Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material
Abstract
The growing need to store an increasing amount of renewable energy in a sustainable way has rekindled interest for sodium-ion battery technology, owing to the natural abundance of sodium. Presently, sodium-ion batteries based on Na3V2(PO4)2F3/C are the subject of intense research focused on improving the energy density by harnessing the third sodium, which has so far been reported to be electrochemically inaccessible. Here, we are able to trigger the activity of the third sodium electrochemically via the formation of a disordered NaxV2(PO4)2F3 phase of tetragonal symmetry (I4/mmm space group). This phase can reversibly uptake 3 sodium ions per formula unit over the 1 to 4.8 V voltage range, with the last one being re-inserted at 1.6 V vs Na+/Na0. We track the sodium-driven structural/charge compensation mechanism associated to the new phase and find that it remains disordered on cycling while its average vanadium oxidation state varies from 3 to 4.5. Full sodium-ion cells based on this phase as positive electrode and carbon as negative electrode show a 10–20% increase in the overall energy density.
- Authors:
-
- Collège de France, Paris (France). Solid-Energy Chemistry; Research Network on Electrochemical Energy Storage (RS2E), Amiens (France)
- Collège de France, Paris (France). Solid-Energy Chemistry; Research Network on Electrochemical Energy Storage (RS2E), Amiens (France); Sorbonne Univ., Paris (France)
- Collège de France, Paris (France). Solid-Energy Chemistry
- Research Network on Electrochemical Energy Storage (RS2E), Amiens (France); Univ. of Orléans (France)
- Univ. of Picardie Jules Verne, Amiens (France)
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); College de France, Paris (France); Research Network on Electrochemical Energy Storage (RS2E), Amiens (France)
- Sponsoring Org.:
- USDOE Office of Science (SC); European Research Council (ERC); National Center for Scientific Research (CNRS) (France)
- OSTI Identifier:
- 1505146
- Grant/Contract Number:
- AC02-06CH11357; 670116-ARPEMA
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; materials for energy and catalysis; materials science
Citation Formats
Yan, Guochun, Mariyappan, Sathiya, Rousse, Gwenaelle, Jacquet, Quentin, Deschamps, Michael, David, Renald, Mirvaux, Boris, Freeland, John William, and Tarascon, Jean-Marie. Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-08359-y.
Yan, Guochun, Mariyappan, Sathiya, Rousse, Gwenaelle, Jacquet, Quentin, Deschamps, Michael, David, Renald, Mirvaux, Boris, Freeland, John William, & Tarascon, Jean-Marie. Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material. United States. https://doi.org/10.1038/s41467-019-08359-y
Yan, Guochun, Mariyappan, Sathiya, Rousse, Gwenaelle, Jacquet, Quentin, Deschamps, Michael, David, Renald, Mirvaux, Boris, Freeland, John William, and Tarascon, Jean-Marie. Mon .
"Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material". United States. https://doi.org/10.1038/s41467-019-08359-y. https://www.osti.gov/servlets/purl/1505146.
@article{osti_1505146,
title = {Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material},
author = {Yan, Guochun and Mariyappan, Sathiya and Rousse, Gwenaelle and Jacquet, Quentin and Deschamps, Michael and David, Renald and Mirvaux, Boris and Freeland, John William and Tarascon, Jean-Marie},
abstractNote = {The growing need to store an increasing amount of renewable energy in a sustainable way has rekindled interest for sodium-ion battery technology, owing to the natural abundance of sodium. Presently, sodium-ion batteries based on Na3V2(PO4)2F3/C are the subject of intense research focused on improving the energy density by harnessing the third sodium, which has so far been reported to be electrochemically inaccessible. Here, we are able to trigger the activity of the third sodium electrochemically via the formation of a disordered NaxV2(PO4)2F3 phase of tetragonal symmetry (I4/mmm space group). This phase can reversibly uptake 3 sodium ions per formula unit over the 1 to 4.8 V voltage range, with the last one being re-inserted at 1.6 V vs Na+/Na0. We track the sodium-driven structural/charge compensation mechanism associated to the new phase and find that it remains disordered on cycling while its average vanadium oxidation state varies from 3 to 4.5. Full sodium-ion cells based on this phase as positive electrode and carbon as negative electrode show a 10–20% increase in the overall energy density.},
