Structural and magnetic properties of the CeCo5–CeZn5 solid solution and potential improvements upon iron substitution

Onyszczak, Michael T.; Lamichhane, Tej N.; Bud’ko, Sergey L.; Canfield, Paul C.; Palasyuk, Andriy

doi:10.1016/j.jmmm.2019.03.024

Title: Structural and magnetic properties of the CeCo₅–CeZn₅ solid solution and potential improvements upon iron substitution

Abstract

In an effort to create high-performance permanent magnets with reduced critical rare earth content, we explored the CeCo_5-xT_x (T = transition metal or metalloid) family of compounds to investigate the effect of substitution on the material’s magnetic properties. In our exploration of the CeCo_5-xZn_x system, we discovered a continuous solid solution at 900 °C between the CeCo₅ and CeZn₅ binary phases with ferromagnetism existing from the CeCo₅ compound to the intermediate CeCo_2.75Zn_2.25 compound. Single crystal studies were also conducted revealing a relatively large anisotropy field of 11.5 T at 300 K for Ce_0.96Ta_0.04Co_4.35Zn_0.65. Here, the addition of iron Ce_0.79Ta_0.07Co_3.77Fe_0.89Zn_0.47 yielded further increases in Curie temperature and saturation magnetization to 800 K and 85.5 emu/g, respectively.

Authors:

Onyszczak, Michael T. ^[1]; Lamichhane, Tej N. ^[1]; Bud’ko, Sergey L. ^[1]; Canfield, Paul C. ^[1];

^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States)

Publication Date:: Wed Mar 06 00:00:00 EST 2019

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1506103

Alternate Identifier(s):: OSTI ID: 1636484

Report Number(s):: IS-J-9919
Journal ID: ISSN 0304-8853

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Magnetism and Magnetic Materials

Additional Journal Information:: Journal Volume: 482; Journal Issue: C; Journal ID: ISSN 0304-8853

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Single crystal; Magnetization; Demagnetization factor; Arrott plot; Transition temperature; Anisotropy constant

Citation Formats


                    Onyszczak, Michael T., Lamichhane, Tej N., Bud’ko, Sergey L., Canfield, Paul C., and Palasyuk, Andriy. Structural and magnetic properties of the CeCo5–CeZn5 solid solution and potential improvements upon iron substitution.  United States: N. p., 2019. 
Web.  doi:10.1016/j.jmmm.2019.03.024.

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                    Onyszczak, Michael T., Lamichhane, Tej N., Bud’ko, Sergey L., Canfield, Paul C., & Palasyuk, Andriy. Structural and magnetic properties of the CeCo5–CeZn5 solid solution and potential improvements upon iron substitution.  United States.  https://doi.org/10.1016/j.jmmm.2019.03.024

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                    Onyszczak, Michael T., Lamichhane, Tej N., Bud’ko, Sergey L., Canfield, Paul C., and Palasyuk, Andriy. Wed .  
"Structural and magnetic properties of the CeCo5–CeZn5 solid solution and potential improvements upon iron substitution".  United States.  https://doi.org/10.1016/j.jmmm.2019.03.024.  https://www.osti.gov/servlets/purl/1506103.

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@article{osti_1506103,

  title        = {Structural and magnetic properties of the CeCo5–CeZn5 solid solution and potential improvements upon iron substitution},

  author       = {Onyszczak, Michael T. and Lamichhane, Tej N. and Bud’ko, Sergey L. and Canfield, Paul C. and Palasyuk, Andriy},

  abstractNote = {In an effort to create high-performance permanent magnets with reduced critical rare earth content, we explored the CeCo5-xTx (T = transition metal or metalloid) family of compounds to investigate the effect of substitution on the material’s magnetic properties. In our exploration of the CeCo5-xZnx system, we discovered a continuous solid solution at 900 °C between the CeCo5 and CeZn5 binary phases with ferromagnetism existing from the CeCo5 compound to the intermediate CeCo2.75Zn2.25 compound. Single crystal studies were also conducted revealing a relatively large anisotropy field of 11.5 T at 300 K for Ce0.96Ta0.04Co4.35Zn0.65. Here, the addition of iron Ce0.79Ta0.07Co3.77Fe0.89Zn0.47 yielded further increases in Curie temperature and saturation magnetization to 800 K and 85.5 emu/g, respectively.},

  doi          = {10.1016/j.jmmm.2019.03.024},

  journal      = {Journal of Magnetism and Magnetic Materials},

  number       = C,

  volume       = 482,

  place        = {United States},

  year         = {Wed Mar 06 00:00:00 EST 2019},

  month        = {Wed Mar 06 00:00:00 EST 2019}

}

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Works referencing / citing this record:

