Improved Models for Metallic Nanoparticle Cores from Atomic Pair Distribution Function (PDF) Analysis
Abstract
X-ray atomic pair distribution functions (PDFs) were collected from a range of canonical metallic nanomaterials, both elemental and alloyed, prepared using different synthesis methods and exhibiting drastically different morphological properties. Widely applied shape-tuned attenuated crystal (AC) fcc models proved inadequate, yielding structured, coherent, and correlated fit residuals. However, equally simple discrete cluster models could account for the largest amplitude features in these difference signals. A hypothesis testing based approach to nanoparticle structure modeling systematically ruled out effects from crystallite size, composition, shape, and surface faceting as primary factors contributing to the AC misfit. On the other hand, decahedrally twinned cluster cores were found to be the origin of the AC structure misfits for a majority of the nanomaterials reported here. It is further motivated that the PDF can readily differentiate between the arrangement of domains in these multiply twinned motifs. Most of the nanomaterials surveyed also fall within the sub-5 nm size regime where traditional electron microscopy cannot easily detect and quantify domain structures, with sampling representative of the average nanocrystal synthesized. Here, the results demonstrate that PDF analysis is a powerful method for understanding internal atomic interfaces in small noble metallic nanomaterials. Such core cluster models, easily built algorithmically,more »
- Authors:
-
[1];
[2];
[6];
[6];
[4];
[8]
- Columbia Univ., New York, NY (United States)
- Univ. of Pennsylvania, Philadelphia, PA (United States)
- Univ. of Copenhagen, Copenhagen (Denmark)
- Univ. of Duisburg-Essen, Essen (Germany)
- State Univ. of New York at Stony Brook, Stony Brook, NY (United States); Fordham Univ., Bronx, NY (United States)
- State Univ. of New York at Stony Brook, Stony Brook, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Columbia Univ., New York, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI); Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1487255
- Report Number(s):
- BNL-209757-2018-JAAM
Journal ID: ISSN 1932-7447
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 122; Journal Issue: 51; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Banerjee, Soham, Liu, Chia -Hao, Lee, Jennifer D., Kovyakh, Anton, Grasmik, Viktoria, Prymak, Oleg, Koenigsmann, Christopher, Liu, Haiqing, Wang, Lei, Abeykoon, A. M. Milinda, Wong, Stanislaus S., Epple, Matthias, Murray, Christopher B., and Billinge, Simon J. L. Improved Models for Metallic Nanoparticle Cores from Atomic Pair Distribution Function (PDF) Analysis. United States: N. p., 2018.
Web. doi:10.1021/acs.jpcc.8b05897.
Banerjee, Soham, Liu, Chia -Hao, Lee, Jennifer D., Kovyakh, Anton, Grasmik, Viktoria, Prymak, Oleg, Koenigsmann, Christopher, Liu, Haiqing, Wang, Lei, Abeykoon, A. M. Milinda, Wong, Stanislaus S., Epple, Matthias, Murray, Christopher B., & Billinge, Simon J. L. Improved Models for Metallic Nanoparticle Cores from Atomic Pair Distribution Function (PDF) Analysis. United States. https://doi.org/10.1021/acs.jpcc.8b05897
Banerjee, Soham, Liu, Chia -Hao, Lee, Jennifer D., Kovyakh, Anton, Grasmik, Viktoria, Prymak, Oleg, Koenigsmann, Christopher, Liu, Haiqing, Wang, Lei, Abeykoon, A. M. Milinda, Wong, Stanislaus S., Epple, Matthias, Murray, Christopher B., and Billinge, Simon J. L. Mon .
"Improved Models for Metallic Nanoparticle Cores from Atomic Pair Distribution Function (PDF) Analysis". United States. https://doi.org/10.1021/acs.jpcc.8b05897. https://www.osti.gov/servlets/purl/1487255.