doi = {10.1038/s41467-019-08359-y},
journal = {Nature Communications},
number = ,
volume = 10,
place = {United States},
year = {Mon Feb 04 00:00:00 EST 2019},
month = {Mon Feb 04 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 169 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:
Figure 1: Electrochemical characterization of NVPF samples in NVPF/Na half cells at a current of C/10 and cycled between 4.4 and 3.0 V. The first charge process alone is controlled by limiting the amount of Na+ extracted (Δx= 2.0, 2.25, 2.50, 2.75, and 3.0). a Voltage-composition curves (left) and theirmore »
All figures and tables
(8 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Review—Practical Issues and Future Perspective for Na-Ion Batteries
journal, January 2015
- Kubota, Kei; Komaba, Shinichi
- Journal of The Electrochemical Society, Vol. 162, Issue 14
V IV Disproportionation Upon Sodium Extraction From Na 3 V 2 (PO 4 ) 2 F 3 Observed by Operando X-ray Absorption Spectroscopy and Solid-State NMR
journal, February 2017
- Broux, Thibault; Bamine, Tahya; Simonelli, Laura
- The Journal of Physical Chemistry C, Vol. 121, Issue 8
Strong Impact of the Oxygen Content in Na 3 V 2 (PO 4 ) 2 F 3– y O y (0 ≤ y ≤ 0.5) on Its Structural and Electrochemical Properties
journal, October 2016
- Broux, Thibault; Bamine, Tahya; Fauth, François
- Chemistry of Materials, Vol. 28, Issue 21
Structure and Dynamics of Fluorophosphate Na-Ion Battery Cathodes
journal, July 2016
- Dacek, Stephen T.; Richards, William D.; Kitchaev, Daniil A.
- Chemistry of Materials, Vol. 28, Issue 15
Towards high energy density sodium ion batteries through electrolyte optimization
journal, January 2013
- Ponrouch, Alexandre; Dedryvère, Rémi; Monti, Damien
- Energy & Environmental Science, Vol. 6, Issue 8
Prototype Sodium-Ion Batteries Using an Air-Stable and Co/Ni-Free O3-Layered Metal Oxide Cathode
journal, October 2015
- Mu, Linqin; Xu, Shuyin; Li, Yunming
- Advanced Materials, Vol. 27, Issue 43
Comprehensive Investigation of the Na 3 V 2 (PO 4 ) 2 F 3 –NaV 2 (PO 4 ) 2 F 3 System by Operando High Resolution Synchrotron X-ray Diffraction
journal, April 2015
- Bianchini, M.; Fauth, F.; Brisset, N.
- Chemistry of Materials, Vol. 27, Issue 8
Modelling one- and two-dimensional solid-state NMR spectra: Modelling 1D and 2D solid-state NMR spectra
journal, December 2001
- Massiot, Dominique; Fayon, Franck; Capron, Mickael
- Magnetic Resonance in Chemistry, Vol. 40, Issue 1
Cathode properties of Na3M2(PO4)2F3 [M = Ti, Fe, V] for sodium-ion batteries
journal, April 2013
- Chihara, Kuniko; Kitajou, Ayuko; Gocheva, Irina D.
- Journal of Power Sources, Vol. 227
Electrochemical Energy Storage for Green Grid
journal, May 2011
- Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
- Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance
journal, November 2017
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Advanced Energy Materials, Vol. 8, Issue 8
Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993
- Rodríguez-Carvajal, Juan
- Physica B: Condensed Matter, Vol. 192, Issue 1-2
Na 3 V 2 (PO 4 ) 2 F 3 Revisited: A High-Resolution Diffraction Study
journal, June 2014
- Bianchini, M.; Brisset, N.; Fauth, F.
- Chemistry of Materials, Vol. 26, Issue 14
Assessment of the Electrochemical Stability of Carbonate-Based Electrolytes in Na-Ion Batteries
journal, January 2018
- Yan, Guochun; Alves-Dalla-Corte, Daniel; Yin, Wei
- Journal of The Electrochemical Society, Vol. 165, Issue 7
The electrochemical insertion properties of sodium vanadium fluorophosphate, Na3V2(PO4)2F3
journal, July 2006
- Gover, R.; Bryan, A.; Burns, P.
- Solid State Ionics, Vol. 177, Issue 17-18
A Family of High-Performance Cathode Materials for Na-ion Batteries, Na 3 (VO 1− x PO 4 ) 2 F 1+2 x (0 ≤ x ≤ 1): Combined First-Principles and Experimental Study
journal, April 2014
- Park, Young-Uk; Seo, Dong-Hwa; Kim, Hyungsub
- Advanced Functional Materials, Vol. 24, Issue 29
Sustainability and in situ monitoring in battery development
journal, December 2016
- Grey, C. P.; Tarascon, J. M.
- Nature Materials, Vol. 16, Issue 1
Crystal Structure, Energetics, And Electrochemistry of Li 2 FeSiO 4 Polymorphs from First Principles Calculations
journal, December 2011
- Saracibar, A.; Van der Ven, A.; Arroyo-de Dompablo, M. E.
- Chemistry of Materials, Vol. 24, Issue 3
71Ga and 69Ga nuclear magnetic resonance study of β-Ga2O3: resolution of four- and six-fold coordinated Ga sites in static conditions
journal, May 1995
- Massiot, Dominique; Farnan, Ian; Gautier, Nathalie
- Solid State Nuclear Magnetic Resonance, Vol. 4, Issue 4
Electrochemical Na Extraction/Insertion of Na 3 V 2 O 2 x (PO 4 ) 2 F 3–2 x
journal, December 2013
- Serras, Paula; Palomares, Verónica; Alonso, Javier
- Chemistry of Materials, Vol. 25, Issue 24
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013
- Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
- Energy & Environmental Science, Vol. 6, Issue 8
Li 3 VO 4 : A Promising Insertion Anode Material for Lithium-Ion Batteries
journal, December 2012
- Li, Huiqiao; Liu, Xizheng; Zhai, Tianyou
- Advanced Energy Materials, Vol. 3, Issue 4
Explaining Performance-Limiting Mechanisms in Fluorophosphate Na-Ion Battery Cathodes through Inactive Transition-Metal Mixing and First-Principles Mobility Calculations
journal, August 2015
- Matts, Ian L.; Dacek, Stephen; Pietrzak, Tomasz K.
- Chemistry of Materials, Vol. 27, Issue 17
Structural evolution of mixed valent (V 3+ /V 4+ ) and V 4+ sodium vanadium fluorophosphates as cathodes in sodium-ion batteries: comparisons, overcharging and mid-term cycling
journal, January 2015
- Palomares, V.; Serras, P.; Brand, H. E. A.
- Journal of Materials Chemistry A, Vol. 3, Issue 45
Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011
- Dunn, B.; Kamath, H.; Tarascon, J. -M.
- Science, Vol. 334, Issue 6058
Optimization of Na-Ion Battery Systems Based on Polyanionic or Layered Positive Electrodes and Carbon Anodes
journal, January 2016
- Dugas, R.; Zhang, B.; Rozier, P.
- Journal of The Electrochemical Society, Vol. 163, Issue 6
Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014
- Larcher, D.; Tarascon, J-M.
- Nature Chemistry, Vol. 7, Issue 1
A New High-Energy Cathode for a Na-Ion Battery with Ultrahigh Stability
journal, September 2013
- Park, Young-Uk; Seo, Dong-Hwa; Kwon, Hyung-Soon
- Journal of the American Chemical Society, Vol. 135, Issue 37
Additional Sodium Insertion into Polyanionic Cathodes for Higher-Energy Na-Ion Batteries
journal, May 2017
- Bianchini, Matteo; Xiao, Penghao; Wang, Yan
- Advanced Energy Materials, Vol. 7, Issue 18
Local Structure and Dynamics in the Na Ion Battery Positive Electrode Material Na 3 V 2 (PO 4 ) 2 F 3
journal, April 2014
- Liu, Zigeng; Hu, Yan-Yan; Dunstan, Matthew T.
