Synthesis of modified graphene oxide and its improvement on flame retardancy of epoxy resin
Abstract
ABSTRACT In this work, the small molecule with double‐phosphaphenanthrene structure was successfully grafted on the surface of graphene oxide (GO), which is called functionalized graphene oxide (FGO). The introduction of FGO improved the poor interfacial compatibility between graphene and epoxy matrix. And FGO could be used as the highly effective flame retardant. The thermogravimetric analysis results showed a significant improvement in the char yield of cured FGO/EP. When the content of FGO was 3 wt %, the limiting oxygen index value reached 30.4%. At the same time, the three‐point bending and thermomechanical tests confirmed that the mechanical properties of the epoxy resin composites were improved. Based on the char analyses of SEM images and Raman spectroscopy, the flame retardant could promote the formation of a stable carbon layer. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137 , 47710.
- Authors:
-
[1]
- Fujian Provincial Key Laboratory of Fire Retardant Materials College of Materials, Xiamen University, Xiamen University Xiamen Fujian 361005 People's Republic of China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1498570
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Applied Polymer Science
- Additional Journal Information:
- Journal Name: Journal of Applied Polymer Science Journal Volume: 137 Journal Issue: 1; Journal ID: ISSN 0021-8995
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Wu, Wenqian, Xu, Yiting, Wu, Haiyang, Chen, Jinmei, Li, Min, Chen, Ting, Hong, Jing, and Dai, Lizong. Synthesis of modified graphene oxide and its improvement on flame retardancy of epoxy resin. United States: N. p., 2019.
Web. doi:10.1002/app.47710.
Wu, Wenqian, Xu, Yiting, Wu, Haiyang, Chen, Jinmei, Li, Min, Chen, Ting, Hong, Jing, & Dai, Lizong. Synthesis of modified graphene oxide and its improvement on flame retardancy of epoxy resin. United States. https://doi.org/10.1002/app.47710
Wu, Wenqian, Xu, Yiting, Wu, Haiyang, Chen, Jinmei, Li, Min, Chen, Ting, Hong, Jing, and Dai, Lizong. Thu .
"Synthesis of modified graphene oxide and its improvement on flame retardancy of epoxy resin". United States. https://doi.org/10.1002/app.47710.
@article{osti_1498570,
title = {Synthesis of modified graphene oxide and its improvement on flame retardancy of epoxy resin},
author = {Wu, Wenqian and Xu, Yiting and Wu, Haiyang and Chen, Jinmei and Li, Min and Chen, Ting and Hong, Jing and Dai, Lizong},
abstractNote = {ABSTRACT In this work, the small molecule with double‐phosphaphenanthrene structure was successfully grafted on the surface of graphene oxide (GO), which is called functionalized graphene oxide (FGO). The introduction of FGO improved the poor interfacial compatibility between graphene and epoxy matrix. And FGO could be used as the highly effective flame retardant. The thermogravimetric analysis results showed a significant improvement in the char yield of cured FGO/EP. When the content of FGO was 3 wt %, the limiting oxygen index value reached 30.4%. At the same time, the three‐point bending and thermomechanical tests confirmed that the mechanical properties of the epoxy resin composites were improved. Based on the char analyses of SEM images and Raman spectroscopy, the flame retardant could promote the formation of a stable carbon layer. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137 , 47710.},
doi = {10.1002/app.47710},
journal = {Journal of Applied Polymer Science},
number = 1,
volume = 137,
place = {United States},
year = {Thu Mar 07 00:00:00 EST 2019},
month = {Thu Mar 07 00:00:00 EST 2019}
}
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