Infrared-pump electronic-probe of methylammonium lead iodide reveals electronically decoupled organic and inorganic sublattices
Abstract
Organic-inorganic hybrid perovskites such as methylammonium lead iodide (CH3NH3PbI3) are game-changing semiconductors for solar cells and light-emitting devices owing to their defect tolerance and exceptionally long carrier lifetimes and diffusion lengths. Determining whether the dynamically disordered organic cations with large dipole moment benefit the optoelectronic properties of CH3NH3PbI3 has been an outstanding challenge. Herein, via transient absorption measurements employing an infrared pump pulse tuned to a methylammonium vibration, we observe slow, nanosecond-long thermal dissipation from the selectively excited organic mode to the inorganic sublattice. The resulting transient electronic signatures, during the period of thermal-nonequilibrium when the induced thermal motions are mostly concentrated on the organic sublattice, reveal that the induced atomic motions of the organic cations do not alter the absorption or the photoluminescence response of CH3NH3PbI3, beyond thermal effects. Our results suggest that the attractive optoelectronic properties of CH3NH3PbI3 mainly derive from the inorganic lead-halide framework.
- Authors:
-
[1];
[3];
[2];
[6]
- Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
- Northern Illinois Univ., DeKalb, IL (United States). Dept. of Chemistry and Biochemistry
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Northwestern Univ., Evanston, IL (United States). Dept. of Physics and Astronomy
- Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials; Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States); Northern Illinois Univ., DeKalb, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); ANL Laboratory Directed Research and Development (LDRD) Program; National Science Foundation (NSF)
- OSTI Identifier:
- 1494797
- Grant/Contract Number:
- AC02-06CH11357; SC0012541; DMR-1806152
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; atomistic models; infrared spectroscopy; ultrafast photonics
Citation Formats
Guo, Peijun, Mannodi-Kanakkithodi, Arun, Gong, Jue, Xia, Yi, Stoumpos, Constantinos C., Cao, Duyen H., Diroll, Benjamin T., Ketterson, John B., Wiederrecht, Gary P., Xu, Tao, Chan, Maria K. Y., Kanatzidis, Mercouri G., and Schaller, Richard D. Infrared-pump electronic-probe of methylammonium lead iodide reveals electronically decoupled organic and inorganic sublattices. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-08363-2.
Guo, Peijun, Mannodi-Kanakkithodi, Arun, Gong, Jue, Xia, Yi, Stoumpos, Constantinos C., Cao, Duyen H., Diroll, Benjamin T., Ketterson, John B., Wiederrecht, Gary P., Xu, Tao, Chan, Maria K. Y., Kanatzidis, Mercouri G., & Schaller, Richard D. Infrared-pump electronic-probe of methylammonium lead iodide reveals electronically decoupled organic and inorganic sublattices. United States. https://doi.org/10.1038/s41467-019-08363-2
Guo, Peijun, Mannodi-Kanakkithodi, Arun, Gong, Jue, Xia, Yi, Stoumpos, Constantinos C., Cao, Duyen H., Diroll, Benjamin T., Ketterson, John B., Wiederrecht, Gary P., Xu, Tao, Chan, Maria K. Y., Kanatzidis, Mercouri G., and Schaller, Richard D. Tue .
"Infrared-pump electronic-probe of methylammonium lead iodide reveals electronically decoupled organic and inorganic sublattices". United States. https://doi.org/10.1038/s41467-019-08363-2. https://www.osti.gov/servlets/purl/1494797.
