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Title: 2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction

Abstract

Covalent organic framework (COF) represents an emerging class of porous materials that have exhibited great potential in various applications, particularly in catalysis. Here, we report a newly designed 2D COF with incorporated Re complex, which exhibits intrinsic light absorption and charge separation (CS) properties. We show that this hybrid catalyst can efficiently reduce CO2 to form CO under visible light illumination with high electivity (98%) and better activity than its homogeneous Re counterpart. Moreover, using advanced transient optical and X-ray absorption spectroscopy and in situ diffuse reflectance spectroscopy, we unraveled three key intermediates that are responsible for CS, the induction period, and rate limiting step in catalysis. This work not only demonstrates the potential of COFs as next generation photocatalysts for solar fuel conversion but also provide unprecedented insight into the mechanistic origins for light-driven CO2 reduction.

Authors:
 [1];  [1];  [2];  [1]; ORCiD logo [1];  [3];  [4]; ORCiD logo [4]; ORCiD logo [3]; ORCiD logo [5]; ORCiD logo [1]
+ Show Author Affiliations
  1. Marquette Univ., Milwaukee, WI (United States)
  2. Univ.of Nebraska−Lincoln, Lincoln, NE (United States)
  3. Argonne National Lab. (ANL), Lemont, IL (United States)
  4. Univ. of Wisconsin−Madison, Madison, WI (United States)
  5. Univ.of Nebraska−Lincoln, Lincoln, NE (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
OSTI Identifier:
1504460
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 140; Journal Issue: 44; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Yang, Sizhuo, Hu, Wenhui, Zhang, Xin, He, Peilei, Pattengale, Brian, Liu, Cunming, Cendejas, Melissa, Hermans, Ive, Zhang, Xiaoyi, Zhang, Jian, and Huang, Jier. 2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction. United States: N. p., 2018. Web. doi:10.1021/jacs.8b09705.
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Yang, Sizhuo, Hu, Wenhui, Zhang, Xin, He, Peilei, Pattengale, Brian, Liu, Cunming, Cendejas, Melissa, Hermans, Ive, Zhang, Xiaoyi, Zhang, Jian, & Huang, Jier. 2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction. United States. https://doi.org/10.1021/jacs.8b09705
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Yang, Sizhuo, Hu, Wenhui, Zhang, Xin, He, Peilei, Pattengale, Brian, Liu, Cunming, Cendejas, Melissa, Hermans, Ive, Zhang, Xiaoyi, Zhang, Jian, and Huang, Jier. Wed . "2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction". United States. https://doi.org/10.1021/jacs.8b09705. https://www.osti.gov/servlets/purl/1504460.
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@article{osti_1504460,
title = {2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction},
author = {Yang, Sizhuo and Hu, Wenhui and Zhang, Xin and He, Peilei and Pattengale, Brian and Liu, Cunming and Cendejas, Melissa and Hermans, Ive and Zhang, Xiaoyi and Zhang, Jian and Huang, Jier},
abstractNote = {Covalent organic framework (COF) represents an emerging class of porous materials that have exhibited great potential in various applications, particularly in catalysis. Here, we report a newly designed 2D COF with incorporated Re complex, which exhibits intrinsic light absorption and charge separation (CS) properties. We show that this hybrid catalyst can efficiently reduce CO2 to form CO under visible light illumination with high electivity (98%) and better activity than its homogeneous Re counterpart. Moreover, using advanced transient optical and X-ray absorption spectroscopy and in situ diffuse reflectance spectroscopy, we unraveled three key intermediates that are responsible for CS, the induction period, and rate limiting step in catalysis. This work not only demonstrates the potential of COFs as next generation photocatalysts for solar fuel conversion but also provide unprecedented insight into the mechanistic origins for light-driven CO2 reduction.},
doi = {10.1021/jacs.8b09705},
journal = {Journal of the American Chemical Society},
number = 44,
volume = 140,
place = {United States},
year = {2018},
month = {10}
}
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https://doi.org/10.1021/jacs.8b09705
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Figures / Tables:

Figure 2 Figure 2: Transient optical spectra of COF (a) and Re-COF (c) following 530 nm excitation. (b) The comparison of kinetics for ICT of COF and Re-COF. (d) The XANES spectrum of Re-COF at Re L3-edge. The bottom panel is the difference spectrum after subtracting the laser-off spectrum from laser-on spectrummore » collected at 150 ps delay time.« less
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Works referenced in this record:

Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders
journal, February 1979

  • Inoue, Tooru; Fujishima, Akira; Konishi, Satoshi
  • Nature, Vol. 277, Issue 5698
  • DOI: 10.1038/277637a0

Carbon Dioxide Capture: Prospects for New Materials
journal, July 2010

  • D'Alessandro, Deanna M.; Smit, Berend; Long, Jeffrey R.
  • Angewandte Chemie International Edition, Vol. 49, Issue 35, p. 6058-6082
  • DOI: 10.1002/anie.201000431

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
journal, June 2013

  • Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.
  • Chemical Reviews, Vol. 113, Issue 8
  • DOI: 10.1021/cr300463y

Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex
journal, September 2013

  • Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G.
  • Journal of the American Chemical Society, Vol. 135, Issue 38
  • DOI: 10.1021/ja4074003

Selective Solar-Driven Reduction of CO 2 to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell
journal, May 2008

  • Barton, Emily E.; Rampulla, David M.; Bocarsly, Andrew B.
  • Journal of the American Chemical Society, Vol. 130, Issue 20
  • DOI: 10.1021/ja0776327

Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO
journal, May 2012

  • Smieja, J. M.; Benson, E. E.; Kumar, B.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
  • DOI: 10.1073/pnas.1119863109

Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
journal, August 2015

Cobalt Imidazolate Metal-Organic Frameworks Photosplit CO 2 under Mild Reaction Conditions
journal, December 2013

  • Wang, Sibo; Yao, Wangshu; Lin, Jinliang
  • Angewandte Chemie International Edition, Vol. 53, Issue 4
  • DOI: 10.1002/anie.201309426

Imidazolium Ionic Liquids, Imidazolylidene Heterocyclic Carbenes, and Zeolitic Imidazolate Frameworks for CO 2 Capture and Photochemical Reduction
journal, December 2015

  • Wang, Sibo; Wang, Xinchen
  • Angewandte Chemie International Edition, Vol. 55, Issue 7
  • DOI: 10.1002/anie.201507145

The atom, the molecule, and the covalent organic framework
journal, March 2017

Chemistry of Covalent Organic Frameworks
journal, November 2015

Spectrally Switchable Photodetection with Near-Infrared-Absorbing Covalent Organic Frameworks
journal, August 2017

  • Bessinger, Derya; Ascherl, Laura; Auras, Florian
  • Journal of the American Chemical Society, Vol. 139, Issue 34
  • DOI: 10.1021/jacs.7b06599

Oligothiophene-Bridged Conjugated Covalent Organic Frameworks
journal, June 2017

  • Keller, Niklas; Bessinger, Derya; Reuter, Stephan
  • Journal of the American Chemical Society, Vol. 139, Issue 24
  • DOI: 10.1021/jacs.7b01631

Highly Emissive Covalent Organic Frameworks
journal, April 2016

  • Dalapati, Sasanka; Jin, Enquan; Addicoat, Matthew
  • Journal of the American Chemical Society, Vol. 138, Issue 18
  • DOI: 10.1021/jacs.6b02700

Covalent Organic Frameworks with High Charge Carrier Mobility
journal, September 2011

  • Wan, Shun; Gándara, Felipe; Asano, Atsushi
  • Chemistry of Materials, Vol. 23, Issue 18, p. 4094-4097
  • DOI: 10.1021/cm201140r

A Metal-Free Covalent Organic Polymer for Electrocatalytic Hydrogen Evolution
journal, August 2017

  • Patra, Bidhan Chandra; Khilari, Santimoy; Manna, Rabindra Nath
  • ACS Catalysis, Vol. 7, Issue 9
  • DOI: 10.1021/acscatal.7b01067

Single-crystal x-ray diffraction structures of covalent organic frameworks
journal, July 2018

Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(II)
journal, February 2016

  • Ding, San-Yuan; Dong, Ming; Wang, Ya-Wen
  • Journal of the American Chemical Society, Vol. 138, Issue 9
  • DOI: 10.1021/jacs.5b10754

Two-dimensional sp 2 carbon–conjugated covalent organic frameworks
journal, August 2017

Covalent organic frameworks: a materials platform for structural and functional designs
journal, September 2016

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
journal, August 2015

A highly efficient covalent organic framework film photocatalyst for selective solar fuel production from CO 2
journal, January 2016

