The remarkable influence of N, O-ligands in the assembly of a bis-calix[4]arene-supported [MnIV2MnIII10MnII8] cluster

Coletta, Marco; Sanz, Sergio; McCormick, Laura J.; Teat, Simon J.; Brechin, Euan K.; Dalgarno, Scott J.

doi:10.1039/c7dt04233g

Title: The remarkable influence of N, O-ligands in the assembly of a bis-calix[4]arene-supported [Mn^IV₂Mn^III₁₀Mn^II₈] cluster

Journal Article · 24 November 2017 · Dalton Transactions

DOI: https://doi.org/10.1039/c7dt04233g · OSTI ID:1530277

^[1];

^[2];

^[3]; Teat, Simon J. ^[3];

^[2];

^[1]

Heriot-Watt Univ., Riccarton, Edinburgh (United Kingdom)
Univ. of Edinburgh, Scotland (United Kingdom)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

We report that calix[4]arenes are versatile ligands, capable of supporting the formation of a wide variety of polymetallic clusters comprising 3d, 4f or 3d-4f metal ions. Calixarene-based metal ion fragments act as both bridging and structure capping moieties in these systems, and this behaviour is systematically extended upon moving to bis-calix[4]arene, a relatively new ligand in which two calix[4]arenes are tethered at the methylene bridge position. N,O-Ligands greatly influence cluster formation with bis-calix[4]arene, affording a remarkable mixed-valence [Mn^IV₂Mn^III₁₀Mn^II₈] cluster that displays coordination chemistry typical of each ligand type, but also new structure capping behaviour for the latter.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1530277

Journal Information:: Dalton Transactions, Vol. 46, Issue 48; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 10 works

Citation information provided by
Web of Science

References (42)

