Solid-state electrolyte considerations for electric vehicle batteries

Shen, Hao; Yi, Eongyu; Cheng, Lei; Amores, Marco; Chen, Guoying; Sofie, Stephen W.; Doeff, Marca M.

doi:10.1039/C9SE00119K

Title: Solid-state electrolyte considerations for electric vehicle batteries

Abstract

This paper is an overview of materials and cell fabrication considerations for all solid-state batteries meant for large format applications.

Authors:

Shen, Hao ^[1]; Yi, Eongyu ^[2]; Cheng, Lei ^[3];

^[4];

^[2];

^[5];

^[2]

Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Center for Advancing Materials Performance from the Nanoscale (CAMP-Nano)
Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, USA
Robert Bosch LLC, Research and Technology Center, Sunnyvale, USA
Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Chemistry
Department of Mechanical & Industrial Engineering, Montana State University, Bozeman, USA

Publication Date:: Tue Jun 25 00:00:00 EDT 2019

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1511517

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Sustainable Energy & Fuels

Additional Journal Information:: Journal Name: Sustainable Energy & Fuels Journal Volume: 3 Journal Issue: 7; Journal ID: ISSN 2398-4902

Publisher:: Royal Society of Chemistry

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Shen, Hao, Yi, Eongyu, Cheng, Lei, Amores, Marco, Chen, Guoying, Sofie, Stephen W., and Doeff, Marca M. Solid-state electrolyte considerations for electric vehicle batteries.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9SE00119K.

Copy to clipboard


                    Shen, Hao, Yi, Eongyu, Cheng, Lei, Amores, Marco, Chen, Guoying, Sofie, Stephen W., & Doeff, Marca M. Solid-state electrolyte considerations for electric vehicle batteries.  United Kingdom.  https://doi.org/10.1039/C9SE00119K

Copy to clipboard


                    Shen, Hao, Yi, Eongyu, Cheng, Lei, Amores, Marco, Chen, Guoying, Sofie, Stephen W., and Doeff, Marca M. Tue .  
"Solid-state electrolyte considerations for electric vehicle batteries".  United Kingdom.  https://doi.org/10.1039/C9SE00119K.

Copy to clipboard


                    
@article{osti_1511517,

  title        = {Solid-state electrolyte considerations for electric vehicle batteries},

  author       = {Shen, Hao and Yi, Eongyu and Cheng, Lei and Amores, Marco and Chen, Guoying and Sofie, Stephen W. and Doeff, Marca M.},

  abstractNote = {This paper is an overview of materials and cell fabrication considerations for all solid-state batteries meant for large format applications.},

  doi          = {10.1039/C9SE00119K},

  journal      = {Sustainable Energy & Fuels},

  number       = 7,

  volume       = 3,

  place        = {United Kingdom},

  year         = {Tue Jun 25 00:00:00 EDT 2019},

  month        = {Tue Jun 25 00:00:00 EDT 2019}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1039/C9SE00119K

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 29 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Solids with high ionic conductivity in group 1 halide systems
journal, January 1967

Bradley, J. N.; Greene, P. D.
Transactions of the Faraday Society, Vol. 63
DOI: 10.1039/tf9676300424

Fast microwave-assisted synthesis of Li-stuffed garnets and insights into Li diffusion from muon spin spectroscopy
journal, January 2016

Amores, Marco; Ashton, Thomas E.; Baker, Peter J.
Journal of Materials Chemistry A, Vol. 4, Issue 5
DOI: 10.1039/C5TA08107F

Negating interfacial impedance in garnet-based solid-state Li metal batteries
journal, December 2016

Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin)
Nature Materials, Vol. 16, Issue 5
DOI: 10.1038/nmat4821

Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries
journal, January 2017

Kerman, Kian; Luntz, Alan; Viswanathan, Venkatasubramanian
Journal of The Electrochemical Society, Vol. 164, Issue 7
DOI: 10.1149/2.1571707jes

Elastic Properties of the Solid Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO)
journal, December 2015

Yu, Seungho; Schmidt, Robert D.; Garcia-Mendez, Regina
Chemistry of Materials, Vol. 28, Issue 1
DOI: 10.1021/acs.chemmater.5b03854

The Measurement of a Complete Set of Transport Properties for a Concentrated Solid Polymer Electrolyte Solution
journal, January 1995

Ma, Yanping
Journal of The Electrochemical Society, Vol. 142, Issue 6
DOI: 10.1149/1.2044206

A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries
journal, January 2014

Seino, Yoshikatsu; Ota, Tsuyoshi; Takada, Kazunori
Energy Environ. Sci., Vol. 7, Issue 2
DOI: 10.1039/C3EE41655K

3D-Printing Electrolytes for Solid-State Batteries
journal, March 2018

McOwen, Dennis W.; Xu, Shaomao; Gong, Yunhui
Advanced Materials, Vol. 30, Issue 18
DOI: 10.1002/adma.201707132

Hybrid Polymer/Garnet Electrolyte with a Small Interfacial Resistance for Lithium-Ion Batteries
journal, December 2016

Li, Yutao; Xu, Biyi; Xu, Henghui
Angewandte Chemie International Edition, Vol. 56, Issue 3
DOI: 10.1002/anie.201608924

XPS and ionic conductivity studies on Li2O–Al2O3–(TiO2 or GeO2)–P2O5 glass–ceramics
journal, November 2000

Chowdari, B.
Solid State Ionics, Vol. 136-137, Issue 1-2
DOI: 10.1016/S0167-2738(00)00500-2

A New Approach to Develop Safe All-Inorganic Monolithic Li-Ion Batteries
journal, February 2011

Aboulaich, Abelmaula; Bouchet, Renaud; Delaizir, Gaëlle
Advanced Energy Materials, Vol. 1, Issue 2
DOI: 10.1002/aenm.201000050

Lithium garnets: Synthesis, structure, Li + conductivity, Li + dynamics and applications
journal, July 2017

Ramakumar, S.; Deviannapoorani, C.; Dhivya, L.
Progress in Materials Science, Vol. 88
DOI: 10.1016/j.pmatsci.2017.04.007

Effect of Surface Microstructure on Electrochemical Performance of Garnet Solid Electrolytes
journal, January 2015

