Nanoparticle Alloy Formation by Radiolysis
Abstract
Here, this Review Article focuses on the highly versatile and effective method of radiolysis for the synthesis of nanoparticles (NPs). In particular, the formation of bimetallic and alloyed nanoparticles (or nanoalloys), including both known super alloys and novel alloy NP compositions, is described. This Review Article discloses the synthesis techniques that rely on ionizing radiation sources to create metallic NPs. Then, alloy NPs formed from combinations of transition metals and noble metals with varied structures are described. Some of the advantages of radiolysis including exquisite control over the size, monodispersity, and alloying structure of NPs are discussed. Additionally, methodologies that facilitate the synthesis or deposition of NPs onto a range of supports under inert environments are described. Finally, applications of metallic NPs formed by radiolysis are summarized.
- Authors:
-
[3];
[1];
[2]
- Normandie Univ., Caen (France). Lab. Catalyse et Spectrochimie
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Univ. of Lille, Lille (France). Lab. de Spectrochimie Infrarouge et Raman
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1485825
- Report Number(s):
- SAND-2018-12785J
Journal ID: ISSN 1932-7447; 669734
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 122; Journal Issue: 24; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Grand, Julien, Ferreira, Summer R., de Waele, Vincent, Mintova, Svetlana, and Nenoff, Tina M. Nanoparticle Alloy Formation by Radiolysis. United States: N. p., 2018.
Web. doi:10.1021/acs.jpcc.8b01878.
Grand, Julien, Ferreira, Summer R., de Waele, Vincent, Mintova, Svetlana, & Nenoff, Tina M. Nanoparticle Alloy Formation by Radiolysis. United States. doi:10.1021/acs.jpcc.8b01878.
Grand, Julien, Ferreira, Summer R., de Waele, Vincent, Mintova, Svetlana, and Nenoff, Tina M. Fri .
"Nanoparticle Alloy Formation by Radiolysis". United States. doi:10.1021/acs.jpcc.8b01878. https://www.osti.gov/servlets/purl/1485825.
@article{osti_1485825,
title = {Nanoparticle Alloy Formation by Radiolysis},
author = {Grand, Julien and Ferreira, Summer R. and de Waele, Vincent and Mintova, Svetlana and Nenoff, Tina M.},
abstractNote = {Here, this Review Article focuses on the highly versatile and effective method of radiolysis for the synthesis of nanoparticles (NPs). In particular, the formation of bimetallic and alloyed nanoparticles (or nanoalloys), including both known super alloys and novel alloy NP compositions, is described. This Review Article discloses the synthesis techniques that rely on ionizing radiation sources to create metallic NPs. Then, alloy NPs formed from combinations of transition metals and noble metals with varied structures are described. Some of the advantages of radiolysis including exquisite control over the size, monodispersity, and alloying structure of NPs are discussed. Additionally, methodologies that facilitate the synthesis or deposition of NPs onto a range of supports under inert environments are described. Finally, applications of metallic NPs formed by radiolysis are summarized.},
doi = {10.1021/acs.jpcc.8b01878},
journal = {Journal of Physical Chemistry. C},
number = 24,
volume = 122,
place = {United States},
year = {2018},
month = {5}
}
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Figures / Tables:
Table 1: Nanoalloy formation by $y$-radiation or other ionizing radiation techniques. The resulting structures formed are either core-shell (CS) or alloyed unless otherwise noted.
All figures and tables
(8 total)
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Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.