Understanding the electrochemical reaction mechanism of VS2 nanosheets in lithium-ion cells by multiple in situ and ex situ x-ray spectroscopy
Abstract
Recently, 2D layered transition metal dichalcogenides (TMDs) have attracted great scientific interest in electrochemical energy storage research. Vanadium disulfide (VS2) as an important family member of TMDs, is a promising electrode material for lithium-ion cells because of its remarkable electrical conductivity and high Li+ diffusion rate, but its electrochemical reaction mechanism is still poorly understood. Herein, we have prepared VS2 nanosheets as the electrode and systematically investigated its structural and chemical evolution during the electrochemical processes by employing both in situ and ex situ x-ray spectroscopy. The VS2 undergoes intercalation and conversion reactions in sequence during discharge and this process is found to be partially reversible during the subsequent charge. The decreased reversibility of the conversion reaction over extended cycles could be mainly responsible for the capacity fading of the VS2 electrode. Furthermore, the hybridization strength between S and V shows a strong dependence on the states of charge, as directly illustrated by the intensity change of the V-S hybridized states and pure V states. We have additionally found that the solid electrolyte interphase on the electrode surface is dynamically evolved during cycling, which may be a universal phenomenon for the conversion-based electrodes. Our research is expected to be beneficialmore »
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Univ. of California, Los Angeles, CA (United States)
- Univ. of Science and Technology of China, Hefei (China)
- Wuhan Univ. of Technology (China). State Key Lab. of Advanced Technology for Materials Synthesis and Processing
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Santa Cruz, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1542316
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physics. D, Applied Physics
- Additional Journal Information:
- Journal Volume: 51; Journal Issue: 49; Journal ID: ISSN 0022-3727
- Publisher:
- IOP Publishing
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Zhang, Liang, Sun, Dan, Wei, Qiulong, Ju, Huanxin, Feng, Jun, Zhu, Junfa, Mai, Liqiang, Cairns, Elton J., and Guo, Jinghua. Understanding the electrochemical reaction mechanism of VS2 nanosheets in lithium-ion cells by multiple in situ and ex situ x-ray spectroscopy. United States: N. p., 2018.
Web. doi:10.1088/1361-6463/aadde7.
Zhang, Liang, Sun, Dan, Wei, Qiulong, Ju, Huanxin, Feng, Jun, Zhu, Junfa, Mai, Liqiang, Cairns, Elton J., & Guo, Jinghua. Understanding the electrochemical reaction mechanism of VS2 nanosheets in lithium-ion cells by multiple in situ and ex situ x-ray spectroscopy. United States. https://doi.org/10.1088/1361-6463/aadde7
Zhang, Liang, Sun, Dan, Wei, Qiulong, Ju, Huanxin, Feng, Jun, Zhu, Junfa, Mai, Liqiang, Cairns, Elton J., and Guo, Jinghua. Mon .
"Understanding the electrochemical reaction mechanism of VS2 nanosheets in lithium-ion cells by multiple in situ and ex situ x-ray spectroscopy". United States. https://doi.org/10.1088/1361-6463/aadde7. https://www.osti.gov/servlets/purl/1542316.
@article{osti_1542316,
title = {Understanding the electrochemical reaction mechanism of VS2 nanosheets in lithium-ion cells by multiple in situ and ex situ x-ray spectroscopy},
author = {Zhang, Liang and Sun, Dan and Wei, Qiulong and Ju, Huanxin and Feng, Jun and Zhu, Junfa and Mai, Liqiang and Cairns, Elton J. and Guo, Jinghua},
abstractNote = {Recently, 2D layered transition metal dichalcogenides (TMDs) have attracted great scientific interest in electrochemical energy storage research. Vanadium disulfide (VS2) as an important family member of TMDs, is a promising electrode material for lithium-ion cells because of its remarkable electrical conductivity and high Li+ diffusion rate, but its electrochemical reaction mechanism is still poorly understood. Herein, we have prepared VS2 nanosheets as the electrode and systematically investigated its structural and chemical evolution during the electrochemical processes by employing both in situ and ex situ x-ray spectroscopy. The VS2 undergoes intercalation and conversion reactions in sequence during discharge and this process is found to be partially reversible during the subsequent charge. The decreased reversibility of the conversion reaction over extended cycles could be mainly responsible for the capacity fading of the VS2 electrode. Furthermore, the hybridization strength between S and V shows a strong dependence on the states of charge, as directly illustrated by the intensity change of the V-S hybridized states and pure V states. We have additionally found that the solid electrolyte interphase on the electrode surface is dynamically evolved during cycling, which may be a universal phenomenon for the conversion-based electrodes. Our research is expected to be beneficial for the further development of high-performance VS2-based electrodes.},
doi = {10.1088/1361-6463/aadde7},
journal = {Journal of Physics. D, Applied Physics},
number = 49,
volume = 51,
place = {United States},
year = {Mon Sep 17 00:00:00 EDT 2018},
month = {Mon Sep 17 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
SEI Dynamics in Metal Oxide Conversion Electrodes of Li-Ion Batteries
journal, November 2017
- Rezvani, S. J.; Nobili, F.; Gunnella, R.
