Surface Crystallization of Liquid Au-Si and Its Impact on Catalysis
Abstract
In situ transmission electron microscopy reveals that an atomically thin crystalline phase at the surface of liquid Au–Si is stable over an unexpectedly wide range of conditions. By measuring the surface structure as a function of liquid temperature and composition, a simple thermodynamic model is developed to explain the stability of the ordered phase. The presence of surface ordering plays a key role in the pathway by which the Au–Si eutectic solidifies and also dramatically affects the catalytic properties of the liquid, explaining the anomalously slow growth kinetics of Si nanowires at low temperature. A strategy to control the presence of the surface phase is discussed, using it as a tool in designing strategies for nanostructure growth.
- Authors:
-
- Department of Engineering, University of Cambridge, 9 J. J. Thomson Avenue Cambridge CB3 0FA UK, IBM T. J. Watson Research Center, Yorktown Heights NY 10598 USA
- IBM T. J. Watson Research Center, Yorktown Heights NY 10598 USA
- Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton NY 11973 USA
- Department of Engineering, University of Cambridge, 9 J. J. Thomson Avenue Cambridge CB3 0FA UK
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); Univ. of Cambridge (United Kingdom)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); European Research Council (ERC); Engineering and Physical Sciences Research Council (EPSRC)
- OSTI Identifier:
- 1494373
- Alternate Identifier(s):
- OSTI ID: 1484542; OSTI ID: 1514490
- Report Number(s):
- BNL-211597-2019-JAAM
Journal ID: ISSN 0935-9648; 1806544
- Grant/Contract Number:
- SC0012704; 279342; EP/K016636/1; EP/P005152/1
- Resource Type:
- Published Article
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Name: Advanced Materials Journal Volume: 31 Journal Issue: 5; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- Germany
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 2D crystals; in situ transmission electron microscopy; metastable phases; nanowires; surface ordering
Citation Formats
Panciera, Federico, Tersoff, Jerry, Gamalski, Andrew D., Reuter, Mark C., Zakharov, Dmitri, Stach, Eric A., Hofmann, Stephan, and Ross, Frances M. Surface Crystallization of Liquid Au-Si and Its Impact on Catalysis. Germany: N. p., 2018.
Web. doi:10.1002/adma.201806544.
Panciera, Federico, Tersoff, Jerry, Gamalski, Andrew D., Reuter, Mark C., Zakharov, Dmitri, Stach, Eric A., Hofmann, Stephan, & Ross, Frances M. Surface Crystallization of Liquid Au-Si and Its Impact on Catalysis. Germany. https://doi.org/10.1002/adma.201806544
Panciera, Federico, Tersoff, Jerry, Gamalski, Andrew D., Reuter, Mark C., Zakharov, Dmitri, Stach, Eric A., Hofmann, Stephan, and Ross, Frances M. Wed .
"Surface Crystallization of Liquid Au-Si and Its Impact on Catalysis". Germany. https://doi.org/10.1002/adma.201806544.
@article{osti_1494373,
title = {Surface Crystallization of Liquid Au-Si and Its Impact on Catalysis},
author = {Panciera, Federico and Tersoff, Jerry and Gamalski, Andrew D. and Reuter, Mark C. and Zakharov, Dmitri and Stach, Eric A. and Hofmann, Stephan and Ross, Frances M.},
abstractNote = {In situ transmission electron microscopy reveals that an atomically thin crystalline phase at the surface of liquid Au–Si is stable over an unexpectedly wide range of conditions. By measuring the surface structure as a function of liquid temperature and composition, a simple thermodynamic model is developed to explain the stability of the ordered phase. The presence of surface ordering plays a key role in the pathway by which the Au–Si eutectic solidifies and also dramatically affects the catalytic properties of the liquid, explaining the anomalously slow growth kinetics of Si nanowires at low temperature. A strategy to control the presence of the surface phase is discussed, using it as a tool in designing strategies for nanostructure growth.},
doi = {10.1002/adma.201806544},
journal = {Advanced Materials},
number = 5,
volume = 31,
place = {Germany},
year = {Wed Dec 05 00:00:00 EST 2018},
month = {Wed Dec 05 00:00:00 EST 2018}
}
https://doi.org/10.1002/adma.201806544
Web of Science
Figures / Tables:
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