2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction
Abstract
Covalent organic framework (COF) represents an emerging class of porous materials that have exhibited great potential in various applications, particularly in catalysis. Here, we report a newly designed 2D COF with incorporated Re complex, which exhibits intrinsic light absorption and charge separation (CS) properties. We show that this hybrid catalyst can efficiently reduce CO2 to form CO under visible light illumination with high electivity (98%) and better activity than its homogeneous Re counterpart. Moreover, using advanced transient optical and X-ray absorption spectroscopy and in situ diffuse reflectance spectroscopy, we unraveled three key intermediates that are responsible for CS, the induction period, and rate limiting step in catalysis. This work not only demonstrates the potential of COFs as next generation photocatalysts for solar fuel conversion but also provide unprecedented insight into the mechanistic origins for light-driven CO2 reduction.
- Authors:
-
- Marquette Univ., Milwaukee, WI (United States)
- Univ.of Nebraska−Lincoln, Lincoln, NE (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Univ. of Wisconsin−Madison, Madison, WI (United States)
- Univ.of Nebraska−Lincoln, Lincoln, NE (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
- OSTI Identifier:
- 1504460
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 140; Journal Issue: 44; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yang, Sizhuo, Hu, Wenhui, Zhang, Xin, He, Peilei, Pattengale, Brian, Liu, Cunming, Cendejas, Melissa, Hermans, Ive, Zhang, Xiaoyi, Zhang, Jian, and Huang, Jier. 2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction. United States: N. p., 2018.
Web. doi:10.1021/jacs.8b09705.
Yang, Sizhuo, Hu, Wenhui, Zhang, Xin, He, Peilei, Pattengale, Brian, Liu, Cunming, Cendejas, Melissa, Hermans, Ive, Zhang, Xiaoyi, Zhang, Jian, & Huang, Jier. 2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction. United States. https://doi.org/10.1021/jacs.8b09705
Yang, Sizhuo, Hu, Wenhui, Zhang, Xin, He, Peilei, Pattengale, Brian, Liu, Cunming, Cendejas, Melissa, Hermans, Ive, Zhang, Xiaoyi, Zhang, Jian, and Huang, Jier. Wed .
"2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction". United States. https://doi.org/10.1021/jacs.8b09705. https://www.osti.gov/servlets/purl/1504460.
@article{osti_1504460,
title = {2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction},
author = {Yang, Sizhuo and Hu, Wenhui and Zhang, Xin and He, Peilei and Pattengale, Brian and Liu, Cunming and Cendejas, Melissa and Hermans, Ive and Zhang, Xiaoyi and Zhang, Jian and Huang, Jier},
abstractNote = {Covalent organic framework (COF) represents an emerging class of porous materials that have exhibited great potential in various applications, particularly in catalysis. Here, we report a newly designed 2D COF with incorporated Re complex, which exhibits intrinsic light absorption and charge separation (CS) properties. We show that this hybrid catalyst can efficiently reduce CO2 to form CO under visible light illumination with high electivity (98%) and better activity than its homogeneous Re counterpart. Moreover, using advanced transient optical and X-ray absorption spectroscopy and in situ diffuse reflectance spectroscopy, we unraveled three key intermediates that are responsible for CS, the induction period, and rate limiting step in catalysis. This work not only demonstrates the potential of COFs as next generation photocatalysts for solar fuel conversion but also provide unprecedented insight into the mechanistic origins for light-driven CO2 reduction.},
doi = {10.1021/jacs.8b09705},
journal = {Journal of the American Chemical Society},
number = 44,
volume = 140,
place = {United States},
year = {Wed Oct 24 00:00:00 EDT 2018},
month = {Wed Oct 24 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders
journal, February 1979
- Inoue, Tooru; Fujishima, Akira; Konishi, Satoshi
- Nature, Vol. 277, Issue 5698
Carbon Dioxide Capture: Prospects for New Materials
journal, July 2010
- D'Alessandro, Deanna M.; Smit, Berend; Long, Jeffrey R.
