Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides

Juillerat, Christian A.; Klepov, Vladislav V.; Morrison, Gregory; Pace, Kristen A.; zur Loye, Hans-Conrad

doi:10.1039/C8DT04675A

Title: Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides

Journal Article · Tue Mar 05 00:00:00 UTC 2019 · Dalton Transactions

DOI: https://doi.org/10.1039/C8DT04675A · OSTI ID:1493075

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Department of Chemistry and Biochemistry, Center for Hierarchical Wasteform Materials, University of South Carolina, Columbia, USA

Molten flux crystal growth is a thriving field for the discovery of uranium oxides.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016574

OSTI ID:: 1493075

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 10 Vol. 48; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Polarity and Chirality in Uranyl Borates: Insights into Understanding the Vitrification of Nuclear Waste and the Development of Nonlinear Optical Materials Wang, Shuao; Alekseev, Evgeny V.; Ling, Jie Chemistry of Materials, Vol. 22, Issue 6 https://doi.org/10.1021/cm9037796	journal	March 2010
Magnetic Susceptibility of Uranium Complexes Kindra, Douglas R.; Evans, William J. Chemical Reviews, Vol. 114, Issue 18 https://doi.org/10.1021/cr500242w	journal	August 2014
Syntheses and Crystal Structures of Two Topologically Related Modifications of Cs ₂ [(UO ₂ ) ₂ (MoO ₄ ) ₃ ] Krivovichev, S. V.; Cahill, C. L.; Burns, P. C. Inorganic Chemistry, Vol. 41, Issue 1 https://doi.org/10.1021/ic010345y	journal	January 2002
Synthesis and Structure of Ag ₆ [(UO ₂ ) ₃ O(MoO ₄ ) ₅ ]: A Novel Sheet of Triuranyl Clusters and MoO ₄ Tetrahedra Krivovichev, Sergey V.; Burns, Peter C. Inorganic Chemistry, Vol. 41, Issue 16 https://doi.org/10.1021/ic025662z	journal	August 2002
An Unprecedented Uranyl Phosphate Framework in the Structure of [(UO ₂ ) ₃ (PO ₄ )O(OH)(H ₂ O) ₂ ](H ₂ O) Burns, Peter C.; Alexopoulos, Cara M.; Hotchkiss, Peter J. Inorganic Chemistry, Vol. 43, Issue 6 https://doi.org/10.1021/ic0348547	journal	March 2004
Cs ₃ UGe ₇ O ₁₈ : A Pentavalent Uranium Germanate Containing Four- and Six-Coordinate Germanium Nguyen, Quang Bac; Chen, Chun-Liang; Chiang, Yun-Wei Inorganic Chemistry, Vol. 51, Issue 6 https://doi.org/10.1021/ic3000872	journal	March 2012
Flux Synthesis, Crystal Structure, and Photoluminescence of a Heterometallic Uranyl-Europium Germanate with U═O–Eu Linkage: K ₄ [(UO ₂ )Eu ₂ (Ge ₂ O ₇ ) ₂ ] Liu, Shih-Pu; Chen, Meng-Ling; Chang, Bor-Chen Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic302826u	journal	June 2012
High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na ₉ F ₂ ][(U ^V O ₂ )(U ^VI O ₂ ) ₂ (Si ₂ O ₇ ) ₂ ] Chang, Yu-Chih; Chang, Wen-Jung; Boudin, Sophie Inorganic Chemistry, Vol. 52, Issue 12 https://doi.org/10.1021/ic400854j	journal	May 2013
Synthesis and Structure of the [(UO ₂ )S ₄ ] ^6– Anion: A Cation-Stabilized Uranyl Sulfide Ward, Matthew D.; Klingsporn, Jordan M.; Ibers, James A. Inorganic Chemistry, Vol. 52, Issue 18 https://doi.org/10.1021/ic401382g	journal	September 2013
