Enhanced Capacities of Mixed Fatty Acid-Modified Sawdust Aggregators for Remediation of Crude Oil Spill

Shin, Yongsoon; Winder, Eric M.; Han, Kee Sung; Lee, Hongkyung; Bonheyo, George T.

doi:10.1021/acsomega.8b02293

Title: Enhanced Capacities of Mixed Fatty Acid-Modified Sawdust Aggregators for Remediation of Crude Oil Spill

Journal Article · 07 January 2019 · ACS Omega

DOI: https://doi.org/10.1021/acsomega.8b02293 · OSTI ID:1489889

^[1]; Winder, Eric M. ^[2];

^[1];

^[1]; Bonheyo, George T. ^[2]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Materials Sciences
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Marine Science Lab.

Mixed fatty acid-modified aggregators have been developed as potential crude oil sorbents. Cheap pine wood flour was first modified with oleic acid (OA) and further modified with a second fatty acid by a leaving group chemistry, where a surface hydroxyl group is first replaced by p-toluenesulfonyl group and a fatty acid forms a covalent bond on sawdust surface through esterification at the elevated temperature (55 °C). Two OA-modified base materials, pine/OA-106 and pine/OA-124, with different OA-coverages were first prepared and the second fatty acids with C3, C6, C8, C10, C12, C14, or C16 alkyl chains were applied to cover the remaining surface hydroxyl groups. The crude oil sorption capacities of the mixed fatty acid-modified aggregators were studied and compared with those of the base materials. The results showed that mixed fatty acid-modified aggregators increased up to 45.6% more crude oil sorption than those of OA-modified base materials. A correlation between surface property and sorption capacity was studied by moisture sorption, Fourier transform infrared spectroscopy, X-ray diffraction, ¹³C cross polarization and magic angle spinning nuclear magnetic resonance, thermal gravimetric analysis, and scanning electron microscopy. To our knowledge, no report has been published for mixed fatty acid-modified herders or aggregators in the environmental remediation.

View Journal Article

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER); PNNL Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1489889

Alternate ID(s):: OSTI ID: 1507395; OSTI ID: 1512783

Report Number(s):: PNNL-SA-135555

Journal Information:: ACS Omega, Vol. 4, Issue 1; ISSN 2470-1343

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 3 works

Citation information provided by
Web of Science

References (29)

