Intercalating MnO 2 Nanosheets With Transition Metal Cations to Enhance Oxygen Evolution
Abstract
Abstract The catalytic activity of MnO 2 nanosheets towards oxygen evolution depends highly on their interlayer environment. We present a systematic investigation on fine‐tuning of the interlayer environment of MnO 2 nanosheets by intercalation through a facile cation exchange with inexpensive first‐row transition metal cations, including Ni 2+ , Co 2+ , Cu 2+ , Zn 2+ , and Fe 3+ ions. Among them, the Ni‐intercalated MnO 2 nanosheets show remarkably enhanced OER activity and long‐term stability, compared to pristine MnO 2 nanosheets. The overpotential of 330 mV at a current density of 10 mA cm −2 is observed for the Ni‐intercalated MnO 2 nanosheets. The ehancement mechanism of OER is studied by comparing physiochemical properties, such as the oxidation state of Mn, the interlayer distance, the increase in the disorder/twisting of MnO 6 octahedra, and the interlayer cooperative binding of water molecules. The Ni intercalation, different from other metal cations, strengthens the Mn−O bond perpendicularly to the layer chains to facilitate the interlayer catalysis possibly between two Mn sites, and thus promotes the efficiency of oxygen evolution.
- Authors:
-
[1];
- Nanjing Univ. of Science and Technology (China). Dept. of Chemical Engineering; Univ. of Connecticut, Storrs, CT (United States). Dept. of Chemistry
- Univ. of Connecticut, Storrs, CT (United States). Dept. of Chemistry
- Department of ChemistryUniversity of Connecticut Storrs CT 06269 USA
- Univ. of Connecticut, Storrs, CT (United States). Dept. of Chemistry; Univ. of Connecticut, Storrs, CT (United States). Dept. of Chemistry, Institute of Materials; Univ. of Connecticut, Storrs, CT (United States). Dept. of Chemical and Biomolecular Engineering
- Univ. of Connecticut, Storrs, CT (United States). Dept. of Chemistry, Institute of Materials
- Publication Date:
- Research Org.:
- Univ. of Connecticut, Storrs, CT (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1598186
- Alternate Identifier(s):
- OSTI ID: 1496907
- Grant/Contract Number:
- FG02-86ER13622
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemCatChem
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 6; Journal ID: ISSN 1867-3880
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yang, Yue, Su, Xingsong, Zhang, Lei, Kerns, Peter, Achola, Laura, Hayes, Veronica, Quardokus, Rebecca, Suib, Steven L., and He, Jie. Intercalating MnO 2 Nanosheets With Transition Metal Cations to Enhance Oxygen Evolution. United States: N. p., 2019.
Web. doi:10.1002/cctc.201802019.
Yang, Yue, Su, Xingsong, Zhang, Lei, Kerns, Peter, Achola, Laura, Hayes, Veronica, Quardokus, Rebecca, Suib, Steven L., & He, Jie. Intercalating MnO 2 Nanosheets With Transition Metal Cations to Enhance Oxygen Evolution. United States. https://doi.org/10.1002/cctc.201802019
Yang, Yue, Su, Xingsong, Zhang, Lei, Kerns, Peter, Achola, Laura, Hayes, Veronica, Quardokus, Rebecca, Suib, Steven L., and He, Jie. Mon .
"Intercalating MnO 2 Nanosheets With Transition Metal Cations to Enhance Oxygen Evolution". United States. https://doi.org/10.1002/cctc.201802019. https://www.osti.gov/servlets/purl/1598186.
@article{osti_1598186,
title = {Intercalating MnO 2 Nanosheets With Transition Metal Cations to Enhance Oxygen Evolution},
author = {Yang, Yue and Su, Xingsong and Zhang, Lei and Kerns, Peter and Achola, Laura and Hayes, Veronica and Quardokus, Rebecca and Suib, Steven L. and He, Jie},
abstractNote = {Abstract The catalytic activity of MnO 2 nanosheets towards oxygen evolution depends highly on their interlayer environment. We present a systematic investigation on fine‐tuning of the interlayer environment of MnO 2 nanosheets by intercalation through a facile cation exchange with inexpensive first‐row transition metal cations, including Ni 2+ , Co 2+ , Cu 2+ , Zn 2+ , and Fe 3+ ions. Among them, the Ni‐intercalated MnO 2 nanosheets show remarkably enhanced OER activity and long‐term stability, compared to pristine MnO 2 nanosheets. The overpotential of 330 mV at a current density of 10 mA cm −2 is observed for the Ni‐intercalated MnO 2 nanosheets. The ehancement mechanism of OER is studied by comparing physiochemical properties, such as the oxidation state of Mn, the interlayer distance, the increase in the disorder/twisting of MnO 6 octahedra, and the interlayer cooperative binding of water molecules. The Ni intercalation, different from other metal cations, strengthens the Mn−O bond perpendicularly to the layer chains to facilitate the interlayer catalysis possibly between two Mn sites, and thus promotes the efficiency of oxygen evolution.},
doi = {10.1002/cctc.201802019},
journal = {ChemCatChem},
number = 6,
volume = 11,
place = {United States},
year = {Mon Feb 18 00:00:00 EST 2019},
month = {Mon Feb 18 00:00:00 EST 2019}
}
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