  • Yadav, Rajesh K.; Kumar, Abhishek; Park, No-Joong
  • Journal of Materials Chemistry A, Vol. 4, Issue 24
  • DOI: 10.1039/C6TA01625A

A Squaraine-Linked Mesoporous Covalent Organic Framework
journal, February 2013

  • Nagai, Atsushi; Chen, Xiong; Feng, Xiao
  • Angewandte Chemie International Edition, Vol. 52, Issue 13
  • DOI: 10.1002/anie.201300256

Locking Covalent Organic Frameworks with Hydrogen Bonds: General and Remarkable Effects on Crystalline Structure, Physical Properties, and Photochemical Activity
journal, March 2015

  • Chen, Xiong; Addicoat, Matthew; Jin, Enquan
  • Journal of the American Chemical Society, Vol. 137, Issue 9
  • DOI: 10.1021/ja509602c

H 2 Evolution with Covalent Organic Framework Photocatalysts
journal, January 2018

Single-Site Photocatalytic H 2 Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts
journal, November 2017

  • Banerjee, Tanmay; Haase, Frederik; Savasci, Gökcen
  • Journal of the American Chemical Society, Vol. 139, Issue 45
  • DOI: 10.1021/jacs.7b07489

Covalent Organic Framework Electrocatalysts for Clean Energy Conversion
journal, November 2017

  • Lin, Chun-Yu; Zhang, Detao; Zhao, Zhenghang
  • Advanced Materials, Vol. 30, Issue 5
  • DOI: 10.1002/adma.201703646

Diacetylene Functionalized Covalent Organic Framework (COF) for Photocatalytic Hydrogen Generation
journal, January 2018

  • Pachfule, Pradip; Acharjya, Amitava; Roeser, Jérôme
  • Journal of the American Chemical Society, Vol. 140, Issue 4
  • DOI: 10.1021/jacs.7b11255

Oriented Films of Conjugated 2D Covalent Organic Frameworks as Photocathodes for Water Splitting
journal, December 2017

  • Sick, Torben; Hufnagel, Alexander G.; Kampmann, Jonathan
  • Journal of the American Chemical Society, Vol. 140, Issue 6
  • DOI: 10.1021/jacs.7b06081

Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki–Miyaura Coupling Reaction
journal, December 2011

  • Ding, San-Yuan; Gao, Jia; Wang, Qiong
  • Journal of the American Chemical Society, Vol. 133, Issue 49
  • DOI: 10.1021/ja206846p

3D Porphyrin-Based Covalent Organic Frameworks
journal, June 2017

  • Lin, Guiqing; Ding, Huimin; Chen, Rufan
  • Journal of the American Chemical Society, Vol. 139, Issue 25
  • DOI: 10.1021/jacs.7b04141

A hydrazone-based covalent organic framework for photocatalytic hydrogen production
journal, January 2014

  • Stegbauer, Linus; Schwinghammer, Katharina; Lotsch, Bettina V.
  • Chem. Sci., Vol. 5, Issue 7
  • DOI: 10.1039/C4SC00016A

High-Crystallinity Covalent Organic Framework with Dual Fluorescence Emissions and Its Ratiometric Sensing Application
journal, July 2017

  • Qian, Hai-Long; Dai, Cong; Yang, Cheng-Xiong
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 29
  • DOI: 10.1021/acsami.7b08060

The influence of π-conjugation on competitive pathways: charge transfer or electron transfer in new D–π–A and D–π–Si–π–A dyads
journal, January 2016

  • Cho, Yang-Jin; Lee, Ah-Rang; Kim, So-Yoen
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 33
  • DOI: 10.1039/C6CP03259A

Re(bipy-tBu)(CO) 3 Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies
journal, October 2010

  • Smieja, Jonathan M.; Kubiak, Clifford P.
  • Inorganic Chemistry, Vol. 49, Issue 20
  • DOI: 10.1021/ic1008363

Electrochemical Reduction of CO 2 Catalyzed by Re(pyridine-oxazoline)(CO) 3 Cl Complexes
journal, March 2017

Well-Defined Nanographene–Rhenium Complex as an Efficient Electrocatalyst and Photocatalyst for Selective CO 2 Reduction
journal, March 2017

  • Qiao, Xiaoxiao; Li, Qiqi; Schaugaard, Richard N.
  • Journal of the American Chemical Society, Vol. 139, Issue 11
  • DOI: 10.1021/jacs.6b12530

