Bragg coherent diffraction imaging of iron diffusion into gold nanocrystals
Abstract
Understanding how diffusion takes place within nanocrystals is of great importance for their stability and for controlling their synthesis. In this study, we used the strain sensitivity of Bragg coherent diffraction imaging (BCDI) to study the diffusion of iron into individual gold nanocrystals in situ at elevated temperatures. The BCDI experiments were performed at the I-07 beamline at Diamond Light Source, UK. The diffraction pattern of individual gold nanocrystals was measured around the (11-1) Bragg peak of gold before and after iron deposition as a function of temperature and time. Phase retrieval algorithms were used to obtain real space reconstructions of the nanocrystals from their measured diffraction patterns. Alloying of iron with gold at sample temperatures of 300 °C–500 °C and dealloying of iron from gold at 600 °C were observed. The volume of the alloyed region in the nanocrystals was found to increase with the dose of iron. However, no significant time dependence was observed for the structure following each iron deposition, suggesting that the samples reached equilibrium relatively quickly. The resulting phase distribution within the gold nanocrystals after the iron depositions suggests a contraction due to diffusion of iron. Furthermore, our results show that BCDI is a usefulmore »
- Authors:
-
[1];
[3]
- Univ. College London, London (United Kingdom); Rutherford Appleton Lab., Oxon (United Kingdom)
- Diamond Light Source, Oxon (United Kingdom)
- Univ. College London, London (United Kingdom); Rutherford Appleton Lab., Oxon (United Kingdom); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1483748
- Report Number(s):
- BNL-209512-2018-JAAM
Journal ID: ISSN 1367-2630
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- New Journal of Physics
- Additional Journal Information:
- Journal Volume: 20; Journal Issue: 11; Journal ID: ISSN 1367-2630
- Publisher:
- IOP Publishing
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; diffusion; gold iron; Bragg coherent diffraction imaging; nanocrystals
Citation Formats
Estandarte, Ana Katrina C., Lynch, Christopher Michael, Monteforte, Marianne, Rawle, Jonathan, Nicklin, Chris, and Robinson, Ian K. Bragg coherent diffraction imaging of iron diffusion into gold nanocrystals. United States: N. p., 2018.
Web. doi:10.1088/1367-2630/aaebc1.
Estandarte, Ana Katrina C., Lynch, Christopher Michael, Monteforte, Marianne, Rawle, Jonathan, Nicklin, Chris, & Robinson, Ian K. Bragg coherent diffraction imaging of iron diffusion into gold nanocrystals. United States. https://doi.org/10.1088/1367-2630/aaebc1
Estandarte, Ana Katrina C., Lynch, Christopher Michael, Monteforte, Marianne, Rawle, Jonathan, Nicklin, Chris, and Robinson, Ian K. Fri .
"Bragg coherent diffraction imaging of iron diffusion into gold nanocrystals". United States. https://doi.org/10.1088/1367-2630/aaebc1. https://www.osti.gov/servlets/purl/1483748.
@article{osti_1483748,
title = {Bragg coherent diffraction imaging of iron diffusion into gold nanocrystals},
author = {Estandarte, Ana Katrina C. and Lynch, Christopher Michael and Monteforte, Marianne and Rawle, Jonathan and Nicklin, Chris and Robinson, Ian K.},
abstractNote = {Understanding how diffusion takes place within nanocrystals is of great importance for their stability and for controlling their synthesis. In this study, we used the strain sensitivity of Bragg coherent diffraction imaging (BCDI) to study the diffusion of iron into individual gold nanocrystals in situ at elevated temperatures. The BCDI experiments were performed at the I-07 beamline at Diamond Light Source, UK. The diffraction pattern of individual gold nanocrystals was measured around the (11-1) Bragg peak of gold before and after iron deposition as a function of temperature and time. Phase retrieval algorithms were used to obtain real space reconstructions of the nanocrystals from their measured diffraction patterns. Alloying of iron with gold at sample temperatures of 300 °C–500 °C and dealloying of iron from gold at 600 °C were observed. The volume of the alloyed region in the nanocrystals was found to increase with the dose of iron. However, no significant time dependence was observed for the structure following each iron deposition, suggesting that the samples reached equilibrium relatively quickly. The resulting phase distribution within the gold nanocrystals after the iron depositions suggests a contraction due to diffusion of iron. Furthermore, our results show that BCDI is a useful technique for studying diffusion in three dimensions and alloying behaviour in individual crystalline grains.},
doi = {10.1088/1367-2630/aaebc1},
journal = {New Journal of Physics},
number = 11,
volume = 20,
place = {United States},
year = {Fri Nov 16 00:00:00 EST 2018},
month = {Fri Nov 16 00:00:00 EST 2018}
}
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Works referenced in this record:
Diffusion in Nanocrystalline Metals and Alloys—A Status Report
journal, May 2003
- Würschum, R.; Herth, S.; Brossmann, U.
