Nanoassemblies of ultrasmall clusters with remarkable activity in carbon dioxide conversion into C1 fuels

Halder, Avik; Kioseoglou, Joseph; Yang, Bing; Kolipaka, Karthika Lakshmi; Seifert, Soenke; Ilavsky, Jan; Pellin, Michael; Sowwan, Mukhles; Grammatikopoulos, Panagiotis; Vajda, Stefan

doi:10.1039/C8NR06664G

Title: Nanoassemblies of ultrasmall clusters with remarkable activity in carbon dioxide conversion into C1 fuels

Journal Article · Thu Mar 14 00:00:00 UTC 2019 · Nanoscale

DOI: https://doi.org/10.1039/C8NR06664G · OSTI ID:1495230

^[1];

^[2];

^[1]; Kolipaka, Karthika Lakshmi ^[1];

^[3]; Ilavsky, Jan ^[3];

^[1]; Sowwan, Mukhles ^[4];

^[4];

^[5]

Materials Science Division, Argonne National Laboratory, Argonne, USA
Department of Physics, Aristotle University of Thessaloniki, GR-54124 Thessaloniki, Greece
X-ray Science Division, Argonne National Laboratory, Argonne, USA
Nanoparticles by Design Unit, Okinawa Institute of Science and Technology Graduate University, Okinawa 904-0495, Japan
Materials Science Division, Argonne National Laboratory, Argonne, USA, Institute for Molecular Engineering

Cu nanoassemblies formed transiently from cluster tetramer building blocks during reaction turn over CO ₂ to methanol and hydrocarbons with leap in activity.

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Research Organization:: Argonne National Lab. (ANL), Lemont, IL (United States)

Sponsoring Organization:: Okinawa Institute of Science and Technology Graduate University (OIST); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1495230

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 11 Vol. 11; ISSN NANOHL; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (45)