Highly Distorted Uranyl Ion Coordination and One/Two-Dimensional Structural Relationship in the Ba ₂ [UO ₂ (TO ₄ ) ₂ ] (T = P, As) System: An Experimental and Computational Study Wu, Shijun; Kowalski, Piotr M.; Yu, Na Inorganic Chemistry, Vol. 53, Issue 14 https://doi.org/10.1021/ic500965v	journal	June 2014
One-Dimensional Array of Two- and Three-Center Cation−Cation Bonds in the Structure of Li ₄ [(UO ₂ ) ₁₀ O ₁₀ (Mo ₂ O ₈ )] Alekseev, Evgeny V.; Krivovichev, Sergey V.; Malcherek, Thomas Inorganic Chemistry, Vol. 46, Issue 21 https://doi.org/10.1021/ic7009385	journal	October 2007
K ₃ (U ₃ O ₆ )(Si ₂ O ₇ ) and Rb ₃ (U ₃ O ₆ )(Ge ₂ O ₇ ): A Pentavalent-Uranium Silicate and Germanate Lin, Chia-Hui; Chen, Chih-Shan; Shiryaev, A. A. Inorganic Chemistry, Vol. 47, Issue 11 https://doi.org/10.1021/ic800300v	journal	June 2008
Reinvestigation of the Uranium(3.5+) Rare-Earth Oxysulfides “(UO) ₂ LnS ₃ ” (Ln = Yb, Y) Jin, Geng Bang; Choi, Eun Sang; Ibers, James A. Inorganic Chemistry, Vol. 48, Issue 17 https://doi.org/10.1021/ic900860c	journal	September 2009
Flux Synthesis of Salt-Inclusion Uranyl Silicates: [K ₃ Cs ₄ F][(UO ₂ ) ₃ (Si ₂ O ₇ ) ₂ ] and [NaRb ₆ F][(UO ₂ ) ₃ (Si ₂ O ₇ ) ₂ ] Lee, Cheng-Shiuan; Wang, Sue-Lein; Chen, Yen-Hung Inorganic Chemistry, Vol. 48, Issue 17 https://doi.org/10.1021/ic901001n	journal	September 2009
How are Centrosymmetric and Noncentrosymmetric Structures Achieved in Uranyl Borates? Wang, Shuao; Alekseev, Evgeny V.; Stritzinger, Jared T. Inorganic Chemistry, Vol. 49, Issue 6 https://doi.org/10.1021/ic902480n	journal	March 2010
K(UO)Si ₂ O ₆ : A Pentavalent−Uranium Silicate Chen, Chih-Shan; Lee, Shang-Fan; Lii, Kwang-Hwa Journal of the American Chemical Society, Vol. 127, Issue 35 https://doi.org/10.1021/ja0543853	journal	September 2005
Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with U ^VI ═O–Ln ^III Bonding (Ln = Ce, Nd) Volkringer, Christophe; Henry, Natacha; Grandjean, Stéphane Journal of the American Chemical Society, Vol. 134, Issue 2 https://doi.org/10.1021/ja209915n	journal	December 2011
Cs ₂ K(UO) ₂ Si ₄ O ₁₂ : A Mixed-Valence Uranium(IV,V) Silicate Lee, Cheng-Shiuan; Wang, Sue-Lein; Lii, Kwang-Hwa Journal of the American Chemical Society, Vol. 131, Issue 42 https://doi.org/10.1021/ja9071805	journal	October 2009
Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates Morrison, Gregory; Smith, Mark D.; zur Loye, Hans-Conrad Journal of the American Chemical Society, Vol. 138, Issue 22 https://doi.org/10.1021/jacs.6b03205	journal	May 2016
Crystal growth, structural characterization, cation–cation interaction classification, and optical properties of uranium( vi ) containing oxychlorides, A ₄ U ₅ O ₁₆ Cl ₂ (A = K, Rb), Cs ₅ U ₇ O ₂₂ Cl ₃ , and AUO ₃ Cl (A = Rb, Cs) Read, Cory Michael; Yeon, Jeongho; Smith, Mark D. CrystEngComm, Vol. 16, Issue 31 https://doi.org/10.1039/C4CE00281D	journal	January 2014
Flux crystal growth and structural analysis of two cesium uranium oxides, Cs _2.2 U ₅ O ₁₆ and Cs ₂ U ₄ O ₁₃ , containing multiple cation–cation interactions Morrison, Gregory; Read, Cory M.; Smith, Mark D. CrystEngComm, Vol. 17, Issue 9 https://doi.org/10.1039/C4CE02430C	journal	January 2015
