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Title: Anomalously low activation energy of nanoconfined MgCO 3 precipitation

Abstract

Experimental study of nanoconfined MgCO 3 nucleation and growth processes reveals elevated kinetics due to less strongly hydrated Mg 2+ .

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4];  [5]; ORCiD logo [3]
  1. Department of Geology and Geophysics, University of Wyoming, Laramie, USA, Physical and Computational Sciences Directorate
  2. Department of Geology and Geophysics, University of Wyoming, Laramie, USA, School of Energy Resources
  3. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, USA
  4. William R. Wiley Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, USA
  5. Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1523294
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 55 Journal Issue: 48; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Miller, Quin R. S., Kaszuba, John P., Schaef, Herbert T., Bowden, Mark E., McGrail, B. Peter, and Rosso, Kevin M. Anomalously low activation energy of nanoconfined MgCO 3 precipitation. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC01337G.
Miller, Quin R. S., Kaszuba, John P., Schaef, Herbert T., Bowden, Mark E., McGrail, B. Peter, & Rosso, Kevin M. Anomalously low activation energy of nanoconfined MgCO 3 precipitation. United Kingdom. doi:10.1039/C9CC01337G.
Miller, Quin R. S., Kaszuba, John P., Schaef, Herbert T., Bowden, Mark E., McGrail, B. Peter, and Rosso, Kevin M. Tue . "Anomalously low activation energy of nanoconfined MgCO 3 precipitation". United Kingdom. doi:10.1039/C9CC01337G.
@article{osti_1523294,
title = {Anomalously low activation energy of nanoconfined MgCO 3 precipitation},
author = {Miller, Quin R. S. and Kaszuba, John P. and Schaef, Herbert T. and Bowden, Mark E. and McGrail, B. Peter and Rosso, Kevin M.},
abstractNote = {Experimental study of nanoconfined MgCO 3 nucleation and growth processes reveals elevated kinetics due to less strongly hydrated Mg 2+ .},
doi = {10.1039/C9CC01337G},
journal = {Chemical Communications},
number = 48,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {6}
}

Journal Article:
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This content will become publicly available on May 29, 2020
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Works referenced in this record:

Experimental Study of Porosity Changes in Shale Caprocks Exposed to CO 2 -Saturated Brines I: Evolution of Mineralogy, Pore Connectivity, Pore Size Distribution, and Surface Area
journal, October 2016

  • Mouzakis, Katherine M.; Navarre-Sitchler, Alexis K.; Rother, Gernot
  • Environmental Engineering Science, Vol. 33, Issue 10
  • DOI: 10.1089/ees.2015.0588

Permeability, porosity, and mineral surface area changes in basalt cores induced by reactive transport of CO 2 -rich brine : PHYSICAL CHANGES FROM REACTION IN BASALT
journal, March 2017

  • Luhmann, Andrew J.; Tutolo, Benjamin M.; Bagley, Brian C.
  • Water Resources Research, Vol. 53, Issue 3
  • DOI: 10.1002/2016WR019216

Chemical reactions confined within carbon nanotubes
journal, January 2016

  • Miners, Scott A.; Rance, Graham A.; Khlobystov, Andrei N.
  • Chemical Society Reviews, Vol. 45, Issue 17
  • DOI: 10.1039/C6CS00090H

Room Temperature Magnesite Precipitation
journal, October 2017

  • Power, Ian M.; Kenward, Paul A.; Dipple, Gregory M.
  • Crystal Growth & Design, Vol. 17, Issue 11
  • DOI: 10.1021/acs.cgd.7b00311

Surface-Catalyzed Oxygen Exchange during Mineral Carbonation in Nanoscale Water Films
journal, May 2019

  • Miller, Quin R. S.; Dixon, David A.; Burton, Sarah D.
  • The Journal of Physical Chemistry C
  • DOI: 10.1021/acs.jpcc.9b02215

Reaction of water-saturated supercritical CO2 with forsterite: Evidence for magnesite formation at low temperatures
journal, August 2012


Nanogeochemistry: Geochemical reactions and mass transfers in nanopores
journal, January 2003


Hydration of Beryllium, Magnesium, Calcium, and Zinc Ions Using Density Functional Theory
journal, January 1998

  • Pavlov, Maria; Siegbahn, Per E. M.; Sandström, Magnus
  • The Journal of Physical Chemistry A, Vol. 102, Issue 1
  • DOI: 10.1021/jp972072r

Aqueous NaCl Solutions within Charged Carbon-Slit Pores: Partition Coefficients and Density Distributions from Molecular Dynamics Simulations
journal, June 2011