- Angewandte Chemie International Edition, Vol. 49, Issue 35, p. 6058-6082
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
journal, June 2013
- Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.
- Chemical Reviews, Vol. 113, Issue 8
Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex
journal, September 2013
- Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G.
- Journal of the American Chemical Society, Vol. 135, Issue 38
Selective Solar-Driven Reduction of CO 2 to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell
journal, May 2008
- Barton, Emily E.; Rampulla, David M.; Bocarsly, Andrew B.
- Journal of the American Chemical Society, Vol. 130, Issue 20
Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO
journal, May 2012
- Smieja, J. M.; Benson, E. E.; Kumar, B.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
journal, August 2015
- White, James L.; Baruch, Maor F.; Pander, James E.
- Chemical Reviews, Vol. 115, Issue 23
Cobalt Imidazolate Metal-Organic Frameworks Photosplit CO 2 under Mild Reaction Conditions
journal, December 2013
- Wang, Sibo; Yao, Wangshu; Lin, Jinliang
- Angewandte Chemie International Edition, Vol. 53, Issue 4
Imidazolium Ionic Liquids, Imidazolylidene Heterocyclic Carbenes, and Zeolitic Imidazolate Frameworks for CO 2 Capture and Photochemical Reduction
journal, December 2015
- Wang, Sibo; Wang, Xinchen
- Angewandte Chemie International Edition, Vol. 55, Issue 7
The atom, the molecule, and the covalent organic framework
journal, March 2017
- Diercks, Christian S.; Yaghi, Omar M.
- Science, Vol. 355, Issue 6328
Chemistry of Covalent Organic Frameworks
journal, November 2015
- Waller, Peter J.; Gándara, Felipe; Yaghi, Omar M.
- Accounts of Chemical Research, Vol. 48, Issue 12
Spectrally Switchable Photodetection with Near-Infrared-Absorbing Covalent Organic Frameworks
journal, August 2017
- Bessinger, Derya; Ascherl, Laura; Auras, Florian
- Journal of the American Chemical Society, Vol. 139, Issue 34
Oligothiophene-Bridged Conjugated Covalent Organic Frameworks
journal, June 2017
- Keller, Niklas; Bessinger, Derya; Reuter, Stephan
- Journal of the American Chemical Society, Vol. 139, Issue 24
Highly Emissive Covalent Organic Frameworks
journal, April 2016
- Dalapati, Sasanka; Jin, Enquan; Addicoat, Matthew
- Journal of the American Chemical Society, Vol. 138, Issue 18
Covalent Organic Frameworks with High Charge Carrier Mobility
journal, September 2011
- Wan, Shun; Gándara, Felipe; Asano, Atsushi
- Chemistry of Materials, Vol. 23, Issue 18, p. 4094-4097
A Metal-Free Covalent Organic Polymer for Electrocatalytic Hydrogen Evolution
journal, August 2017
- Patra, Bidhan Chandra; Khilari, Santimoy; Manna, Rabindra Nath
- ACS Catalysis, Vol. 7, Issue 9
Single-crystal x-ray diffraction structures of covalent organic frameworks
journal, July 2018
- Ma, Tianqiong; Kapustin, Eugene A.; Yin, Shawn X.
