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Title: Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic

Abstract

Structural transformations of green rust and the partitioning of arsenic were tracked during aging for up to a year.

Authors:
ORCiD logo [1];  [2];  [3]
  1. Geological Survey of Denmark and Greenland (GEUS), Copenhagen, Denmark, Department of Earth Sciences – Geochemistry, Faculty of Geosciences
  2. Department of Earth Sciences – Geochemistry, Faculty of Geosciences, Utrecht University, Utrecht, The Netherlands
  3. Geological Survey of Denmark and Greenland (GEUS), Copenhagen, Denmark
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1545397
Grant/Contract Number:  
AC02-76SF00515
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Environmental Science: Processes & Impacts
Additional Journal Information:
Journal Name: Environmental Science: Processes & Impacts Journal Volume: 21 Journal Issue: 9; Journal ID: ISSN 2050-7887
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

van Genuchten, C. M., Behrends, T., and Dideriksen, K. Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic. United Kingdom: N. p., 2019. Web. doi:10.1039/C9EM00267G.
van Genuchten, C. M., Behrends, T., & Dideriksen, K. Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic. United Kingdom. doi:10.1039/C9EM00267G.
van Genuchten, C. M., Behrends, T., and Dideriksen, K. Wed . "Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic". United Kingdom. doi:10.1039/C9EM00267G.
@article{osti_1545397,
title = {Emerging investigator series: interdependency of green rust transformation and the partitioning and binding mode of arsenic},
author = {van Genuchten, C. M. and Behrends, T. and Dideriksen, K.},
abstractNote = {Structural transformations of green rust and the partitioning of arsenic were tracked during aging for up to a year.},
doi = {10.1039/C9EM00267G},
journal = {Environmental Science: Processes & Impacts},
number = 9,
volume = 21,
place = {United Kingdom},
year = {2019},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9EM00267G

Citation Metrics:
Cited by: 2 works
Citation information provided by
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Works referenced in this record:

Iron-Catalyzed Oxidation of Arsenic(III) by Oxygen and by Hydrogen Peroxide:  pH-Dependent Formation of Oxidants in the Fenton Reaction
journal, June 2003

  • Hug, Stephan J.; Leupin, Olivier
  • Environmental Science & Technology, Vol. 37, Issue 12
  • DOI: 10.1021/es026208x

Arsenic(III) and Arsenic(V) Speciation during Transformation of Lepidocrocite to Magnetite
journal, November 2014

  • Wang, Yuheng; Morin, Guillaume; Ona-Nguema, Georges
  • Environmental Science & Technology, Vol. 48, Issue 24
  • DOI: 10.1021/es5033629

Ferrate(VI)-Induced Arsenite and Arsenate Removal by In Situ Structural Incorporation into Magnetic Iron(III) Oxide Nanoparticles
journal, March 2013

  • Prucek, Robert; Tuček, Jiří; Kolařík, Jan
  • Environmental Science & Technology, Vol. 47, Issue 7
  • DOI: 10.1021/es3042719

Effect of phosphate, silicate, and Ca on Fe(III)-precipitates formed in aerated Fe(II)- and As(III)-containing water studied by X-ray absorption spectroscopy
journal, January 2010

  • Voegelin, Andreas; Kaegi, Ralf; Frommer, Jakob
  • Geochimica et Cosmochimica Acta, Vol. 74, Issue 1
  • DOI: 10.1016/j.gca.2009.09.020

Iron(II,III) Hydroxycarbonate Green Rust Formation and Stabilization from Lepidocrocite Bioreduction
journal, January 2002

  • Ona-Nguema, Georges; Abdelmoula, Mustapha; Jorand, Frédéric
  • Environmental Science & Technology, Vol. 36, Issue 1
  • DOI: 10.1021/es0020456

Effect of citrate on the local Fe coordination in ferrihydrite, arsenate binding, and ternary arsenate complex formation
journal, October 2010

  • Mikutta, Christian; Frommer, Jakob; Voegelin, Andreas
  • Geochimica et Cosmochimica Acta, Vol. 74, Issue 19
  • DOI: 10.1016/j.gca.2010.06.024

Multi-competitive interaction of As(III) and As(V) oxyanions with Ca2+, Mg2+, PO3−4, and CO2−3 ions on goethite
journal, April 2008

