2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO 2 Reduction

Yang, Sizhuo; Hu, Wenhui; Zhang, Xin; He, Peilei; Pattengale, Brian; Liu, Cunming; Cendejas, Melissa; Hermans, Ive; Zhang, Xiaoyi; Zhang, Jian; Huang, Jier

doi:10.1021/jacs.8b09705

Title: 2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO ₂ Reduction

Journal Article · 23 October 2018 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.8b09705 · OSTI ID:1504460

Yang, Sizhuo ^[1]; Hu, Wenhui ^[1]; Zhang, Xin ^[2]; He, Peilei ^[1];

^[1]; Liu, Cunming ^[3]; Cendejas, Melissa ^[4];

^[4];

^[3];

^[5];

^[1]

Marquette Univ., Milwaukee, WI (United States)
Univ.of Nebraska−Lincoln, Lincoln, NE (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Univ. of Wisconsin−Madison, Madison, WI (United States)
Univ.of Nebraska−Lincoln, Lincoln, NE (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Covalent organic framework (COF) represents an emerging class of porous materials that have exhibited great potential in various applications, particularly in catalysis. Here, we report a newly designed 2D COF with incorporated Re complex, which exhibits intrinsic light absorption and charge separation (CS) properties. We show that this hybrid catalyst can efficiently reduce CO₂ to form CO under visible light illumination with high electivity (98%) and better activity than its homogeneous Re counterpart. Moreover, using advanced transient optical and X-ray absorption spectroscopy and in situ diffuse reflectance spectroscopy, we unraveled three key intermediates that are responsible for CS, the induction period, and rate limiting step in catalysis. This work not only demonstrates the potential of COFs as next generation photocatalysts for solar fuel conversion but also provide unprecedented insight into the mechanistic origins for light-driven CO₂ reduction.

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Research Organization:: Argonne National Lab. (ANL), Lemont, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1504460

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 44 Vol. 140; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (46)