- Science, Vol. 361, Issue 6397
Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(II)
journal, February 2016
- Ding, San-Yuan; Dong, Ming; Wang, Ya-Wen
- Journal of the American Chemical Society, Vol. 138, Issue 9
Two-dimensional sp 2 carbon–conjugated covalent organic frameworks
journal, August 2017
- Jin, Enquan; Asada, Mizue; Xu, Qing
- Science, Vol. 357, Issue 6352
Covalent organic frameworks: a materials platform for structural and functional designs
journal, September 2016
- Huang, Ning; Wang, Ping; Jiang, Donglin
- Nature Reviews Materials, Vol. 1, Issue 10
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
journal, August 2015
- Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao
- Science, Vol. 349, Issue 6253
A highly efficient covalent organic framework film photocatalyst for selective solar fuel production from CO 2
journal, January 2016
- Yadav, Rajesh K.; Kumar, Abhishek; Park, No-Joong
- Journal of Materials Chemistry A, Vol. 4, Issue 24
A Squaraine-Linked Mesoporous Covalent Organic Framework
journal, February 2013
- Nagai, Atsushi; Chen, Xiong; Feng, Xiao
- Angewandte Chemie International Edition, Vol. 52, Issue 13
Locking Covalent Organic Frameworks with Hydrogen Bonds: General and Remarkable Effects on Crystalline Structure, Physical Properties, and Photochemical Activity
journal, March 2015
- Chen, Xiong; Addicoat, Matthew; Jin, Enquan
- Journal of the American Chemical Society, Vol. 137, Issue 9
H 2 Evolution with Covalent Organic Framework Photocatalysts
journal, January 2018
- Banerjee, Tanmay; Gottschling, Kerstin; Savasci, Gökcen
- ACS Energy Letters, Vol. 3, Issue 2
Single-Site Photocatalytic H 2 Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts
journal, November 2017
- Banerjee, Tanmay; Haase, Frederik; Savasci, Gökcen
- Journal of the American Chemical Society, Vol. 139, Issue 45
Covalent Organic Framework Electrocatalysts for Clean Energy Conversion
journal, November 2017
- Lin, Chun-Yu; Zhang, Detao; Zhao, Zhenghang
- Advanced Materials, Vol. 30, Issue 5
Diacetylene Functionalized Covalent Organic Framework (COF) for Photocatalytic Hydrogen Generation
journal, January 2018
- Pachfule, Pradip; Acharjya, Amitava; Roeser, Jérôme
- Journal of the American Chemical Society, Vol. 140, Issue 4
Oriented Films of Conjugated 2D Covalent Organic Frameworks as Photocathodes for Water Splitting
journal, December 2017
- Sick, Torben; Hufnagel, Alexander G.; Kampmann, Jonathan
- Journal of the American Chemical Society, Vol. 140, Issue 6
Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki–Miyaura Coupling Reaction
journal, December 2011
- Ding, San-Yuan; Gao, Jia; Wang, Qiong
- Journal of the American Chemical Society, Vol. 133, Issue 49
3D Porphyrin-Based Covalent Organic Frameworks
journal, June 2017
- Lin, Guiqing; Ding, Huimin; Chen, Rufan
- Journal of the American Chemical Society, Vol. 139, Issue 25
A hydrazone-based covalent organic framework for photocatalytic hydrogen production
journal, January 2014
- Stegbauer, Linus; Schwinghammer, Katharina; Lotsch, Bettina V.
- Chem. Sci., Vol. 5, Issue 7
High-Crystallinity Covalent Organic Framework with Dual Fluorescence Emissions and Its Ratiometric Sensing Application
journal, July 2017
- Qian, Hai-Long; Dai, Cong; Yang, Cheng-Xiong
- ACS Applied Materials & Interfaces, Vol. 9, Issue 29
The influence of π-conjugation on competitive pathways: charge transfer or electron transfer in new D–π–A and D–π–Si–π–A dyads
journal, January 2016
- Cho, Yang-Jin; Lee, Ah-Rang; Kim, So-Yoen
- Physical Chemistry Chemical Physics, Vol. 18, Issue 33
Tetrathiafulvalene-1,3,5-triazines as (Multi)Donor–Acceptor Systems with Tunable Charge Transfer: Structural, Photophysical, and Theoretical Investigations
journal, April 2013
- Pop, Flavia; Riobé, François; Seifert, Sabine
- Inorganic Chemistry, Vol. 52, Issue 9
Re(bipy-tBu)(CO) 3 Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies
journal, October 2010
- Smieja, Jonathan M.; Kubiak, Clifford P.
