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Title: Nanoparticle Alloy Formation by Radiolysis

Abstract

Here, this Review Article focuses on the highly versatile and effective method of radiolysis for the synthesis of nanoparticles (NPs). In particular, the formation of bimetallic and alloyed nanoparticles (or nanoalloys), including both known super alloys and novel alloy NP compositions, is described. This Review Article discloses the synthesis techniques that rely on ionizing radiation sources to create metallic NPs. Then, alloy NPs formed from combinations of transition metals and noble metals with varied structures are described. Some of the advantages of radiolysis including exquisite control over the size, monodispersity, and alloying structure of NPs are discussed. Additionally, methodologies that facilitate the synthesis or deposition of NPs onto a range of supports under inert environments are described. Finally, applications of metallic NPs formed by radiolysis are summarized.

Authors:
 [1];  [2]; ORCiD logo [3]; ORCiD logo [1]; ORCiD logo [2]
  1. Normandie Univ., Caen (France). Lab. Catalyse et Spectrochimie
  2. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  3. Univ. of Lille, Lille (France). Lab. de Spectrochimie Infrarouge et Raman
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1485825
Report Number(s):
SAND-2018-12785J
Journal ID: ISSN 1932-7447; 669734
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Volume: 122; Journal Issue: 24; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Grand, Julien, Ferreira, Summer R., de Waele, Vincent, Mintova, Svetlana, and Nenoff, Tina M. Nanoparticle Alloy Formation by Radiolysis. United States: N. p., 2018. Web. doi:10.1021/acs.jpcc.8b01878.
Grand, Julien, Ferreira, Summer R., de Waele, Vincent, Mintova, Svetlana, & Nenoff, Tina M. Nanoparticle Alloy Formation by Radiolysis. United States. https://doi.org/10.1021/acs.jpcc.8b01878
Grand, Julien, Ferreira, Summer R., de Waele, Vincent, Mintova, Svetlana, and Nenoff, Tina M. Fri . "Nanoparticle Alloy Formation by Radiolysis". United States. https://doi.org/10.1021/acs.jpcc.8b01878. https://www.osti.gov/servlets/purl/1485825.
@article{osti_1485825,
title = {Nanoparticle Alloy Formation by Radiolysis},
author = {Grand, Julien and Ferreira, Summer R. and de Waele, Vincent and Mintova, Svetlana and Nenoff, Tina M.},
abstractNote = {Here, this Review Article focuses on the highly versatile and effective method of radiolysis for the synthesis of nanoparticles (NPs). In particular, the formation of bimetallic and alloyed nanoparticles (or nanoalloys), including both known super alloys and novel alloy NP compositions, is described. This Review Article discloses the synthesis techniques that rely on ionizing radiation sources to create metallic NPs. Then, alloy NPs formed from combinations of transition metals and noble metals with varied structures are described. Some of the advantages of radiolysis including exquisite control over the size, monodispersity, and alloying structure of NPs are discussed. Additionally, methodologies that facilitate the synthesis or deposition of NPs onto a range of supports under inert environments are described. Finally, applications of metallic NPs formed by radiolysis are summarized.},
doi = {10.1021/acs.jpcc.8b01878},
journal = {Journal of Physical Chemistry. C},
number = 24,
volume = 122,
place = {United States},
year = {2018},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

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Cited by: 3 works
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Figures / Tables:

Table 1 Table 1: Nanoalloy formation by $y$-radiation or other ionizing radiation techniques. The resulting structures formed are either core-shell (CS) or alloyed unless otherwise noted.

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Bimetallic Pd 96 Fe 4 nanodendrites embedded in graphitic carbon nanosheets as highly efficient anode electrocatalysts
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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.