Cheng, Lei; Chen, Wei; Kunz, Martin
ACS Applied Materials & Interfaces, Vol. 7, Issue 3
DOI: 10.1021/am508111r

The fast lithium-ion conducting oxides Li3xLa2/3−xTiO3 from fundamentals to application
journal, March 2008

Bohnke, O.
Solid State Ionics, Vol. 179, Issue 1-6
DOI: 10.1016/j.ssi.2007.12.022

Improving Li-ion battery charge rate acceptance through highly ordered hierarchical electrode design
journal, March 2018

Kim, Yunsung; Drews, Andy; Chandrasekaran, Rajeswari
Ionics, Vol. 24, Issue 10
DOI: 10.1007/s11581-018-2502-x

The origin of conductivity variations in Al-stabilized Li7La3Zr2O12 ceramics
journal, June 2018

Wachter-Welzl, A.; Kirowitz, J.; Wagner, R.
Solid State Ionics, Vol. 319
DOI: 10.1016/j.ssi.2018.01.036

Stabilization of cubic lithium-stuffed garnets of the type “Li7La3Zr2O12” by addition of gallium
journal, March 2013

El Shinawi, Hany; Janek, Jürgen
Journal of Power Sources, Vol. 225
DOI: 10.1016/j.jpowsour.2012.09.111

Solid Electrolyte: the Key for High-Voltage Lithium Batteries
journal, October 2014

Li, Juchuan; Ma, Cheng; Chi, Miaofang
Advanced Energy Materials, Vol. 5, Issue 4
DOI: 10.1002/aenm.201401408

High temperature sodium batteries: status, challenges and future trends
journal, January 2013

Hueso, Karina B.; Armand, Michel; Rojo, Teófilo
Energy & Environmental Science, Vol. 6, Issue 3
DOI: 10.1039/c3ee24086j

Ta-Doped Li ₇ La ₃ Zr ₂ O ₁₂ for Water-Stable Lithium Electrode of Lithium-Air Batteries
journal, January 2014

Ishiguro, K.; Nemori, H.; Sunahiro, S.
Journal of The Electrochemical Society, Vol. 161, Issue 5
DOI: 10.1149/2.013405jes

Recent advances in all-solid-state rechargeable lithium batteries
journal, March 2017

Sun, Chunwen; Liu, Jin; Gong, Yudong
Nano Energy, Vol. 33
DOI: 10.1016/j.nanoen.2017.01.028

Preparation of Garnet-Type Li7 − 3xAlxLa3Zr2O12 at Lower Temperature by Using Powders of Mixed Pre-treatment Conditions
journal, April 2018

Lu, Xiaojuan; Yang, Dongyu
Journal of Inorganic and Organometallic Polymers and Materials, Vol. 28, Issue 5
DOI: 10.1007/s10904-018-0859-y

High-Energy All-Solid-State Lithium Batteries with Ultralong Cycle Life
journal, October 2016

Yao, Xiayin; Liu, Deng; Wang, Chunsheng
Nano Letters, Vol. 16, Issue 11
DOI: 10.1021/acs.nanolett.6b03448

Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density
journal, January 2016

Sharafi, Asma; Meyer, Harry M.; Nanda, Jagjit
Journal of Power Sources, Vol. 302
DOI: 10.1016/j.jpowsour.2015.10.053

Freeze casting – A review of processing, microstructure and properties via the open data repository, FreezeCasting.net
journal, May 2018

Scotti, Kristen L.; Dunand, David C.
Progress in Materials Science, Vol. 94
DOI: 10.1016/j.pmatsci.2018.01.001

A lithium superionic conductor
journal, July 2011

Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
Nature Materials, Vol. 10, Issue 9, p. 682-686
DOI: 10.1038/nmat3066

Lithium metal electrode kinetics and ionic conductivity of the solid lithium ion conductors “Li7La3Zr2O12” and Li7−xLa3Zr2−xTaxO12 with garnet-type structure
journal, May 2012

Buschmann, Henrik; Berendts, Stefan; Mogwitz, Boris
Journal of Power Sources, Vol. 206
DOI: 10.1016/j.jpowsour.2012.01.094

Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte
journal, January 2017

Cheng, Eric Jianfeng; Sharafi, Asma; Sakamoto, Jeff
Electrochimica Acta, Vol. 223
DOI: 10.1016/j.electacta.2016.12.018

Inorganic solid Li ion conductors: An overview
journal, June 2009

Knauth, Philippe
Solid State Ionics, Vol. 180, Issue 14-16, p. 911-916
DOI: 10.1016/j.ssi.2009.03.022

Prospects of microwave processing: An overview
journal, February 2009

Das, S.; Mukhopadhyay, A. K.; Datta, S.
Bulletin of Materials Science, Vol. 32, Issue 1
DOI: 10.1007/s12034-009-0001-4

Transport property measurements of polymer electrolytes
journal, April 1998

Ferry, Anders; Doeff, Marca M.; DeJonghe, Lutgard C.
Electrochimica Acta, Vol. 43, Issue 10-11
DOI: 10.1016/S0013-4686(97)10069-X

Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics
journal, August 2016

Guo, Jing; Guo, Hanzheng; Baker, Amanda L.
Angewandte Chemie International Edition, Vol. 55, Issue 38
DOI: 10.1002/anie.201605443

Development of the cold sintering process and its application in solid-state lithium batteries
journal, July 2018

Liu, Yulong; Sun, Qian; Wang, Dawei
Journal of Power Sources, Vol. 393
DOI: 10.1016/j.jpowsour.2018.05.015

A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride
journal, January 1997

Yu, Xiaohua; Bates, J. B.; Jellison, G. E.
Journal of The Electrochemical Society, Vol. 144, Issue 2, p. 524-532
DOI: 10.1149/1.1837443

A shortcut to garnet-type fast Li-ion conductors for all-solid state batteries
journal, January 2015

Afyon, Semih; Krumeich, Frank; Rupp, Jennifer L. M.
Journal of Materials Chemistry A, Vol. 3, Issue 36
DOI: 10.1039/C5TA03239C