- Inorganic Chemistry, Vol. 49, Issue 20
Involvement of a Binuclear Species with the Re−C(O)O−Re Moiety in CO 2 Reduction Catalyzed by Tricarbonyl Rhenium(I) Complexes with Diimine Ligands: Strikingly Slow Formation of the Re−Re and Re−C(O)O−Re Species from Re(dmb)(CO) 3 S (dmb = 4,4‘-Dimethyl-2,2‘-bipyridine, S = Solvent)
journal, October 2003
- Hayashi, Yukiko; Kita, Shouichi; Brunschwig, Bruce S.
- Journal of the American Chemical Society, Vol. 125, Issue 39
Electrochemical Reduction of CO 2 Catalyzed by Re(pyridine-oxazoline)(CO) 3 Cl Complexes
journal, March 2017
- Nganga, John K.; Samanamu, Christian R.; Tanski, Joseph M.
- Inorganic Chemistry, Vol. 56, Issue 6
Well-Defined Nanographene–Rhenium Complex as an Efficient Electrocatalyst and Photocatalyst for Selective CO 2 Reduction
journal, March 2017
- Qiao, Xiaoxiao; Li, Qiqi; Schaugaard, Richard N.
- Journal of the American Chemical Society, Vol. 139, Issue 11
Optical limiting properties and ultrafast dynamics of six-branched styryl derivatives based on 1,3,5-triazine
journal, August 2011
- Wang, Yaochuan; Jiang, Yihua; Hua, Jianli
- Journal of Applied Physics, Vol. 110, Issue 3
Probing ultrafast excited state dynamics and nonlinear absorption properties of three star-shaped conjugated oligomers with 1,3,5-triazine core
journal, January 2014
- Wang, Yaochuan; Yin, Shuhui; Liu, Jianyong
- RSC Advances, Vol. 4, Issue 21
Ultrafast Excited-State Dynamics of Cytosine Aza-Derivative and Analogues
journal, March 2017
- Zhou, Zhongneng; Zhou, Xueyao; Wang, Xueli
- The Journal of Physical Chemistry A, Vol. 121, Issue 14
Re and Br X-ray Absorption Near-Edge Structure Study of the Ground and Excited States of [ReBr(CO) 3 (bpy)] Interpreted by DFT and TD-DFT Calculations
journal, April 2013
- Záliš, Stanislav; Milne, Chris J.; El Nahhas, Amal
- Inorganic Chemistry, Vol. 52, Issue 10
X-ray Absorption Spectroscopy of Ground and Excited Rhenium–Carbonyl–Diimine Complexes: Evidence for a Two-Center Electron Transfer
journal, January 2013
- El Nahhas, A.; van der Veen, R. M.; Penfold, T. J.
- The Journal of Physical Chemistry A, Vol. 117, Issue 2
Plasmon-Enhanced Photocatalytic CO 2 Conversion within Metal–Organic Frameworks under Visible Light
journal, December 2016
- Choi, Kyung Min; Kim, Dohyung; Rungtaweevoranit, Bunyarat
- Journal of the American Chemical Society, Vol. 139, Issue 1
Time-Resolved IR Spectroscopy Reveals a Mechanism with TiO 2 as a Reversible Electron Acceptor in a TiO 2 –Re Catalyst System for CO 2 Photoreduction
journal, January 2017
- Abdellah, Mohamed; El-Zohry, Ahmed M.; Antila, Liisa J.