  • Kalluri, Raja Kirthi; Konatham, Deepthi; Striolo, Alberto
  • The Journal of Physical Chemistry C, Vol. 115, Issue 28
  • DOI: 10.1021/jp203086x

Field Validation of Supercritical CO 2 Reactivity with Basalts
journal, November 2016

  • McGrail, B. Peter; Schaef, Herbert T.; Spane, Frank A.
  • Environmental Science & Technology Letters, Vol. 4, Issue 1
  • DOI: 10.1021/acs.estlett.6b00387

The Nanoscale Basis of CO 2 Trapping for Geologic Storage
journal, August 2015

  • Bourg, Ian C.; Beckingham, Lauren E.; DePaolo, Donald J.
  • Environmental Science & Technology, Vol. 49, Issue 17
  • DOI: 10.1021/acs.est.5b03003

Phase selectivity triggered by nanoconfinement: the impact of corral dimensions
journal, January 2019

  • Hu, Yi; Bragança, Ana M.; Verstraete, Lander
  • Chemical Communications, Vol. 55, Issue 15
  • DOI: 10.1039/C8CC08602H

Water Structure Controls Carbonic Acid Formation in Adsorbed Water Films
journal, August 2018

  • Miller, Quin R. S.; Ilton, Eugene S.; Qafoku, Odeta
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 17
  • DOI: 10.1021/acs.jpclett.8b02162

Effects of nano-confinement on Zn(II) adsorption to nanoporous silica
journal, November 2018


Anomalously low dielectric constant of confined water
journal, June 2018


2D Materials with Nanoconfined Fluids for Electrochemical Energy Storage
journal, November 2017


Impacts of Organic Ligands on Forsterite Reactivity in Supercritical CO 2 Fluids
journal, March 2015

  • Miller, Quin R. S.; Kaszuba, John P.; Schaef, Herbert T.
  • Environmental Science & Technology, Vol. 49, Issue 7
  • DOI: 10.1021/es506065d

Co 3 O 4 nanoparticle embedded carbonaceous fibres: a nanoconfinement effect on enhanced lithium-ion storage
journal, January 2015

  • Sun, Jin; Li, Daohao; Xia, Yanzhi
  • Chemical Communications, Vol. 51, Issue 90
  • DOI: 10.1039/C5CC06160A

Dielectric Constant of Water Confined in a Nanocavity
journal, June 2001

  • Senapati, Sanjib; Chandra, Amalendu
  • The Journal of Physical Chemistry B, Vol. 105, Issue 22
  • DOI: 10.1021/jp011058i

Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions
journal, June 2016


Internal Domains of Natural Porous Media Revealed: Critical Locations for Transport, Storage, and Chemical Reaction
journal, February 2016

  • Zachara, John; Brantley, Sue; Chorover, Jon
  • Environmental Science & Technology, Vol. 50, Issue 6
  • DOI: 10.1021/acs.est.5b05015

Tunable Manipulation of Mineral Carbonation Kinetics in Nanoscale Water Films via Citrate Additives
journal, May 2018

  • Miller, Quin R. S.; Schaef, Herbert T.; Kaszuba, John P.
  • Environmental Science & Technology, Vol. 52, Issue 12
  • DOI: 10.1021/acs.est.8b00438

Nanoconfined Iron Oxychloride Material as a High-Performance Cathode for Rechargeable Chloride Ion Batteries
journal, September 2017


Insights into silicate carbonation processes in water-bearing supercritical CO2 fluids
journal, July 2013

  • Miller, Q. R. S.; Thompson, C. J.; Loring, J. S.
  • International Journal of Greenhouse Gas Control, Vol. 15
  • DOI: 10.1016/j.ijggc.2013.02.005

Sintering-resistant Ni-based reforming catalysts obtained via the nanoconfinement effect
journal, January 2013

  • Zhang, Chengxi; Zhu, Wancheng; Li, Shuirong
  • Chemical Communications, Vol. 49, Issue 82
  • DOI: 10.1039/c3cc43895c

Molecular insight into the nanoconfined calcite–solution interface
journal, October 2016

  • Diao, Yijue; Espinosa-Marzal, Rosa M.
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 43
  • DOI: 10.1073/pnas.1605920113

Forsterite [Mg 2 SiO 4 )] Carbonation in Wet Supercritical CO 2 : An in Situ High-Pressure X-ray Diffraction Study
journal, June 2012

  • Todd Schaef, Herbert; McGrail, Bernard P.; Loring, John L.
  • Environmental Science & Technology, Vol. 47, Issue 1
  • DOI: 10.1021/es301126f