Self-Supported Interconnected Pt Nanoassemblies as Highly Stable Electrocatalysts for Low-Temperature Fuel Cells Xia, Bao Yu; Ng, Wan Theng; Wu, Hao Bin Angewandte Chemie International Edition, Vol. 51, Issue 29 https://doi.org/10.1002/anie.201201553	journal	June 2012
Support-dependent Performance of Size-selected Subnanometer Cobalt Cluster-based Catalysts in the Dehydrogenation of Cyclohexene Lee, Sungsik; Di Vece, Marcel; Lee, Byeongdu ChemCatChem, Vol. 4, Issue 10 https://doi.org/10.1002/cctc.201200294	journal	August 2012
Methanol synthesis and reverse water-gas shift kinetics over clean polycrystalline copper Yoshihara, Jun; Parker, S. C.; Schafer, Adam Catalysis Letters, Vol. 31, Issue 4 https://doi.org/10.1007/BF00808595	journal	January 1995
Water dimer properties in the gradient-corrected density functional theory Laasonen, K.; Csajka, F.; Parrinello, M. Chemical Physics Letters, Vol. 194, Issue 3 https://doi.org/10.1016/0009-2614(92)85529-J	journal	June 1992
Highly efficient Cu-decorated iron oxide nanocatalyst for low pressure CO2 conversion Halder, Avik; Kilianová, Martina; Yang, Bing Applied Catalysis B: Environmental, Vol. 225 https://doi.org/10.1016/j.apcatb.2017.11.047	journal	June 2018
Correlations between synthesis, precursor, and catalyst structure and activity of a large set of CuO/ZnO/Al2O3 catalysts for methanol synthesis Baltes, C.; Vukojevic, S.; Schuth, F. Journal of Catalysis, Vol. 258, Issue 2 https://doi.org/10.1016/j.jcat.2008.07.004	journal	September 2008
Simultaneous measurement of X-ray small angle scattering, absorption and reactivity: A continuous flow catalysis reactor Lee, Sungsik; Lee, Byeongdu; Seifert, Soenke Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 649, Issue 1 https://doi.org/10.1016/j.nima.2010.12.172	journal	September 2011
Reactivity of Metal Clusters Luo, Zhixun; Castleman, A. W.; Khanna, Shiv N. Chemical Reviews, Vol. 116, Issue 23 https://doi.org/10.1021/acs.chemrev.6b00230	journal	November 2016
Copper Cluster Size Effect in Methanol Synthesis from CO ₂ Yang, Bing; Liu, Cong; Halder, Avik The Journal of Physical Chemistry C, Vol. 121, Issue 19 https://doi.org/10.1021/acs.jpcc.7b01835	journal	May 2017
Hydrogenation of CO ₂ to Methanol: Importance of Metal–Oxide and Metal–Carbide Interfaces in the Activation of CO ₂ Rodriguez, José A.; Liu, Ping; Stacchiola, Dario J. ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01755	journal	October 2015
The Structure of the Cu–CuO Sites Determines the Catalytic Activity of Cu Nanoparticles Caldas, Paula C. P.; Gallo, Jean Marcel R.; Lopez-Castillo, Alejandro ACS Catalysis, Vol. 7, Issue 4 https://doi.org/10.1021/acscatal.6b03642	journal	March 2017
Sintering of Catalytic Nanoparticles: Particle Migration or Ostwald Ripening? Hansen, Thomas W.; DeLaRiva, Andrew T.; Challa, Sivakumar R. Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar3002427	journal	April 2013
Transformation of Carbon Dioxide Sakakura, Toshiyasu; Choi, Jun-Chul; Yasuda, Hiroyuki Chemical Reviews, Vol. 107, Issue 6 https://doi.org/10.1021/cr068357u	journal	June 2007
Gaussian density functional calculations on hydrogen-bonded systems Sim, Fiona; St. Amant, Alain; Papai, Imre Journal of the American Chemical Society, Vol. 114, Issue 11 https://doi.org/10.1021/ja00037a055	journal	May 1992
Anthropogenic Chemical Carbon Cycle for a Sustainable Future Olah, George A.; Prakash, G. K. Surya; Goeppert, Alain Journal of the American Chemical Society, Vol. 133, Issue 33 https://doi.org/10.1021/ja202642y	journal	August 2011
Isolated Metal Active Site Concentration and Stability Control Catalytic CO ₂ Reduction Selectivity Matsubu, John C.; Yang, Vanessa N.; Christopher, Phillip Journal of the American Chemical Society, Vol. 137, Issue 8 https://doi.org/10.1021/ja5128133	journal	February 2015
Carbon Dioxide Conversion to Methanol over Size-Selected Cu ₄ Clusters at Low Pressures Liu, Cong; Yang, Bing; Tyo, Eric Journal of the American Chemical Society, Vol. 137, Issue 27 https://doi.org/10.1021/jacs.5b03668	journal	July 2015
On the Accuracy of DFT for Describing Hydrogen Bonds: Dependence on the Bond Directionality Ireta, Joel; Neugebauer, Jörg; Scheffler, Matthias The Journal of Physical Chemistry A, Vol. 108, Issue 26 https://doi.org/10.1021/jp0377073	journal	July 2004
Structure and Energetics of the Hydronium Hydration Shells Markovitch, Omer; Agmon, Noam The Journal of Physical Chemistry A, Vol. 111, Issue 12 https://doi.org/10.1021/jp068960g	journal	March 2007
Catalyst support effects on hydrogen spillover Karim, Waiz; Spreafico, Clelia; Kleibert, Armin Nature, Vol. 541, Issue 7635 https://doi.org/10.1038/nature20782	journal	January 2017
