ experiments journal, October 2008

Controls on the formation of Fe(II,III) (hydr)oxides by Fe(0) electrolysis journal, October 2018

Oxidation modes and thermodynamics of FeII–III oxyhydroxycarbonate green rust: Dissolution–precipitation versus in situ deprotonation journal, February 2010

Surface speciation of As(III) and As(V) in relation to charge distribution journal, October 2006

Electrochemical formation of a new Fe(II)Fe(III) hydroxy-carbonate green rust: characterisation and morphology journal, March 2001

Iron control by equilibria between hydroxy-Green Rusts and solutions in hydromorphic soils journal, October 1999

Surface complexation of arsenic(V) to iron(III) (hydr)oxides: structural mechanism from ab initio molecular geometries and EXAFS spectroscopy journal, November 2003

Identification of Green Rust in Groundwater journal, May 2009

SIXPack a Graphical User Interface for XAS Analysis Using IFEFFIT journal, January 2005

Remarkable efficiency of phosphate removal: Ferrate(VI)-induced in situ sorption on core-shell nanoparticles journal, October 2016

Formation of green rust and elemental sulfur in an analogue for oxygenated ferro-euxinic transition zones of Precambrian oceans journal, January 2019

Composition and structure of Fe(III)-precipitates formed by Fe(II) oxidation in water at near-neutral pH: Interdependent effects of phosphate, silicate and Ca journal, August 2015

Fe(III) Nucleation in the Presence of Bivalent Cations and Oxyanions Leads to Subnanoscale 7 Å Polymers journal, October 2014

Production and Transformation of Mixed-Valent Nanoparticles Generated by Fe(0) Electrocoagulation journal, February 2015

A key role for green rust in the Precambrian oceans and the genesis of iron formations journal, January 2017

Formation of single domain magnetite by green rust oxidation promoted by microbial anaerobic nitrate-dependent iron oxidation journal, August 2014

Potential indicators for the assessment of arsenic natural attenuation in the subsurface journal, June 2003

Chemical stability of hydroxysulphate green rust synthetised in the presence of foreign anions: carbonate, phosphate and silicate journal, November 2006

Reactivity of Fe(II)-Bearing Minerals toward Reductive Transformation of Organic Contaminants journal, February 2004

Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy journal, May 2012

Reduction of SeO 4 2 - Anions and Anoxic Formation of Iron(II)−Iron(III) Hydroxy-Selenate Green Rust journal, March 2000

Thermodynamic Studies of the Arsenic Adsorption on Iron Species Generated by Electrocoagulation journal, November 2009

Effects of silicate, sulfate, and carbonate on arsenic removal by ferric chloride journal, March 2000

Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate journal, May 1993

The mechanisms of reduction of hexavalent chromium by green rust sodium sulphate: Formation of Cr-goethite journal, July 2006

The Structure of Magnetite and the Spinels journal, July 1915

Removing Arsenic from Synthetic Groundwater with Iron Electrocoagulation: An Fe and As K-Edge EXAFS Study journal, December 2011

Fougerite, a new mineral of the pyroaurite-iowaite group: description and crystal structure journal, June 2007

Effects of phosphate and silicate on the transformation of hydroxycarbonate green rust to ferric oxyhydroxides journal, December 2015

Quantitative antimony speciation in shooting-range soils by EXAFS spectroscopy journal, July 2006

Significance of Iron(II,III) Hydroxycarbonate Green Rust in Arsenic Remediation Using Zerovalent Iron in Laboratory Column Tests journal, October 2004

Structure and stability of the Fe(II)–Fe(III) green rust “fougerite” mineral and its potential for reducing pollutants in soil solutions journal, April 2001

Arsenic(III, V) adsorption on a goethite-based adsorbent in the presence of major co-existing ions: Modeling competitive adsorption consistent with spectroscopic and molecular evidence journal, April 2013

Refinement of the crystal structure of scorodite journal, January 1975

Green rust as a precursor for magnetite: an in situ synchrotron based study journal, February 2008

Modeling As(III) Oxidation and Removal with Iron Electrocoagulation in Groundwater journal, October 2012

Biogenic iron oxyhydroxide formation at mid-ocean ridge hydrothermal vents: Juan de Fuca Ridge journal, January 2009

Mn(II) Oxidation in Fenton and Fenton Type Systems: Identification of Reaction Efficiency and Reaction Products journal, February 2017