First-Principles Studies on Cation Dopants and Electrolyte|Cathode Interphases for Lithium Garnets
journal, May 2015

Miara, Lincoln J.; Richards, William Davidson; Wang, Yan E.
Chemistry of Materials, Vol. 27, Issue 11
DOI: 10.1021/acs.chemmater.5b01023

Field assisted sintering of dense Al-substituted cubic phase Li7La3Zr2O12 solid electrolytes
journal, December 2014

Zhang, Yanhua; Chen, Fei; Tu, Rong
Journal of Power Sources, Vol. 268
DOI: 10.1016/j.jpowsour.2014.03.148

Composite solid electrolytes: recent advances and design strategies
journal, December 2008

Uvarov, N. F.
Journal of Solid State Electrochemistry, Vol. 15, Issue 2
DOI: 10.1007/s10008-008-0739-4

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

Xu, Kang
Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418
DOI: 10.1021/cr030203g

The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces
journal, January 2005

Monroe, Charles; Newman, John
Journal of The Electrochemical Society, Vol. 152, Issue 2
DOI: 10.1149/1.1850854

A surfactant-assisted strategy to tailor Li-ion charge transfer interfacial resistance for scalable all-solid-state Li batteries
journal, January 2018

Zhou, Chengtian; Samson, Alfred Junio; Hofstetter, Kyle
Sustainable Energy & Fuels, Vol. 2, Issue 10
DOI: 10.1039/C8SE00234G

Garnet related lithium ion conductor processed by spark plasma sintering for all solid state batteries
journal, March 2014

Baek, Seung-Wook; Lee, Jae-Myung; Kim, Tae Young
Journal of Power Sources, Vol. 249
DOI: 10.1016/j.jpowsour.2013.10.089

Freeze-Casting of Porous Ceramics: A Review of Current Achievements and Issues
journal, March 2008

Deville, S.
Advanced Engineering Materials, Vol. 10, Issue 3, p. 155-169
DOI: 10.1002/adem.200700270

pH sensors with lithium lanthanum titanate sensitive material: applications in food industry
journal, April 2003

Bohnke, Cl.; Duroy, H.; Fourquet, J. -L.
Sensors and Actuators B: Chemical, Vol. 89, Issue 3
DOI: 10.1016/S0925-4005(02)00473-2

Effect of microstructure and surface impurity segregation on the electrical and electrochemical properties of dense Al-substituted Li ₇ La ₃ Zr ₂ O ₁₂
journal, January 2014

Cheng, Lei; Park, Joong Sun; Hou, Huaming
J. Mater. Chem. A, Vol. 2, Issue 1
DOI: 10.1039/C3TA13999A

High-rate lithium cycling in a scalable trilayer Li-garnet-electrolyte architecture
journal, January 2019

Hitz, Gregory T.; McOwen, Dennis W.; Zhang, Lei
Materials Today, Vol. 22
DOI: 10.1016/j.mattod.2018.04.004

Structure and dynamics of the fast lithium ion conductor “Li7La3Zr2O12”
journal, January 2011

Buschmann, Henrik; Dölle, Janis; Berendts, Stefan
Physical Chemistry Chemical Physics, Vol. 13, Issue 43
DOI: 10.1039/c1cp22108f

Fast Lithium Ion Conduction in Garnet-Type Li₇La₃Zr₂O₁₂
journal, October 2007

Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner
Angewandte Chemie International Edition, Vol. 46, Issue 41, p. 7778-7781
DOI: 10.1002/anie.200701144

Stability of Nb-Doped Cubic Li ₇ La ₃ Zr ₂ O ₁₂ with Lithium Metal
journal, January 2013

Ishiguro, K.; Nakata, Y.; Matsui, M.
Journal of The Electrochemical Society, Vol. 160, Issue 10
DOI: 10.1149/2.036310jes

Crystal Chemistry and Stability of “Li₇La₃Zr₂O₁₂ ” Garnet: A Fast Lithium-Ion Conductor
journal, February 2011

Geiger, Charles A.; Alekseev, Evgeny; Lazic, Biljana
Inorganic Chemistry, Vol. 50, Issue 3, p. 1089-1097
DOI: 10.1021/ic101914e

Atomic-scale origin of the large grain-boundary resistance in perovskite Li-ion-conducting solid electrolytes
journal, January 2014

Ma, Cheng; Chen, Kai; Liang, Chengdu
Energy & Environmental Science, Vol. 7, Issue 5
DOI: 10.1039/c4ee00382a

High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes
journal, January 2019

Han, Fudong; Westover, Andrew S.; Yue, Jie
Nature Energy, Vol. 4, Issue 3
DOI: 10.1038/s41560-018-0312-z

Effect of Electrolyte Composition on the Performance of Sodium/Polymer Cells
journal, January 1997

Doeff, Marca M.
Journal of The Electrochemical Society, Vol. 144, Issue 2
DOI: 10.1149/1.1837419

Multi-Scale Mechanical Behavior of the Li ₃ PS ₄ Solid-Phase Electrolyte
journal, October 2016

Baranowski, Lauryn L.; Heveran, Chelsea M.; Ferguson, Virginia L.
ACS Applied Materials & Interfaces, Vol. 8, Issue 43
DOI: 10.1021/acsami.6b06612

Compatibility issues between electrodes and electrolytes in solid-state batteries
journal, January 2017

Tian, Yaosen; Shi, Tan; Richards, William D.
Energy & Environmental Science, Vol. 10, Issue 5
DOI: 10.1039/C7EE00534B

The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes
journal, January 2014

Cheng, Lei; Crumlin, Ethan J.; Chen, Wei
Phys. Chem. Chem. Phys., Vol. 16, Issue 34
DOI: 10.1039/C4CP02921F

Fundamental study on the wetting property of liquid lithium
journal, September 2018

Wang, Jiangyan; Wang, Hansen; Xie, Jin
Energy Storage Materials, Vol. 14
DOI: 10.1016/j.ensm.2018.05.021

Garnet Electrolyte Surface Degradation and Recovery
journal, October 2018

Cheng, Lei; Liu, Miao; Mehta, Apurva
ACS Applied Energy Materials, Vol. 1, Issue 12
DOI: 10.1021/acsaem.8b01723

Demonstration of high current densities and extended cycling in the garnet Li7La3Zr2O12 solid electrolyte
journal, August 2018

Taylor, Nathan J.; Stangeland-Molo, Sandra; Haslam, Catherine G.
Journal of Power Sources, Vol. 396
DOI: 10.1016/j.jpowsour.2018.06.055

Freeze Tape Cast Thick Mo Doped Li ₄ Ti ₅ O ₁₂ Electrodes for Lithium-Ion Batteries
journal, January 2017

Ghadkolai, Milad Azami; Creager, Stephen; Nanda, Jagjit
Journal of The Electrochemical Society, Vol. 164, Issue 12
DOI: 10.1149/2.1311712jes

Electrical and flexural anisotropy in freeze tape cast stainless steel porous substrates
journal, December 2011

Driscoll, David; Weisenstein, Adam J.; Sofie, Stephen W.
Materials Letters, Vol. 65, Issue 23-24
DOI: 10.1016/j.matlet.2011.07.066

A solid future for battery development
journal, September 2016

Janek, Jürgen; Zeier, Wolfgang G.
Nature Energy, Vol. 1, Issue 9
DOI: 10.1038/nenergy.2016.141

Thermal analysis of a solid polymer electrolyte and a subsequent electrochemical investigation of a lithium polymer battery
journal, February 2003

Edman, L.
Solid State Ionics, Vol. 158, Issue 1-2
DOI: 10.1016/S0167-2738(02)00716-6

Rational design of multi-channel continuous electronic/ionic conductive networks for room temperature vanadium tetrasulfide-based all-solid-state lithium-sulfur batteries
journal, March 2019

Zhang, Qiang; Wan, Hongli; Liu, Gaozhan
Nano Energy, Vol. 57
DOI: 10.1016/j.nanoen.2019.01.004

Effects of Fluorine Doping on Structural and Electrochemical Properties of Li _6.25 Ga _0.25 La ₃ Zr ₂ O ₁₂ as Electrolytes for Solid-State Lithium Batteries
journal, December 2018

Lu, Yao; Meng, Xiaoyi; Alonso, José A.
ACS Applied Materials & Interfaces, Vol. 11, Issue 2
DOI: 10.1021/acsami.8b17656

Interrelationships among Grain Size, Surface Composition, Air Stability, and Interfacial Resistance of Al-Substituted Li ₇ La ₃ Zr ₂ O ₁₂ Solid Electrolytes
journal, August 2015

Cheng, Lei; Wu, Cheng Hao; Jarry, Angelique
ACS Applied Materials & Interfaces, Vol. 7, Issue 32
DOI: 10.1021/acsami.5b02528

Flame made nanoparticles permit processing of dense, flexible, Li ⁺ conducting ceramic electrolyte thin films of cubic-Li ₇ La ₃ Zr ₂ O ₁₂ (c-LLZO)
journal, January 2016

Yi, Eongyu; Wang, Weimin; Kieffer, John
Journal of Materials Chemistry A, Vol. 4, Issue 33
DOI: 10.1039/C6TA04492A

Interfacial Stability of Li Metal–Solid Electrolyte Elucidated via in Situ Electron Microscopy
journal, October 2016

Ma, Cheng; Cheng, Yongqiang; Yin, Kuibo
Nano Letters, Vol. 16, Issue 11
DOI: 10.1021/acs.nanolett.6b03223

Fast Li+ Ion Conduction in Li₂O-Al₂O₃-TiO₂-SiO₂-P₂O₂ Glass-Ceramics
journal, July 1997

Fu, Jie
Journal of the American Ceramic Society, Vol. 80, Issue 7, p. 1901-1903
DOI: 10.1111/j.1151-2916.1997.tb03070.x

Compatibility of Li[sub 7]La[sub 3]Zr[sub 2]O[sub 12] Solid Electrolyte to All-Solid-State Battery Using Li Metal Anode
journal, January 2010

Kotobuki, Masashi; Munakata, Hirokazu; Kanamura, Kiyoshi
Journal of The Electrochemical Society, Vol. 157, Issue 10
DOI: 10.1149/1.3474232

Ceramic and polymeric solid electrolytes for lithium-ion batteries
journal, August 2010

Fergus, Jeffrey W.
Journal of Power Sources, Vol. 195, Issue 15, p. 4554-4569
DOI: 10.1016/j.jpowsour.2010.01.076

A Synthesis and Crystal Chemical Study of the Fast Ion Conductor Li _{7–3 x} Ga _x La ₃ Zr ₂ O ₁₂ with x = 0.08 to 0.84
journal, May 2014

Rettenwander, Daniel; Geiger, Charles A.; Tribus, Martina
Inorganic Chemistry, Vol. 53, Issue 12
DOI: 10.1021/ic500803h

Ion exchange properties of and rates of ionic diffusion in beta-alumina
journal, September 1967

Yung-Fang Yu Yao, ; Kummer, J. T.
Journal of Inorganic and Nuclear Chemistry, Vol. 29, Issue 9
DOI: 10.1016/0022-1902(67)80301-4

Flash Sintering of Nanograin Zirconia in <5 s at 850°C
journal, September 2010

Cologna, Marco; Rashkova, Boriana; Raj, Rishi
Journal of the American Ceramic Society, Vol. 93, Issue 11, p. 3556-3559
DOI: 10.1111/j.1551-2916.2010.04089.x

Review of flash sintering: materials, mechanisms and modelling
journal, December 2016

Yu, Min; Grasso, Salvatore; Mckinnon, Ruth
Advances in Applied Ceramics, Vol. 116, Issue 1
DOI: 10.1080/17436753.2016.1251051

Three-dimensional bilayer garnet solid electrolyte based high energy density lithium metal–sulfur batteries
journal, January 2017

Fu, Kun (Kelvin); Gong, Yunhui; Hitz, Gregory T.
Energy & Environmental Science, Vol. 10, Issue 7
DOI: 10.1039/C7EE01004D

Structure and ionic conductivity in lithium garnets
journal, January 2010

Cussen, Edmund J.
Journal of Materials Chemistry, Vol. 20, Issue 25
DOI: 10.1039/b925553b

