Supercritical methanol depolymerization and hydrodeoxygenation of lignin and biomass over reduced copper porous metal oxides

McClelland, Daniel J.; Galebach, Peter H.; Motagamwala, Ali Hussain; Wittrig, Ashley M.; Karlen, Steven D.; Buchanan, J. Scott; Dumesic, James A.; Huber, George W.

doi:10.1039/C9GC00589G

Title: Supercritical methanol depolymerization and hydrodeoxygenation of lignin and biomass over reduced copper porous metal oxides

Abstract

Supercritical methanol upgrading with a CuMgAlO _x catalyst is effective at depolymerizing and hydrodeoxygenating lignin into monomers and oligomers.

Authors:

McClelland, Daniel J. ^[1];

^[1]; Motagamwala, Ali Hussain ^[2]; Wittrig, Ashley M. ^[3];

^[4]; Buchanan, J. Scott ^[3];

^[2];

^[1]

Department of Chemical and Biological Engineering, University of Wisconsin–Madison, Madison, USA
Department of Chemical and Biological Engineering, University of Wisconsin–Madison, Madison, USA, Great Lakes Bioenergy Research Center
ExxonMobil Research and Engineering, Annandale, USA
Great Lakes Bioenergy Research Center, Wisconsin Energy Institute, Madison, USA, Department of Biochemistry

Publication Date:: Tue Jun 04 00:00:00 EDT 2019

Sponsoring Org.:: USDOE

OSTI Identifier:: 1514763

Grant/Contract Number:: DOE BER Office of Science DE-SC0018409

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Green Chemistry

Additional Journal Information:: Journal Name: Green Chemistry Journal Volume: 21 Journal Issue: 11; Journal ID: ISSN 1463-9262

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    McClelland, Daniel J., Galebach, Peter H., Motagamwala, Ali Hussain, Wittrig, Ashley M., Karlen, Steven D., Buchanan, J. Scott, Dumesic, James A., and Huber, George W. Supercritical methanol depolymerization and hydrodeoxygenation of lignin and biomass over reduced copper porous metal oxides.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9GC00589G.

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                    McClelland, Daniel J., Galebach, Peter H., Motagamwala, Ali Hussain, Wittrig, Ashley M., Karlen, Steven D., Buchanan, J. Scott, Dumesic, James A., & Huber, George W. Supercritical methanol depolymerization and hydrodeoxygenation of lignin and biomass over reduced copper porous metal oxides.  United Kingdom.  https://doi.org/10.1039/C9GC00589G

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                    McClelland, Daniel J., Galebach, Peter H., Motagamwala, Ali Hussain, Wittrig, Ashley M., Karlen, Steven D., Buchanan, J. Scott, Dumesic, James A., and Huber, George W. Tue .  
"Supercritical methanol depolymerization and hydrodeoxygenation of lignin and biomass over reduced copper porous metal oxides".  United Kingdom.  https://doi.org/10.1039/C9GC00589G.

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@article{osti_1514763,

  title        = {Supercritical methanol depolymerization and hydrodeoxygenation of lignin and biomass over reduced copper porous metal oxides},

  author       = {McClelland, Daniel J. and Galebach, Peter H. and Motagamwala, Ali Hussain and Wittrig, Ashley M. and Karlen, Steven D. and Buchanan, J. Scott and Dumesic, James A. and Huber, George W.},

  abstractNote = {Supercritical methanol upgrading with a CuMgAlO x catalyst is effective at depolymerizing and hydrodeoxygenating lignin into monomers and oligomers.},

  doi          = {10.1039/C9GC00589G},

  journal      = {Green Chemistry},

  number       = 11,

  volume       = 21,

  place        = {United Kingdom},

  year         = {Tue Jun 04 00:00:00 EDT 2019},

  month        = {Tue Jun 04 00:00:00 EDT 2019}

}

Copy to clipboard

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https://doi.org/10.1039/C9GC00589G

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Similar Records

Title: Supercritical methanol depolymerization and hydrodeoxygenation of lignin and biomass over reduced copper porous metal oxides

Abstract

Citation Formats

Catalytic disassembly of an organosolv lignin via hydrogen transfer from supercritical methanol journal, January 2010

Insights into the catalytic activity and surface modification of MoO 3 during the hydrodeoxygenation of lignin-derived model compounds into aromatic hydrocarbons under low hydrogen pressures journal, January 2014