  • Stachowicz, Monika; Hiemstra, Tjisse; van Riemsdijk, Willem H.
  • Journal of Colloid and Interface Science, Vol. 320, Issue 2
  • DOI: 10.1016/j.jcis.2008.01.007

Secondary mineralization pathways induced by dissimilatory iron reduction of ferrihydrite under advective flow
journal, August 2003


Effect of orthophosphate on the oxidation products of Fe(II)-Fe(III) hydroxycarbonate: the transformation of green rust to ferrihydrite
journal, June 2001


Distinctive Arsenic(V) Trapping Modes by Magnetite Nanoparticles Induced by Different Sorption Processes
journal, September 2011

  • Wang, Yuheng; Morin, Guillaume; Ona-Nguema, Georges
  • Environmental Science & Technology, Vol. 45, Issue 17
  • DOI: 10.1021/es200299f

Dynamic Fe-precipitate formation induced by Fe(II) oxidation in aerated phosphate-containing water
journal, September 2013

  • Voegelin, Andreas; Senn, Anna-Caterina; Kaegi, Ralf
  • Geochimica et Cosmochimica Acta, Vol. 117
  • DOI: 10.1016/j.gca.2013.04.022

Identification of Uranyl Surface Complexes on Ferrihydrite: Advanced EXAFS Data Analysis and CD-MUSIC Modeling
journal, March 2009

  • Rossberg, André; Ulrich, Kai-Uwe; Weiss, Stephan
  • Environmental Science & Technology, Vol. 43, Issue 5
  • DOI: 10.1021/es801727w

Magnetite and Green Rust: Synthesis, Properties, and Environmental Applications of Mixed-Valent Iron Minerals
journal, February 2018


Removal of arsenic from drinking water by the electrocoagulation using Fe and Al electrodes
journal, May 2011


Complexation of uranium(VI) with protocatechuic acid?application of iterative transformation factor analysis to EXAFS spectroscopy
journal, July 2003

  • Ro�berg, A.; Reich, T.; Bernhard, G.
  • Analytical and Bioanalytical Chemistry, Vol. 376, Issue 5
  • DOI: 10.1007/s00216-003-1963-5

The Dutch–Belgian beamline at the ESRF
journal, May 1998


High-order multiple-scattering calculations of x-ray-absorption fine structure
journal, December 1992


Evidence for Different Surface Speciation of Arsenite and Arsenate on Green Rust: An EXAFS and XANES Study
journal, January 2010

  • Wang, Yuheng; Morin, Guillaume; Ona-Nguema, Georges
  • Environmental Science & Technology, Vol. 44, Issue 1
  • DOI: 10.1021/es901627e

Implementation of a combined SAXS/WAXS/QEXAFS set-up for time-resolved in situ experiments
journal, October 2008

  • Nikitenko, Sergey; Beale, Andrew M.; van der Eerden, Ad M. J.
  • Journal of Synchrotron Radiation, Vol. 15, Issue 6
  • DOI: 10.1107/S0909049508023327

Controls on the formation of Fe(II,III) (hydr)oxides by Fe(0) electrolysis
journal, October 2018


Oxidation modes and thermodynamics of FeII–III oxyhydroxycarbonate green rust: Dissolution–precipitation versus in situ deprotonation
journal, February 2010

  • Ruby, Christian; Abdelmoula, Mustapha; Naille, Sébastien
  • Geochimica et Cosmochimica Acta, Vol. 74, Issue 3
  • DOI: 10.1016/j.gca.2009.10.030

Surface speciation of As(III) and As(V) in relation to charge distribution
journal, October 2006

  • Stachowicz, Monika; Hiemstra, Tjisse; van Riemsdijk, Willem H.
  • Journal of Colloid and Interface Science, Vol. 302, Issue 1
  • DOI: 10.1016/j.jcis.2006.06.030

Electrochemical formation of a new Fe(II)Fe(III) hydroxy-carbonate green rust: characterisation and morphology
journal, March 2001


Iron control by equilibria between hydroxy-Green Rusts and solutions in hydromorphic soils
journal, October 1999

  • Bourrié, Guilhem; Trolard, Fabienne; Jaffrezic, Jean-Marie Robert GéninAnne
  • Geochimica et Cosmochimica Acta, Vol. 63, Issue 19-20
  • DOI: 10.1016/S0016-7037(99)00262-8