@article{osti_1487255,
title = {Improved Models for Metallic Nanoparticle Cores from Atomic Pair Distribution Function (PDF) Analysis},
author = {Banerjee, Soham and Liu, Chia -Hao and Lee, Jennifer D. and Kovyakh, Anton and Grasmik, Viktoria and Prymak, Oleg and Koenigsmann, Christopher and Liu, Haiqing and Wang, Lei and Abeykoon, A. M. Milinda and Wong, Stanislaus S. and Epple, Matthias and Murray, Christopher B. and Billinge, Simon J. L.},
abstractNote = {X-ray atomic pair distribution functions (PDFs) were collected from a range of canonical metallic nanomaterials, both elemental and alloyed, prepared using different synthesis methods and exhibiting drastically different morphological properties. Widely applied shape-tuned attenuated crystal (AC) fcc models proved inadequate, yielding structured, coherent, and correlated fit residuals. However, equally simple discrete cluster models could account for the largest amplitude features in these difference signals. A hypothesis testing based approach to nanoparticle structure modeling systematically ruled out effects from crystallite size, composition, shape, and surface faceting as primary factors contributing to the AC misfit. On the other hand, decahedrally twinned cluster cores were found to be the origin of the AC structure misfits for a majority of the nanomaterials reported here. It is further motivated that the PDF can readily differentiate between the arrangement of domains in these multiply twinned motifs. Most of the nanomaterials surveyed also fall within the sub-5 nm size regime where traditional electron microscopy cannot easily detect and quantify domain structures, with sampling representative of the average nanocrystal synthesized. Here, the results demonstrate that PDF analysis is a powerful method for understanding internal atomic interfaces in small noble metallic nanomaterials. Such core cluster models, easily built algorithmically, should serve as starting structures for more advanced models able to capture atomic positional disorder, ligand induced or otherwise, near nanocrystal surfaces.},
doi = {10.1021/acs.jpcc.8b05897},
journal = {Journal of Physical Chemistry. C},
number = 51,
volume = 122,
place = {United States},
year = {Mon Nov 26 00:00:00 EST 2018},
month = {Mon Nov 26 00:00:00 EST 2018}
}
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Works referenced in this record:
Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies
journal, August 2000
- Murray, C. B.; Kagan, C. R.; Bawendi, M. G.
- Annual Review of Materials Science, Vol. 30, Issue 1, p. 545-610
Nanoparticles for Catalysis
journal, April 2013
- Xia, Younan; Yang, Hong; Campbell, Charles T.
- Accounts of Chemical Research, Vol. 46, Issue 8
Nanostructures in Biodiagnostics
journal, April 2005
- Rosi, Nathaniel L.; Mirkin, Chad A.
- Chemical Reviews, Vol. 105, Issue 4, p. 1547-1562
Inorganic Nanoparticles as Carriers of Nucleic Acids into Cells
journal, February 2008
- Sokolova, Viktoriya; Epple, Matthias
- Angewandte Chemie International Edition, Vol. 47, Issue 8
Enhanced Electrocatalytic Performance of Processed, Ultrathin, Supported Pd–Pt Core–Shell Nanowire Catalysts for the Oxygen Reduction Reaction
journal, June 2011
- Koenigsmann, Christopher; Santulli, Alexander C.; Gong, Kuanping
- Journal of the American Chemical Society, Vol. 133, Issue 25
Semiconductor Clusters, Nanocrystals, and Quantum Dots
journal, February 1996
- Alivisatos, A. P.
- Science, Vol. 271, Issue 5251, p. 933-937
Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005
- Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
- Nature Materials, Vol. 4, Issue 5, p. 366-377
Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology
journal, December 2003
- Daniel, Marie-Christine; Astruc, Didier
- Chemical Reviews, Vol. 104, Issue 1
Nonclassical nucleation and growth of inorganic nanoparticles
journal, June 2016
- Lee, Jisoo; Yang, Jiwoong; Kwon, Soon Gu
- Nature Reviews Materials, Vol. 1, Issue 8
The Problem with Determining Atomic Structure at the Nanoscale
journal, April 2007
- Billinge, S. J. L.; Levin, I.