Optical limiting properties and ultrafast dynamics of six-branched styryl derivatives based on 1,3,5-triazine
journal, August 2011

  • Wang, Yaochuan; Jiang, Yihua; Hua, Jianli
  • Journal of Applied Physics, Vol. 110, Issue 3
  • DOI: 10.1063/1.3619796

Ultrafast Excited-State Dynamics of Cytosine Aza-Derivative and Analogues
journal, March 2017

  • Zhou, Zhongneng; Zhou, Xueyao; Wang, Xueli
  • The Journal of Physical Chemistry A, Vol. 121, Issue 14
  • DOI: 10.1021/acs.jpca.6b12290

Re and Br X-ray Absorption Near-Edge Structure Study of the Ground and Excited States of [ReBr(CO) 3 (bpy)] Interpreted by DFT and TD-DFT Calculations
journal, April 2013

  • Záliš, Stanislav; Milne, Chris J.; El Nahhas, Amal
  • Inorganic Chemistry, Vol. 52, Issue 10
  • DOI: 10.1021/ic3025843

X-ray Absorption Spectroscopy of Ground and Excited Rhenium–Carbonyl–Diimine Complexes: Evidence for a Two-Center Electron Transfer
journal, January 2013

  • El Nahhas, A.; van der Veen, R. M.; Penfold, T. J.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 2
  • DOI: 10.1021/jp3106502

Plasmon-Enhanced Photocatalytic CO 2 Conversion within Metal–Organic Frameworks under Visible Light
journal, December 2016

  • Choi, Kyung Min; Kim, Dohyung; Rungtaweevoranit, Bunyarat
  • Journal of the American Chemical Society, Vol. 139, Issue 1
  • DOI: 10.1021/jacs.6b11027

Time-Resolved IR Spectroscopy Reveals a Mechanism with TiO 2 as a Reversible Electron Acceptor in a TiO 2 –Re Catalyst System for CO 2 Photoreduction
journal, January 2017

  • Abdellah, Mohamed; El-Zohry, Ahmed M.; Antila, Liisa J.
  • Journal of the American Chemical Society, Vol. 139, Issue 3
  • DOI: 10.1021/jacs.6b11308
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    journal, January 2020

    • Sharma, Rakesh Kumar; Yadav, Priya; Yadav, Manavi
    • Materials Horizons, Vol. 7, Issue 2
    • DOI: 10.1039/c9mh00856j

    Rational synthesis of interpenetrated 3D covalent organic frameworks for asymmetric photocatalysis
    journal, January 2020

    • Kang, Xing; Wu, Xiaowei; Han, Xing
    • Chemical Science, Vol. 11, Issue 6
    • DOI: 10.1039/c9sc04882k

    Dynamic covalent chemistry steers synchronizing nanoparticle self-assembly with interfacial polymerization
    journal, October 2019

    Postsynthetic functionalization of covalent organic frameworks
    journal, August 2019

    • Yusran, Yusran; Guan, Xinyu; Li, Hui
    • National Science Review, Vol. 7, Issue 1
    • DOI: 10.1093/nsr/nwz122

    A stable covalent organic framework for photocatalytic carbon dioxide reduction
    journal, January 2020

    • Fu, Zhiwei; Wang, Xiaoyan; Gardner, Adrian M.
    • Chemical Science, Vol. 11, Issue 2
    • DOI: 10.1039/c9sc03800k

    A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials
    journal, February 2020

    • Leith, Gabrielle A.; Rice, Allison M.; Yarbrough, Brandon J.
    • Angewandte Chemie International Edition, Vol. 59, Issue 15
    • DOI: 10.1002/anie.201914233

    Covalent Organic Frameworks: Chemical Approaches to Designer Structures and Built‐In Functions
    journal, March 2020

    • Chen, Xinyi; Geng, Keyu; Liu, Ruoyang
    • Angewandte Chemie International Edition, Vol. 59, Issue 13
    • DOI: 10.1002/anie.201904291

    All-inorganic perovskite/graphitic carbon nitride composites for CO 2 photoreduction into C1 compounds under low concentrations of CO 2
    journal, January 2019

    • You, Siqi; Guo, Shaohong; Zhao, Xue
    • Dalton Transactions, Vol. 48, Issue 37
    • DOI: 10.1039/c9dt02468a

    Hot π‐Electron Tunneling of Metal–Insulator–COF Nanostructures for Efficient Hydrogen Production
    journal, November 2019