@article{osti_1494797,
title = {Infrared-pump electronic-probe of methylammonium lead iodide reveals electronically decoupled organic and inorganic sublattices},
author = {Guo, Peijun and Mannodi-Kanakkithodi, Arun and Gong, Jue and Xia, Yi and Stoumpos, Constantinos C. and Cao, Duyen H. and Diroll, Benjamin T. and Ketterson, John B. and Wiederrecht, Gary P. and Xu, Tao and Chan, Maria K. Y. and Kanatzidis, Mercouri G. and Schaller, Richard D.},
abstractNote = {Organic-inorganic hybrid perovskites such as methylammonium lead iodide (CH3NH3PbI3) are game-changing semiconductors for solar cells and light-emitting devices owing to their defect tolerance and exceptionally long carrier lifetimes and diffusion lengths. Determining whether the dynamically disordered organic cations with large dipole moment benefit the optoelectronic properties of CH3NH3PbI3 has been an outstanding challenge. Herein, via transient absorption measurements employing an infrared pump pulse tuned to a methylammonium vibration, we observe slow, nanosecond-long thermal dissipation from the selectively excited organic mode to the inorganic sublattice. The resulting transient electronic signatures, during the period of thermal-nonequilibrium when the induced thermal motions are mostly concentrated on the organic sublattice, reveal that the induced atomic motions of the organic cations do not alter the absorption or the photoluminescence response of CH3NH3PbI3, beyond thermal effects. Our results suggest that the attractive optoelectronic properties of CH3NH3PbI3 mainly derive from the inorganic lead-halide framework.},
doi = {10.1038/s41467-019-08363-2},
journal = {Nature Communications},
number = ,
volume = 10,
place = {United States},
year = {Tue Jan 29 00:00:00 EST 2019},
month = {Tue Jan 29 00:00:00 EST 2019}
}
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Figure 1: Static and infrared pump electronic-probe (IPEP) measurements of CH3NH3PbI3. a Static, temperature-dependent absorbance around the bandgap. b Static, temperature-dependent absorbance around the N-H-as vibrational modes. c ΔOD spectral map measured with on-resonance infrared pump (centered at 3120 cm−1) at 10 K. The dashed line shows the wavelength atmore »
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Works referenced in this record:
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors
journal, September 2015
- Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.
- Accounts of Chemical Research, Vol. 48, Issue 10
Vapour-Deposited Cesium Lead Iodide Perovskites: Microsecond Charge Carrier Lifetimes and Enhanced Photovoltaic Performance
journal, August 2017
- Hutter, Eline M.; Sutton, Rebecca J.; Chandrashekar, Sanjana
- ACS Energy Letters, Vol. 2, Issue 8
Solvent-controlled growth of inorganic perovskite films in dry environment for efficient and stable solar cells
journal, June 2018
- Wang, Pengyang; Zhang, Xingwang; Zhou, Yuqin
- Nature Communications, Vol. 9, Issue 1
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Temperature-Dependent Charge-Carrier Dynamics in CH 3 NH 3 PbI 3 Perovskite Thin Films
journal, September 2015
- Milot, Rebecca L.; Eperon, Giles E.; Snaith, Henry J.
- Advanced Functional Materials, Vol. 25, Issue 39
Selective Stabilization and Photophysical Properties of Metastable Perovskite Polymorphs of CsPbI 3 in Thin Films
journal, September 2017
- Fu, Yongping; Rea, Morgan T.; Chen, Jie
- Chemistry of Materials, Vol. 29, Issue 19
Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide
journal, October 2016
- Whitfield, P. S.; Herron, N.; Guise, W. E.
- Scientific Reports, Vol. 6, Issue 1
Vibrational relaxation of CH3I in the gas phase and in solution
journal, April 2004
- Elles, Christopher G.; Cox, M. Jocelyn; Crim, F. Fleming
- The Journal of Chemical Physics, Vol. 120, Issue 15
Van der Waals density functionals applied to solids
journal, May 2011
- Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
- Physical Review B, Vol. 83, Issue 19
Square-Centimeter Solution-Processed Planar CH 3 NH 3 PbI 3 Perovskite Solar Cells with Efficiency Exceeding 15%
journal, September 2015
- Yang, Mengjin; Zhou, Yuanyuan; Zeng, Yining
- Advanced Materials, Vol. 27, Issue 41
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
journal, May 2015
- Yang, W. S.; Noh, J. H.; Jeon, N. J.
- Science, Vol. 348, Issue 6240
Enhanced mobility CsPbI 3 quantum dot arrays for record-efficiency, high-voltage photovoltaic cells
journal, October 2017
- Sanehira, Erin M.; Marshall, Ashley R.; Christians, Jeffrey A.
- Science Advances, Vol. 3, Issue 10
Cross-plane coherent acoustic phonons in two-dimensional organic-inorganic hybrid perovskites
journal, May 2018
- Guo, Peijun; Stoumpos, Constantinos C.; Mao, Lingling
- Nature Communications, Vol. 9, Issue 1
Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process
journal, January 2018
- Davies, Christopher L.; Filip, Marina R.; Patel, Jay B.
- Nature Communications, Vol. 9, Issue 1
Rashba Spin–Orbit Coupling Enhanced Carrier Lifetime in CH 3 NH 3 PbI 3
journal, November 2015
- Zheng, Fan; Tan, Liang Z.; Liu, Shi
- Nano Letters, Vol. 15, Issue 12
Revealing the role of organic cations in hybrid halide perovskite CH3NH3PbI3
journal, April 2015
- Motta, Carlo; El-Mellouhi, Fedwa; Kais, Sabre
- Nature Communications, Vol. 6, Issue 1
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
journal, April 2016
- Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J.
- Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867
Screening in crystalline liquids protects energetic carriers in hybrid perovskites
journal, September 2016
- Zhu, H.; Miyata, K.; Fu, Y.
- Science, Vol. 353, Issue 6306
Ab initiomolecular dynamics for liquid metals
journal, January 1993
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 47, Issue 1, p. 558-561
Orientational order controls crystalline and amorphous thermal transport in superatomic crystals
journal, September 2016
- Ong, Wee-Liat; O’Brien, Evan S.; Dougherty, Patrick S. M.
- Nature Materials, Vol. 16, Issue 1
Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells
journal, April 2014
- Frost, Jarvist M.; Butler, Keith T.; Brivio, Federico
- Nano Letters, Vol. 14, Issue 5
What Remains Unexplained about the Properties of Halide Perovskites?
journal, March 2018
- Egger, David A.; Bera, Achintya; Cahen, David
- Advanced Materials, Vol. 30, Issue 20
Vibrational Coupling between Organic and Inorganic Sublattices of Hybrid Perovskites
journal, September 2018
- Grechko, Maksim; Bretschneider, Simon A.; Vietze, Laura
- Angewandte Chemie International Edition, Vol. 57, Issue 41
Investigating the Role of the Organic Cation in Formamidinium Lead Iodide Perovskite Using Ultrafast Spectroscopy
journal, February 2018
- Taylor, Victoria C. A.; Tiwari, Devendra; Duchi, Marta
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 4
Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites
journal, July 2017
- Wu, Xiaoxi; Tan, Liang Z.; Shen, Xiaozhe
- Science Advances, Vol. 3, Issue 7
How Important Is the Organic Part of Lead Halide Perovskite Photovoltaic Cells? Efficient CsPbBr 3 Cells
journal, June 2015
- Kulbak, Michael; Cahen, David; Hodes, Gary
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 13
ShengBTE: A solver of the Boltzmann transport equation for phonons
journal, June 2014
- Li, Wu; Carrete, Jesús; A. Katcho, Nebil
- Computer Physics Communications, Vol. 185, Issue 6
Surface chemistry mediates thermal transport in three-dimensional nanocrystal arrays
journal, March 2013
- Ong, Wee-Liat; Rupich, Sara M.; Talapin, Dmitri V.
- Nature Materials, Vol. 12, Issue 5
Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter‐wave spectroscopy
journal, December 1987
- Poglitsch, A.; Weber, D.
- The Journal of Chemical Physics, Vol. 87, Issue 11, p. 6373-6378
Slow thermal equilibration in methylammonium lead iodide revealed by transient mid-infrared spectroscopy
journal, July 2018
- Guo, Peijun; Gong, Jue; Sadasivam, Sridhar
- Nature Communications, Vol. 9, Issue 1
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Large polarons in lead halide perovskites
journal, August 2017
- Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan
- Science Advances, Vol. 3, Issue 8
Trap States in Lead Iodide Perovskites
journal, January 2015
- Wu, Xiaoxi; Trinh, M. Tuan; Niesner, Daniel
- Journal of the American Chemical Society, Vol. 137, Issue 5
Metal-free three-dimensional perovskite ferroelectrics
journal, July 2018
- Ye, Heng-Yun; Tang, Yuan-Yuan; Li, Peng-Fei
- Science, Vol. 361, Issue 6398
Lattice dynamics and vibrational spectra of the orthorhombic, tetragonal, and cubic phases of methylammonium lead iodide
journal, October 2015
- Brivio, Federico; Frost, Jarvist M.; Skelton, Jonathan M.