- Science, Vol. 316, Issue 5824
Nanosized Pd145(CO)x(PEt3)30 Containing a Capped Three-Shell 145-Atom Metal-Core Geometry of Pseudo Icosahedral Symmetry
journal, November 2000
- Tran, Nguyet T.; Powell, Douglas R.; Dahl, Lawrence F.
- Angewandte Chemie, Vol. 39, Issue 22
Plasmonic twinned silver nanoparticles with molecular precision
journal, September 2016
- Yang, Huayan; Wang, Yu; Chen, Xi
- Nature Communications, Vol. 7, Issue 1
Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 A Resolution
journal, October 2007
- Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.
- Science, Vol. 318, Issue 5849
Crystal Structure of Faradaurate-279: Au 279 (SPh- t Bu) 84 Plasmonic Nanocrystal Molecules
journal, October 2017
- Sakthivel, Naga Arjun; Theivendran, Shevanuja; Ganeshraj, Vigneshraja
- Journal of the American Chemical Society, Vol. 139, Issue 43
MicroED Structure of Au 146 (p-MBA) 57 at Subatomic Resolution Reveals a Twinned FCC Cluster
journal, October 2017
- Vergara, Sandra; Lukes, Dylan A.; Martynowycz, Michael W.
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 22
Atomic electron tomography: 3D structures without crystals
journal, September 2016
- Miao, J.; Ercius, P.; Billinge, S. J. L.
- Science, Vol. 353, Issue 6306
PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals
journal, July 2007
- Farrow, C. L.; Juhas, P.; Liu, J. W.
- Journal of Physics: Condensed Matter, Vol. 19, Issue 33
Quantitative size-dependent structure and strain determination of CdSe nanoparticles using atomic pair distribution function analysis
journal, September 2007
- Masadeh, A. S.; Božin, E. S.; Farrow, C. L.
- Physical Review B, Vol. 76, Issue 11
Confirmation of disordered structure of ultrasmall CdSe nanoparticles from X-ray atomic pair distribution function analysis
journal, January 2013
- Yang, Xiaohao; Masadeh, Ahmad S.; McBride, James R.
- Physical Chemistry Chemical Physics, Vol. 15, Issue 22
Evidence for Anomalous Bond Softening and Disorder Below 2 nm Diameter in Carbon-Supported Platinum Nanoparticles from the Temperature-Dependent Peak Width of the Atomic Pair Distribution Function
journal, March 2013
- Shi, Chenyang; Redmond, Erin L.; Mazaheripour, Amir
- The Journal of Physical Chemistry C, Vol. 117, Issue 14
Robust structure and morphology parameters for CdS nanoparticles by combining small-angle X-ray scattering and atomic pair distribution function data in a complex modeling framework
journal, March 2014
- Farrow, Christopher L.; Shi, Chenyang; Juhás, Pavol
- Journal of Applied Crystallography, Vol. 47, Issue 2
Finite size effects of nanoparticles on the atomic pair distribution functions
journal, October 2006
- Kodama, Katsuaki; Iikubo, Satoshi; Taguchi, Tomitsugu
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 62, Issue 6, p. 444-453
Structural and Architectural Evaluation of Bimetallic Nanoparticles: A Case Study of Pt−Ru Core−Shell and Alloy Nanoparticles
journal, October 2009
- Alayoglu, Selim; Zavalij, Peter; Eichhorn, Bryan
- ACS Nano, Vol. 3, Issue 10, p. 3127-3137
Crystal Structure and the Paraelectric-to-Ferroelectric Phase Transition of Nanoscale BaTiO 3
journal, June 2008
- Smith, Millicent B.; Page, Katharine; Siegrist, Theo
- Journal of the American Chemical Society, Vol. 130, Issue 22
Probing Local Dipoles and Ligand Structure in BaTiO 3 Nanoparticles
journal, August 2010
- Page, Katharine; Proffen, Thomas; Niederberger, Markus
- Chemistry of Materials, Vol. 22, Issue 15
Universal solvent restructuring induced by colloidal nanoparticles
journal, January 2015
- Zobel, M.; Neder, R. B.; Kimber, S. A. J.