- Journal of the American Chemical Society, Vol. 139, Issue 3
Works referencing / citing this record:
A Covalent Triazine‐Based Framework Consisting of Donor–Acceptor Dyads for Visible‐Light‐Driven Photocatalytic CO 2 Reduction
journal, September 2019
- Zhong, Hong; Hong, Zixiao; Yang, Can
- ChemSusChem, Vol. 12, Issue 19
Dynamic covalent chemistry steers synchronizing nanoparticle self-assembly with interfacial polymerization
journal, October 2019
- Zhang, Fenghua; Yang, Zhijie; Hao, Jinjie
- Communications Chemistry, Vol. 2, Issue 1
Postsynthetic functionalization of covalent organic frameworks
journal, August 2019
- Yusran, Yusran; Guan, Xinyu; Li, Hui
- National Science Review, Vol. 7, Issue 1
A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials
journal, February 2020
- Leith, Gabrielle A.; Rice, Allison M.; Yarbrough, Brandon J.
- Angewandte Chemie International Edition, Vol. 59, Issue 15
Covalent Organic Frameworks: Chemical Approaches to Designer Structures and Built‐In Functions
journal, March 2020
- Chen, Xinyi; Geng, Keyu; Liu, Ruoyang
- Angewandte Chemie International Edition, Vol. 59, Issue 13
A facilely synthesized glutathione-functionalized silver nanoparticle-grafted covalent organic framework for rapid and highly efficient enrichment of N-linked glycopeptides
journal, January 2019
- Ma, Yu-Fang; Wang, Li-Juan; Zhou, Ying-Lin
- Nanoscale, Vol. 11, Issue 12
All-inorganic perovskite/graphitic carbon nitride composites for CO 2 photoreduction into C1 compounds under low concentrations of CO 2
journal, January 2019
- You, Siqi; Guo, Shaohong; Zhao, Xue
- Dalton Transactions, Vol. 48, Issue 37
Hot π‐Electron Tunneling of Metal–Insulator–COF Nanostructures for Efficient Hydrogen Production
journal, November 2019
- Ming, Jintao; Liu, Ai; Zhao, Jiwu
- Angewandte Chemie, Vol. 131, Issue 50
Facile fabrication of triphenylamine-based conjugated porous polymers and their application in organic degradation under visible light
journal, January 2020
- Lan, Lidan; Liu, Fei; Dan, Yi
- New Journal of Chemistry, Vol. 44, Issue 7
Stable Covalent Organic Frameworks for Photochemical Applications
journal, June 2019
- Guo, Liping; Jin, Shangbin
- ChemPhotoChem, Vol. 3, Issue 10
Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO 2 Photoreduction with H 2 O
journal, September 2019
- Lu, Meng; Liu, Jiang; Li, Qiang
- Angewandte Chemie International Edition, Vol. 58, Issue 36
Bismuth‐Based Photocatalysts for Solar Photocatalytic Carbon Dioxide Conversion
journal, July 2019
- Ye, Liqun; Deng, Yu; Wang, Li
- ChemSusChem, Vol. 12, Issue 16
Toward ideal carbon dioxide functionalization
journal, January 2019
- Yang, Yang; Lee, Ji-Woong
- Chemical Science, Vol. 10, Issue 14
Donor–acceptor covalent organic frameworks for visible light induced free radical polymerization
journal, January 2019
- Pachfule, Pradip; Acharjya, Amitava; Roeser, Jérôme
- Chemical Science, Vol. 10, Issue 36
Tailored covalent organic frameworks by post-synthetic modification
journal, January 2020
- Ding, Huimin; Mal, Arindam; Wang, Cheng
- Materials Chemistry Frontiers, Vol. 4, Issue 1
Single vs double atom catalyst for N 2 activation in nitrogen reduction reaction: A DFT perspective
journal, January 2020
- Qian, Yumin; Liu, Yuanyue; Zhao, Yu