- Chemistry of Materials, Vol. 26, Issue 8
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Insertion compounds and composites made by ball milling for advanced sodium-ion batteries
journal, January 2016
- Zhang, Biao; Dugas, Romain; Rousse, Gwenaelle
- Nature Communications, Vol. 7, Issue 1
A Family of High-Performance Cathode Materials for Na-ion Batteries, Na 3 (VO 1− x PO 4 ) 2 F 1+2 x (0 ≤ x ≤ 1): Combined First-Principles and Experimental Study
journal, April 2014
- Park, Young-Uk; Seo, Dong-Hwa; Kim, Hyungsub
- Advanced Functional Materials, Vol. 24, Issue 29
Soft X-ray absorption spectroscopy of vanadium oxides
journal, March 1993
- Abbate, M.; Pen, H.; Czyżyk, M. T.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 62, Issue 1-2
71Ga and 69Ga nuclear magnetic resonance study of β-Ga2O3: resolution of four- and six-fold coordinated Ga sites in static conditions
journal, May 1995
- Massiot, Dominique; Farnan, Ian; Gautier, Nathalie
- Solid State Nuclear Magnetic Resonance, Vol. 4, Issue 4
Comprehensive Investigation of the Na 3 V 2 (PO 4 ) 2 F 3 –NaV 2 (PO 4 ) 2 F 3 System by Operando High Resolution Synchrotron X-ray Diffraction
journal, April 2015
- Bianchini, M.; Fauth, F.; Brisset, N.
- Chemistry of Materials, Vol. 27, Issue 8
Explaining Performance-Limiting Mechanisms in Fluorophosphate Na-Ion Battery Cathodes through Inactive Transition-Metal Mixing and First-Principles Mobility Calculations
journal, August 2015
- Matts, Ian L.; Dacek, Stephen; Pietrzak, Tomasz K.
- Chemistry of Materials, Vol. 27, Issue 17
Structure and Dynamics of Fluorophosphate Na-Ion Battery Cathodes
journal, July 2016
- Dacek, Stephen T.; Richards, William D.; Kitchaev, Daniil A.
- Chemistry of Materials, Vol. 28, Issue 15
V IV Disproportionation Upon Sodium Extraction From Na 3 V 2 (PO 4 ) 2 F 3 Observed by Operando X-ray Absorption Spectroscopy and Solid-State NMR
journal, February 2017
- Broux, Thibault; Bamine, Tahya; Simonelli, Laura
- The Journal of Physical Chemistry C, Vol. 121, Issue 8
Crystal Structure, Energetics, And Electrochemistry of Li 2 FeSiO 4 Polymorphs from First Principles Calculations
journal, December 2011
- Saracibar, A.; Van der Ven, A.; Arroyo-de Dompablo, M. E.
- Chemistry of Materials, Vol. 24, Issue 3
Electrochemical Na Extraction/Insertion of Na 3 V 2 O 2 x (PO 4 ) 2 F 3–2 x
journal, December 2013
- Serras, Paula; Palomares, Verónica; Alonso, Javier
- Chemistry of Materials, Vol. 25, Issue 24
Local Structure and Dynamics in the Na Ion Battery Positive Electrode Material Na 3 V 2 (PO 4 ) 2 F 3
journal, April 2014
- Liu, Zigeng; Hu, Yan-Yan; Dunstan, Matthew T.
- Chemistry of Materials, Vol. 26, Issue 8
Na 3 V 2 (PO 4 ) 2 F 3 Revisited: A High-Resolution Diffraction Study
journal, June 2014
- Bianchini, M.; Brisset, N.; Fauth, F.
- Chemistry of Materials, Vol. 26, Issue 14
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
A New High-Energy Cathode for a Na-Ion Battery with Ultrahigh Stability
journal, September 2013
- Park, Young-Uk; Seo, Dong-Hwa; Kwon, Hyung-Soon
- Journal of the American Chemical Society, Vol. 135, Issue 37
Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014
- Larcher, D.; Tarascon, J-M.
- Nature Chemistry, Vol. 7, Issue 1
Insertion compounds and composites made by ball milling for advanced sodium-ion batteries
journal, January 2016
- Zhang, Biao; Dugas, Romain; Rousse, Gwenaelle
- Nature Communications, Vol. 7, Issue 1
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013
- Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
- Energy & Environmental Science, Vol. 6, Issue 8
Towards high energy density sodium ion batteries through electrolyte optimization
journal, January 2013
- Ponrouch, Alexandre; Dedryvère, Rémi; Monti, Damien
- Energy & Environmental Science, Vol. 6, Issue 8
Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011
- Dunn, B.; Kamath, H.; Tarascon, J. -M.
- Science, Vol. 334, Issue 6058
Optimization of Na-Ion Battery Systems Based on Polyanionic or Layered Positive Electrodes and Carbon Anodes
journal, January 2016
- Dugas, R.; Zhang, B.; Rozier, P.