Synthesis and structure of the new pentanary uranium( vi ) silicate, K ₄ CaUSi ₄ O ₁₄ , a member of a structural family related to fresnoite Morrison, Gregory; Smith, Mark D.; Tran, T. Thao CrystEngComm, Vol. 17, Issue 22 https://doi.org/10.1039/C5CE00504C	journal	January 2015
Overview of the crystal chemistry of the actinide chalcogenides: incorporation of the alkaline-earth elements Mesbah, Adel; Prakash, Jai; Ibers, James. A. Dalton Transactions, Vol. 45, Issue 41 https://doi.org/10.1039/C6DT02540D	journal	January 2016
Supercritical synthesis and topological analysis of K ₅ U ₅ O ₁₇ (OH) Felder, Justin B.; Smith, Mark D.; zur Loye, Hans-Conrad CrystEngComm, Vol. 19, Issue 25 https://doi.org/10.1039/C7CE00746A	journal	January 2017
Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates Pace, Kristen A.; Klepov, Vladislav V.; Morrison, Gregory Chemical Communications, Vol. 54, Issue 98 https://doi.org/10.1039/C8CC07789D	journal	January 2018
Nine isomorphous lanthanide–uranyl f–f bimetallic materials with 2-thiophenecarboxylic acid and terpyridine: structure and concomitant luminescent properties Ridenour, J. August; Cahill, Christopher L. CrystEngComm, Vol. 20, Issue 34 https://doi.org/10.1039/C8CE00811F	journal	January 2018
Novel layered uranyl arsenates, Ag6[(UO2)2(As2O7)(As4O13)] and AI6[(UO2)2(AsO4)2(As2O7)] (AI–Ag and Na): first observation of a linear As4O136− anion and structure type evolution Alekseev, Evgeny V.; Krivovichev, Sergey V.; Depmeier, Wulf Journal of Materials Chemistry, Vol. 19, Issue 17 https://doi.org/10.1039/b818757f	journal	January 2009
Syntheses and characterization of some solid-state actinide (Th, U, Np) compounds Bugaris, Daniel E.; Ibers, James A. Dalton Transactions, Vol. 39, Issue 26 https://doi.org/10.1039/b927026d	journal	January 2010
Homometallic UO22+ diphosphonates assembled under ambient and hydrothermal conditions Knope, Karah E.; Cahill, Christopher L. Dalton Transactions, Vol. 39, Issue 35 https://doi.org/10.1039/c0dt00538j	journal	January 2010
Recent progress in actinide borate chemistry Wang, Shuao; Alekseev, Evgeny V.; Depmeier, Wulf Chemical Communications, Vol. 47, Issue 39 https://doi.org/10.1039/c1cc14023j	journal	January 2011
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Single-crystal structure of lead uranate(VI) Cremers, T. L.; Eller, P. G.; Larson, E. M. Acta Crystallographica Section C Crystal Structure Communications, Vol. 42, Issue 12 https://doi.org/10.1107/S0108270186090947	journal	December 1986
Synthèse et structure du borouranate de sodium, NaBUO5 Gasperin, M. Acta Crystallographica Section C Crystal Structure Communications, Vol. 44, Issue 3 https://doi.org/10.1107/S0108270187011405	journal	March 1988
Synthèse et structure du diborouranate de magnésium, MgB2UO7 Gasperin, M. Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 12 https://doi.org/10.1107/S0108270187088139	journal	December 1987
Synthèse et structure du borouranate de calcium: CaB2U2O10 Gasperin, M. Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 7 https://doi.org/10.1107/S0108270187092278	journal	July 1987
Synthèse et structure du niobouranate de césium: CsNbUO6 Gasperin, M. Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 3 https://doi.org/10.1107/S0108270187095581	journal	March 1987