- The Journal of Physical Chemistry C, Vol. 121, Issue 47
RESONANT SOFT X-RAY EMISSION SPECTROSCOPY OF V 2 O 3 , VO 2 and NaV 2 O 5
journal, April 2002
- Schmitt, T.; Duda, L. -C.; Augustsson, A.
- Surface Review and Letters, Vol. 09, Issue 02
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Nanowire Electrodes for Electrochemical Energy Storage Devices
journal, October 2014
- Mai, Liqiang; Tian, Xiaocong; Xu, Xu
- Chemical Reviews, Vol. 114, Issue 23
Understanding Conversion-Type Electrodes for Lithium Rechargeable Batteries
journal, January 2018
- Yu, Seung-Ho; Feng, Xinran; Zhang, Na
- Accounts of Chemical Research, Vol. 51, Issue 2
MoS 2 Nanosheets Vertically Grown on Graphene Sheets for Lithium-Ion Battery Anodes
journal, August 2016
- Teng, Yongqiang; Zhao, Hailei; Zhang, Zijia
- ACS Nano, Vol. 10, Issue 9
Valence band electronic structure of V2O5 as determined by resonant soft X-ray emission spectroscopy
journal, November 2005
- Khyzhun, O. Yu.; Strunskus, T.; Grünert, W.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 149, Issue 1-3
Breathing and oscillating growth of solid-electrolyte-interphase upon electrochemical cycling
journal, January 2018
- Zhuo, Zengqing; Lu, Peng; Delacourt, Charles
- Chemical Communications, Vol. 54, Issue 7
Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights
journal, October 2015
- Gauthier, Magali; Carney, Thomas J.; Grimaud, Alexis
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
Lithium ion battery applications of molybdenum disulfide (MoS 2 ) nanocomposites
journal, January 2014
- Stephenson, Tyler; Li, Zhi; Olsen, Brian
- Energy Environ. Sci., Vol. 7, Issue 1
-edge absorption spectra of selected vanadium compounds
journal, November 1984
- Wong, J.; Lytle, F. W.; Messmer, R. P.
- Physical Review B, Vol. 30, Issue 10
Recent Progress on Synchrotron-Based In-Situ Soft X-ray Spectroscopy for Energy Materials
journal, May 2014
- Liu, Xiaosong; Yang, Wanli; Liu, Zhi
- Advanced Materials, Vol. 26, Issue 46
Sulfur K -Edge X-Ray-Absorption Study of the Charge Transfer upon Lithium Intercalation into Titanium Disulfide
journal, September 1996
- Wu, Z. Y.; Ouvrard, G.; Lemaux, S.
- Physical Review Letters, Vol. 77, Issue 10
X-ray absorption fine structure studies of FeS2 cathodes in lithium polymer electrolyte batteries
journal, September 1999
- Kostov, S.; denBoer, M.; Strauss, E.
- Journal of Power Sources, Vol. 81-82
Electrochemical Reaction Mechanism of the MoS 2 Electrode in a Lithium-Ion Cell Revealed by in Situ and Operando X-ray Absorption Spectroscopy
journal, January 2018
- Zhang, Liang; Sun, Dan; Kang, Jun
- Nano Letters, Vol. 18, Issue 2
VS 2 /Graphene Heterostructures as Promising Anode Material for Li-Ion Batteries
journal, October 2017
- Mikhaleva, Natalia S.; Visotin, Maxim A.; Kuzubov, Aleksandr A.