- Physical Review B, Vol. 92, Issue 14
Large polarization-dependent exciton optical Stark effect in lead iodide perovskites
journal, August 2016
- Yang, Ye; Yang, Mengjin; Zhu, Kai
- Nature Communications, Vol. 7, Issue 1
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
First principles phonon calculations in materials science
journal, November 2015
- Togo, Atsushi; Tanaka, Isao
- Scripta Materialia, Vol. 108
Organic Cation Rotation and Immobilization in Pure and Mixed Methylammonium Lead-Halide Perovskites
journal, March 2017
- Selig, Oleg; Sadhanala, Aditya; Müller, Christian
- Journal of the American Chemical Society, Vol. 139, Issue 11
Spin-polarized exciton quantum beating in hybrid organic–inorganic perovskites
journal, May 2017
- Odenthal, Patrick; Talmadge, William; Gundlach, Nathan
- Nature Physics, Vol. 13, Issue 9
Inversion symmetry and bulk Rashba effect in methylammonium lead iodide perovskite single crystals
journal, May 2018
- Frohna, Kyle; Deshpande, Tejas; Harter, John
- Nature Communications, Vol. 9, Issue 1
Calorimetric and IR spectroscopic studies of phase transitions in methylammonium trihalogenoplumbates (II)†
journal, January 1990
- Onoda-Yamamuro, Noriko; Matsuo, Takasuke; Suga, Hiroshi
- Journal of Physics and Chemistry of Solids, Vol. 51, Issue 12
Inhomogeneous Electron Gas
journal, November 1964
- Hohenberg, P.; Kohn, W.
- Physical Review, Vol. 136, Issue 3B, p. B864-B871
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013
- Xing, G.; Mathews, N.; Sun, S.
- Science, Vol. 342, Issue 6156, p. 344-347
The dynamics of methylammonium ions in hybrid organic–inorganic perovskite solar cells
journal, May 2015
- Leguy, Aurelien M. A.; Frost, Jarvist Moore; McMahon, Andrew P.
- Nature Communications, Vol. 6, Issue 1
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012
- Lee, M. M.; Teuscher, J.; Miyasaka, T.
- Science, Vol. 338, Issue 6107, p. 643-647
Femtosecond Time-Resolved Transient Absorption Spectroscopy of CH 3 NH 3 PbI 3 Perovskite Films: Evidence for Passivation Effect of PbI 2
journal, August 2014
- Wang, Lili; McCleese, Christopher; Kovalsky, Anton
- Journal of the American Chemical Society, Vol. 136, Issue 35
Continuous-wave lasing in an organic–inorganic lead halide perovskite semiconductor
journal, November 2017
- Jia, Yufei; Kerner, Ross A.; Grede, Alex J.
- Nature Photonics, Vol. 11, Issue 12
Organic Cations Might Not Be Essential to the Remarkable Properties of Band Edge Carriers in Lead Halide Perovskites
journal, October 2016
- Zhu, Haiming; Trinh, M. Tuan; Wang, Jue
- Advanced Materials, Vol. 29, Issue 1
White-Light Emission from Layered Halide Perovskites
journal, February 2018
- Smith, Matthew D.; Karunadasa, Hemamala I.
- Accounts of Chemical Research, Vol. 51, Issue 3
Electron–phonon coupling in hybrid lead halide perovskites
journal, May 2016
- Wright, Adam D.; Verdi, Carla; Milot, Rebecca L.
- Nature Communications, Vol. 7, Issue 1
VMD: Visual molecular dynamics
journal, February 1996
- Humphrey, William; Dalke, Andrew; Schulten, Klaus
- Journal of Molecular Graphics, Vol. 14, Issue 1
Long-range hot-carrier transport in hybrid perovskites visualized by ultrafast microscopy
journal, April 2017
- Guo, Zhi; Wan, Yan; Yang, Mengjin
- Science, Vol. 356, Issue 6333
Real-Time Observation of Organic Cation Reorientation in Methylammonium Lead Iodide Perovskites
journal, August 2015
- Bakulin, Artem A.; Selig, Oleg; Bakker, Huib J.
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 18
Inhomogeneous Electron Gas
journal, March 1973
- Rajagopal, A. K.; Callaway, J.
- Physical Review B, Vol. 7, Issue 5
Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites
text, January 2017
- Wu, Xiaoxi; Tan, Liang Z.; Shen, Xiaozhe
- Columbia University
High-resolution X-ray luminescence extension imaging
journal, February 2021
- Ou, Xiangyu; Qin, Xian; Huang, Bolong
- Nature, Vol. 590, Issue 7846
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020
- Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna
- Scientific Reports, Vol. 10, Issue 1
Lead palladium titanate: A room temperature nanoscale multiferroic thin film
journal, February 2020
- Mishra, K. K.; Instan, Alvaro A.; Kumari, Shalini
- Scientific Reports, Vol. 10, Issue 1
Vapour-Deposited Cesium Lead Iodide Perovskites: Microsecond Charge Carrier Lifetimes and Enhanced Photovoltaic Performance.
