Non‐Tacky Fluorinated and Elastomeric STEM Networks
Abstract
Abstract Soft, elastomeric, non‐tacky polymer networks are synthesized by reversible deactivation radical polymerization (RDRP). First, the pristine, structurally tailored and engineered macromolecular (STEM) networks are synthesized by reversible addition–fragmentation chain transfer (RAFT) polymerization and incorporated an atom transfer radical polymerization (ATRP) inimer into the network. Subsequently, poly( n ‐butyl acrylate) (PBA) and/or poly(octafluoropentyl acrylate) (POFPA) side chains are grafted from the network by photo‐induced ATRP. These low glass transition temperature side chains produced soft materials ( E = 104–178 kPa). However, only the POFPA‐containing networks are also non‐tacky. The fluorine content and material properties are investigated by dynamic mechanical analysis, elemental analysis, spectroscopy, and contact angle measurements.
- Authors:
-
[1];
[1];
[1];
[1];
[1];
[1];
[1];
[1]
- Department of Chemistry Carnegie Mellon University 4400 Fifth Avenue Pittsburgh PA 15213 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1494201
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Macromolecular Rapid Communications
- Additional Journal Information:
- Journal Name: Macromolecular Rapid Communications Journal Volume: 40 Journal Issue: 10; Journal ID: ISSN 1022-1336
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Cuthbert, Julia, Martinez, Michael R., Sun, Mingkang, Flum, Jacob, Li, Lingchun, Olszewski, Mateusz, Wang, Zhenhua, Kowalewski, Tomasz, and Matyjaszewski, Krzysztof. Non‐Tacky Fluorinated and Elastomeric STEM Networks. Germany: N. p., 2019.
Web. doi:10.1002/marc.201800876.
Cuthbert, Julia, Martinez, Michael R., Sun, Mingkang, Flum, Jacob, Li, Lingchun, Olszewski, Mateusz, Wang, Zhenhua, Kowalewski, Tomasz, & Matyjaszewski, Krzysztof. Non‐Tacky Fluorinated and Elastomeric STEM Networks. Germany. https://doi.org/10.1002/marc.201800876
Cuthbert, Julia, Martinez, Michael R., Sun, Mingkang, Flum, Jacob, Li, Lingchun, Olszewski, Mateusz, Wang, Zhenhua, Kowalewski, Tomasz, and Matyjaszewski, Krzysztof. Sun .
"Non‐Tacky Fluorinated and Elastomeric STEM Networks". Germany. https://doi.org/10.1002/marc.201800876.
@article{osti_1494201,
title = {Non‐Tacky Fluorinated and Elastomeric STEM Networks},
author = {Cuthbert, Julia and Martinez, Michael R. and Sun, Mingkang and Flum, Jacob and Li, Lingchun and Olszewski, Mateusz and Wang, Zhenhua and Kowalewski, Tomasz and Matyjaszewski, Krzysztof},
abstractNote = {Abstract Soft, elastomeric, non‐tacky polymer networks are synthesized by reversible deactivation radical polymerization (RDRP). First, the pristine, structurally tailored and engineered macromolecular (STEM) networks are synthesized by reversible addition–fragmentation chain transfer (RAFT) polymerization and incorporated an atom transfer radical polymerization (ATRP) inimer into the network. Subsequently, poly( n ‐butyl acrylate) (PBA) and/or poly(octafluoropentyl acrylate) (POFPA) side chains are grafted from the network by photo‐induced ATRP. These low glass transition temperature side chains produced soft materials ( E = 104–178 kPa). However, only the POFPA‐containing networks are also non‐tacky. The fluorine content and material properties are investigated by dynamic mechanical analysis, elemental analysis, spectroscopy, and contact angle measurements.},
doi = {10.1002/marc.201800876},
journal = {Macromolecular Rapid Communications},
number = 10,
volume = 40,
place = {Germany},
year = {Sun Feb 10 00:00:00 EST 2019},
month = {Sun Feb 10 00:00:00 EST 2019}
}
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