- Advanced Engineering Materials, Vol. 5, Issue 5
Correlating Catalytic Activity of Ag–Au Nanoparticles with 3D Compositional Variations
journal, March 2014
- Slater, Thomas J. A.; Macedo, Alexandra; Schroeder, Sven L. M.
- Nano Letters, Vol. 14, Issue 4
Die äußere Form der Kristalle in ihrem Einfluß auf die Interferenzerscheinungen an Raumgittern
journal, January 1936
- v. Laue, M.
- Annalen der Physik, Vol. 418, Issue 1
Three-dimensional imaging of strain in a single ZnO nanorod
journal, December 2009
- Newton, Marcus C.; Leake, Steven J.; Harder, Ross
- Nature Materials, Vol. 9, Issue 2
Diffusion Studies of Solids by Quasielastic Neutron Scattering
book, January 2005
- Springer, Tasso; Lechner, Ruep E.
- Diffusion in Condensed Matter
Comparison of depth profiling techniques using ion sputtering from the practical point of view
journal, February 2003
- Oswald, S.
- Thin Solid Films, Vol. 425, Issue 1-2
Applications of Secondary Ion Mass Spectrometry (SIMS) in Materials Science
journal, February 2006
- McPhail, D. S.
- Journal of Materials Science, Vol. 41, Issue 3
Apparatus for X-ray diffraction in ultrahigh vacuum
journal, May 1984
- Fuoss, P. H.; Robinson, I. K.
- Nuclear Instruments and Methods in Physics Research, Vol. 222, Issue 1-2
Atomic Diffusion within Individual Gold Nanocrystal
journal, October 2014
- Xiong, Gang; Clark, Jesse N.; Nicklin, Chris
- Scientific Reports, Vol. 4, Issue 1
Diffusion of Gold from the Inner Core to the Surface of Ag 2 S Nanocrystals
journal, February 2010
- Yang, Jun; Ying, Jackie Y.
- Journal of the American Chemical Society, Vol. 132, Issue 7
Strain-relief by single dislocation loops in calcite crystals grown on self-assembled monolayers
text, January 2016
- Ihli, Johannes; Clark, Jesse N.; Côté, Alexander S.
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Formation of Nanotubes and Hollow Nanoparticles Based on Kirkendall and Diffusion Processes: A Review
journal, October 2007
- Fan, Hong Jin; Gösele, Ulrich; Zacharias, Margit
- Small, Vol. 3, Issue 10
Asymmetric diffusion at the interfaces in Fe/Si multilayers
journal, April 2010
- Gupta, Ajay; Kumar, Dileep; Phatak, Vaishali
- Physical Review B, Vol. 81, Issue 15
Magnetic nanoparticles in MR imaging and drug delivery☆
journal, August 2008
- Sun, C.; Lee, J.; Zhang, M.
- Advanced Drug Delivery Reviews, Vol. 60, Issue 11
Coherent X-Ray Diffraction Imaging and Characterization of Strain in Silicon-on-Insulator Nanostructures
journal, June 2014
- Xiong, Gang; Moutanabbir, Oussama; Reiche, Manfred
- Advanced Materials, Vol. 26, Issue 46
Methodology for studying strain inhomogeneities in polycrystalline thin films during in situ thermal loading using coherent x-ray diffraction
journal, March 2010
- Vaxelaire, N.; Proudhon, H.; Labat, S.
- New Journal of Physics, Vol. 12, Issue 3
Characterization of thin titanium oxide adhesion layers on gold: resistivity, morphology, and composition
journal, January 1994
- Vogt, K. W.; Kohl, P. A.; Carter, W. B.
- Surface Science, Vol. 301, Issue 1-3
The epitaxial growth of iron on (111) Au at substrate temperatures of 600–700°C
journal, May 1981
- Engelbrecht, J. A. A.; Snyman, H. C.
- Thin Solid Films, Vol. 79, Issue 1
Three-dimensional mapping of a deformation field inside a nanocrystal
journal, July 2006
- Pfeifer, Mark A.; Williams, Garth J.; Vartanyants, Ivan A.
- Nature, Vol. 442, Issue 7098
Analysis of strain and stacking faults in single nanowires using Bragg coherent diffraction imaging
journal, March 2010
- Favre-Nicolin, V.; Mastropietro, F.; Eymery, J.
- New Journal of Physics, Vol. 12, Issue 3
Differential stress induced by thiol adsorption on facetted nanocrystals
journal, September 2011
- Watari, Moyu; McKendry, Rachel A.; Vögtli, Manuel
- Nature Materials, Vol. 10, Issue 11
Survival times of anomalous melt inclusions from element diffusion in olivine and chromite
journal, May 2007
- Spandler, C.; O’Neill, H. St C.; Kamenetsky, V. S.