Polytopic ligand directed self-assembly—polymetallic [n×n] grids versus non-grid oligomers Dawe, Louise N.; Shuvaev, Konstantin V.; Thompson, Laurence K. Chemical Society Reviews, Vol. 38, Issue 8 https://doi.org/10.1039/b807219c	journal	January 2009
The Use of Calixarenes in Metal-Based Catalysis Homden, Damien M.; Redshaw, Carl Chemical Reviews, Vol. 108, Issue 12 https://doi.org/10.1021/cr8002196	journal	December 2008
Synthesis, structure, and properties of a new representative of the family of calix[4]arene-containing [MnII 2MnIII 2]-clusters Aldoshin, S. M.; Antipin, I. S.; Ovcharenko, V. I. Russian Chemical Bulletin, Vol. 62, Issue 2 https://doi.org/10.1007/s11172-013-0074-5	journal	February 2013
Transition metal and lanthanide cluster complexes constructed with thiacalix[n]arene and its derivatives Kajiwara, Takashi; Iki, Nobuhiko; Yamashita, Masahiro Coordination Chemistry Reviews, Vol. 251, Issue 13-14, p. 1734-1746 https://doi.org/10.1016/j.ccr.2007.01.001	journal	July 2007
Unusual Structural Types in Manganese Cluster Chemistry from the Use of N , N , N ‘, N ‘-Tetrakis(2-hydroxyethyl)ethylenediamine: Mn ₈ , Mn ₁₂ , and Mn ₂₀ Clusters Bagai, Rashmi; Abboud, Khalil A.; Christou, George Inorganic Chemistry, Vol. 47, Issue 2 https://doi.org/10.1021/ic701971d	journal	January 2008
Calix[4]arene-Based Single-Molecule Magnets Karotsis, Georgios; Teat, Simon J.; Wernsdorfer, Wolfgang Angewandte Chemie International Edition, Vol. 48, Issue 44 https://doi.org/10.1002/anie.200904094	journal	September 2009
Supertetrahedral icosanuclear and ring-like decanuclear mixed valent manganese(ii/iii) triethanolamine clusters Langley, Stuart K.; Moubaraki, Boujemaa; Berry, Kevin J. Dalton Transactions, Vol. 39, Issue 20 https://doi.org/10.1039/b926795f	journal	January 2010
Calix[4]arene-supported rare earth octahedra Sanz, Sergio; McIntosh, Ruaraidh D.; Beavers, Christine M. Chem. Commun., Vol. 48, Issue 10 https://doi.org/10.1039/C1CC14603C	journal	January 2012
Heterometallic 3d–4f Single-Molecule Magnets: Ligand and Metal Ion Influences on the Magnetic Relaxation Langley, Stuart K.; Le, Crystal; Ungur, Liviu Inorganic Chemistry, Vol. 54, Issue 7 https://doi.org/10.1021/acs.inorgchem.5b00219	journal	March 2015
Experimental and theoretical study of the influence of peripheral environment on magnetic properties of tetranuclear manganese skeleton in new representatives of calix[4]arene-containing [MnII2 MnIII2] clusters Aldoshin, S. M.; Antipin, I. S.; Solov’eva, S. E. Journal of Molecular Structure, Vol. 1081 https://doi.org/10.1016/j.molstruc.2014.10.022	journal	February 2015
Calixarene-supported hexadysprosium cluster showing single molecule magnet behavior Bi, YanFeng; Xu, GuanCheng; Liao, WuPing Science China Chemistry, Vol. 55, Issue 6 https://doi.org/10.1007/s11426-012-4570-5	journal	April 2012
Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer McLellan, Ross; Taylor, Stephanie M.; McIntosh, Ruaraidh D. Dalton Transactions, Vol. 42, Issue 19 https://doi.org/10.1039/c3dt50294e	journal	January 2013
Synthesis of Single-molecule Magnets Using Metallocyanates Rebilly, Jean-Noel; Mallah, Talal Structure and Bonding https://doi.org/10.1007/430_032	book	January 2006
Metallocalixarene catalysts: α-olefin polymerization and ROP of cyclic esters Redshaw, Carl Dalton Transactions, Vol. 45, Issue 22 https://doi.org/10.1039/C6DT01529H	journal	January 2016
A Mixed-Valence Polyoxovanadate(III,IV) Cluster with a Calixarene Cap Exhibiting Ferromagnetic V(III)−V(IV) Interactions Aronica, Christophe; Chastanet, Guillaume; Zueva, Ekaterina Journal of the American Chemical Society, Vol. 130, Issue 7 https://doi.org/10.1021/ja078030q	journal	February 2008
Synthesis and characterization of a series of manganese phosphonate complexes with various valences and nuclearity Wang, Mei; Ma, Chengbing; Wen, Huimin Dalton Trans., Issue 6 https://doi.org/10.1039/B814794A	journal	January 2009
Synthesis and reactions of a 2-chlorocalix[4]arene and a 2,2′-coupled dicalixarene Carroll, Louise T.; Hill, P. Aru; Ngo, Chinh Q. Tetrahedron, Vol. 69, Issue 24 https://doi.org/10.1016/j.tet.2013.04.010	journal	June 2013
Thiacalixarene-based nanoscale polyhedral coordination cages Bi, Yanfeng; Du, Shangchao; Liao, Wuping Coordination Chemistry Reviews, Vol. 276 https://doi.org/10.1016/j.ccr.2014.06.011	journal	September 2014
Core expansion of bis-calix[4]arene-supported clusters Coletta, Marco; McLellan, Ross; Waddington, Amy Chemical Communications, Vol. 52, Issue 99 https://doi.org/10.1039/C6CC08059F	journal	January 2016
Linked Supramolecular Building Blocks for Enhanced Cluster Formation McLellan, Ross; Palacios, Maria A.; Beavers, Christine M. Chemistry - A European Journal, Vol. 21, Issue 7 https://doi.org/10.1002/chem.201405746	journal	January 2015
Calixarene supported enneanuclear Cu(ii) clusters Karotsis, Georgios; Kennedy, Stuart; Dalgarno, Scott J. Chemical Communications, Vol. 46, Issue 22 https://doi.org/10.1039/c0cc00011f	journal	January 2010
Diol-type ligands as central ‘players’ in the chemistry of high-spin molecules and single-molecule magnets Tasiopoulos, Anastasios J.; Perlepes, Spyros P. Dalton Transactions, Issue 41 https://doi.org/10.1039/b805014g	journal	January 2008
