Nitrogen-doped carbons derived from poly(ionic liquid)s with various backbones and cations
Abstract
In this study, poly(ionic liquid)s (PILs) with various backbone/cation pairings (backbones - ethyl methacrylate, styrene; covalently attached cations - butylimidazolium, trimethylammonium, butylpyrrolidinium) were successfully synthesized as carbon precursors. Pyrolysis of PILs produced carbons with sheet-like structures with a metallic luster in contrast to the powder form of carbons produced from polyacrylonitrile. The results also show that cation type has a significant impact on surface area, graphitic content, graphitic nitrogen content, nitrogen retention, carbon yield and surface chemistry of the PIL-derived carbons. The design of nitrogen-doped carbons based on a diverse set of PILs with various cation and polymer backbone chemistries may be an effective strategy to optimize carbon properties for subsequent application in energy storage devices.
- Authors:
-
[1]
- Texas A & M Univ., College Station, TX (United States)
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1544536
- Report Number(s):
- NREL/JA-5900-74350
Journal ID: ISSN 0959-8103
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Polymer International
- Additional Journal Information:
- Journal Volume: 68; Journal Issue: 9; Journal ID: ISSN 0959-8103
- Publisher:
- Society of Chemical Industry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; ionic liquid; polymer; carbon; nitrogen; graphitic; capacitor; battery
Citation Formats
Sun, Rui, Meek, Kelly M., Ho, Hoi Chun, and Elabd, Yossef A. Nitrogen-doped carbons derived from poly(ionic liquid)s with various backbones and cations. United States: N. p., 2019.
Web. doi:10.1002/pi.5864.
Sun, Rui, Meek, Kelly M., Ho, Hoi Chun, & Elabd, Yossef A. Nitrogen-doped carbons derived from poly(ionic liquid)s with various backbones and cations. United States. https://doi.org/10.1002/pi.5864
Sun, Rui, Meek, Kelly M., Ho, Hoi Chun, and Elabd, Yossef A. Fri .
"Nitrogen-doped carbons derived from poly(ionic liquid)s with various backbones and cations". United States. https://doi.org/10.1002/pi.5864. https://www.osti.gov/servlets/purl/1544536.
@article{osti_1544536,
title = {Nitrogen-doped carbons derived from poly(ionic liquid)s with various backbones and cations},
author = {Sun, Rui and Meek, Kelly M. and Ho, Hoi Chun and Elabd, Yossef A.},
abstractNote = {In this study, poly(ionic liquid)s (PILs) with various backbone/cation pairings (backbones - ethyl methacrylate, styrene; covalently attached cations - butylimidazolium, trimethylammonium, butylpyrrolidinium) were successfully synthesized as carbon precursors. Pyrolysis of PILs produced carbons with sheet-like structures with a metallic luster in contrast to the powder form of carbons produced from polyacrylonitrile. The results also show that cation type has a significant impact on surface area, graphitic content, graphitic nitrogen content, nitrogen retention, carbon yield and surface chemistry of the PIL-derived carbons. The design of nitrogen-doped carbons based on a diverse set of PILs with various cation and polymer backbone chemistries may be an effective strategy to optimize carbon properties for subsequent application in energy storage devices.},
doi = {10.1002/pi.5864},
journal = {Polymer International},
number = 9,
volume = 68,
place = {United States},
year = {Fri May 31 00:00:00 EDT 2019},
month = {Fri May 31 00:00:00 EDT 2019}
}
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