    Facile fabrication of triphenylamine-based conjugated porous polymers and their application in organic degradation under visible light
    journal, January 2020

    • Lan, Lidan; Liu, Fei; Dan, Yi
    • New Journal of Chemistry, Vol. 44, Issue 7
    • DOI: 10.1039/c9nj05500b

    Stable Covalent Organic Frameworks for Photochemical Applications
    journal, June 2019

    Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO 2 Photoreduction with H 2 O
    journal, September 2019

    • Lu, Meng; Liu, Jiang; Li, Qiang
    • Angewandte Chemie International Edition, Vol. 58, Issue 36
    • DOI: 10.1002/anie.201906890

    Bismuth‐Based Photocatalysts for Solar Photocatalytic Carbon Dioxide Conversion
    journal, July 2019

    Post-synthetic modification of covalent organic frameworks
    journal, January 2019

    • Segura, José L.; Royuela, Sergio; Mar Ramos, M.
    • Chemical Society Reviews, Vol. 48, Issue 14
    • DOI: 10.1039/c8cs00978c

    Toward ideal carbon dioxide functionalization
    journal, January 2019

    Donor–acceptor covalent organic frameworks for visible light induced free radical polymerization
    journal, January 2019

    • Pachfule, Pradip; Acharjya, Amitava; Roeser, Jérôme
    • Chemical Science, Vol. 10, Issue 36
    • DOI: 10.1039/c9sc02601k

    Tailored covalent organic frameworks by post-synthetic modification
    journal, January 2020

    • Ding, Huimin; Mal, Arindam; Wang, Cheng
    • Materials Chemistry Frontiers, Vol. 4, Issue 1
    • DOI: 10.1039/c9qm00555b

    Single vs double atom catalyst for N 2 activation in nitrogen reduction reaction: A DFT perspective
    journal, January 2020

    Conjugated polymers for visible-light-driven photocatalysis
    journal, January 2020

    • Dai, Chunhui; Liu, Bin
    • Energy & Environmental Science, Vol. 13, Issue 1
    • DOI: 10.1039/c9ee01935a

    Hot π‐Electron Tunneling of Metal–Insulator–COF Nanostructures for Efficient Hydrogen Production
    journal, December 2019

    • Ming, Jintao; Liu, Ai; Zhao, Jiwu
    • Angewandte Chemie International Edition, Vol. 58, Issue 50
    • DOI: 10.1002/anie.201912344

    Molecular Porous Photosystems Tailored for Long‐Term Photocatalytic CO 2 Reduction
    journal, March 2020

    • Wisser, Florian M.; Duguet, Mathis; Perrinet, Quentin
    • Angewandte Chemie International Edition, Vol. 59, Issue 13
    • DOI: 10.1002/anie.201912883

    Triphenylamine based conjugated microporous polymers for selective photoreduction of CO 2 to CO under visible light
    journal, January 2019

    • Dai, Chunhui; Zhong, Lixiang; Gong, Xuezhong
    • Green Chemistry, Vol. 21, Issue 24
    • DOI: 10.1039/c9gc03131f

    Kovalente organische Gerüstverbindungen: chemische Ansätze für Designerstrukturen und integrierte Funktionen
    journal, December 2019

    An overview of photocatalysis facilitated by 2D heterojunctions
    journal, September 2019

    Ultrathin Two‐Dimensional Semiconductors for Photocatalysis in Energy and Environment Applications
    journal, October 2019

    Covalent‐Organic‐Framework‐Based Li–CO 2 Batteries
    journal, October 2019

    Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO 2 Photoreduction with H 2 O
    journal, July 2019

    Covalent Organic Frameworks: A Sustainable Photocatalyst toward Visible‐Light‐Accelerated C3 Arylation and Alkylation of Quinoxalin‐2(1 H )‐Ones
    journal, November 2019

    • Tian, Miao; Liu, Shuyang; Bu, Xiubin
    • Chemistry – A European Journal, Vol. 26, Issue 2
    • DOI: 10.1002/chem.201904860

    Photothermally assisted photocatalytic conversion of CO 2 –H 2 O into fuels over a WN–WO 3 Z-scheme heterostructure
    journal, January 2020

    • Liu, Dali; Xu, You; Sun, Mengyao
    • Journal of Materials Chemistry A, Vol. 8, Issue 3
    • DOI: 10.1039/c9ta10629d

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    other, January 2019

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