Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles

Paull, Ryan J.; Ly, Tiffany; Mansley, Zachary R.; Poeppelmeier, Kenneth R.; Marks, Laurence D.

doi:10.3390/cryst9040218

Title: Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles

Abstract

A general approach to the formation of well-faceted nanoparticles is discussed and successfully applied to the production of several rare-earth scandates. Two steps were used, with higher temperatures first to nucleate the perovskite phase, followed by lower temperatures to smooth the particle surfaces. Exploiting these two different regimes led to smaller nanoparticles with more faceting. This general approach may be tailored to other material systems as a step towards producing shape-controlled nanoparticles for a desired application.

Authors:

;

; Mansley, Zachary R.; Poeppelmeier, Kenneth R.; Marks, Laurence D.

Publication Date:: Tue Apr 23 00:00:00 EDT 2019

Research Org.:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Science Foundation (NSF)

OSTI Identifier:: 1508657

Alternate Identifier(s):: OSTI ID: 1609436

Grant/Contract Number:: FG02-03ER15457; DMR-1507101

Resource Type:: Published Article

Journal Name:: Crystals

Additional Journal Information:: Journal Name: Crystals Journal Volume: 9 Journal Issue: 4; Journal ID: ISSN 2073-4352

Publisher:: MDPI

Country of Publication:: Germany

Language:: English

Subject:: 77 NANOSCIENCE AND NANOTECHNOLOGY; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; crystallography; materials science; rare-earth scandate; perovskite; nucleation and growth

Citation Formats


                    Paull, Ryan J., Ly, Tiffany, Mansley, Zachary R., Poeppelmeier, Kenneth R., and Marks, Laurence D. Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles.  Germany: N. p., 2019. 
Web.  doi:10.3390/cryst9040218.

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                    Paull, Ryan J., Ly, Tiffany, Mansley, Zachary R., Poeppelmeier, Kenneth R., & Marks, Laurence D. Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles.  Germany.  https://doi.org/10.3390/cryst9040218

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                    Paull, Ryan J., Ly, Tiffany, Mansley, Zachary R., Poeppelmeier, Kenneth R., and Marks, Laurence D. Tue .  
"Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles".  Germany.  https://doi.org/10.3390/cryst9040218.

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@article{osti_1508657,

  title        = {Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles},

  author       = {Paull, Ryan J. and Ly, Tiffany and Mansley, Zachary R. and Poeppelmeier, Kenneth R. and Marks, Laurence D.},

  abstractNote = {A general approach to the formation of well-faceted nanoparticles is discussed and successfully applied to the production of several rare-earth scandates. Two steps were used, with higher temperatures first to nucleate the perovskite phase, followed by lower temperatures to smooth the particle surfaces. Exploiting these two different regimes led to smaller nanoparticles with more faceting. This general approach may be tailored to other material systems as a step towards producing shape-controlled nanoparticles for a desired application.},

  doi          = {10.3390/cryst9040218},

  journal      = {Crystals},

  number       = 4,

  volume       = 9,

  place        = {Germany},

  year         = {Tue Apr 23 00:00:00 EDT 2019},

  month        = {Tue Apr 23 00:00:00 EDT 2019}

}

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Title: Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles

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Water vapor-assisted solid-state reaction for the synthesis of nanocrystalline BaZrO3 powder
journal, January 2013

Surface functionalization of nanoparticles for nanomedicine
journal, January 2012

Luminescent Rare-earth-based Nanoparticles: A Summarized Overview of their Synthesis, Functionalization, and Applications
journal, July 2016

Theory of diffusion-limited precipitation
journal, September 1958

Hydrothermal synthesis of LnMnO3 (Ln = Ho–Lu and Y): exploiting amphoterism in late rare-earth oxides
journal, January 2009

Electronic properties of small silver particles: the optical constants and their temperature dependence
journal, July 1974