Characterization and acetylation behavior of bamboo pulp Yang, Zhanping; Xu, Songwei; Ma, Xiaolong Wood Science and Technology, Vol. 42, Issue 8 https://doi.org/10.1007/s00226-008-0194-5	journal	April 2008
Hydrocarbon-utilizing microorganisms naturally associated with sawdust Ali, N.; Eliyas, M.; Al-Sarawi, H. Chemosphere, Vol. 83, Issue 9 https://doi.org/10.1016/j.chemosphere.2011.03.052	journal	May 2011
Experimental investigation of various vegetable fibers as sorbent materials for oil spills Annunciado, T. R.; Sydenstricker, T. H. D.; Amico, S. C. Marine Pollution Bulletin, Vol. 50, Issue 11 https://doi.org/10.1016/j.marpolbul.2005.04.043	journal	November 2005
The 2010 oil spill in the Gulf of Mexico: What would Mother Nature do? Mitsch, William J. Ecological Engineering, Vol. 36, Issue 12 https://doi.org/10.1016/j.ecoleng.2010.08.009	journal	December 2010
Hydrophobic treatment of corn cob by acetylation: Kinetics and thermodynamics studies Nwadiogbu, Joseph O.; Okoye, Patrice A. C.; Ajiwe, Vincent I. Journal of Environmental Chemical Engineering, Vol. 2, Issue 3 https://doi.org/10.1016/j.jece.2014.06.003	journal	September 2014
Characterization of Ultrathin Films of Cellulose Esters Kosaka, P. M.; Kawano, Y.; Salvadori, M. C. Microscopy and Microanalysis, Vol. 11, Issue S03 https://doi.org/10.1017/s143192760505097x	journal	December 2005
Carbon-13 nuclear magnetic resonance spectrometric study of wood and wood pulping with cross polarization and magic-angle spinning Haw, James F.; Maciel, Gary E.; Schroeder, Herbert A. Analytical Chemistry, Vol. 56, Issue 8 https://doi.org/10.1021/ac00272a028	journal	July 1984
Acetylation of sugarcane bagasse using NBS as a catalyst under mild reaction conditions for the production of oil sorption-active materials Sun, X. Bioresource Technology, Vol. 95, Issue 3 https://doi.org/10.1016/j.biortech.2004.02.025	journal	December 2004
Degradation of Lignin in Wheat Straw during Growth of the Oyster Mushroom (Pleurotus ostreatus) Using Off-line Thermochemolysis with Tetramethylammonium Hydroxide and Solid-State ¹³C NMR Vane, Christopher H.; Martin, Shona C.; Snape, Colin E. Journal of Agricultural and Food Chemistry, Vol. 49, Issue 6 https://doi.org/10.1021/jf001409a	journal	May 2001
Investigation of the effectiveness of absorbent materials in oil spills clean up Teas, Ch.; Kalligeros, S.; Zanikos, F. Desalination, Vol. 140, Issue 3 https://doi.org/10.1016/S0011-9164(01)00375-7	journal	November 2001
The 2010 oil spill in the Gulf of Mexico: What would Mother Nature do? Mitsch, William J. Ecological Engineering, Vol. 36, Issue 12 https://doi.org/10.1016/j.ecoleng.2010.08.009	journal	December 2010
Experimental investigation of various vegetable fibers as sorbent materials for oil spills Annunciado, T. R.; Sydenstricker, T. H. D.; Amico, S. C. Marine Pollution Bulletin, Vol. 50, Issue 11 https://doi.org/10.1016/j.marpolbul.2005.04.043	journal	November 2005
Oil Spill Cleanup from Sea Water by Sorbent Materials Bayat, A.; Aghamiri, S. F.; Moheb, A. Chemical Engineering & Technology, Vol. 28, Issue 12 https://doi.org/10.1002/ceat.200407083	journal	December 2005
Rational design of materials interface at nanoscale towards intelligent oil–water separation Ge, Mingzheng; Cao, Chunyan; Huang, Jianying Nanoscale Horizons, Vol. 3, Issue 3 https://doi.org/10.1039/C7NH00185A	journal	January 2018
Constructing multifunctional MOF@rGO hydro-/aerogels by the self-assembly process for customized water remediation Mao, Jiajun; Ge, Mingzheng; Huang, Jianying Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA01343D	journal	January 2017
Robust fluorine-free superhydrophobic PDMS–ormosil@fabrics for highly effective self-cleaning and efficient oil–water separation Cao, Chunyan; Ge, Mingzheng; Huang, Jianying Journal of Materials Chemistry A, Vol. 4, Issue 31 https://doi.org/10.1039/C6TA04420D	journal	January 2016
Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil-water separation Gao, Shouwei; Dong, Xiuli; Huang, Jianying Chemical Engineering Journal, Vol. 333 https://doi.org/10.1016/j.cej.2017.10.006	journal	February 2018