Formic-acid-induced depolymerization of oxidized lignin to aromatics journal, November 2014

Production of Alcohols from Cellulose by Supercritical Methanol Depolymerization and Hydrodeoxygenation journal, February 2018

Catalytic Depolymerization of Lignin in Supercritical Ethanol journal, May 2014

Synergy in Lignin Upgrading by a Combination of Cu-Based Mixed Oxide and Ni-Phosphide Catalysts in Supercritical Ethanol journal, March 2017

Comparative Studies on Cellulolytic Enzyme Lignin and Milled Wood Lignin of Sweetgum and Spruce journal, January 1975

Monolignol ferulate conjugates are naturally incorporated into plant lignins journal, October 2016

Temperature Tuning the Catalytic Reactivity of Cu-Doped Porous Metal Oxides with Lignin Models journal, December 2017

Probing the Lignin Disassembly Pathways with Modified Catalysts Based on Cu-Doped Porous Metal Oxides journal, March 2017

Reductive lignocellulose fractionation into soluble lignin-derived phenolic monomers and dimers and processable carbohydrate pulps journal, January 2015

Flowthrough Reductive Catalytic Fractionation of Biomass journal, November 2017

Integrating lignin valorization and bio-ethanol production: on the role of Ni-Al 2 O 3 catalyst pellets during lignin-first fractionation journal, January 2017

Lignin monomer production integrated into the γ-valerolactone sugar platform journal, January 2015

Liquid fuels, hydrogen and chemicals from lignin A critical review journal, May 2013

Catalytic Transformation of Lignin for the Production of Chemicals and Fuels journal, October 2015

A Convergent Approach for a Deep Converting Lignin-First Biorefinery Rendering High-Energy-Density Drop-in Fuels journal, June 2018

Solution-state 2D NMR of ball-milled plant cell wall gels in DMSO-d6/pyridine-d5 journal, January 2010

PVT measurements for pure methanol in the near-critical and supercritical regions journal, June 2007

Catalytic Conversion of Nonfood Woody Biomass Solids to Organic Liquids journal, April 2014

Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources journal, January 2018

Kinetic Studies of Lignin Solvolysis and Reduction by Reductive Catalytic Fractionation Decoupled in Flow-Through Reactors journal, April 2018

Exploring, Tuning, and Exploiting the Basicity of Hydrotalcites for Applications in Heterogeneous Catalysis journal, April 2009

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Enhancing Aromatic Production from Reductive Lignin Disassembly: in Situ O-Methylation of Phenolic Intermediates journal, September 2016

Aspects of the mechanism of the flame ionization detector journal, May 1999

Role of Cu–Mg–Al Mixed Oxide Catalysts in Lignin Depolymerization in Supercritical Ethanol journal, November 2015

One-Pot Catalytic Conversion of Cellulose and of Woody Biomass Solids to Liquid Fuels journal, September 2011

Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization journal, October 2016

Isolation and Structural Characterization of the Milled Wood Lignin, Dioxane Lignin, and Cellulolytic Lignin Preparations from Brewer’s Spent Grain journal, January 2015

Low temperature hydrogenation of pyrolytic lignin over Ru/TiO 2 : 2D HSQC and 13 C NMR study of reactants and products journal, January 2016

Promising bulk production of a potentially benign bisphenol A replacement from a hardwood lignin platform journal, January 2018

Selective C-alkylation of phenol with methanol over catalysts derived from copper-aluminium hydrotalcite-like compounds journal, October 1996

Depolymerization of concentrated sulfuric acid hydrolysis lignin to high-yield aromatic monomers in basic sub- and supercritical fluids journal, June 2017

Designer lignins: harnessing the plasticity of lignification journal, February 2016

Structural Characterization of Wheat Straw Lignin as Revealed by Analytical Pyrolysis, 2D-NMR, and Reductive Cleavage Methods journal, December 2011

Protection Group Effects During α,γ-Diol Lignin Stabilization Promote High-Selectivity Monomer Production journal, January 2018

Catalytic disassembly of an organosolv lignin via hydrogen transfer from supercritical methanol
journal, January 2010