Garnet Electrolyte with an Ultralow Interfacial Resistance for Li-Metal Batteries
journal, April 2018

Li, Yutao; Chen, Xi; Dolocan, Andrei
Journal of the American Chemical Society, Vol. 140, Issue 20
DOI: 10.1021/jacs.8b03106

High-Performance All-Solid-State Lithium-Sulfur Batteries Enabled by Amorphous Sulfur-Coated Reduced Graphene Oxide Cathodes
journal, May 2017

Yao, Xiayin; Huang, Ning; Han, Fudong
Advanced Energy Materials, Vol. 7, Issue 17
DOI: 10.1002/aenm.201602923

Capacity Fade in Solid-State Batteries: Interphase Formation and Chemomechanical Processes in Nickel-Rich Layered Oxide Cathodes and Lithium Thiophosphate Solid Electrolytes
journal, June 2017

Koerver, Raimund; Aygün, Isabel; Leichtweiß, Thomas
Chemistry of Materials, Vol. 29, Issue 13
DOI: 10.1021/acs.chemmater.7b00931

The importance of the lithium ion transference number in lithium/polymer cells
journal, September 1994

Doyle, Marc; Fuller, Thomas F.; Newman, John
Electrochimica Acta, Vol. 39, Issue 13
DOI: 10.1016/0013-4686(94)85091-7

A thin-film solid-state microbattery
journal, April 1993

Jones, Steven D.; Akridge, James R.
Journal of Power Sources, Vol. 44, Issue 1-3
DOI: 10.1016/0378-7753(93)80196-V

Fabrication of Functionally Graded and Aligned Porosity in Thin Ceramic Substrates With the Novel Freeze?Tape-Casting Process
journal, July 2007

Sofie, Stephen W.
Journal of the American Ceramic Society, Vol. 90, Issue 7
DOI: 10.1111/j.1551-2916.2007.01720.x

Drawing a Soft Interface: An Effective Interfacial Modification Strategy for Garnet-Type Solid-State Li Batteries
journal, May 2018

Shao, Yuanjun; Wang, Hongchun; Gong, Zhengliang
ACS Energy Letters, Vol. 3, Issue 6
DOI: 10.1021/acsenergylett.8b00453

Chemo-mechanical expansion of lithium electrode materials – on the route to mechanically optimized all-solid-state batteries
journal, January 2018

Koerver, Raimund; Zhang, Wenbo; de Biasi, Lea
Energy & Environmental Science, Vol. 11, Issue 8
DOI: 10.1039/C8EE00907D

All-solid-state lithium-ion and lithium metal batteries – paving the way to large-scale production
journal, April 2018

Schnell, Joscha; Günther, Till; Knoche, Thomas
Journal of Power Sources, Vol. 382
DOI: 10.1016/j.jpowsour.2018.02.062

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries
journal, December 2017

Albertus, Paul; Babinec, Susan; Litzelman, Scott
Nature Energy, Vol. 3, Issue 1
DOI: 10.1038/s41560-017-0047-2

Recent progress of glass and glass-ceramics as solid electrolytes for lithium secondary batteries
journal, October 2006

Minami, T.; Hayashi, A.; Tatsumisago, M.
Solid State Ionics, Vol. 177, Issue 26-32
DOI: 10.1016/j.ssi.2006.07.017

Thin-film lithium and lithium-ion batteries
journal, November 2000

Bates, J.
Solid State Ionics, Vol. 135, Issue 1-4
DOI: 10.1016/S0167-2738(00)00327-1

Similar Records in DOE PAGES and OSTI.GOV collections:

Solid-state electrolyte considerations for electric vehicle batteries

Journal Article Shen, Hao ; Yi, Eongyu ; Cheng, Lei ; ... - Sustainable Energy & Fuels

The recent upsurge of interest in all solid-state lithium batteries for electric vehicles is driven by a need for improved safety and higher energy densities than what are currently available from conventional lithium-ion batteries. Replacement of flammable liquid electrolytic solutions with solid electrolytes allows the use of higher energy lithium metal anodes instead of graphite, and lessens the probability of catastrophic failure, which can result in fire. Most solid-state batteries available today, however, are fabricated in small, thin film formats requiring costly vacuum deposition technologies, and suffer from low practical energy densities due to low areal capacities that restrict theirmore »« less
https://doi.org/10.1039/c9se00119k
Roll-to-Roll Production of Flexible Composite Solid-State Electrolytes for Lithium Metal Batteries in Electric and Hybrid Electric Vehicles using Gravure Printing

Technical Report Du, Hui ; Chen, Chen ; Brown, Emery ; ...

To make the electrical vehicles more competitive with internal combustion engine ones, the United States Advanced Battery Consortium has listed a set of goals for future lithium-ion batteries to meet, which includes a higher specific energy (275 Wh/kg) and energy output (50 kWh). Since current lithium-ion batteries are not capable of reaching these goals, rechargeable lithium-metal batteries have been of particular interest in recent years. However, due to the dendrite growth issue of lithium metal anodes, the key factor to commercialize lithium-metal batteries is to develop suitable solid-state electrolytes to replace the organic liquid electrolytes. Among the solid-state materials, sulfidemore »« less
Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All‐Solid‐State Batteries

Journal Article Park, Kern Ho ; Bai, Qiang ; Kim, Dong Hyeon ; ... - Advanced Energy Materials

Abstract Owing to the ever‐increasing safety concerns about conventional lithium‐ion batteries, whose applications have expanded to include electric vehicles and grid‐scale energy storage, batteries with solidified electrolytes that utilize nonflammable inorganic materials are attracting considerable attention. In particular, owing to their superionic conductivities (as high as ≈10 ⁻² S cm ⁻¹ ) and deformability, sulfide materials as the solid electrolytes (SEs) are considered the enabling material for high‐energy bulk‐type all‐solid‐state batteries. Herein the authors provide a brief review on recent progress in sulfide Li‐ and Na‐ion SEs for all‐solid‐state batteries. After the basic principles in designing SEs are considered, themore »« less
Cited by 343
https://doi.org/10.1002/aenm.201800035
Review of modification strategies in emerging inorganic solid-state electrolytes for lithium, sodium, and potassium batteries