Surface complexation of arsenic(V) to iron(III) (hydr)oxides: structural mechanism from ab initio molecular geometries and EXAFS spectroscopy
journal, November 2003


Identification of Green Rust in Groundwater
journal, May 2009

  • Christiansen, B. C.; Balic-Zunic, T.; Dideriksen, K.
  • Environmental Science & Technology, Vol. 43, Issue 10
  • DOI: 10.1021/es8011047

Remarkable efficiency of phosphate removal: Ferrate(VI)-induced in situ sorption on core-shell nanoparticles
journal, October 2016


Formation of green rust and elemental sulfur in an analogue for oxygenated ferro-euxinic transition zones of Precambrian oceans
journal, January 2019

  • Koeksoy, E.; Sundman, A.; Byrne, J. M.
  • Geology, Vol. 47, Issue 3
  • DOI: 10.1130/G45501.1

Composition and structure of Fe(III)-precipitates formed by Fe(II) oxidation in water at near-neutral pH: Interdependent effects of phosphate, silicate and Ca
journal, August 2015


Fe(III) Nucleation in the Presence of Bivalent Cations and Oxyanions Leads to Subnanoscale 7 Å Polymers
journal, October 2014

  • van Genuchten, Case M.; Gadgil, Ashok J.; Peña, Jasquelin
  • Environmental Science & Technology, Vol. 48, Issue 20
  • DOI: 10.1021/es503281a

Production and Transformation of Mixed-Valent Nanoparticles Generated by Fe(0) Electrocoagulation
journal, February 2015

  • Dubrawski, Kristian L.; van Genuchten, Case M.; Delaire, Caroline
  • Environmental Science & Technology, Vol. 49, Issue 4
  • DOI: 10.1021/es505059d

A key role for green rust in the Precambrian oceans and the genesis of iron formations
journal, January 2017

  • Halevy, I.; Alesker, M.; Schuster, E. M.
  • Nature Geoscience, Vol. 10, Issue 2
  • DOI: 10.1038/ngeo2878

Formation of single domain magnetite by green rust oxidation promoted by microbial anaerobic nitrate-dependent iron oxidation
journal, August 2014


Potential indicators for the assessment of arsenic natural attenuation in the subsurface
journal, June 2003


Chemical stability of hydroxysulphate green rust synthetised in the presence of foreign anions: carbonate, phosphate and silicate
journal, November 2006


Reactivity of Fe(II)-Bearing Minerals toward Reductive Transformation of Organic Contaminants
journal, February 2004

  • Elsner, Martin; Schwarzenbach, René P.; Haderlein, Stefan B.
  • Environmental Science & Technology, Vol. 38, Issue 3
  • DOI: 10.1021/es0345569

Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy
journal, May 2012

  • Manceau, A.; Marcus, M. A.; Grangeon, S.
  • American Mineralogist, Vol. 97, Issue 5-6
  • DOI: 10.2138/am.2012.3903

Reduction of SeO 4 2 - Anions and Anoxic Formation of Iron(II)−Iron(III) Hydroxy-Selenate Green Rust
journal, March 2000

  • Refait, Philippe; Simon, Lilian; Génin, Jean-Marie R.
  • Environmental Science & Technology, Vol. 34, Issue 5
  • DOI: 10.1021/es990376g

Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate
journal, May 1993


The mechanisms of reduction of hexavalent chromium by green rust sodium sulphate: Formation of Cr-goethite
journal, July 2006

  • Skovbjerg, L. L.; Stipp, S. L. S.; Utsunomiya, S.
  • Geochimica et Cosmochimica Acta, Vol. 70, Issue 14
  • DOI: 10.1016/j.gca.2006.02.017

The Structure of Magnetite and the Spinels
journal, July 1915


Removing Arsenic from Synthetic Groundwater with Iron Electrocoagulation: An Fe and As K-Edge EXAFS Study
journal, December 2011

  • van Genuchten, Case M.; Addy, Susan E. A.; Peña, Jasquelin
  • Environmental Science & Technology, Vol. 46, Issue 2
  • DOI: 10.1021/es201913a