text, January 2017
- Hutter, Eline M.; Sutton, Rebecca J.; Chandrashekar, Sanjana
- Apollo - University of Cambridge Repository
Investigating the Role of the Organic Cation in Formamidinium Lead Iodide Perovskite using Ultrafast Spectroscopy
dataset, January 2018
- Oliver, Thomas; Duchi, Marta; Taylor, Victoria
- University of Bristol
Van der Waals density functionals applied to solids
text, January 2011
- Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
- arXiv
Revealing the role of organic cations in hybrid halide perovskites CH3NH3PbI3
text, January 2014
- Motta, Carlo; Mellouhi, Fedwa El; Kais, Sabre
- arXiv
First principles phonon calculations in materials science
preprint, January 2015
- Togo, Atsushi; Tanaka, Isao
- arXiv
Local polar fluctuations in lead halide perovskite crystals
text, January 2016
- Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z.
- arXiv
Square-Centimeter Solution-Processed Planar CH 3 NH 3 PbI 3 Perovskite Solar Cells with Efficiency Exceeding 15%
journal, September 2015
- Yang, Mengjin; Zhou, Yuanyuan; Zeng, Yining
- Advanced Materials, Vol. 27, Issue 41
Organic Cations Might Not Be Essential to the Remarkable Properties of Band Edge Carriers in Lead Halide Perovskites
journal, October 2016
- Zhu, Haiming; Trinh, M. Tuan; Wang, Jue
- Advanced Materials, Vol. 29, Issue 1
Vibrational Coupling between Organic and Inorganic Sublattices of Hybrid Perovskites
journal, September 2018
- Grechko, Maksim; Bretschneider, Simon A.; Vietze, Laura
- Angewandte Chemie International Edition, Vol. 57, Issue 41
Calorimetric and IR spectroscopic studies of phase transitions in methylammonium trihalogenoplumbates (II)†
journal, January 1990
- Onoda-Yamamuro, Noriko; Matsuo, Takasuke; Suga, Hiroshi
- Journal of Physics and Chemistry of Solids, Vol. 51, Issue 12
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors
journal, September 2015
- Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.
- Accounts of Chemical Research, Vol. 48, Issue 10
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
journal, April 2016
- Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J.
- Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867
Real-Time Observation of Organic Cation Reorientation in Methylammonium Lead Iodide Perovskites
journal, August 2015
- Bakulin, Artem A.; Selig, Oleg; Bakker, Huib J.
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 18
Investigating the Role of the Organic Cation in Formamidinium Lead Iodide Perovskite Using Ultrafast Spectroscopy
journal, February 2018
- Taylor, Victoria C. A.; Tiwari, Devendra; Duchi, Marta
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 4
Rashba Spin–Orbit Coupling Enhanced Carrier Lifetime in CH 3 NH 3 PbI 3
journal, November 2015
- Zheng, Fan; Tan, Liang Z.; Liu, Shi
- Nano Letters, Vol. 15, Issue 12
Vapour-Deposited Cesium Lead Iodide Perovskites: Microsecond Charge Carrier Lifetimes and Enhanced Photovoltaic Performance
journal, August 2017
- Hutter, Eline M.; Sutton, Rebecca J.; Chandrashekar, Sanjana
- ACS Energy Letters, Vol. 2, Issue 8
Trap States in Lead Iodide Perovskites
journal, January 2015
- Wu, Xiaoxi; Trinh, M. Tuan; Niesner, Daniel
- Journal of the American Chemical Society, Vol. 137, Issue 5
Organic Cation Rotation and Immobilization in Pure and Mixed Methylammonium Lead-Halide Perovskites
journal, March 2017
- Selig, Oleg; Sadhanala, Aditya; Müller, Christian
- Journal of the American Chemical Society, Vol. 139, Issue 11
Large polarization-dependent exciton optical Stark effect in lead iodide perovskites
journal, August 2016
- Yang, Ye; Yang, Mengjin; Zhu, Kai
- Nature Communications, Vol. 7, Issue 1
Revealing the role of organic cations in hybrid halide perovskite CH3NH3PbI3
journal, April 2015
- Motta, Carlo; El-Mellouhi, Fedwa; Kais, Sabre
- Nature Communications, Vol. 6, Issue 1
The dynamics of methylammonium ions in hybrid organic–inorganic perovskite solar cells
journal, May 2015
- Leguy, Aurelien M. A.; Frost, Jarvist Moore; McMahon, Andrew P.
