Nanoparticle Alloy Formation by Radiolysis

Grand, Julien; Ferreira, Summer R.; de Waele, Vincent; Mintova, Svetlana; Nenoff, Tina M.

doi:10.1021/acs.jpcc.8b01878

Title: Nanoparticle Alloy Formation by Radiolysis

Journal Article · 25 May 2018 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.8b01878 · OSTI ID:1485825

Grand, Julien ^[1]; Ferreira, Summer R. ^[2];

^[3];

^[1];

^[2]

Normandie Univ., Caen (France). Lab. Catalyse et Spectrochimie
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Univ. of Lille, Lille (France). Lab. de Spectrochimie Infrarouge et Raman

Here, this Review Article focuses on the highly versatile and effective method of radiolysis for the synthesis of nanoparticles (NPs). In particular, the formation of bimetallic and alloyed nanoparticles (or nanoalloys), including both known super alloys and novel alloy NP compositions, is described. This Review Article discloses the synthesis techniques that rely on ionizing radiation sources to create metallic NPs. Then, alloy NPs formed from combinations of transition metals and noble metals with varied structures are described. Some of the advantages of radiolysis including exquisite control over the size, monodispersity, and alloying structure of NPs are discussed. Additionally, methodologies that facilitate the synthesis or deposition of NPs onto a range of supports under inert environments are described. Finally, applications of metallic NPs formed by radiolysis are summarized.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1485825

Report Number(s):: SAND-2018-12785J; 669734

Journal Information:: Journal of Physical Chemistry. C, Vol. 122, Issue 24; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 28 works

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