Metallic Ti3C2Tx MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio

Kim, Seon Joon; Koh, Hyeong -Jun; Ren, Chang E.; Kwon, Ohmin; Maleski, Kathleen; Cho, Soo -Yeon; Anasori, Babak; Kim, Choong -Ki; Choi, Yang -Kyu; Kim, Jihan; Gogotsi, Yury; Jung, Hee -Tae

doi:10.1021/acsnano.7b07460

Title: Metallic Ti₃C₂T_x MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio

Journal Article · 24 January 2018 · ACS Nano

DOI: https://doi.org/10.1021/acsnano.7b07460 · OSTI ID:1488925

Kim, Seon Joon ^[1]; Koh, Hyeong -Jun ^[1]; Ren, Chang E. ^[2]; Kwon, Ohmin ^[3];

^[2]; Cho, Soo -Yeon ^[1];

^[2]; Kim, Choong -Ki ^[4];

^[4]; Kim, Jihan ^[5];

^[2];

^[6]

Korea Advanced Institute of Science and Technology (KAIST), Daejeon (Korea). National Research Lab. for Organic Optoelectronic Materials
Drexel Univ., Philadelphia, PA (United States). A.J. Drexel Nanomaterials Institute
Korea Advanced Institute of Science and Technology (KAIST), Daejeon (Korea). Dept. of Chemical and Biomolecular Engineering (BK-21 Plus)
Korea Advanced Institute of Science and Technology (KAIST), Daejeon (Korea). School of Electrical Engineering
Korea Advanced Institute of Science and Technology (KAIST), Daejeon (Korea). Dept. of Chemical and Biomolecular Engineering (BK-21 Plus) and KAIST Inst. for Nanocentury
Korea Advanced Institute of Science and Technology (KAIST), Daejeon (Korea). National Research Lab. for Organic Optoelectronic Materials and KAIST Inst. for Nanocentury

Achieving high sensitivity in solid-state gas sensors can allow the precise detection of chemical agents. In particular, detection of volatile organic compounds (VOCs) at the parts per billion (ppb) level is critical for the early diagnosis of diseases. To obtain high sensitivity, two requirements need to be simultaneously satisfied: (i) low electrical noise and (ii) strong signal, which existing sensor materials cannot meet. Here, we demonstrate that 2D metal carbide MXenes, which possess high metallic conductivity for low noise and a fully functionalized surface for a strong signal, greatly outperform the sensitivity of conventional semiconductor channel materials. Ti₃C₂T_x MXene gas sensors exhibited a very low limit of detection of 50–100 ppb for VOC gases at room temperature. Also, the extremely low noise led to a signal-to-noise ratio 2 orders of magnitude higher than that of other 2D materials, surpassing the best sensors known. Furthermore, our results provide insight in utilizing highly functionalized metallic sensing channels for developing highly sensitive sensors.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1488925