- Nature, Vol. 447, Issue 7142
Diffusion in Solids: Fundamentals, Methods, Materials, Diffusion-Controlled Processes
book, January 2007
- Mehrer, Helmut
- Springer Series in Solid-State Sciences
Nanocrystal Diffusion Doping
journal, September 2013
- Vlaskin, Vladimir A.; Barrows, Charles J.; Erickson, Christian S.
- Journal of the American Chemical Society, Vol. 135, Issue 38
Biocompatible high-moment FeCo-Au magnetic nanoparticles for magnetic hyperthermia treatment optimization
journal, May 2009
- Kline, Timothy L.; Xu, Yun-Hao; Jing, Ying
- Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 10
Self-diffusion of iron in -ordered FePt thin films
journal, September 2006
- Rennhofer, M.; Sepiol, B.; Sladecek, M.
- Physical Review B, Vol. 74, Issue 10
Quasi-Elastic Neutron Scattering Studies on Dynamics of Water Confined in Nanoporous Copper Rubeanate Hydrates
journal, November 2011
- Yamada, Takeshi; Yonamine, Ryo; Yamada, Teppei
- The Journal of Physical Chemistry B, Vol. 115, Issue 46
On the strengthening effects of interfaces in multilayer fee metallic composites
journal, March 2002
- Hoagland, R. G.; Mitchell, T. E.; Hirth, J. P.
- Philosophical Magazine A, Vol. 82, Issue 4
Anti-Cancer Drug Loaded Iron–Gold Core–Shell Nanoparticles (Fe@Au) for Magnetic Drug Targeting
journal, September 2010
- Kayal, Sibnath; Ramanujan, Raju Vijayaraghavan
- Journal of Nanoscience and Nanotechnology, Vol. 10, Issue 9
Emerging Strategies for the Total Synthesis of Inorganic Nanostructures
journal, April 2013
- Buck, Matthew R.; Schaak, Raymond E.
- Angewandte Chemie International Edition, Vol. 52, Issue 24
Strain field in (Ga,Mn)As/GaAs periodic wires revealed by coherent X-ray diffraction
journal, May 2011
- Minkevich, A. A.; Fohtung, E.; Slobodskyy, T.
- EPL (Europhysics Letters), Vol. 94, Issue 6
Doped Nanocrystals
journal, March 2008
- Norris, D. J.; Efros, A. L.; Erwin, S. C.
- Science, Vol. 319, Issue 5871
Surface faceting and elemental diffusion behaviour at atomic scale for alloy nanoparticles during in situ annealing
journal, November 2015
- Chi, Miaofang; Wang, Chao; Lei, Yinkai
- Nature Communications, Vol. 6, Issue 1
Oxygen Diffusion in Nanocrystalline ZrO2
journal, October 2004
- Brossmann, U.; Knoener, G.; Schaefer, H. -E.
- ChemInform, Vol. 35, Issue 42
On the stability of AuFe alloy nanoparticles
journal, May 2014
- Velasco, V.; Pohl, D.; Surrey, A.
- Nanotechnology, Vol. 25, Issue 21
Gold-coated iron nanoparticles: a novel magnetic resonance agent for T 1 and T 2 weighted imaging
journal, January 2006
- Cho, Sung-Jin; Jarrett, Benjamin R.; Louie, Angelique Y.
- Nanotechnology, Vol. 17, Issue 3
Quasi-Elastic Neutron Scattering and Molecular Dynamics Study of Methane Diffusion in Metal Organic Frameworks MIL-47(V) and MIL-53(Cr)
journal, August 2008
- Rosenbach, Nilton; Jobic, Hervé; Ghoufi, Aziz
- Angewandte Chemie International Edition, Vol. 47, Issue 35
Sub-Nanometer-Resolution Elemental Mapping of “Pt 3 Co” Nanoparticle Catalyst Degradation in Proton-Exchange Membrane Fuel Cells
journal, January 2012
- Carlton, Christopher E.; Chen, Shuo; Ferreira, Paulo J.
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 2
3D lattice distortions and defect structures in ion-implanted nano-crystals
journal, April 2017
- Hofmann, Felix; Tarleton, Edmund; Harder, Ross J.
- Scientific Reports, Vol. 7, Issue 1
Three-dimensional reconstruction of the size and shape of protein microcrystals using Bragg coherent diffractive imaging
journal, March 2016
- Coughlan, H. D.; Darmanin, C.; Kirkwood, H. J.
- Journal of Optics, Vol. 18, Issue 5
Nanoscale mapping of the three-dimensional deformation field within commercial nanodiamonds
journal, January 2017
- Maqbool, Muhammad Salman; Hoxley, David; Phillips, Nicholas W.