Reduction of Halogenated Ethanes by Green rust journal, January 2004

The oxidation of carbonate green rust into ferric phases:solid-state reaction or transformation via solution journal, September 2004

Arsenite sorption at the magnetite–water interface during aqueous precipitation of magnetite: EXAFS evidence for a new arsenite surface complex journal, June 2008

Arsenic Removal with Iron(II) and Iron(III) in Waters with High Silicate and Phosphate Concentrations journal, January 2004

The interfacial reactivity of arsenic species with green rust sulfate (GRSO4) journal, January 2019

IFEFFIT : interactive XAFS analysis and FEFF fitting journal, March 2001

Synthesis and phase transformations involving scorodite, ferric arsenate and arsenical ferrihydrite: Implications for arsenic mobility journal, June 2008

Iron-Catalyzed Oxidation of Arsenic(III) by Oxygen and by Hydrogen Peroxide: pH-Dependent Formation of Oxidants in the Fenton Reaction
journal, June 2003

Arsenic(III) and Arsenic(V) Speciation during Transformation of Lepidocrocite to Magnetite
journal, November 2014

Transformation of hydroxycarbonate green rust into crystalline iron (hydr)oxides: Influences of reaction conditions and underlying mechanisms
journal, August 2013

Ferrate(VI)-Induced Arsenite and Arsenate Removal by In Situ Structural Incorporation into Magnetic Iron(III) Oxide Nanoparticles
journal, March 2013

Effect of phosphate, silicate, and Ca on Fe(III)-precipitates formed in aerated Fe(II)- and As(III)-containing water studied by X-ray absorption spectroscopy
journal, January 2010

Sorption of As(III) and As(V) to siderite, green rust (fougerite) and magnetite: Implications for arsenic release in anoxic groundwaters
journal, September 2008

Iron(II,III) Hydroxycarbonate Green Rust Formation and Stabilization from Lepidocrocite Bioreduction
journal, January 2002

Effect of citrate on the local Fe coordination in ferrihydrite, arsenate binding, and ternary arsenate complex formation
journal, October 2010

Multi-competitive interaction of As(III) and As(V) oxyanions with Ca2+, Mg2+, PO3−4, and CO2−3 ions on goethite
journal, April 2008

Secondary mineralization pathways induced by dissimilatory iron reduction of ferrihydrite under advective flow
journal, August 2003

Effect of orthophosphate on the oxidation products of Fe(II)-Fe(III) hydroxycarbonate: the transformation of green rust to ferrihydrite
journal, June 2001

Distinctive Arsenic(V) Trapping Modes by Magnetite Nanoparticles Induced by Different Sorption Processes
journal, September 2011

Dynamic Fe-precipitate formation induced by Fe(II) oxidation in aerated phosphate-containing water
journal, September 2013

Identification of Uranyl Surface Complexes on Ferrihydrite: Advanced EXAFS Data Analysis and CD-MUSIC Modeling
journal, March 2009

Magnetite and Green Rust: Synthesis, Properties, and Environmental Applications of Mixed-Valent Iron Minerals
journal, February 2018

Removal of arsenic from drinking water by the electrocoagulation using Fe and Al electrodes
journal, May 2011

Complexation of uranium(VI) with protocatechuic acid?application of iterative transformation factor analysis to EXAFS spectroscopy
journal, July 2003

The Dutch–Belgian beamline at the ESRF
journal, May 1998

High-order multiple-scattering calculations of x-ray-absorption fine structure
journal, December 1992

Evidence for Different Surface Speciation of Arsenite and Arsenate on Green Rust: An EXAFS and XANES Study
journal, January 2010

Implementation of a combined SAXS/WAXS/QEXAFS set-up for time-resolved in situ experiments
journal, October 2008

Controls on the formation of Fe(II,III) (hydr)oxides by Fe(0) electrolysis
journal, October 2018

Oxidation modes and thermodynamics of FeII–III oxyhydroxycarbonate green rust: Dissolution–precipitation versus in situ deprotonation
journal, February 2010

Surface speciation of As(III) and As(V) in relation to charge distribution
journal, October 2006

Electrochemical formation of a new Fe(II)Fe(III) hydroxy-carbonate green rust: characterisation and morphology
journal, March 2001

Iron control by equilibria between hydroxy-Green Rusts and solutions in hydromorphic soils
journal, October 1999

Surface complexation of arsenic(V) to iron(III) (hydr)oxides: structural mechanism from ab initio molecular geometries and EXAFS spectroscopy
journal, November 2003