Journal Information:: ACS Nano, Journal Name: ACS Nano Journal Issue: 2 Vol. 12; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes) Hantanasirisakul, Kanit; Gogotsi, Yury Advanced Materials, Vol. 30, Issue 52 https://doi.org/10.1002/adma.201804779	journal	November 2018
Two-dimensional MXene-reinforced robust surface superhydrophobicity with self-cleaning and photothermal-actuating binary effects Cao, Wen-Tao; Feng, Wei; Jiang, Ying-Ying Materials Horizons, Vol. 6, Issue 5 https://doi.org/10.1039/c8mh01566j	journal	January 2019
Recent Advances in Emerging 2D Material‐Based Gas Sensors: Potential in Disease Diagnosis Zhang, Lu; Khan, Karim; Zou, Jifei Advanced Materials Interfaces, Vol. 6, Issue 22 https://doi.org/10.1002/admi.201901329	journal	September 2019
Realization of vertical metal semiconductor heterostructures via solution phase epitaxy. Wang, Xiaoshan; Wang, Zhiwei; Zhang, Jindong Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.27947	text	January 2018
Two-dimensional materials for gas sensors: from first discovery to future possibilities Barzegar, Maryam; Tudu, Bharati Surface Innovations, Vol. 6, Issue 4–5 https://doi.org/10.1680/jsuin.18.00013	journal	September 2018
Wearable Electronics Based on 2D Materials for Human Physiological Information Detection Pang, Yu; Yang, Zhen; Yang, Yi Small, Vol. 16, Issue 15 https://doi.org/10.1002/smll.201901124	journal	July 2019
Control of MXenes’ electronic properties through termination and intercalation Hart, James L.; Hantanasirisakul, Kanit; Lang, Andrew C. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-018-08169-8	journal	January 2019
First-Principles Studies of Adsorptive Remediation of Water and Air Pollutants Using Two-Dimensional MXene Materials Zhang, Yujuan; Zhang, Ningning; Ge, Changchun Materials, Vol. 11, Issue 11 https://doi.org/10.3390/ma11112281	journal	November 2018
pH-Response of polycation/Ti ₃ C ₂ T _x MXene layer-by-layer assemblies for use as resistive sensors Echols, Ian J.; An, Hyosung; Zhao, Xiaofei Molecular Systems Design & Engineering, Vol. 5, Issue 1 https://doi.org/10.1039/c9me00142e	journal	January 2020
Recent developments in emerging two-dimensional materials and their applications Khan, Karim; Tareen, Ayesha Khan; Aslam, Muhammad Journal of Materials Chemistry C, Vol. 8, Issue 2 https://doi.org/10.1039/c9tc04187g	journal	January 2020
Scalable Synthesis of Ti ₃ C ₂ T _x MXene Shuck, Christopher E.; Sarycheva, Asia; Anayee, Mark Advanced Engineering Materials, Vol. 22, Issue 3 https://doi.org/10.1002/adem.201901241	journal	March 2020
Novel gas sensing platform based on a stretchable laser-induced graphene pattern with self-heating capabilities Yang, Li; Yi, Ning; Zhu, Jia Journal of Materials Chemistry A, Vol. 8, Issue 14 https://doi.org/10.1039/c9ta07855j	journal	January 2020
Realization of vertical metal semiconductor heterostructures via solution phase epitaxy Wang, Xiaoshan; Wang, Zhiwei; Zhang, Jindong Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06053-z	journal	September 2018
Review— Recent Exploration of Two-Dimensional MXenes for Gas Sensing: From a Theoretical to an Experimental View Lee, Eunji; Kim, Dong-Joo Journal of The Electrochemical Society, Vol. 167, Issue 3 https://doi.org/10.1149/2.0152003jes	journal	January 2020
MXene and MXene-based composites: synthesis, properties and environment-related applications Zhan, Xiaoxue; Si, Chen; Zhou, Jian Nanoscale Horizons, Vol. 5, Issue 2 https://doi.org/10.1039/c9nh00571d	journal	January 2020
Configurable multi-state non-volatile memory behaviors in Ti ₃ C ₂ nanosheets Ding, Guanglong; Zeng, Kelin; Zhou, Kui Nanoscale, Vol. 11, Issue 15 https://doi.org/10.1039/c9nr00747d	journal	January 2019
Rapid and Low‐Temperature Salt‐Templated Production of 2D Metal Oxide/Oxychloride/Hydroxide Gu, Jianan; Zhang, Chao; Du, Zhiguo Small, Vol. 15, Issue 45 https://doi.org/10.1002/smll.201904587	journal	September 2019
Nanohybrids of a MXene and transition metal dichalcogenide for selective detection of volatile organic compounds Chen, Winston Yenyu; Jiang, Xiaofan; Lai, Sz-Nian Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15092-4	journal	March 2020
Lightweight and flexible MXene/CNF/silver composite membranes with a brick-like structure and high-performance electromagnetic-interference shielding Xin, Wei; Xi, Guo-Qiang; Cao, Wen-Tao RSC Advances, Vol. 9, Issue 51 https://doi.org/10.1039/c9ra06399d	journal	January 2019
Realization of vertical metal semiconductor heterostructures via solution phase epitaxy Wang, Xiaoshan; Wang, Zhiwei; Zhang, Jindong Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06053-z	journal	September 2018
State of the Art in Alcohol Sensing with 2D Materials Boroujerdi, Ramin; Abdelkader, Amor; Paul, Richard Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.62514	text	January 2020
A highly flexible and multifunctional strain sensor based on a network-structured MXene/polyurethane mat with ultra-high sensitivity and a broad sensing range Yang, Kai; Yin, Fuxing; Xia, Dan Nanoscale, Vol. 11, Issue 20 https://doi.org/10.1039/c9nr00488b	journal	January 2019

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