Fougerite, a new mineral of the pyroaurite-iowaite group: description and crystal structure
journal, June 2007

  • Trolard, Fabienne; Bourrié, Guilhem; Abdelmoula, Mustapha
  • Clays and Clay Minerals, Vol. 55, Issue 3
  • DOI: 10.1346/CCMN.2007.0550308

Effects of phosphate and silicate on the transformation of hydroxycarbonate green rust to ferric oxyhydroxides
journal, December 2015


Quantitative antimony speciation in shooting-range soils by EXAFS spectroscopy
journal, July 2006

  • Scheinost, Andreas C.; Rossberg, Andre; Vantelon, Delphine
  • Geochimica et Cosmochimica Acta, Vol. 70, Issue 13
  • DOI: 10.1016/j.gca.2006.03.020

Significance of Iron(II,III) Hydroxycarbonate Green Rust in Arsenic Remediation Using Zerovalent Iron in Laboratory Column Tests
journal, October 2004

  • Su, Chunming; Puls, Robert W.
  • Environmental Science & Technology, Vol. 38, Issue 19
  • DOI: 10.1021/es0495462

Structure and stability of the Fe(II)–Fe(III) green rust “fougerite” mineral and its potential for reducing pollutants in soil solutions
journal, April 2001


Refinement of the crystal structure of scorodite
journal, January 1975

  • Kitahama, K.; Kiriyama, R.; Baba, Y.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 31, Issue 1
  • DOI: 10.1107/S056774087500266X

Green rust as a precursor for magnetite: an in situ synchrotron based study
journal, February 2008


Modeling As(III) Oxidation and Removal with Iron Electrocoagulation in Groundwater
journal, October 2012

  • Li, Lei; van Genuchten, Case M.; Addy, Susan E. A.
  • Environmental Science & Technology, Vol. 46, Issue 21
  • DOI: 10.1021/es302456b

Biogenic iron oxyhydroxide formation at mid-ocean ridge hydrothermal vents: Juan de Fuca Ridge
journal, January 2009

  • Toner, Brandy M.; Santelli, Cara M.; Marcus, Matthew A.
  • Geochimica et Cosmochimica Acta, Vol. 73, Issue 2
  • DOI: 10.1016/j.gca.2008.09.035

Mn(II) Oxidation in Fenton and Fenton Type Systems: Identification of Reaction Efficiency and Reaction Products
journal, February 2017

  • van Genuchten, Case M.; Peña, Jasquelin
  • Environmental Science & Technology, Vol. 51, Issue 5
  • DOI: 10.1021/acs.est.6b05584

Reduction of Halogenated Ethanes by Green rust
journal, January 2004

  • O'Loughlin, Edward J.; Burris, David R.
  • Environmental Toxicology and Chemistry, Vol. 23, Issue 1
  • DOI: 10.1897/03-45

The oxidation of carbonate green rust into ferric phases:solid-state reaction or transformation via solution
journal, September 2004

  • Legrand, Ludovic; Mazerolles, Léo; Chaussé, Annie
  • Geochimica et Cosmochimica Acta, Vol. 68, Issue 17
  • DOI: 10.1016/j.gca.2004.02.019

Arsenite sorption at the magnetite–water interface during aqueous precipitation of magnetite: EXAFS evidence for a new arsenite surface complex
journal, June 2008

  • Wang, Yuheng; Morin, Guillaume; Ona-Nguema, Georges
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 11
  • DOI: 10.1016/j.gca.2008.03.011

Arsenic Removal with Iron(II) and Iron(III) in Waters with High Silicate and Phosphate Concentrations
journal, January 2004

  • Roberts, Linda C.; Hug, Stephan J.; Ruettimann, Thomas
  • Environmental Science & Technology, Vol. 38, Issue 1
  • DOI: 10.1021/es0343205

The interfacial reactivity of arsenic species with green rust sulfate (GRSO4)
journal, January 2019


IFEFFIT  : interactive XAFS analysis and FEFF fitting
journal, March 2001


Synthesis and phase transformations involving scorodite, ferric arsenate and arsenical ferrihydrite: Implications for arsenic mobility
journal, June 2008

  • Paktunc, Dogan; Dutrizac, John; Gertsman, Valery
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 11
  • DOI: 10.1016/j.gca.2008.03.012