Journal Article Feng, Xuyong ; Fang, Hong ; Wu, Nan ; ... - Joule

The design of solid-state electrolyte (SSE) entails controlling not only its bulk structure but also the internal (e.g., grain boundary and pore) and heterophase (e.g., anode-SSE reaction layer) interfaces. Moreover, defects are integral for establishing both the initial all-solid-state battery (ASSB) cell performance and its ultimate cycling lifetime. This topical review discusses 5 highly promising inorganic lithium-, sodium-, and potassium-based SSEs, providing case studies of strategies to enhance ionic conductivity, tune the internal and heterophase interfaces, and prevent dendrites and deleterious side reactions. The primary focus is on garnet LLZO (Li₇La₃Zr₂O₁₂), argyrodite (Li₆AS₅X, A = P, Sb and X =more »« less
https://doi.org/10.1016/j.joule.2022.01.015
Consolidation of composite cathodes with NCM and sulfide solid-state electrolytes by hot pressing for all-solid-state Li metal batteries

Journal Article Yersak, Thomas A. ; Hao, Fang ; Kang, Chansoon ; ... - Journal of Solid State Electrochemistry

In this study, hot pressing was evaluated as a method of cell fabrication to increase the energy density of next-generation all-solid-state batteries with NCM active material and sulfide solid-state electrolyte. Hot pressing involves consolidating glassy sulfide electrolyte by the application of pressure at a temperature above the electrolyte’s glass transition temperature. Typically, cell stacks are formed at room temperature and retain 15–30% porosity that limits cell energy density. On the other hand, the porosity of hot-pressed cell stacks is reduced to less than 10%. The electrochemical function of hot-pressed cathode composites was assessed as a function of active material andmore »« less
https://doi.org/10.1007/s10008-021-05104-8

Full Text Available

Similar Records

Title: Solid-state electrolyte considerations for electric vehicle batteries

Abstract

Citation Formats

Solids with high ionic conductivity in group 1 halide systems journal, January 1967

Fast microwave-assisted synthesis of Li-stuffed garnets and insights into Li diffusion from muon spin spectroscopy journal, January 2016

Negating interfacial impedance in garnet-based solid-state Li metal batteries journal, December 2016

Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries journal, January 2017

Elastic Properties of the Solid Electrolyte Li 7 La 3 Zr 2 O 12 (LLZO) journal, December 2015

The Measurement of a Complete Set of Transport Properties for a Concentrated Solid Polymer Electrolyte Solution journal, January 1995

A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries journal, January 2014

3D-Printing Electrolytes for Solid-State Batteries journal, March 2018

Hybrid Polymer/Garnet Electrolyte with a Small Interfacial Resistance for Lithium-Ion Batteries journal, December 2016

XPS and ionic conductivity studies on Li2O–Al2O3–(TiO2 or GeO2)–P2O5 glass–ceramics journal, November 2000

A New Approach to Develop Safe All-Inorganic Monolithic Li-Ion Batteries journal, February 2011

Lithium garnets: Synthesis, structure, Li + conductivity, Li + dynamics and applications journal, July 2017

Effect of Surface Microstructure on Electrochemical Performance of Garnet Solid Electrolytes journal, January 2015

The fast lithium-ion conducting oxides Li3xLa2/3−xTiO3 from fundamentals to application journal, March 2008

Improving Li-ion battery charge rate acceptance through highly ordered hierarchical electrode design journal, March 2018

The origin of conductivity variations in Al-stabilized Li7La3Zr2O12 ceramics journal, June 2018

Stabilization of cubic lithium-stuffed garnets of the type “Li7La3Zr2O12” by addition of gallium journal, March 2013

Solid Electrolyte: the Key for High-Voltage Lithium Batteries journal, October 2014

High temperature sodium batteries: status, challenges and future trends journal, January 2013

Ta-Doped Li 7 La 3 Zr 2 O 12 for Water-Stable Lithium Electrode of Lithium-Air Batteries journal, January 2014

Recent advances in all-solid-state rechargeable lithium batteries journal, March 2017

Preparation of Garnet-Type Li7 − 3xAlxLa3Zr2O12 at Lower Temperature by Using Powders of Mixed Pre-treatment Conditions journal, April 2018

High-Energy All-Solid-State Lithium Batteries with Ultralong Cycle Life journal, October 2016

Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density journal, January 2016

Freeze casting – A review of processing, microstructure and properties via the open data repository, FreezeCasting.net journal, May 2018

A lithium superionic conductor journal, July 2011

Lithium metal electrode kinetics and ionic conductivity of the solid lithium ion conductors “Li7La3Zr2O12” and Li7−xLa3Zr2−xTaxO12 with garnet-type structure journal, May 2012

Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte journal, January 2017

Inorganic solid Li ion conductors: An overview journal, June 2009

Prospects of microwave processing: An overview journal, February 2009

Transport property measurements of polymer electrolytes journal, April 1998

Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics journal, August 2016

Development of the cold sintering process and its application in solid-state lithium batteries journal, July 2018

A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride journal, January 1997

A shortcut to garnet-type fast Li-ion conductors for all-solid state batteries journal, January 2015

First-Principles Studies on Cation Dopants and Electrolyte|Cathode Interphases for Lithium Garnets journal, May 2015

Field assisted sintering of dense Al-substituted cubic phase Li7La3Zr2O12 solid electrolytes journal, December 2014

Composite solid electrolytes: recent advances and design strategies journal, December 2008

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal, October 2004

The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces journal, January 2005

A surfactant-assisted strategy to tailor Li-ion charge transfer interfacial resistance for scalable all-solid-state Li batteries journal, January 2018

Garnet related lithium ion conductor processed by spark plasma sintering for all solid state batteries journal, March 2014

Freeze-Casting of Porous Ceramics: A Review of Current Achievements and Issues journal, March 2008

pH sensors with lithium lanthanum titanate sensitive material: applications in food industry journal, April 2003

Effect of microstructure and surface impurity segregation on the electrical and electrochemical properties of dense Al-substituted Li 7 La 3 Zr 2 O 12 journal, January 2014