A hydrazone-based covalent organic framework for photocatalytic hydrogen production Stegbauer, Linus; Schwinghammer, Katharina; Lotsch, Bettina V. Chem. Sci., Vol. 5, Issue 7 https://doi.org/10.1039/C4SC00016A	journal	January 2014
Time-Resolved IR Spectroscopy Reveals a Mechanism with TiO ₂ as a Reversible Electron Acceptor in a TiO ₂ –Re Catalyst System for CO ₂ Photoreduction Abdellah, Mohamed; El-Zohry, Ahmed M.; Antila, Liisa J. Journal of the American Chemical Society, Vol. 139, Issue 3 https://doi.org/10.1021/jacs.6b11308	journal	January 2017
Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO Smieja, J. M.; Benson, E. E.; Kumar, B. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1119863109	journal	May 2012
Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders Inoue, Tooru; Fujishima, Akira; Konishi, Satoshi Nature, Vol. 277, Issue 5698 https://doi.org/10.1038/277637a0	journal	February 1979
Two-dimensional sp ² carbon–conjugated covalent organic frameworks Jin, Enquan; Asada, Mizue; Xu, Qing Science, Vol. 357, Issue 6352 https://doi.org/10.1126/science.aan0202	journal	August 2017
Spectrally Switchable Photodetection with Near-Infrared-Absorbing Covalent Organic Frameworks Bessinger, Derya; Ascherl, Laura; Auras, Florian Journal of the American Chemical Society, Vol. 139, Issue 34 https://doi.org/10.1021/jacs.7b06599	journal	August 2017
Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki–Miyaura Coupling Reaction Ding, San-Yuan; Gao, Jia; Wang, Qiong Journal of the American Chemical Society, Vol. 133, Issue 49 https://doi.org/10.1021/ja206846p	journal	December 2011
Well-Defined Nanographene–Rhenium Complex as an Efficient Electrocatalyst and Photocatalyst for Selective CO ₂ Reduction Qiao, Xiaoxiao; Li, Qiqi; Schaugaard, Richard N. Journal of the American Chemical Society, Vol. 139, Issue 11 https://doi.org/10.1021/jacs.6b12530	journal	March 2017
The influence of π-conjugation on competitive pathways: charge transfer or electron transfer in new D–π–A and D–π–Si–π–A dyads Cho, Yang-Jin; Lee, Ah-Rang; Kim, So-Yoen Physical Chemistry Chemical Physics, Vol. 18, Issue 33 https://doi.org/10.1039/C6CP03259A	journal	January 2016
A Squaraine-Linked Mesoporous Covalent Organic Framework Nagai, Atsushi; Chen, Xiong; Feng, Xiao Angewandte Chemie International Edition, Vol. 52, Issue 13 https://doi.org/10.1002/anie.201300256	journal	February 2013
Plasmon-Enhanced Photocatalytic CO ₂ Conversion within Metal–Organic Frameworks under Visible Light Choi, Kyung Min; Kim, Dohyung; Rungtaweevoranit, Bunyarat Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b11027	journal	December 2016
Involvement of a Binuclear Species with the Re−C(O)O−Re Moiety in CO ₂ Reduction Catalyzed by Tricarbonyl Rhenium(I) Complexes with Diimine Ligands: Strikingly Slow Formation of the Re−Re and Re−C(O)O−Re Species from Re(dmb)(CO) ₃ S (dmb = 4,4‘-Dimethyl-2,2‘-bipyridine, S = Solvent) Hayashi, Yukiko; Kita, Shouichi; Brunschwig, Bruce S. Journal of the American Chemical Society, Vol. 125, Issue 39 https://doi.org/10.1021/ja035960a	journal	October 2003
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO ₂ reduction in water Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao Science, Vol. 349, Issue 6253 https://doi.org/10.1126/science.aac8343	journal	August 2015
Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(II) Ding, San-Yuan; Dong, Ming; Wang, Ya-Wen Journal of the American Chemical Society, Vol. 138, Issue 9 https://doi.org/10.1021/jacs.5b10754	journal	February 2016
Cobalt Imidazolate Metal-Organic Frameworks Photosplit CO ₂ under Mild Reaction Conditions Wang, Sibo; Yao, Wangshu; Lin, Jinliang Angewandte Chemie International Edition, Vol. 53, Issue 4 https://doi.org/10.1002/anie.201309426	journal	December 2013
Locking Covalent Organic Frameworks with Hydrogen Bonds: General and Remarkable Effects on Crystalline Structure, Physical Properties, and Photochemical Activity Chen, Xiong; Addicoat, Matthew; Jin, Enquan Journal of the American Chemical Society, Vol. 137, Issue 9 https://doi.org/10.1021/ja509602c	journal	March 2015