Hydrophobic treatment of corn cob by acetylation: Kinetics and thermodynamics studies Nwadiogbu, Joseph O.; Okoye, Patrice A. C.; Ajiwe, Vincent I. Journal of Environmental Chemical Engineering, Vol. 2, Issue 3 https://doi.org/10.1016/j.jece.2014.06.003	journal	September 2014
Acetylation of sugarcane bagasse using NBS as a catalyst under mild reaction conditions for the production of oil sorption-active materials Sun, X. Bioresource Technology, Vol. 95, Issue 3 https://doi.org/10.1016/j.biortech.2004.02.025	journal	December 2004
Hydrocarbon-utilizing microorganisms naturally associated with sawdust Ali, N.; Eliyas, M.; Al-Sarawi, H. Chemosphere, Vol. 83, Issue 9 https://doi.org/10.1016/j.chemosphere.2011.03.052	journal	May 2011
Characterization of Ultrathin Films of Cellulose Esters Kosaka, P. M.; Kawano, Y.; Salvadori, M. C. Cellulose, Vol. 12, Issue 4 https://doi.org/10.1007/s10570-005-2205-0	journal	August 2005
Characterization and acetylation behavior of bamboo pulp Yang, Zhanping; Xu, Songwei; Ma, Xiaolong Wood Science and Technology, Vol. 42, Issue 8 https://doi.org/10.1007/s00226-008-0194-5	journal	April 2008
Exhaustive crystal structure search and crystal modeling of β-chitin Yui, Toshifumi; Taki, Naoto; Sugiyama, Junji International Journal of Biological Macromolecules, Vol. 40, Issue 4 https://doi.org/10.1016/j.ijbiomac.2006.08.017	journal	March 2007
Magnetic Resonance Studies of Hierarchically Ordered Replicas of Wood Cellular Structures Prepared by Surfactant-Mediated Mineralization Wang, Li-Qiong; Shin, Yongsoon; Samuels, W. D. The Journal of Physical Chemistry B, Vol. 107, Issue 50 https://doi.org/10.1021/jp030027f	journal	November 2003
Carbon-13 nuclear magnetic resonance spectrometric study of wood and wood pulping with cross polarization and magic-angle spinning Haw, James F.; Maciel, Gary E.; Schroeder, Herbert A. Analytical Chemistry, Vol. 56, Issue 8 https://doi.org/10.1021/ac00272a028	journal	July 1984
Degradation of Lignin in Wheat Straw during Growth of the Oyster Mushroom (Pleurotus ostreatus) Using Off-line Thermochemolysis with Tetramethylammonium Hydroxide and Solid-State ¹³C NMR Vane, Christopher H.; Martin, Shona C.; Snape, Colin E. Journal of Agricultural and Food Chemistry, Vol. 49, Issue 6 https://doi.org/10.1021/jf001409a	journal	May 2001
Fibrous long-chain organic acid cellulose esters and their characterization by diffuse reflectance FTIR spectroscopy, solid-state CP/MAS13C-NMR, and X-ray diffraction Jandura, Peter; Kokta, Bohuslav V.; Riedl, Bernard Journal of Applied Polymer Science, Vol. 78, Issue 7 https://doi.org/10.1002/1097-4628(20001114)78:7<1354::AID-APP60>3.0.CO;2-V	journal	January 2000
Heterogeneous modification of various celluloses with fatty acids Uschanov, Pirita; Johansson, Leena-Sisko; Maunu, Sirkka Liisa Cellulose, Vol. 18, Issue 2 https://doi.org/10.1007/s10570-010-9478-7	journal	December 2010
NMR studies of wood and wood products Maunu, S. L. Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 40, Issue 2 https://doi.org/10.1016/S0079-6565(01)00041-3	journal	February 2002

Figures / Tables (9)

Similar Records

Elongation of exogenous fatty acids by the bioluminescent bacterium Vibrio harveyi

Journal Article · 1989 · J. Bacteriol.; (United States) · OSTI ID:6325588

Byers, D M

Novel Bioplastics and biocomposites from Vegetable Oils

Thesis/Dissertation · 2008 · OSTI ID:939375

Henna, Phillip H.

The series of carbon-chain complexes {Ru(dppe)Cp*}₂{μ-(C≡C_)x} (x = 4–8, 11): Synthesis, structures, properties and some reactions

Journal Article · 2015 · Polyhedron · OSTI ID:1171266

Bruce, Michael I.; Cole, Marcus L.; Ellis, Benjamin G.; +5 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
carbonyl compounds (organic)
granular materials
phase
remediation
water purification
Superhydrophobic
Sorption capacity
Crude oil
Aggregator
fatty acids

Title: Enhanced Capacities of Mixed Fatty Acid-Modified Sawdust Aggregators for Remediation of Crude Oil Spill

Citation Formats

References (29)

Figures / Tables (9)

Similar Records

Related Subjects