- The Journal of Physical Chemistry C, Vol. 121, Issue 43
Solid Electrolyte Interphase in Li-Ion Batteries: Evolving Structures Measured In situ by Neutron Reflectometry
journal, May 2012
- Owejan, Jeanette E.; Owejan, Jon P.; DeCaluwe, Steven C.
- Chemistry of Materials, Vol. 24, Issue 11
Recent development of two-dimensional transition metal dichalcogenides and their applications
journal, April 2017
- Choi, Wonbong; Choudhary, Nitin; Han, Gang Hee
- Materials Today, Vol. 20, Issue 3
Understanding the Charging Mechanism of Lithium-Sulfur Batteries Using Spatially Resolved Operando X-Ray Absorption Spectroscopy
journal, January 2016
- Gorlin, Yelena; Patel, Manu U. M.; Freiberg, Anna
- Journal of The Electrochemical Society, Vol. 163, Issue 6
A Study of the Solid-Electrolyte-Interface (SEI) of ZnMn 2 O 4 : A Conversion-Type Anode Material for Li-Ion Batteries
journal, January 2015
- Duncan, Hugues; Courtel, Fabrice M.; Abu-Lebdeh, Yaser
- Journal of The Electrochemical Society, Vol. 162, Issue 13
MoS 2 -Based Nanocomposites for Electrochemical Energy Storage
journal, December 2016
- Wang, Tianyi; Chen, Shuangqiang; Pang, Huan
- Advanced Science, Vol. 4, Issue 2
Phase evolution for conversion reaction electrodes in lithium-ion batteries
journal, February 2014
- Lin, Feng; Nordlund, Dennis; Weng, Tsu-Chien
- Nature Communications, Vol. 5, Issue 1
The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013
- Goodenough, John B.; Park, Kyu-Sung
- Journal of the American Chemical Society, Vol. 135, Issue 4
Ultimate Limits to Intercalation Reactions for Lithium Batteries
journal, October 2014
- Whittingham, M. Stanley
- Chemical Reviews, Vol. 114, Issue 23
Electronic structure studies of by soft x-ray emission spectroscopy: Band-like and excitonic vanadium states
journal, March 2004
- Schmitt, T.; Duda, L. -C.; Matsubara, M.
- Physical Review B, Vol. 69, Issue 12
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000
- Poizot, P.; Laruelle, S.; Grugeon, S.
- Nature, Vol. 407, Issue 6803, p. 496-499
Hierarchical VS 2 Nanosheet Assemblies: A Universal Host Material for the Reversible Storage of Alkali Metal Ions
journal, July 2017
- Zhou, Junhua; Wang, Lu; Yang, Mingye
- Advanced Materials, Vol. 29, Issue 35
Revealing the Electrochemical Charging Mechanism of Nanosized Li 2 S by in Situ and Operando X-ray Absorption Spectroscopy
journal, July 2017
- Zhang, Liang; Sun, Dan; Feng, Jun
- Nano Letters, Vol. 17, Issue 8
Electron Energy-loss Spectroscopy Study of the Metal-insulator Transition in VO 2
journal, January 1997
- Abe, Hiroyuki; Terauchi, Masami; Tanaka, Michiyoshi
- Japanese Journal of Applied Physics, Vol. 36, Issue Part 1, No. 1A
Recent Advances in Ultrathin Two-Dimensional Nanomaterials
journal, March 2017
- Tan, Chaoliang; Cao, Xiehong; Wu, Xue-Jun
- Chemical Reviews, Vol. 117, Issue 9
Metallic VS 2 Monolayer: A Promising 2D Anode Material for Lithium Ion Batteries
journal, November 2013
- Jing, Yu; Zhou, Zhen; Cabrera, Carlos R.