Cerium-based R Co ₅ ( R = Ce, La _0.35 Ce _0.65 , and misch-metal) type nanocrystalline hard magnetic materials with high coercivity
journal, September 2019

Zuo, Wen-Liang; Mohapatra, Jeotikanta; Liu, J. Ping
APL Materials, Vol. 7, Issue 9
DOI: 10.1063/1.5104295

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Similar Records

Title: Structural and magnetic properties of the CeCo5–CeZn5 solid solution and potential improvements upon iron substitution

Abstract

Citation Formats

Co energy and magnetization anisotropies in RCo5 intermetallics between 4.2 K and 300 K journal, March 1981

An empirical correction for absorption anisotropy journal, January 1995

Growth of single crystals from metallic fluxes journal, June 1992

ChemInform Abstract: Phase Relations and Crystal Structures in the System Ce-Ni-Zn at 800 °C. journal, October 2012

A Family of New Cobalt‐Base Permanent Magnet Materials journal, March 1967

Investigation of weak itinerant ferromagnetism and critical behavior of Y 2 Ni 7 journal, November 2011

ChemInform Abstract: The System Ce-Zn-B at 800 °C journal, December 2011

Comparison of the interaction of components in the La–Co–Zn and Ce–Co–Zn ternary systems at 470 K journal, April 2001

Structural and Ferromagnetic Properties of an Orthorhombic Phase of MnBi Stabilized with Rh Additions journal, July 2015

Magnetic anisotropy and high-field magnetization process of CeCo5 journal, March 1994

Theory of ferromagnetism in CeCo 5 journal, May 1990

Phase relations and crystal structures in the system Ce–Ni–Zn at 800°C journal, October 2012

High-temperature solution growth of intermetallic single crystals and quasicrystals journal, May 2001

Recent advances in magnetic structure determination by neutron powder diffraction journal, October 1993

The system Ce–Zn–B at 800°C journal, November 2011

Approximate Equation of State For Nickel Near its Critical Temperature journal, October 1967

Ce 3 − x Mg x Co 9 : Transformation of a Pauli Paramagnet into a Strong Permanent Magnet journal, February 2018

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Title: Structural and magnetic properties of the CeCo₅–CeZn₅ solid solution and potential improvements upon iron substitution

Co energy and magnetization anisotropies in RCo5 intermetallics between 4.2 K and 300 K
journal, March 1981

An empirical correction for absorption anisotropy
journal, January 1995

Growth of single crystals from metallic fluxes
journal, June 1992

ChemInform Abstract: Phase Relations and Crystal Structures in the System Ce-Ni-Zn at 800 °C.
journal, October 2012

A Family of New Cobalt‐Base Permanent Magnet Materials
journal, March 1967

Investigation of weak itinerant ferromagnetism and critical behavior of Y $_{2}$ Ni $_{7}$
journal, November 2011

ChemInform Abstract: The System Ce-Zn-B at 800 °C
journal, December 2011

Comparison of the interaction of components in the La–Co–Zn and Ce–Co–Zn ternary systems at 470 K
journal, April 2001

Structural and Ferromagnetic Properties of an Orthorhombic Phase of MnBi Stabilized with Rh Additions
journal, July 2015

Magnetic anisotropy and high-field magnetization process of CeCo5
journal, March 1994

Theory of ferromagnetism in ${CeCo}_{5}$
journal, May 1990

Phase relations and crystal structures in the system Ce–Ni–Zn at 800°C
journal, October 2012

High-temperature solution growth of intermetallic single crystals and quasicrystals
journal, May 2001

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

The system Ce–Zn–B at 800°C
journal, November 2011

Approximate Equation of State For Nickel Near its Critical Temperature
journal, October 1967

${Ce}_{3 - x} {Mg}_{x} {Co}_{9}$ : Transformation of a Pauli Paramagnet into a Strong Permanent Magnet
journal, February 2018

Cerium-based R Co ₅ ( R = Ce, La _0.35 Ce _0.65 , and misch-metal) type nanocrystalline hard magnetic materials with high coercivity
journal, September 2019