Probing ultrafast excited state dynamics and nonlinear absorption properties of three star-shaped conjugated oligomers with 1,3,5-triazine core Wang, Yaochuan; Yin, Shuhui; Liu, Jianyong RSC Advances, Vol. 4, Issue 21 https://doi.org/10.1039/c3ra45544k	journal	January 2014
Re and Br X-ray Absorption Near-Edge Structure Study of the Ground and Excited States of [ReBr(CO) ₃ (bpy)] Interpreted by DFT and TD-DFT Calculations Záliš, Stanislav; Milne, Chris J.; El Nahhas, Amal Inorganic Chemistry, Vol. 52, Issue 10 https://doi.org/10.1021/ic3025843	journal	April 2013
Single-Site Photocatalytic H ₂ Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts Banerjee, Tanmay; Haase, Frederik; Savasci, Gökcen Journal of the American Chemical Society, Vol. 139, Issue 45 https://doi.org/10.1021/jacs.7b07489	journal	November 2017
H ₂ Evolution with Covalent Organic Framework Photocatalysts Banerjee, Tanmay; Gottschling, Kerstin; Savasci, Gökcen ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01123	journal	January 2018
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO ₂ Fixation Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B. Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300463y	journal	June 2013
Ultrafast Excited-State Dynamics of Cytosine Aza-Derivative and Analogues Zhou, Zhongneng; Zhou, Xueyao; Wang, Xueli The Journal of Physical Chemistry A, Vol. 121, Issue 14 https://doi.org/10.1021/acs.jpca.6b12290	journal	March 2017
A highly efficient covalent organic framework film photocatalyst for selective solar fuel production from CO ₂ Yadav, Rajesh K.; Kumar, Abhishek; Park, No-Joong Journal of Materials Chemistry A, Vol. 4, Issue 24 https://doi.org/10.1039/C6TA01625A	journal	January 2016
X-ray Absorption Spectroscopy of Ground and Excited Rhenium–Carbonyl–Diimine Complexes: Evidence for a Two-Center Electron Transfer El Nahhas, A.; van der Veen, R. M.; Penfold, T. J. The Journal of Physical Chemistry A, Vol. 117, Issue 2 https://doi.org/10.1021/jp3106502	journal	January 2013
Carbon Dioxide Capture: Prospects for New Materials D'Alessandro, Deanna M.; Smit, Berend; Long, Jeffrey R. Angewandte Chemie International Edition, Vol. 49, Issue 35, p. 6058-6082 https://doi.org/10.1002/anie.201000431	journal	July 2010
3D Porphyrin-Based Covalent Organic Frameworks Lin, Guiqing; Ding, Huimin; Chen, Rufan Journal of the American Chemical Society, Vol. 139, Issue 25 https://doi.org/10.1021/jacs.7b04141	journal	June 2017
Highly Emissive Covalent Organic Frameworks Dalapati, Sasanka; Jin, Enquan; Addicoat, Matthew Journal of the American Chemical Society, Vol. 138, Issue 18 https://doi.org/10.1021/jacs.6b02700	journal	April 2016
Covalent organic frameworks: a materials platform for structural and functional designs Huang, Ning; Wang, Ping; Jiang, Donglin Nature Reviews Materials, Vol. 1, Issue 10 https://doi.org/10.1038/natrevmats.2016.68	journal	September 2016
Selective Solar-Driven Reduction of CO ₂ to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell Barton, Emily E.; Rampulla, David M.; Bocarsly, Andrew B. Journal of the American Chemical Society, Vol. 130, Issue 20 https://doi.org/10.1021/ja0776327	journal	May 2008
Imidazolium Ionic Liquids, Imidazolylidene Heterocyclic Carbenes, and Zeolitic Imidazolate Frameworks for CO ₂ Capture and Photochemical Reduction Wang, Sibo; Wang, Xinchen Angewandte Chemie International Edition, Vol. 55, Issue 7 https://doi.org/10.1002/anie.201507145	journal	December 2015
Covalent Organic Frameworks with High Charge Carrier Mobility Wan, Shun; Gándara, Felipe; Asano, Atsushi Chemistry of Materials, Vol. 23, Issue 18, p. 4094-4097 https://doi.org/10.1021/cm201140r	journal	September 2011
Optical limiting properties and ultrafast dynamics of six-branched styryl derivatives based on 1,3,5-triazine Wang, Yaochuan; Jiang, Yihua; Hua, Jianli Journal of Applied Physics, Vol. 110, Issue 3 https://doi.org/10.1063/1.3619796	journal	August 2011
Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G. Journal of the American Chemical Society, Vol. 135, Issue 38 https://doi.org/10.1021/ja4074003	journal	September 2013
