The remarkable influence of N, O-ligands in the assembly of a bis-calix[4]arene-supported [MnIV2MnIII10MnII8] cluster

Coletta, Marco; Sanz, Sergio; McCormick, Laura J.; Teat, Simon J.; Brechin, Euan K.; Dalgarno, Scott J.

doi:10.1039/c7dt04233g

Title: The remarkable influence of N, O-ligands in the assembly of a bis-calix[4]arene-supported [Mn^IV₂Mn^III₁₀Mn^II₈] cluster

Journal Article · 23 November 2017 · Dalton Transactions

DOI: https://doi.org/10.1039/c7dt04233g · OSTI ID:1530277

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Heriot-Watt Univ., Riccarton, Edinburgh (United Kingdom)
Univ. of Edinburgh, Scotland (United Kingdom)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

We report that calix[4]arenes are versatile ligands, capable of supporting the formation of a wide variety of polymetallic clusters comprising 3d, 4f or 3d-4f metal ions. Calixarene-based metal ion fragments act as both bridging and structure capping moieties in these systems, and this behaviour is systematically extended upon moving to bis-calix[4]arene, a relatively new ligand in which two calix[4]arenes are tethered at the methylene bridge position. N,O-Ligands greatly influence cluster formation with bis-calix[4]arene, affording a remarkable mixed-valence [Mn^IV₂Mn^III₁₀Mn^II₈] cluster that displays coordination chemistry typical of each ligand type, but also new structure capping behaviour for the latter.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1530277

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 48 Vol. 46; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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With complements of the ligands: an unusual S -shaped [Mn ₇ ] ₂ assembly from tethered calixarenes Coletta, Marco; Sanz, Sergio; Brechin, Euan K. Dalton Transactions, Vol. 49, Issue 28 https://doi.org/10.1039/d0dt01766c	journal	January 2020

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Title: The remarkable influence of N, O-ligands in the assembly of a bis-calix[4]arene-supported [MnIV2MnIII10MnII8] cluster

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Title: The remarkable influence of N, O-ligands in the assembly of a bis-calix[4]arene-supported [Mn^IV₂Mn^III₁₀Mn^II₈] cluster