Identification of Green Rust in Groundwater
journal, May 2009

SIXPack a Graphical User Interface for XAS Analysis Using IFEFFIT
journal, January 2005

Remarkable efficiency of phosphate removal: Ferrate(VI)-induced in situ sorption on core-shell nanoparticles
journal, October 2016

Formation of green rust and elemental sulfur in an analogue for oxygenated ferro-euxinic transition zones of Precambrian oceans
journal, January 2019

Composition and structure of Fe(III)-precipitates formed by Fe(II) oxidation in water at near-neutral pH: Interdependent effects of phosphate, silicate and Ca
journal, August 2015

Fe(III) Nucleation in the Presence of Bivalent Cations and Oxyanions Leads to Subnanoscale 7 Å Polymers
journal, October 2014

Production and Transformation of Mixed-Valent Nanoparticles Generated by Fe(0) Electrocoagulation
journal, February 2015

A key role for green rust in the Precambrian oceans and the genesis of iron formations
journal, January 2017

Formation of single domain magnetite by green rust oxidation promoted by microbial anaerobic nitrate-dependent iron oxidation
journal, August 2014

Potential indicators for the assessment of arsenic natural attenuation in the subsurface
journal, June 2003

Chemical stability of hydroxysulphate green rust synthetised in the presence of foreign anions: carbonate, phosphate and silicate
journal, November 2006

Reactivity of Fe(II)-Bearing Minerals toward Reductive Transformation of Organic Contaminants
journal, February 2004

Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy
journal, May 2012

Reduction of SeO ₄ ² ^- Anions and Anoxic Formation of Iron(II)−Iron(III) Hydroxy-Selenate Green Rust
journal, March 2000

Thermodynamic Studies of the Arsenic Adsorption on Iron Species Generated by Electrocoagulation
journal, November 2009

Effects of silicate, sulfate, and carbonate on arsenic removal by ferric chloride
journal, March 2000

Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate
journal, May 1993

The mechanisms of reduction of hexavalent chromium by green rust sodium sulphate: Formation of Cr-goethite
journal, July 2006

The Structure of Magnetite and the Spinels
journal, July 1915

Removing Arsenic from Synthetic Groundwater with Iron Electrocoagulation: An Fe and As K-Edge EXAFS Study
journal, December 2011

Fougerite, a new mineral of the pyroaurite-iowaite group: description and crystal structure
journal, June 2007

Effects of phosphate and silicate on the transformation of hydroxycarbonate green rust to ferric oxyhydroxides
journal, December 2015

Quantitative antimony speciation in shooting-range soils by EXAFS spectroscopy
journal, July 2006

Significance of Iron(II,III) Hydroxycarbonate Green Rust in Arsenic Remediation Using Zerovalent Iron in Laboratory Column Tests
journal, October 2004

Structure and stability of the Fe(II)–Fe(III) green rust “fougerite” mineral and its potential for reducing pollutants in soil solutions
journal, April 2001

Arsenic(III, V) adsorption on a goethite-based adsorbent in the presence of major co-existing ions: Modeling competitive adsorption consistent with spectroscopic and molecular evidence
journal, April 2013

Refinement of the crystal structure of scorodite
journal, January 1975

Green rust as a precursor for magnetite: an in situ synchrotron based study
journal, February 2008

Modeling As(III) Oxidation and Removal with Iron Electrocoagulation in Groundwater
journal, October 2012

Biogenic iron oxyhydroxide formation at mid-ocean ridge hydrothermal vents: Juan de Fuca Ridge
journal, January 2009

Mn(II) Oxidation in Fenton and Fenton Type Systems: Identification of Reaction Efficiency and Reaction Products
journal, February 2017

Reduction of Halogenated Ethanes by Green rust
journal, January 2004

The oxidation of carbonate green rust into ferric phases:solid-state reaction or transformation via solution
journal, September 2004

Arsenite sorption at the magnetite–water interface during aqueous precipitation of magnetite: EXAFS evidence for a new arsenite surface complex
journal, June 2008

Arsenic Removal with Iron(II) and Iron(III) in Waters with High Silicate and Phosphate Concentrations
journal, January 2004

The interfacial reactivity of arsenic species with green rust sulfate (GRSO4)
journal, January 2019

IFEFFIT : interactive XAFS analysis and FEFF fitting
journal, March 2001

Synthesis and phase transformations involving scorodite, ferric arsenate and arsenical ferrihydrite: Implications for arsenic mobility
journal, June 2008