The coordination chemistry of pyridyl oximes Milios, Constantinos J.; Stamatatos, Theocharis C.; Perlepes, Spyros P. Polyhedron, Vol. 25, Issue 1 https://doi.org/10.1016/j.poly.2005.07.022	journal	January 2006
Self-assembly of two high-nuclearity manganese calixarene-phosphonate clusters: diamond-like Mn ₁₆ and drum-like Mn ₁₄ Su, Kongzhao; Jiang, Feilong; Qian, Jinjie RSC Advances, Vol. 5, Issue 42 https://doi.org/10.1039/C5RA02530C	journal	January 2015
[Mn ^III ₄ Ln ^III ₄ ] Calix[4]arene Clusters as Enhanced Magnetic Coolers and Molecular Magnets Karotsis, Georgios; Kennedy, Stuart; Teat, Simon J. Journal of the American Chemical Society, Vol. 132, Issue 37 https://doi.org/10.1021/ja104848m	journal	September 2010
Elucidating the Ring Inversion Mechanism(s) for Biscalixarenes Murphy, Paul; Dalgarno, Scott J.; Paterson, Martin J. The Journal of Physical Chemistry A, Vol. 118, Issue 36 https://doi.org/10.1021/jp5070616	journal	August 2014
Self-assembly and decay of Mn(ii) pivalate–phosphonate complexes Burkovskaya, Nataliya; Aleksandrov, Grigory; Ugolkova, Elena New Journal of Chemistry, Vol. 38, Issue 4 https://doi.org/10.1039/c3nj00899a	journal	January 2014
Syntheses and Properties of Metal-Centered Mixed-Valent [NEt4]{MnII?[MnII3MnIII3Cl6(L)6]} Manganese Wheels Saalfrank, Rolf W.; Nakajima, Takayuki; Mooren, Nicolai European Journal of Inorganic Chemistry, Vol. 2005, Issue 6 https://doi.org/10.1002/ejic.200400773	journal	March 2005
Design of magnetic coordination complexes for quantum computing Aromí, Guillem; Aguilà, David; Gamez, Patrick Chem. Soc. Rev., Vol. 41, Issue 2 https://doi.org/10.1039/C1CS15115K	journal	January 2012
Calix[4]arene-supported FeIII2LnIII2 clusters Sanz, Sergio; Ferreira, Kerry; McIntosh, Ruaraidh D. Chemical Communications, Vol. 47, Issue 32 https://doi.org/10.1039/c1cc13055b	journal	January 2011
Phosphonate Ligands Stabilize Mixed-Valent {MnIII20−xMnIIx} Clusters with Large Spin and Coercivity Maheswaran, Shanmugam; Chastanet, Guillaume; Teat, Simon J. Angewandte Chemie International Edition, Vol. 44, Issue 32 https://doi.org/10.1002/anie.200501265	journal	August 2005
Facile Interchange of 3d and 4f Ions in Single-Molecule Magnets: Stepwise Assembly of [Mn ₄ ], [Mn ₃ Ln] and [Mn ₂ Ln ₂ ] Cages within Calix[4]arene Scaffolds Palacios, Maria A.; McLellan, Ross; Beavers, Christine M. Chemistry - A European Journal, Vol. 21, Issue 31 https://doi.org/10.1002/chem.201500001	journal	June 2015
A Family of Calix[4]arene-Supported [MnIII2MnII2] Clusters Taylor, Stephanie M.; Karotsis, Georgios; McIntosh, Ruaraidh D. Chemistry - A European Journal, Vol. 17, Issue 27 https://doi.org/10.1002/chem.201003327	journal	May 2011
A New Family of 3 d -4 f Bis-Calix[4]arene-Supported Clusters Coletta, Marco; McLellan, Ross; Sanz, Sergio Chemistry - A European Journal, Vol. 23, Issue 56 https://doi.org/10.1002/chem.201703197	journal	September 2017
Lanthanide ion complexes of the calixarenes. Part 4. Double inclusion by p-t-butylcalix[4]arene (H4L). Crystal structures of [Eu2(HL)2(dmf)4].7dmf (dmf = dimethylformamide) and H4L.dmso (dmso = dimethyl sulphoxide) Furphy, Brenda M.; Harrowfield, Jack MacB.; Ogden, Mark I. Journal of the Chemical Society, Dalton Transactions, Issue 11 https://doi.org/10.1039/dt9890002217	journal	January 1989
A new class of single-molecule magnets: mixed-valent [Mn4(O2CMe)2(Hpdm)6][ClO4]2 with an S = 8 ground state Brechin, Euan K.; Huffman, John C.; Christou, George Chemical Communications, Issue 9 https://doi.org/10.1039/a901106d	journal	January 1999
A Mn15 single-molecule magnet consisting of a supertetrahedron incorporated in a loop Moushi, Eleni E.; Masello, Antonio; Wernsdorfer, Wolfgang Dalton Transactions, Vol. 39, Issue 20 https://doi.org/10.1039/b927205d	journal	January 2010
Coordination Cluster Nuclearity Decreases with Decreasing Rare Earth Ionic Radius in 1:1 Cr/Ln N -Butyldiethanolamine Compounds: A Journey across the Lanthanide Series from Cr ₄ ^III La ₄ –Cr ₄ ^III Tb ₄ via Cr ₃ ^III Dy ₃ and Cr ₃ ^III Ho ₃ to Cr ₂ ^III Er ₂ –Cr ₂ ^III Lu ₂ Rinck, Julia; Lan, Yanhua; Anson, Christopher E. Inorganic Chemistry, Vol. 54, Issue 7 https://doi.org/10.1021/ic502930p	journal	March 2015
Heterometallic Rings: Their Physics and use as Supramolecular Building Blocks McInnes, Eric J. L.; Timco, Grigore A.; Whitehead, George F. S. Angewandte Chemie International Edition, Vol. 54, Issue 48 https://doi.org/10.1002/anie.201502730	journal	October 2015
Calix[4]arene-Based Single-Molecule Magnets Karotsis, Georgios; Teat, Simon J.; Wernsdorfer, Wolfgang Angewandte Chemie, Vol. 121, Issue 44 https://doi.org/10.1002/ange.200904094	journal	September 2009
The Coordination Chemistry of Pyridyl Oximes Milios, Constantinos J.; Stamatatos, Theocharis C.; Perlepes, Spyros P. ChemInform, Vol. 37, Issue 22 https://doi.org/10.1002/chin.200622259	journal	May 2006
Phosphonate Ligands Stabilize Mixed-Valent {MnIII20−xMnIIx} Clusters with Large Spin and Coercivity Maheswaran, Shanmugam; Chastanet, Guillaume; Teat, Simon J. Angewandte Chemie, Vol. 117, Issue 32 https://doi.org/10.1002/ange.200501265	journal	August 2005