- Journal of The Electrochemical Society, Vol. 163, Issue 6
Review—Practical Issues and Future Perspective for Na-Ion Batteries
journal, January 2015
- Kubota, Kei; Komaba, Shinichi
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Works referencing / citing this record:
Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries
journal, January 2020
- Xu, Xiaoming; Xiong, Fangyu; Meng, Jiashen
- Advanced Functional Materials, Vol. 30, Issue 10
Three Electron Reversible Redox Reaction in Sodium Vanadium Chromium Phosphate as a High‐Energy‐Density Cathode for Sodium‐Ion Batteries
journal, January 2020
- Zhao, Yongjie; Gao, Xiangwen; Gao, Hongcai
- Advanced Functional Materials, Vol. 30, Issue 10
Reaching the Energy Density Limit of Layered O3‐NaNi 0.5 Mn 0.5 O 2 Electrodes via Dual Cu and Ti Substitution
journal, August 2019
- Wang, Qing; Mariyappan, Sathiya; Vergnet, Jean
- Advanced Energy Materials, Vol. 9, Issue 36
Development and Investigation of a NASICON‐Type High‐Voltage Cathode Material for High‐Power Sodium‐Ion Batteries
journal, December 2019
- Chen, Mingzhe; Hua, Weibo; Xiao, Jin
- Angewandte Chemie, Vol. 132, Issue 6
Development and Investigation of a NASICON‐Type High‐Voltage Cathode Material for High‐Power Sodium‐Ion Batteries
journal, February 2020
- Chen, Mingzhe; Hua, Weibo; Xiao, Jin
- Angewandte Chemie International Edition, Vol. 59, Issue 6
Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy
journal, July 2019
- Chen, Mingzhe; Chou, Shu‐Lei; Dou, Shi‐Xue
- Batteries & Supercaps, Vol. 2, Issue 10
Nitrogen‐Doped Hard Carbon on Nickel Foam as Free‐Standing Anodes for High‐Performance Sodium‐Ion Batteries
journal, December 2019
- Li, Ruizi; Huang, Jianfeng; Li, Jiayin
- ChemElectroChem, Vol. 7, Issue 3
Highly Electrochemically‐Reversible Mesoporous Na 2 FePO 4 F/C as Cathode Material for High‐Performance Sodium‐Ion Batteries
journal, October 2019
- Zhang, Jiexin; Zhou, Xi; Wang, Yunxiao
- Small, Vol. 15, Issue 46
Aluminum substitution for vanadium in the Na 3 V 2 (PO 4 ) 2 F 3 and Na 3 V 2 (PO 4 ) 2 FO 2 type materials
journal, January 2019
- Olchowka, Jacob; Nguyen, Long H. B.; Broux, Thibault
- Chemical Communications, Vol. 55, Issue 78
Advances in sodium secondary batteries utilizing ionic liquid electrolytes
journal, January 2019
- Matsumoto, Kazuhiko; Hwang, Jinkwang; Kaushik, Shubham
- Energy & Environmental Science, Vol. 12, Issue 11
A black phosphorus/Ti 3 C 2 MXene nanocomposite for sodium-ion batteries: a combined experimental and theoretical study
journal, January 2019
- Li, Huan; Liu, Anmin; Ren, Xuefeng
- Nanoscale, Vol. 11, Issue 42
High-performance sodium-ion batteries with a hard carbon anode: transition from the half-cell to full-cell perspective
journal, January 2019
- Chen, Xinlong; Zheng, Yuheng; Liu, Wenjian
- Nanoscale, Vol. 11, Issue 46
An alkali metal–selenium battery with a wide temperature range and low self-discharge
journal, January 2019
- Zhao, Xiaosen; Yin, Lichang; Yang, Zhenzhen
- Journal of Materials Chemistry A, Vol. 7, Issue 38
Emerging polyanionic and organic compounds for high energy density, non-aqueous potassium-ion batteries
journal, January 2020
- Chen, Mingzhe; Liu, Qiannan; Zhang, Yanyan
- Journal of Materials Chemistry A, Vol. 8, Issue 32
Reversible structural evolution of sodium-rich rhombohedral Prussian blue for sodium-ion batteries
journal, February 2020
- Wang, Wanlin; Gang, Yong; Hu, Zhe
- Nature Communications, Vol. 11, Issue 1
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.