High-rate lithium cycling in a scalable trilayer Li-garnet-electrolyte architecture journal, January 2019

Structure and dynamics of the fast lithium ion conductor “Li7La3Zr2O12” journal, January 2011

Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12 journal, October 2007

Stability of Nb-Doped Cubic Li 7 La 3 Zr 2 O 12 with Lithium Metal journal, January 2013

Crystal Chemistry and Stability of “Li7La3Zr2O12 ” Garnet: A Fast Lithium-Ion Conductor journal, February 2011

Atomic-scale origin of the large grain-boundary resistance in perovskite Li-ion-conducting solid electrolytes journal, January 2014

High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes journal, January 2019

Effect of Electrolyte Composition on the Performance of Sodium/Polymer Cells journal, January 1997

Multi-Scale Mechanical Behavior of the Li 3 PS 4 Solid-Phase Electrolyte journal, October 2016

Compatibility issues between electrodes and electrolytes in solid-state batteries journal, January 2017

The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes journal, January 2014

Fundamental study on the wetting property of liquid lithium journal, September 2018

Garnet Electrolyte Surface Degradation and Recovery journal, October 2018

Demonstration of high current densities and extended cycling in the garnet Li7La3Zr2O12 solid electrolyte journal, August 2018

Freeze Tape Cast Thick Mo Doped Li 4 Ti 5 O 12 Electrodes for Lithium-Ion Batteries journal, January 2017

Electrical and flexural anisotropy in freeze tape cast stainless steel porous substrates journal, December 2011

A solid future for battery development journal, September 2016

Thermal analysis of a solid polymer electrolyte and a subsequent electrochemical investigation of a lithium polymer battery journal, February 2003

Rational design of multi-channel continuous electronic/ionic conductive networks for room temperature vanadium tetrasulfide-based all-solid-state lithium-sulfur batteries journal, March 2019

Effects of Fluorine Doping on Structural and Electrochemical Properties of Li 6.25 Ga 0.25 La 3 Zr 2 O 12 as Electrolytes for Solid-State Lithium Batteries journal, December 2018

Interrelationships among Grain Size, Surface Composition, Air Stability, and Interfacial Resistance of Al-Substituted Li 7 La 3 Zr 2 O 12 Solid Electrolytes journal, August 2015

Flame made nanoparticles permit processing of dense, flexible, Li + conducting ceramic electrolyte thin films of cubic-Li 7 La 3 Zr 2 O 12 (c-LLZO) journal, January 2016

Interfacial Stability of Li Metal–Solid Electrolyte Elucidated via in Situ Electron Microscopy journal, October 2016

Fast Li+ Ion Conduction in Li2O-Al2O3-TiO2-SiO2-P2O2 Glass-Ceramics journal, July 1997

Compatibility of Li[sub 7]La[sub 3]Zr[sub 2]O[sub 12] Solid Electrolyte to All-Solid-State Battery Using Li Metal Anode journal, January 2010

Ceramic and polymeric solid electrolytes for lithium-ion batteries journal, August 2010

A Synthesis and Crystal Chemical Study of the Fast Ion Conductor Li 7–3 x Ga x La 3 Zr 2 O 12 with x = 0.08 to 0.84 journal, May 2014

Ion exchange properties of and rates of ionic diffusion in beta-alumina journal, September 1967

Flash Sintering of Nanograin Zirconia in <5 s at 850°C journal, September 2010

Review of flash sintering: materials, mechanisms and modelling journal, December 2016

Three-dimensional bilayer garnet solid electrolyte based high energy density lithium metal–sulfur batteries journal, January 2017

Structure and ionic conductivity in lithium garnets journal, January 2010

Solids with high ionic conductivity in group 1 halide systems
journal, January 1967

Fast microwave-assisted synthesis of Li-stuffed garnets and insights into Li diffusion from muon spin spectroscopy
journal, January 2016

Negating interfacial impedance in garnet-based solid-state Li metal batteries
journal, December 2016

Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries
journal, January 2017

Elastic Properties of the Solid Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO)
journal, December 2015

The Measurement of a Complete Set of Transport Properties for a Concentrated Solid Polymer Electrolyte Solution
journal, January 1995

A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries
journal, January 2014

3D-Printing Electrolytes for Solid-State Batteries
journal, March 2018

Hybrid Polymer/Garnet Electrolyte with a Small Interfacial Resistance for Lithium-Ion Batteries
journal, December 2016

XPS and ionic conductivity studies on Li2O–Al2O3–(TiO2 or GeO2)–P2O5 glass–ceramics
journal, November 2000

A New Approach to Develop Safe All-Inorganic Monolithic Li-Ion Batteries
journal, February 2011

Lithium garnets: Synthesis, structure, Li + conductivity, Li + dynamics and applications
journal, July 2017

Effect of Surface Microstructure on Electrochemical Performance of Garnet Solid Electrolytes
journal, January 2015

The fast lithium-ion conducting oxides Li3xLa2/3−xTiO3 from fundamentals to application
journal, March 2008

Improving Li-ion battery charge rate acceptance through highly ordered hierarchical electrode design
journal, March 2018

The origin of conductivity variations in Al-stabilized Li7La3Zr2O12 ceramics
journal, June 2018

Stabilization of cubic lithium-stuffed garnets of the type “Li7La3Zr2O12” by addition of gallium
journal, March 2013

Solid Electrolyte: the Key for High-Voltage Lithium Batteries
journal, October 2014

High temperature sodium batteries: status, challenges and future trends
journal, January 2013

Ta-Doped Li ₇ La ₃ Zr ₂ O ₁₂ for Water-Stable Lithium Electrode of Lithium-Air Batteries
journal, January 2014

Recent advances in all-solid-state rechargeable lithium batteries
journal, March 2017

Preparation of Garnet-Type Li7 − 3xAlxLa3Zr2O12 at Lower Temperature by Using Powders of Mixed Pre-treatment Conditions
journal, April 2018

High-Energy All-Solid-State Lithium Batteries with Ultralong Cycle Life
journal, October 2016

Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density
journal, January 2016

Freeze casting – A review of processing, microstructure and properties via the open data repository, FreezeCasting.net
journal, May 2018