Insights into the catalytic activity and surface modification of MoO ₃ during the hydrodeoxygenation of lignin-derived model compounds into aromatic hydrocarbons under low hydrogen pressures
journal, January 2014

Formic-acid-induced depolymerization of oxidized lignin to aromatics
journal, November 2014

Production of Alcohols from Cellulose by Supercritical Methanol Depolymerization and Hydrodeoxygenation
journal, February 2018

Catalytic Depolymerization of Lignin in Supercritical Ethanol
journal, May 2014

Synergy in Lignin Upgrading by a Combination of Cu-Based Mixed Oxide and Ni-Phosphide Catalysts in Supercritical Ethanol
journal, March 2017

Comparative Studies on Cellulolytic Enzyme Lignin and Milled Wood Lignin of Sweetgum and Spruce
journal, January 1975

Monolignol ferulate conjugates are naturally incorporated into plant lignins
journal, October 2016

Temperature Tuning the Catalytic Reactivity of Cu-Doped Porous Metal Oxides with Lignin Models
journal, December 2017

Probing the Lignin Disassembly Pathways with Modified Catalysts Based on Cu-Doped Porous Metal Oxides
journal, March 2017

Reductive lignocellulose fractionation into soluble lignin-derived phenolic monomers and dimers and processable carbohydrate pulps
journal, January 2015

Flowthrough Reductive Catalytic Fractionation of Biomass
journal, November 2017

Integrating lignin valorization and bio-ethanol production: on the role of Ni-Al ₂ O ₃ catalyst pellets during lignin-first fractionation
journal, January 2017

Lignin monomer production integrated into the γ-valerolactone sugar platform
journal, January 2015

Liquid fuels, hydrogen and chemicals from lignin A critical review
journal, May 2013

Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
journal, October 2015

A Convergent Approach for a Deep Converting Lignin-First Biorefinery Rendering High-Energy-Density Drop-in Fuels
journal, June 2018

Solution-state 2D NMR of ball-milled plant cell wall gels in DMSO-d6/pyridine-d5
journal, January 2010

PVT measurements for pure methanol in the near-critical and supercritical regions
journal, June 2007

Catalytic Conversion of Nonfood Woody Biomass Solids to Organic Liquids
journal, April 2014

Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources
journal, January 2018

Kinetic Studies of Lignin Solvolysis and Reduction by Reductive Catalytic Fractionation Decoupled in Flow-Through Reactors
journal, April 2018

Exploring, Tuning, and Exploiting the Basicity of Hydrotalcites for Applications in Heterogeneous Catalysis
journal, April 2009

Catalytic Biorefining of Plant Biomass to Non-Pyrolytic Lignin Bio-Oil and Carbohydrates through Hydrogen Transfer Reactions
journal, June 2014

Enhancing Aromatic Production from Reductive Lignin Disassembly: in Situ O-Methylation of Phenolic Intermediates
journal, September 2016

Aspects of the mechanism of the flame ionization detector
journal, May 1999

Role of Cu–Mg–Al Mixed Oxide Catalysts in Lignin Depolymerization in Supercritical Ethanol
journal, November 2015

One-Pot Catalytic Conversion of Cellulose and of Woody Biomass Solids to Liquid Fuels
journal, September 2011

Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization
journal, October 2016

Isolation and Structural Characterization of the Milled Wood Lignin, Dioxane Lignin, and Cellulolytic Lignin Preparations from Brewer’s Spent Grain
journal, January 2015

Low temperature hydrogenation of pyrolytic lignin over Ru/TiO ₂ : 2D HSQC and ¹³ C NMR study of reactants and products
journal, January 2016

Promising bulk production of a potentially benign bisphenol A replacement from a hardwood lignin platform
journal, January 2018

Selective C-alkylation of phenol with methanol over catalysts derived from copper-aluminium hydrotalcite-like compounds
journal, October 1996

Depolymerization of concentrated sulfuric acid hydrolysis lignin to high-yield aromatic monomers in basic sub- and supercritical fluids
journal, June 2017

Designer lignins: harnessing the plasticity of lignification
journal, February 2016

Structural Characterization of Wheat Straw Lignin as Revealed by Analytical Pyrolysis, 2D-NMR, and Reductive Cleavage Methods
journal, December 2011

Protection Group Effects During α,γ-Diol Lignin Stabilization Promote High-Selectivity Monomer Production
journal, January 2018