- Science, Vol. 347, Issue 6219
Bulk Metallic Glass-like Scattering Signal in Small Metallic Nanoparticles
journal, May 2014
- Doan-Nguyen, Vicky V. T.; Kimber, Simon A. J.; Pontoni, Diego
- ACS Nano, Vol. 8, Issue 6
Ab initio determination of solid-state nanostructure
journal, March 2006
- Juhás, P.; Cherba, D. M.; Duxbury, P. M.
- Nature, Vol. 440, Issue 7084
Periodicity and Atomic Ordering in Nanosized Particles of Crystals
journal, May 2008
- Petkov, Valeri; Bedford, Nick; Knecht, Marc R.
- The Journal of Physical Chemistry C, Vol. 112, Issue 24
Atomic structure of nanometer-sized amorphous
journal, December 2008
- Zhang, Hengzhong; Chen, Bin; Banfield, Jillian F.
- Physical Review B, Vol. 78, Issue 21
Building and refining complete nanoparticle structures with total scattering data
journal, February 2011
- Page, Katharine; Hood, Taylor C.; Proffen, Thomas
- Journal of Applied Crystallography, Vol. 44, Issue 2
Atomic Structures and Gram Scale Synthesis of Three Tetrahedral Quantum Dots
journal, July 2014
- Beecher, Alexander N.; Yang, Xiaohao; Palmer, Joshua H.
- Journal of the American Chemical Society, Vol. 136, Issue 30
Polymorphism in magic-sized Au144(SR)60 clusters
journal, June 2016
- Jensen, Kirsten M. Ø.; Juhas, Pavol; Tofanelli, Marcus A.
- Nature Communications, Vol. 7, Issue 1
Pair distribution function analysis applied to decahedral gold nanoparticles
journal, October 2017
- Nakotte, H.; Silkwood, C.; Page, K.
- Physica Scripta, Vol. 92, Issue 11
Distorted f.c.c. arrangement of gold nanoclusters: a model of spherical particles with microstrains and stacking faults
journal, March 2008
- Longo, Alessandro; Martorana, Antonino
- Journal of Applied Crystallography, Vol. 41, Issue 2
Faulting in finite face-centered-cubic crystallites
journal, April 2011
- Beyerlein, Kenneth R.; Snyder, Robert L.; Scardi, Paolo
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 67, Issue 3
Determination of nanoparticle structure type, size and strain distribution from X-ray data for monatomic f.c.c.-derived non-crystallographic nanoclusters
journal, September 2003
- Cervellino, Antonio; Giannini, Cinzia; Guagliardi, Antonietta
- Journal of Applied Crystallography, Vol. 36, Issue 5
Quantitative analysis of gold nanoparticles from synchrotron data by means of least-squares techniques: Least-squares analysis of gold nanoparticles
journal, October 2004
- Cervellino, A.; Giannini, C.; Guagliardi, A.
- The European Physical Journal B, Vol. 41, Issue 4
Element-specific structure of materials with intrinsic disorder by high-energy resonant x-ray diffraction and differential atomic pair-distribution functions: A study of PtPd nanosized catalysts
journal, April 2010
- Petkov, V.; Shastri, S. D.
- Physical Review B, Vol. 81, Issue 16
Composition–Structure–Activity Relationships for Palladium-Alloyed Nanocatalysts in Oxygen Reduction Reaction: An Ex-Situ/In-Situ High Energy X-ray Diffraction Study
journal, August 2015
- Wu, Jinfang; Shan, Shiyao; Petkov, Valeri
- ACS Catalysis, Vol. 5, Issue 9
Pt–Au Alloying at the Nanoscale
journal, July 2012
- Petkov, Valeri; Wanjala, Bridgid N.; Loukrakpam, Rameshwori
- Nano Letters, Vol. 12, Issue 8
Resolving Atomic Ordering Differences in Group 11 Nanosized Metals and Binary Alloy Catalysts by Resonant High-Energy X-ray Diffraction and Computer Simulations
journal, October 2013
- Petkov, Valeri; Shastri, Sarvjit; Shan, Shiyao
- The Journal of Physical Chemistry C, Vol. 117, Issue 42
Identifying the Atomic-Level Effects of Metal Composition on the Structure and Catalytic Activity of Peptide-Templated Materials
journal, October 2015
- Merrill, Nicholas A.; McKee, Erik M.; Merino, Kyle C.
