A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs
Abstract
Abstract The introduction of a symmetry‐ and size‐matching pore‐partitioning agent in the form of either a molecular ligand, such as 2,4,6‐tri(4‐pyridinyl)‐1,3,5‐triazine ( tpt ), or a metal‐complex cluster, into the hexagonal channels of MIL‐88/MOF‐235‐type (the acs net) to create pacs ‐type (partitioned acs ) crystalline porous materials is an effective strategy to develop high‐performance gas adsorbents. We have developed an integrated COF–MOF coassembly strategy as a new method for pore‐space partitioning through the coassembly of [(M 3 (OH) 1− x (O) x (COO) 6 ] MOF‐type and [B 3 O 3 (py) 3 ] COF‐type trimers. With this strategy, the coordination‐driven assembly of the acs framework occurred concurrently and synergistically with the COF‐1‐type condensation of pyridine‐4‐boronic acid into a C 3 ‐symmetric trimeric boroxine molecule. The resulting boroxine‐based pacs materials exhibited dramatically enhanced gas‐sorption properties as compared to nonpartitioned acs ‐type materials and are among the most efficient NH 3 ‐sorption materials.
- Authors:
-
[1]
- Department of Chemistry University of California Riverside CA 92521 USA
- Department of Chemistry and Biochemistry California State University Long Beach Long Beach CA 90840 USA
- Department of Chemistry University of California Riverside CA 92521 USA, Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization Taiyuan University of Technology Taiyuan Shanxi 030024 China
- Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization Taiyuan University of Technology Taiyuan Shanxi 030024 China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1504507
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 19; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Wang, Yanxiang, Zhao, Xiang, Yang, Huajun, Bu, Xianhui, Wang, Yong, Jia, Xiaoxia, Li, Jinping, and Feng, Pingyun. A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs. Germany: N. p., 2019.
Web. doi:10.1002/ange.201901343.
Wang, Yanxiang, Zhao, Xiang, Yang, Huajun, Bu, Xianhui, Wang, Yong, Jia, Xiaoxia, Li, Jinping, & Feng, Pingyun. A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs. Germany. https://doi.org/10.1002/ange.201901343
Wang, Yanxiang, Zhao, Xiang, Yang, Huajun, Bu, Xianhui, Wang, Yong, Jia, Xiaoxia, Li, Jinping, and Feng, Pingyun. Tue .
"A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs". Germany. https://doi.org/10.1002/ange.201901343.
@article{osti_1504507,
title = {A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs},
author = {Wang, Yanxiang and Zhao, Xiang and Yang, Huajun and Bu, Xianhui and Wang, Yong and Jia, Xiaoxia and Li, Jinping and Feng, Pingyun},
abstractNote = {Abstract The introduction of a symmetry‐ and size‐matching pore‐partitioning agent in the form of either a molecular ligand, such as 2,4,6‐tri(4‐pyridinyl)‐1,3,5‐triazine ( tpt ), or a metal‐complex cluster, into the hexagonal channels of MIL‐88/MOF‐235‐type (the acs net) to create pacs ‐type (partitioned acs ) crystalline porous materials is an effective strategy to develop high‐performance gas adsorbents. We have developed an integrated COF–MOF coassembly strategy as a new method for pore‐space partitioning through the coassembly of [(M 3 (OH) 1− x (O) x (COO) 6 ] MOF‐type and [B 3 O 3 (py) 3 ] COF‐type trimers. With this strategy, the coordination‐driven assembly of the acs framework occurred concurrently and synergistically with the COF‐1‐type condensation of pyridine‐4‐boronic acid into a C 3 ‐symmetric trimeric boroxine molecule. The resulting boroxine‐based pacs materials exhibited dramatically enhanced gas‐sorption properties as compared to nonpartitioned acs ‐type materials and are among the most efficient NH 3 ‐sorption materials.},
doi = {10.1002/ange.201901343},
journal = {Angewandte Chemie},
number = 19,
volume = 131,
place = {Germany},
year = {Tue Apr 02 00:00:00 EDT 2019},
month = {Tue Apr 02 00:00:00 EDT 2019}
}
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