- EcoMat, Vol. 2, Issue 1
Conjugated polymers for visible-light-driven photocatalysis
journal, January 2020
- Dai, Chunhui; Liu, Bin
- Energy & Environmental Science, Vol. 13, Issue 1
Hot π‐Electron Tunneling of Metal–Insulator–COF Nanostructures for Efficient Hydrogen Production
journal, December 2019
- Ming, Jintao; Liu, Ai; Zhao, Jiwu
- Angewandte Chemie International Edition, Vol. 58, Issue 50
Molecular Porous Photosystems Tailored for Long‐Term Photocatalytic CO 2 Reduction
journal, March 2020
- Wisser, Florian M.; Duguet, Mathis; Perrinet, Quentin
- Angewandte Chemie International Edition, Vol. 59, Issue 13
Triphenylamine based conjugated microporous polymers for selective photoreduction of CO 2 to CO under visible light
journal, January 2019
- Dai, Chunhui; Zhong, Lixiang; Gong, Xuezhong
- Green Chemistry, Vol. 21, Issue 24
Kovalente organische Gerüstverbindungen: chemische Ansätze für Designerstrukturen und integrierte Funktionen
journal, December 2019
- Chen, Xinyi; Geng, Keyu; Liu, Ruoyang
- Angewandte Chemie, Vol. 132, Issue 13
An overview of photocatalysis facilitated by 2D heterojunctions
journal, September 2019
- Su, Tongming; Qin, Zuzeng; Ji, Hongbing
- Nanotechnology, Vol. 30, Issue 50
Ultrathin Two‐Dimensional Semiconductors for Photocatalysis in Energy and Environment Applications
journal, October 2019
- Hu, Sujuan; Zhu, Mingshan
- ChemCatChem, Vol. 11, Issue 24
Covalent‐Organic‐Framework‐Based Li–CO 2 Batteries
journal, October 2019
- Li, Xing; Wang, Hui; Chen, Zhongxin
- Advanced Materials, Vol. 31, Issue 48
Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO 2 Photoreduction with H 2 O
journal, July 2019
- Lu, Meng; Liu, Jiang; Li, Qiang
- Angewandte Chemie, Vol. 131, Issue 36
Covalent Organic Frameworks: A Sustainable Photocatalyst toward Visible‐Light‐Accelerated C3 Arylation and Alkylation of Quinoxalin‐2(1 H )‐Ones
journal, November 2019
- Tian, Miao; Liu, Shuyang; Bu, Xiubin
- Chemistry – A European Journal, Vol. 26, Issue 2
Photothermally assisted photocatalytic conversion of CO 2 –H 2 O into fuels over a WN–WO 3 Z-scheme heterostructure
journal, January 2020
- Liu, Dali; Xu, You; Sun, Mengyao
- Journal of Materials Chemistry A, Vol. 8, Issue 3
Imidazolium‐Salt‐Functionalized Covalent Organic Frameworks for Highly Efficient Catalysis of CO 2 Conversion
journal, May 2019
- Qiu, Jikuan; Zhao, Yuling; Li, Zhiyong
- ChemSusChem
Molecular Porous Photosystems Tailored for Long‐Term Photocatalytic CO 2 Reduction
journal, February 2020
- Wisser, Florian M.; Duguet, Mathis; Perrinet, Quentin
- Angewandte Chemie, Vol. 132, Issue 13
A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials
journal, February 2020
- Leith, Gabrielle A.; Rice, Allison M.; Yarbrough, Brandon J.
- Angewandte Chemie, Vol. 132, Issue 15
Covalent Organic Frameworks: A Sustainable Photocatalyst toward Visible‐Light‐Accelerated C3 Arylation and Alkylation of Quinoxalin‐2(1 H )‐ones
journal, November 2019
- Tian, Miao; Liu, Shuyang; Bu, Xiubin
- Chemistry – A European Journal, Vol. 26, Issue 2
Donor-acceptor covalent organic frameworks for visible light induced free radical polymerization
other, January 2019
- Pachfule, Pradip; Acharjya, Amitava; Roeser, Jérôme
- Cambridge : RSC
Figures / Tables found in this record: