From Tb3Ni2 to Tb3CoNi : The interplay between chemistry, structure, and magnetism

Ritter, Clemens; Provino, Alessia; Fauth, Francois; Dhar, Sudesh K.; Pecharsky, Vitalij K.; Manfrinetti, Pietro

doi:10.1103/PhysRevMaterials.3.024406

Title: From $T b_{3} N i_{2}$ to $T b_{3} CoNi$ : The interplay between chemistry, structure, and magnetism

Abstract

Formation, crystal structure, and macroscopic and microscopic magnetism of the binary Tb₃Ni₂ and derivative pseudobinary Tb₃Co_xNi_2-x phases have been investigated using an array of experimental methods. While Tb₃Ni₂ crystallizes in the monoclinic Dy₃Ni₂ structure type (mS20, C2/m), the substitution of Co for Ni results in a structural transition into the rhombohedral Er₃Ni₂ type (hR45, R$$\overline{3}$$h) at x(Co) ≈ 0.34 and beyond in the Tb₃Co_xNi_2-x system. In both the monoclinic and rhombohedral phases, the addition of Co leads to an anisotropic change of lattice parameters and unexpected reduction of the cell volume. Measurements of bulk properties reveal that these compounds order ferrimagnetically or ferromagnetically at about 100 K. Complex noncollinear ferromagnetic ordering in the Tb sublattices is weakly dependent on composition. Lastly, for x > 0.34 the long-range magnetic ordering leads to a strong anisotropic magnetostriction accompanied by a symmetry reduction from rhombohedral to triclinic.

Authors:

Ritter, Clemens ^[1]; Provino, Alessia ^[2]; Fauth, Francois ^[3]; Dhar, Sudesh K. ^[4]; Pecharsky, Vitalij K. ^[5]; Manfrinetti, Pietro ^[2]

Institut Laue-Langevin, Grenoble (France)
University of Genova (Italy); Ames Lab. and Iowa State Univ., Ames, IA (United States); Institute SPIN-CNR, Genova (Italy)
CELLS-ALBA Synchrotron, Barcelona (Spain)
Tata Institute of Fundamental Research, Mumbai (India)
Ames Lab. and Iowa State Univ., Ames, IA (United States)

Publication Date:: Wed Feb 20 00:00:00 EST 2019

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1498681

Alternate Identifier(s):: OSTI ID: 1495238

Report Number(s):: IS-J-9900
Journal ID: ISSN 2475-9953; PRMHAR

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Materials

Additional Journal Information:: Journal Volume: 3; Journal Issue: 2; Journal ID: ISSN 2475-9953

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE

Citation Formats


                    Ritter, Clemens, Provino, Alessia, Fauth, Francois, Dhar, Sudesh K., Pecharsky, Vitalij K., and Manfrinetti, Pietro. From Tb3Ni2 to Tb3CoNi : The interplay between chemistry, structure, and magnetism.  United States: N. p., 2019. 
Web.  doi:10.1103/PhysRevMaterials.3.024406.

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                    Ritter, Clemens, Provino, Alessia, Fauth, Francois, Dhar, Sudesh K., Pecharsky, Vitalij K., & Manfrinetti, Pietro. From Tb3Ni2 to Tb3CoNi : The interplay between chemistry, structure, and magnetism.  United States.  https://doi.org/10.1103/PhysRevMaterials.3.024406

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                    Ritter, Clemens, Provino, Alessia, Fauth, Francois, Dhar, Sudesh K., Pecharsky, Vitalij K., and Manfrinetti, Pietro. Wed .  
"From Tb3Ni2 to Tb3CoNi : The interplay between chemistry, structure, and magnetism".  United States.  https://doi.org/10.1103/PhysRevMaterials.3.024406.  https://www.osti.gov/servlets/purl/1498681.

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@article{osti_1498681,

  title        = {From Tb3Ni2 to Tb3CoNi : The interplay between chemistry, structure, and magnetism},

  author       = {Ritter, Clemens and Provino, Alessia and Fauth, Francois and Dhar, Sudesh K. and Pecharsky, Vitalij K. and Manfrinetti, Pietro},

  abstractNote = {Formation, crystal structure, and macroscopic and microscopic magnetism of the binary Tb3Ni2 and derivative pseudobinary Tb3CoxNi2-x phases have been investigated using an array of experimental methods. While Tb3Ni2 crystallizes in the monoclinic Dy3Ni2 structure type (mS20, C2/m), the substitution of Co for Ni results in a structural transition into the rhombohedral Er3Ni2 type (hR45, R$\overline{3}$h) at x(Co) ≈ 0.34 and beyond in the Tb3CoxNi2-x system. In both the monoclinic and rhombohedral phases, the addition of Co leads to an anisotropic change of lattice parameters and unexpected reduction of the cell volume. Measurements of bulk properties reveal that these compounds order ferrimagnetically or ferromagnetically at about 100 K. Complex noncollinear ferromagnetic ordering in the Tb sublattices is weakly dependent on composition. Lastly, for x > 0.34 the long-range magnetic ordering leads to a strong anisotropic magnetostriction accompanied by a symmetry reduction from rhombohedral to triclinic.},

  doi          = {10.1103/PhysRevMaterials.3.024406},

  journal      = {Physical Review Materials},

  number       = 2,

  volume       = 3,

  place        = {United States},

  year         = {Wed Feb 20 00:00:00 EST 2019},

  month        = {Wed Feb 20 00:00:00 EST 2019}

}

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Title: From T b 3 N i 2 to T b 3 CoNi : The interplay between chemistry, structure, and magnetism

Abstract

Citation Formats

Giant Magnetocaloric Effect in Gd5(Si2Ge2) journal, June 1997

Electronically- and crystal-structure-driven magnetic structures and physical properties of RScSb (R = rare earth) compounds: a neutron diffraction, magnetization and heat capacity study journal, August 2014

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Y 3 Ni 2 : a new tetragonal phase with Ni-centred trigonal prisms journal, November 1977

Magnetic structures of R 5 Ni 2 In 4 and R 11 Ni 4 In 9 ( R = Tb and Ho): strong hierarchy in the temperature dependence of the magnetic ordering in the multiple rare-earth sublattices journal, November 2015

Atomic-environment classification of the chemical elements journal, June 1993

The monoclinic, CrB-related, crystal structure of Tb3Ni2, Dy3Ni2 and Ho3Ni2 journal, November 1974

Phase diagram of the Tb–Ni binary system journal, May 2005

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Phase equilibria in the Gd–Ni binary and Mg–Ni–Gd ternary systems journal, January 2012

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Title: From $T b_{3} N i_{2}$ to $T b_{3} CoNi$ : The interplay between chemistry, structure, and magnetism

Giant Magnetocaloric Effect in ${Gd}_{5} ({Si}_{2} {Ge}_{2})$
journal, June 1997

Electronically- and crystal-structure-driven magnetic structures and physical properties of RScSb (R = rare earth) compounds: a neutron diffraction, magnetization and heat capacity study
journal, August 2014

An economics strategy for criticality – Application to rare earth element Yttrium in new lighting technology and its sustainable availability
journal, September 2017

Magnetoelastic coupling in the triangular lattice antiferromagnet ${CuCrS}_{2}$
journal, September 2009

Magnetic properties and magnetocaloric effects in R ₃ Ni ₂ ( R = Ho and Er) compounds
journal, September 2011

Y ₃ Ni ₂ : a new tetragonal phase with Ni-centred trigonal prisms
journal, November 1977

Magnetic structures of R ₅ Ni ₂ In ₄ and R ₁₁ Ni ₄ In ₉ ( R = Tb and Ho): strong hierarchy in the temperature dependence of the magnetic ordering in the multiple rare-earth sublattices
journal, November 2015

Atomic-environment classification of the chemical elements
journal, June 1993

The monoclinic, CrB-related, crystal structure of Tb3Ni2, Dy3Ni2 and Ho3Ni2
journal, November 1974

Phase diagram of the Tb–Ni binary system
journal, May 2005

Non-hysteretic first-order phase transition with large latent heat and giant low-field magnetocaloric effect
journal, July 2018

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journal, August 2001

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