- Nature Communications, Vol. 6, Issue 1
Surface chemistry mediates thermal transport in three-dimensional nanocrystal arrays
journal, March 2013
- Ong, Wee-Liat; Rupich, Sara M.; Talapin, Dmitri V.
- Nature Materials, Vol. 12, Issue 5
Spin-polarized exciton quantum beating in hybrid organic–inorganic perovskites
journal, May 2017
- Odenthal, Patrick; Talmadge, William; Gundlach, Nathan
- Nature Physics, Vol. 13, Issue 9
Inversion symmetry and bulk Rashba effect in methylammonium lead iodide perovskite single crystals
journal, May 2018
- Frohna, Kyle; Deshpande, Tejas; Harter, John
- Nature Communications, Vol. 9, Issue 1
Cross-plane coherent acoustic phonons in two-dimensional organic-inorganic hybrid perovskites
journal, May 2018
- Guo, Peijun; Stoumpos, Constantinos C.; Mao, Lingling
- Nature Communications, Vol. 9, Issue 1
Solvent-controlled growth of inorganic perovskite films in dry environment for efficient and stable solar cells
journal, June 2018
- Wang, Pengyang; Zhang, Xingwang; Zhou, Yuqin
- Nature Communications, Vol. 9, Issue 1
Observation of second sound in graphite over 200 K
journal, January 2022
- Ding, Zhiwei; Chen, Ke; Song, Bai
- Nature Communications, Vol. 13, Issue 1
Continuous-wave lasing in an organic–inorganic lead halide perovskite semiconductor
journal, November 2017
- Jia, Yufei; Kerner, Ross A.; Grede, Alex J.
- Nature Photonics, Vol. 11, Issue 12
Stepwise gating of the Sec61 protein-conducting channel by Sec63 and Sec62
journal, January 2021
- Itskanov, Samuel; Kuo, Katie M.; Gumbart, James C.
- Nature Structural & Molecular Biology, Vol. 28, Issue 2
(Fe,Ni)2P allabogdanite can be an ambient pressure phase in iron meteorites
journal, June 2020
- Litasov, Konstantin D.; Bekker, Tatyana B.; Sagatov, Nursultan E.
- Scientific Reports, Vol. 10, Issue 1
Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide
journal, October 2016
- Whitfield, P. S.; Herron, N.; Guise, W. E.
- Scientific Reports, Vol. 6, Issue 1
Vibrational relaxation of CH3I in the gas phase and in solution
journal, April 2004
- Elles, Christopher G.; Cox, M. Jocelyn; Crim, F. Fleming
- The Journal of Chemical Physics, Vol. 120, Issue 15
Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter‐wave spectroscopy
journal, December 1987
- Poglitsch, A.; Weber, D.
- The Journal of Chemical Physics, Vol. 87, Issue 11, p. 6373-6378
Large polarons in lead halide perovskites
journal, August 2017
- Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan
- Science Advances, Vol. 3, Issue 8
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012
- Lee, M. M.; Teuscher, J.; Miyasaka, T.
- Science, Vol. 338, Issue 6107, p. 643-647
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013
- Xing, G.; Mathews, N.; Sun, S.
- Science, Vol. 342, Issue 6156, p. 344-347
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
journal, May 2015
- Yang, W. S.; Noh, J. H.; Jeon, N. J.
- Science, Vol. 348, Issue 6240
Screening in crystalline liquids protects energetic carriers in hybrid perovskites
journal, September 2016
- Zhu, H.; Miyata, K.; Fu, Y.
- Science, Vol. 353, Issue 6306
Metal-free three-dimensional perovskite ferroelectrics
journal, July 2018
- Ye, Heng-Yun; Tang, Yuan-Yuan; Li, Peng-Fei
- Science, Vol. 361, Issue 6398
Atomistic origins of high-performance in hybrid halide perovskite solar cells
text, January 2014
- Frost, Jarvist M.; Butler, Keith T.; Brivio, Federico
- arXiv
Theoretical analysis of doped graphene as cathode catalyst in Li-O2 and Na-O2 batteries -- the impact of the computational scheme
preprint, January 2020
- Novčić, Katarina A.; Dobrota, Ana S.; Petković, Milena
- arXiv
Works referencing / citing this record:
Incorporating Large A Cations into Lead Iodide Perovskite Cages: Relaxed Goldschmidt Tolerance Factor and Impact on Exciton–Phonon Interaction
journal, July 2019
- Fu, Yongping; Hautzinger, Matthew P.; Luo, Ziyu
- ACS Central Science, Vol. 5, Issue 8
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