- The Journal of Physical Chemistry C, Vol. 117, Issue 48
Hierarchical flower-like VS2 nanosheets – A high rate-capacity and stable anode material for sodium-ion battery
journal, March 2018
- Yu, Dongxu; Pang, Qiang; Gao, Yu
- Energy Storage Materials, Vol. 11
Behind the color switching in gasochromic VO 2
journal, January 2015
- Chen, Jeng-Lung; Chang, Chun-Chieh; Ho, Ying-Kai
- Physical Chemistry Chemical Physics, Vol. 17, Issue 5
Na-Ion Intercalation and Charge Storage Mechanism in 2D Vanadium Carbide
journal, July 2017
- Bak, Seong-Min; Qiao, Ruimin; Yang, Wanli
- Advanced Energy Materials, Vol. 7, Issue 20
One-step strategy to three-dimensional graphene/VO 2 nanobelt composite hydrogels for high performance supercapacitors
journal, January 2014
- Wang, Huanwen; Yi, Huan; Chen, Xiao
- J. Mater. Chem. A, Vol. 2, Issue 4
Electrode–electrolyte interfaces in lithium-based batteries
journal, January 2018
- Yu, Xingwen; Manthiram, Arumugam
- Energy & Environmental Science, Vol. 11, Issue 3
Recent Developments on and Prospects for Electrode Materials with Hierarchical Structures for Lithium-Ion Batteries
journal, November 2017
- Zhou, Limin; Zhang, Kai; Hu, Zhe
- Advanced Energy Materials, Vol. 8, Issue 6
First-principles investigations of vanadium disulfide for lithium and sodium ion battery applications
journal, January 2016
- Wang, Wenhui; Sun, Zhongti; Zhang, Wenshuai
- RSC Advances, Vol. 6, Issue 60
Study on structure and electrochemical properties of carbon-coated monoclinic Li3V2(PO4)3 using synchrotron based in situ X-ray diffraction and absorption
journal, August 2013
- Yoon, Jeongbae; Muhammad, Shoaib; Jang, Donghyuk
- Journal of Alloys and Compounds, Vol. 569
Novel layer-by-layer stacked VS2 nanosheets with intercalation pseudocapacitance for high-rate sodium ion charge storage
journal, May 2017
- Sun, Ruimin; Wei, Qiulong; Sheng, Jinzhi
- Nano Energy, Vol. 35
Vanadium K-Edge X-ray Absorption Spectroscopy as a Probe of the Heterogeneous Lithiation of V 2 O 5 : First-Principles Modeling and Principal Component Analysis
journal, October 2016
- Horrocks, Gregory A.; Braham, Erick J.; Liang, Yufeng
- The Journal of Physical Chemistry C, Vol. 120, Issue 42
First principles calculations of the structure and V L-edge X-ray absorption spectra of V2O5 using local pair natural orbital coupled cluster theory and spin–orbit coupled configuration interaction approaches
journal, January 2013
- Maganas, Dimitrios; Roemelt, Michael; Hävecker, Michael
- Physical Chemistry Chemical Physics, Vol. 15, Issue 19
Investigation of electronic and local structural changes during lithium uptake and release of nano-crystalline NiFe2O4 by X-ray absorption spectroscopy
journal, February 2017
- Zhou, Dong; Permien, Stefan; Rana, Jatinkumar
- Journal of Power Sources, Vol. 342
Formation of graphene-encapsulated CoS 2 hybrid composites with hierarchical structures for high-performance lithium-ion batteries
journal, January 2017
- Tao, Shi; Huang, Weifeng; Xie, Hui
- RSC Advances, Vol. 7, Issue 63
Li–O2 and Li–S batteries with high energy storage
journal, January 2012
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 1, p. 19-29
Key electronic states in lithium battery materials probed by soft X-ray spectroscopy
journal, October 2013
- Yang, Wanli; Liu, Xiaosong; Qiao, Ruimin
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 190
Amorphous Metal Polysulfides: Electrode Materials with Unique Insertion/Extraction Reactions
journal, June 2017
- Sakuda, Atsushi; Ohara, Koji; Fukuda, Katsutoshi
- Journal of the American Chemical Society, Vol. 139, Issue 26
Review—SEI: Past, Present and Future
journal, January 2017
- Peled, E.; Menkin, S.
- Journal of The Electrochemical Society, Vol. 164, Issue 7
Facile Hydrothermal Synthesis of VS 2 /Graphene Nanocomposites with Superior High-Rate Capability as Lithium-Ion Battery Cathodes
journal, March 2015
- Fang, Wenying; Zhao, Hongbin; Xie, Yanping
- ACS Applied Materials & Interfaces, Vol. 7, Issue 23
Works referencing / citing this record:
Emerging Layered Metallic Vanadium Disulfide for Rechargeable Metal‐Ion Batteries: Progress and Opportunities
journal, March 2020
- Li, Wenbin; Kheimeh Sari, Hirbod Maleki; Li, Xifei
- ChemSusChem, Vol. 13, Issue 6