The effect of particle proximity on the oxygen reduction rate of size-selected platinum clusters Nesselberger, Markus; Roefzaad, Melanie; Fayçal Hamou, R. Nature Materials, Vol. 12, Issue 10 https://doi.org/10.1038/nmat3712	journal	July 2013
Penetration of thin C60 films by metal nanoparticles Duffe, Stefanie; Grönhagen, Niklas; Patryarcha, Lukas Nature Nanotechnology, Vol. 5, Issue 5 https://doi.org/10.1038/nnano.2010.45	journal	April 2010
Catalysis by clusters with precise numbers of atoms Tyo, Eric C.; Vajda, Stefan Nature Nanotechnology, Vol. 10, Issue 7 https://doi.org/10.1038/nnano.2015.140	journal	July 2015
Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction Weng, Zhe; Wu, Yueshen; Wang, Maoyu Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-02819-7	journal	January 2018
CO ₂ conversion to methanol on Cu( i ) oxide nanolayers and clusters: an electronic structure insight into the reaction mechanism Uzunova, Ellie L.; Seriani, Nicola; Mikosch, Hans Physical Chemistry Chemical Physics, Vol. 17, Issue 16 https://doi.org/10.1039/C5CP01267H	journal	January 2015
The p-type conduction mechanism in Cu2O: a first principles study Nolan, Michael; Elliott, Simon D. Physical Chemistry Chemical Physics, Vol. 8, Issue 45 https://doi.org/10.1039/b611969g	journal	January 2006
Oxidative dehydrogenation of cyclohexene on size selected subnanometer cobalt clusters: improved catalytic performance via evolution of cluster-assembled nanostructures Lee, Sungsik; Vece, Marcel Di; Lee, Byeongdu Physical Chemistry Chemical Physics, Vol. 14, Issue 26 https://doi.org/10.1039/c2cp40162b	journal	January 2012
Atomically precise (catalytic) particles synthesized by a novel cluster deposition instrument Yin, C.; Tyo, E.; Kuchta, K. The Journal of Chemical Physics, Vol. 140, Issue 17, Article No. 174201 https://doi.org/10.1063/1.4871799	journal	May 2014
Optimising self-assembly through time-dependent interactions Fullerton, Christopher J.; Jack, Robert L. The Journal of Chemical Physics, Vol. 145, Issue 24 https://doi.org/10.1063/1.4972861	journal	December 2016
Simple analytical model of nanocluster coalescence for porous thin film design Grammatikopoulos, P.; Toulkeridou, E.; Nordlund, K. Modelling and Simulation in Materials Science and Engineering, Vol. 23, Issue 1 https://doi.org/10.1088/0965-0393/23/1/015008	journal	December 2014
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Pinning of size-selected gold and nickel nanoclusters on graphite Di Vece, M.; Palomba, S.; Palmer, R. E. Physical Review B, Vol. 72, Issue 7 https://doi.org/10.1103/PhysRevB.72.073407	journal	August 2005
Polar distortions in hydrogen-bonded organic ferroelectrics Stroppa, Alessandro; Di Sante, Domenico; Horiuchi, Sachio Physical Review B, Vol. 84, Issue 1 https://doi.org/10.1103/PhysRevB.84.014101	journal	July 2011
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)] Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 78, Issue 7 https://doi.org/10.1103/PhysRevLett.78.1396	journal	February 1997
A refinement of the crystal structure of copper(II) oxide with a discussion of some exceptional e.s.d.'s Åsbrink, S.; Norrby, L. J. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 26, Issue 1 https://doi.org/10.1107/S0567740870001838	journal	January 1970
Modern Global Climate Change Karl, T. R. Science, Vol. 302, Issue 5651 https://doi.org/10.1126/science.1090228	journal	December 2003
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au₈ Clusters on MgO Yoon, Bokwon; Häkkinen, Hannu; Landman, Uzi Science, Vol. 307, Issue 5708, p. 403-407 https://doi.org/10.1126/science.1104168	journal	January 2005
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects Lei, Y.; Mehmood, F.; Lee, S. Science, Vol. 328, Issue 5975, p. 224-228 https://doi.org/10.1126/science.1185200	journal	April 2010
The Active Site of Methanol Synthesis over Cu/ZnO/Al₂O₃ Industrial Catalysts Behrens, M.; Studt, F.; Kasatkin, I. Science, Vol. 336, Issue 6083, p. 893-897 https://doi.org/10.1126/science.1219831	journal	April 2012
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2 Graciani, J.; Mudiyanselage, K.; Xu, F. Science, Vol. 345, Issue 6196 https://doi.org/10.1126/science.1253057	journal	July 2014
Design of Nanomaterial Synthesis by Aerosol Processes Buesser, Beat; Pratsinis, Sotiris E. Annual Review of Chemical and Biomolecular Engineering, Vol. 3, Issue 1 https://doi.org/10.1146/annurev-chembioeng-062011-080930	journal	July 2012
Size-Selected Platinum Clusters as Electrocatalysts for the Oxygen Reduction Reaction Nesselberger, M.; Kunz, S.; Schweinberger, F. F. ECS Transactions, Vol. 50, Issue 2 https://doi.org/10.1149/05002.1333ecst	journal	March 2013

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Title: Nanoassemblies of ultrasmall clusters with remarkable activity in carbon dioxide conversion into C1 fuels

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