- ACS Nano, Vol. 9, Issue 12
On the road to metallic nanoparticles by rational design: bridging the gap between atomic-level theoretical modeling and reality by total scattering experiments
journal, January 2015
- Prasai, Binay; Wilson, A. R.; Wiley, B. J.
- Nanoscale, Vol. 7, Issue 42
Surface Atomic Structure and Functionality of Metallic Nanoparticles: A Case Study of Au–Pd Nanoalloy Catalysts
journal, March 2017
- Petkov, Valeri; Prasai, Binay; Shastri, Sarvjit
- The Journal of Physical Chemistry C, Vol. 121, Issue 14
Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996
- Hammersley, A. P.; Svensson, S. O.; Hanfland, M.
- High Pressure Research, Vol. 14, Issue 4-6, p. 235-248
PyFAI, a versatile library for azimuthal regrouping
journal, March 2013
- Kieffer, Jérôme; Karkoulis, Dimitrios
- Journal of Physics: Conference Series, Vol. 425, Issue 20
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration
journal, May 2015
- Prescher, Clemens; Prakapenka, Vitali B.
- High Pressure Research, Vol. 35, Issue 3
PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions
journal, March 2013
- Juhás, P.; Davis, T.; Farrow, C. L.
- Journal of Applied Crystallography, Vol. 46, Issue 2
PDFFIT , a program for full profile structural refinement of the atomic pair distribution function
journal, June 1999
- Proffen, Th.; Billinge, S. J. L.
- Journal of Applied Crystallography, Vol. 32, Issue 3
Complex modeling: a strategy and software program for combining multiple information sources to solve ill posed structure and nanostructure inverse problems
journal, September 2015
- Juhás, Pavol; Farrow, Christopher L.; Yang, Xiaohao
- Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 6, p. 562-568
Zerstreuung von Röntgenstrahlen
journal, January 1915
- Debye, P.
- Annalen der Physik, Vol. 351, Issue 6
The atomic simulation environment—a Python library for working with atoms
journal, June 2017
- Hjorth Larsen, Ask; Jørgen Mortensen, Jens; Blomqvist, Jakob
- Journal of Physics: Condensed Matter, Vol. 29, Issue 27
A dense non-crystallographic packing of equal spheres
journal, September 1962
- Mackay, A. L.
- Acta Crystallographica, Vol. 15, Issue 9
A Dense Packing of Hard Spheres with Five-fold Symmetry
journal, November 1965
- Bagley, B. G.
- Nature, Vol. 208, Issue 5011
Structure of gold nanoparticles suspended in water studied by x-ray diffraction and computer simulations
journal, November 2005
- Petkov, Valeri; Peng, Yong; Williams, Geoff
- Physical Review B, Vol. 72, Issue 19
Chasing Changing Nanoparticles with Time-Resolved Pair Distribution Function Methods
journal, March 2012
- Newton, Mark A.; Chapman, Karena W.; Thompsett, David
- Journal of the American Chemical Society, Vol. 134, Issue 11
Super-Stable, Highly Monodisperse Plasmonic Faradaurate-500 Nanocrystals with 500 Gold Atoms: Au ∼500 (SR) ∼120
journal, May 2014
- Kumara, Chanaka; Zuo, Xiaobing; Ilavsky, Jan
- Journal of the American Chemical Society, Vol. 136, Issue 20
Gold Nanoparticle Internal Structure and Symmetry Probed by Unified Small-Angle X-ray Scattering and X-ray Diffraction Coupled with Molecular Dynamics Analysis
journal, August 2015
- Fleury, Blaise; Cortes-Huerto, Robinson; Taché, Olivier
- Nano Letters, Vol. 15, Issue 9
Size of Au-Nanoparticles Supported on Mesostructural Cellular Foams Studied by the Pair Distribution Function Technique
journal, September 2016
- Poulain, Agnieszka; Sobczak, Izabela; Ziolek, Maria
- Crystal Growth & Design, Vol. 16, Issue 10
Modelling and validation of particle size distributions of supported nanoparticles using the pair distribution function technique
journal, April 2017
- Gamez-Mendoza, Liliana; Terban, Maxwell W.; Billinge, Simon J. L.