Synthèse et structure du tétraborouranate de nickel, Ni7B4UO16 Gasperin, M. Acta Crystallographica Section C Crystal Structure Communications, Vol. 45, Issue 7 https://doi.org/10.1107/S010827018900020X	journal	July 1989
Synthèse et structure du borouranate de lithium LiBUO5 Gasperin, M. Acta Crystallographica Section C Crystal Structure Communications, Vol. 46, Issue 3 https://doi.org/10.1107/S0108270189007948	journal	March 1990
Structure de K9BiU6O24 Gasperin, M.; Rebizant, J.; Dancausse, J. P. Acta Crystallographica Section C Crystal Structure Communications, Vol. 47, Issue 11 https://doi.org/10.1107/S0108270191004973	journal	November 1991
Crystal chemical studies of the 5 f -series of elements. IV. The crystal structure of Ca(UO ₂ )O ₂ and Sr(UO ₂ )O ₂ Zachariasen, W. H. Acta Crystallographica, Vol. 1, Issue 6 https://doi.org/10.1107/S0365110X48000776	journal	December 1948
Crystal chemical studies of the 5 f -series of elements. XXI. The crystal structure of magnesium orthouranate Zachariasen, W. H. Acta Crystallographica, Vol. 7, Issue 12 https://doi.org/10.1107/S0365110X54002459	journal	December 1954
The crystal structure of caesium uranyl oxychloride Cs _x (UO ₂ )OCl _x ( x approximately 0.9) Allpress, J. G.; Wadsley, A. D. Acta Crystallographica, Vol. 17, Issue 1 https://doi.org/10.1107/S0365110X64000081	journal	January 1964
The crystal structure of Pb ₃ UO ₆ Sterns, M. Acta Crystallographica, Vol. 23, Issue 2 https://doi.org/10.1107/S0365110X67002580	journal	August 1967
Thermodynamic Assessment of P ₂ O ₅ Jung, In-Ho; Hudon, Pierre Journal of the American Ceramic Society, Vol. 95, Issue 11 https://doi.org/10.1111/j.1551-2916.2012.05382.x	journal	August 2012
Cation-cation interactions between uranyl(VI) ions Serezhkin, V. N.; Sidorenko, G. V.; Pushkin, D. V. Radiochemistry, Vol. 56, Issue 2 https://doi.org/10.1134/S1066362214020015	journal	March 2014
Notizen: Über Erdalkaliuranate (VI) und ihre Reduktionsprodukte Rüdorff, Walter; Pfitzer, Franz Zeitschrift für Naturforschung B, Vol. 9, Issue 8 https://doi.org/10.1515/znb-1954-0815	journal	August 1954
CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. III. NEW STRUCTURAL THEMES IN Na6[(UO2)2O(MoO4)4], Na6[(UO2)(MoO4)4] AND K6[(UO2)2O(MoO4)4] Krivovichev, S. V.; Burns, P. C. The Canadian Mineralogist, Vol. 39, Issue 1 https://doi.org/10.2113/gscanmin.39.1.197	journal	February 2001
CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VI. NEW URANYL MOLYBDATE UNITS IN THE STRUCTURES OF Cs4[(UO2)3O(MoO4)2(MoO5)] AND Cs6[(UO2)(MoO4)4] Krivovichev, S. V.; Burns, P. C. The Canadian Mineralogist, Vol. 40, Issue 1 https://doi.org/10.2113/gscanmin.40.1.201	journal	February 2002
U6+ Minerals and Inorganic Compounds: Insights into an Expanded Structural Hierarchy of Crystal Structures Burns, P. C. The Canadian Mineralogist, Vol. 43, Issue 6 https://doi.org/10.2113/gscanmin.43.6.1839	journal	December 2005
A Revised and Expanded Structure Hierarchy of Natural and Synthetic Hexavalent Uranium Compounds Lussier, Aaron J.; Lopez, Rachel A. K.; Burns, Peter C. The Canadian Mineralogist, Vol. 54, Issue 1 https://doi.org/10.3749/canmin.1500078	journal	January 2016

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