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes White, James L.; Baruch, Maor F.; Pander, James E. Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00370	journal	August 2015
A Metal-Free Covalent Organic Polymer for Electrocatalytic Hydrogen Evolution Patra, Bidhan Chandra; Khilari, Santimoy; Manna, Rabindra Nath ACS Catalysis, Vol. 7, Issue 9 https://doi.org/10.1021/acscatal.7b01067	journal	August 2017
Re(bipy-tBu)(CO) ₃ Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies Smieja, Jonathan M.; Kubiak, Clifford P. Inorganic Chemistry, Vol. 49, Issue 20 https://doi.org/10.1021/ic1008363	journal	October 2010
Oligothiophene-Bridged Conjugated Covalent Organic Frameworks Keller, Niklas; Bessinger, Derya; Reuter, Stephan Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b01631	journal	June 2017
Chemistry of Covalent Organic Frameworks Waller, Peter J.; Gándara, Felipe; Yaghi, Omar M. Accounts of Chemical Research, Vol. 48, Issue 12 https://doi.org/10.1021/acs.accounts.5b00369	journal	November 2015
Oriented Films of Conjugated 2D Covalent Organic Frameworks as Photocathodes for Water Splitting Sick, Torben; Hufnagel, Alexander G.; Kampmann, Jonathan Journal of the American Chemical Society, Vol. 140, Issue 6 https://doi.org/10.1021/jacs.7b06081	journal	December 2017
Single-crystal x-ray diffraction structures of covalent organic frameworks Ma, Tianqiong; Kapustin, Eugene A.; Yin, Shawn X. Science, Vol. 361, Issue 6397 https://doi.org/10.1126/science.aat7679	journal	July 2018
Tetrathiafulvalene-1,3,5-triazines as (Multi)Donor–Acceptor Systems with Tunable Charge Transfer: Structural, Photophysical, and Theoretical Investigations Pop, Flavia; Riobé, François; Seifert, Sabine Inorganic Chemistry, Vol. 52, Issue 9 https://doi.org/10.1021/ic3027336	journal	April 2013
Covalent Organic Framework Electrocatalysts for Clean Energy Conversion Lin, Chun-Yu; Zhang, Detao; Zhao, Zhenghang Advanced Materials, Vol. 30, Issue 5 https://doi.org/10.1002/adma.201703646	journal	November 2017
Electrochemical Reduction of CO ₂ Catalyzed by Re(pyridine-oxazoline)(CO) ₃ Cl Complexes Nganga, John K.; Samanamu, Christian R.; Tanski, Joseph M. Inorganic Chemistry, Vol. 56, Issue 6 https://doi.org/10.1021/acs.inorgchem.6b02384	journal	March 2017
Diacetylene Functionalized Covalent Organic Framework (COF) for Photocatalytic Hydrogen Generation Pachfule, Pradip; Acharjya, Amitava; Roeser, Jérôme Journal of the American Chemical Society, Vol. 140, Issue 4 https://doi.org/10.1021/jacs.7b11255	journal	January 2018
High-Crystallinity Covalent Organic Framework with Dual Fluorescence Emissions and Its Ratiometric Sensing Application Qian, Hai-Long; Dai, Cong; Yang, Cheng-Xiong ACS Applied Materials & Interfaces, Vol. 9, Issue 29 https://doi.org/10.1021/acsami.7b08060	journal	July 2017
The atom, the molecule, and the covalent organic framework Diercks, Christian S.; Yaghi, Omar M. Science, Vol. 355, Issue 6328 https://doi.org/10.1126/science.aal1585	journal	March 2017

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A stable covalent organic framework for photocatalytic carbon dioxide reduction Fu, Zhiwei; Wang, Xiaoyan; Gardner, Adrian M. Chemical Science, Vol. 11, Issue 2 https://doi.org/10.1039/c9sc03800k	journal	January 2020
Covalent‐Organic‐Framework‐Based Li–CO ₂ Batteries Li, Xing; Wang, Hui; Chen, Zhongxin Advanced Materials, Vol. 31, Issue 48 https://doi.org/10.1002/adma.201905879	journal	October 2019
Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO ₂ Photoreduction with H ₂ O Lu, Meng; Liu, Jiang; Li, Qiang Angewandte Chemie, Vol. 131, Issue 36 https://doi.org/10.1002/ange.201906890	journal	July 2019
Photothermally assisted photocatalytic conversion of CO ₂ –H ₂ O into fuels over a WN–WO ₃ Z-scheme heterostructure Liu, Dali; Xu, You; Sun, Mengyao Journal of Materials Chemistry A, Vol. 8, Issue 3 https://doi.org/10.1039/c9ta10629d	journal	January 2020
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Title: 2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO ₂ Reduction