- Journal of Applied Crystallography, Vol. 50, Issue 3
Faradaurate-940: Synthesis, Mass Spectrometry, Electron Microscopy, High-Energy X-ray Diffraction, and X-ray Scattering Study of Au ∼940±20 (SR) ∼160±4 Nanocrystals
journal, May 2014
- Kumara, Chanaka; Zuo, Xiaobing; Cullen, David A.
- ACS Nano, Vol. 8, Issue 6
Metastability and Structural Polymorphism in Noble Metals: The Role of Composition and Metal Atom Coordination in Mono- and Bimetallic Nanoclusters
journal, January 2013
- Sanchez, Sergio I.; Small, Matthew W.; Bozin, Emil S.
- ACS Nano, Vol. 7, Issue 2
Structure and Bonding in the Ubiquitous Icosahedral Metallic Gold Cluster Au 144 (SR) 60
journal, January 2009
- Lopez-Acevedo, Olga; Akola, Jaakko; Whetten, Robert L.
- The Journal of Physical Chemistry C, Vol. 113, Issue 13
STEM Electron Diffraction and High-Resolution Images Used in the Determination of the Crystal Structure of the Au 144 (SR) 60 Cluster
journal, March 2013
- Bahena, Daniel; Bhattarai, Nabraj; Santiago, Ulises
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 6
Polyol Synthesis of Uniform Silver Nanowires: A Plausible Growth Mechanism and the Supporting Evidence
journal, July 2003
- Sun, Yugang; Mayers, Brian; Herricks, Thurston
- Nano Letters, Vol. 3, Issue 7
Growth of Silver Nanowires from Solutions: A Cyclic Penta-twinned-Crystal Growth Mechanism
journal, May 2005
- Zhang, Shu-Hong; Jiang, Zhi-Yuan; Xie, Zhao-Xiong
- The Journal of Physical Chemistry B, Vol. 109, Issue 19
The role of twinning in shape evolution of anisotropic noble metal nanostructures
journal, January 2006
- Elechiguerra, Jose Luis; Reyes-Gasga, Jose; Yacaman, Miguel Jose
- Journal of Materials Chemistry, Vol. 16, Issue 40
One-Pot, High-Yield Synthesis of 5-Fold Twinned Pd Nanowires and Nanorods
journal, April 2009
- Huang, Xiaoqing; Zheng, Nanfeng
- Journal of the American Chemical Society, Vol. 131, Issue 13, p. 4602-4603
Size- and Composition-Dependent Enhancement of Electrocatalytic Oxygen Reduction Performance in Ultrathin Palladium–Gold (Pd 1– x Au x ) Nanowires
journal, July 2012
- Koenigsmann, Christopher; Sutter, Eli; Adzic, Radoslav R.
- The Journal of Physical Chemistry C, Vol. 116, Issue 29
Probing Ultrathin One-Dimensional Pd–Ni Nanostructures As Oxygen Reduction Reaction Catalysts
journal, July 2014
- Liu, Haiqing; Koenigsmann, Christopher; Adzic, Radoslav R.
- ACS Catalysis, Vol. 4, Issue 8
Direct observation of the structure of gold nanoparticles by total scattering powder neutron diffraction
journal, August 2004
- Page, Katharine; Proffen, Thomas; Terrones, Humberto
- Chemical Physics Letters, Vol. 393, Issue 4-6
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journal, January 2019
- Harada, Masafumi; Ikegami, Risa; Kumara, Loku Singgappulige Rosantha
- RSC Advances, Vol. 9, Issue 51
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journal, January 2019
- Rostek, A.; Loza, K.; Heggen, M.
- RSC Advances, Vol. 9, Issue 46