A lithium superionic conductor
journal, July 2011

Lithium metal electrode kinetics and ionic conductivity of the solid lithium ion conductors “Li7La3Zr2O12” and Li7−xLa3Zr2−xTaxO12 with garnet-type structure
journal, May 2012

Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte
journal, January 2017

Inorganic solid Li ion conductors: An overview
journal, June 2009

Prospects of microwave processing: An overview
journal, February 2009

Transport property measurements of polymer electrolytes
journal, April 1998

Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics
journal, August 2016

Development of the cold sintering process and its application in solid-state lithium batteries
journal, July 2018

A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride
journal, January 1997

A shortcut to garnet-type fast Li-ion conductors for all-solid state batteries
journal, January 2015

First-Principles Studies on Cation Dopants and Electrolyte|Cathode Interphases for Lithium Garnets
journal, May 2015

Field assisted sintering of dense Al-substituted cubic phase Li7La3Zr2O12 solid electrolytes
journal, December 2014

Composite solid electrolytes: recent advances and design strategies
journal, December 2008

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces
journal, January 2005

A surfactant-assisted strategy to tailor Li-ion charge transfer interfacial resistance for scalable all-solid-state Li batteries
journal, January 2018

Garnet related lithium ion conductor processed by spark plasma sintering for all solid state batteries
journal, March 2014

Freeze-Casting of Porous Ceramics: A Review of Current Achievements and Issues
journal, March 2008

pH sensors with lithium lanthanum titanate sensitive material: applications in food industry
journal, April 2003

Effect of microstructure and surface impurity segregation on the electrical and electrochemical properties of dense Al-substituted Li ₇ La ₃ Zr ₂ O ₁₂
journal, January 2014

High-rate lithium cycling in a scalable trilayer Li-garnet-electrolyte architecture
journal, January 2019

Structure and dynamics of the fast lithium ion conductor “Li7La3Zr2O12”
journal, January 2011

Fast Lithium Ion Conduction in Garnet-Type Li₇La₃Zr₂O₁₂
journal, October 2007

Stability of Nb-Doped Cubic Li ₇ La ₃ Zr ₂ O ₁₂ with Lithium Metal
journal, January 2013

Crystal Chemistry and Stability of “Li₇La₃Zr₂O₁₂ ” Garnet: A Fast Lithium-Ion Conductor
journal, February 2011

Atomic-scale origin of the large grain-boundary resistance in perovskite Li-ion-conducting solid electrolytes
journal, January 2014

High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes
journal, January 2019

Effect of Electrolyte Composition on the Performance of Sodium/Polymer Cells
journal, January 1997

Multi-Scale Mechanical Behavior of the Li ₃ PS ₄ Solid-Phase Electrolyte
journal, October 2016

Compatibility issues between electrodes and electrolytes in solid-state batteries
journal, January 2017

The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes
journal, January 2014

Fundamental study on the wetting property of liquid lithium
journal, September 2018

Garnet Electrolyte Surface Degradation and Recovery
journal, October 2018

Demonstration of high current densities and extended cycling in the garnet Li7La3Zr2O12 solid electrolyte
journal, August 2018

Freeze Tape Cast Thick Mo Doped Li ₄ Ti ₅ O ₁₂ Electrodes for Lithium-Ion Batteries
journal, January 2017

Electrical and flexural anisotropy in freeze tape cast stainless steel porous substrates
journal, December 2011

A solid future for battery development
journal, September 2016

Thermal analysis of a solid polymer electrolyte and a subsequent electrochemical investigation of a lithium polymer battery
journal, February 2003

Rational design of multi-channel continuous electronic/ionic conductive networks for room temperature vanadium tetrasulfide-based all-solid-state lithium-sulfur batteries
journal, March 2019

Effects of Fluorine Doping on Structural and Electrochemical Properties of Li _6.25 Ga _0.25 La ₃ Zr ₂ O ₁₂ as Electrolytes for Solid-State Lithium Batteries
journal, December 2018

Interrelationships among Grain Size, Surface Composition, Air Stability, and Interfacial Resistance of Al-Substituted Li ₇ La ₃ Zr ₂ O ₁₂ Solid Electrolytes
journal, August 2015

Flame made nanoparticles permit processing of dense, flexible, Li ⁺ conducting ceramic electrolyte thin films of cubic-Li ₇ La ₃ Zr ₂ O ₁₂ (c-LLZO)
journal, January 2016

Interfacial Stability of Li Metal–Solid Electrolyte Elucidated via in Situ Electron Microscopy
journal, October 2016

Fast Li+ Ion Conduction in Li₂O-Al₂O₃-TiO₂-SiO₂-P₂O₂ Glass-Ceramics
journal, July 1997

Compatibility of Li[sub 7]La[sub 3]Zr[sub 2]O[sub 12] Solid Electrolyte to All-Solid-State Battery Using Li Metal Anode
journal, January 2010

Ceramic and polymeric solid electrolytes for lithium-ion batteries
journal, August 2010

A Synthesis and Crystal Chemical Study of the Fast Ion Conductor Li _{7–3 x} Ga _x La ₃ Zr ₂ O ₁₂ with x = 0.08 to 0.84
journal, May 2014

Ion exchange properties of and rates of ionic diffusion in beta-alumina
journal, September 1967

Flash Sintering of Nanograin Zirconia in <5 s at 850°C
journal, September 2010

Review of flash sintering: materials, mechanisms and modelling
journal, December 2016

Three-dimensional bilayer garnet solid electrolyte based high energy density lithium metal–sulfur batteries
journal, January 2017

Structure and ionic conductivity in lithium garnets
journal, January 2010

Garnet Electrolyte with an Ultralow Interfacial Resistance for Li-Metal Batteries
journal, April 2018

High-Performance All-Solid-State Lithium-Sulfur Batteries Enabled by Amorphous Sulfur-Coated Reduced Graphene Oxide Cathodes
journal, May 2017

Capacity Fade in Solid-State Batteries: Interphase Formation and Chemomechanical Processes in Nickel-Rich Layered Oxide Cathodes and Lithium Thiophosphate Solid Electrolytes
journal, June 2017