- International Journal of Nanotechnology, Vol. 14, Issue 1/2/3/4/5/6
Multimetallic Au/FePt 3 Nanoparticles as Highly Durable Electrocatalyst
journal, March 2011
- Wang, Chao; van der Vliet, Dennis; More, Karren L.
- Nano Letters, Vol. 11, Issue 3
Identifying Defects with Guided Algorithms in Bragg Coherent Diffractive Imaging
journal, August 2017
- Ulvestad, A.; Nashed, Y.; Beutier, G.
- Scientific Reports, Vol. 7, Issue 1
Mixed Ti–O–Si oxide films formation by oxidation of titanium–silicon interfaces
journal, May 2014
- Benito, N.; Palacio, C.
- Applied Surface Science, Vol. 301
Ultrafast Three-Dimensional Imaging of Lattice Dynamics in Individual Gold Nanocrystals
journal, May 2013
- Clark, J. N.; Beitra, L.; Xiong, G.
- Science, Vol. 341, Issue 6141
Strain-relief by single dislocation loops in calcite crystals grown on self-assembled monolayers
journal, June 2016
- Ihli, Johannes; Clark, Jesse N.; Côté, Alexander S.
- Nature Communications, Vol. 7, Issue 1
Templated synthesis of gold–iron alloy nanoparticles using pulsed laser deposition
journal, September 2006
- Chang, Won-Suk; Park, Jin-Won; Rawat, Vijay
- Nanotechnology, Vol. 17, Issue 20
Closed and open-ended stacking fault tetrahedra formation along the interfaces of Cu–Al nanolayered metals
journal, August 2015
- Li, Ruizhi; Chew, Huck Beng
- Philosophical Magazine, Vol. 95, Issue 25
Three-dimensional imaging of dislocation propagation during crystal growth and dissolution
journal, June 2015
- Clark, Jesse N.; Ihli, Johannes; Schenk, Anna S.
- Nature Materials, Vol. 14, Issue 8
Reconstruction of the Shapes of Gold Nanocrystals Using Coherent X-Ray Diffraction
journal, October 2001
- Robinson, I. K.; Vartanyants, I. A.; Williams, G. J.
- Physical Review Letters, Vol. 87, Issue 19
Application of optimization technique to noncrystalline x-ray diffraction microscopy: Guided hybrid input-output method
journal, August 2007
- Chen, Chien-Chun; Miao, Jianwei; Wang, C. W.
- Physical Review B, Vol. 76, Issue 6
Reconstruction of an object from the modulus of its Fourier transform
journal, January 1978
- Fienup, J. R.
- Optics Letters, Vol. 3, Issue 1, p. 27-29
Coherent X-ray diffraction investigation of twinned microcrystals
journal, October 2010
- Aranda, Miguel A. G.; Berenguer, Felisa; Bean, Richard J.
- Journal of Synchrotron Radiation, Vol. 17, Issue 6
X-ray image reconstruction from a diffraction pattern alone
journal, October 2003
- Marchesini, S.; He, H.; Chapman, H. N.
- Physical Review B, Vol. 68, Issue 14
Crystal truncation rods and surface roughness
journal, March 1986
- Robinson, I. K.
- Physical Review B, Vol. 33, Issue 6
Phase retrieval algorithms: a comparison
journal, January 1982
- Fienup, J. R.
- Applied Optics, Vol. 21, Issue 15
Phase-retrieval stagnation problems and solutions
journal, January 1986
- Fienup, J. R.; Wackerman, C. C.
- Journal of the Optical Society of America A, Vol. 3, Issue 11
Bulk Dislocation Core Dissociation Probed by Coherent X Rays in Silicon
journal, February 2011
- Jacques, V. L. R.; Ravy, S.; Le Bolloc’h, D.
- Physical Review Letters, Vol. 106, Issue 6
Quasi-Elastic Neutron Scattering and Molecular Dynamics Study of Methane Diffusion in Metal Organic Frameworks MIL-47(V) and MIL-53(Cr)
journal, August 2008
- Rosenbach, Nilton; Jobic, Hervé; Ghoufi, Aziz
- Angewandte Chemie, Vol. 120, Issue 35
Diffusion in solids
journal, February 1964
- Barrer, R. M.
- International Journal of Heat and Mass Transfer, Vol. 7, Issue 2
Diffusion in Solids. [材料科学の成果と展望 固体における拡散]
journal, January 1997
- Nakajima, Hideo
- Materia Japan, Vol. 36, Issue 9
Bulk dislocation core dissociation probed by coherent X rays in silicon
journal, August 2011
- Ravy, S.; Jacques, V.; Le Bolloc'h, D.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 67, Issue a1
Reconstruction of the Shapes of Gold Nanocrystals Using Coherent X-Ray Diffraction
text, January 2001
- Pfeifer, M. A.; Pitney, J. A.; Robinson, I. K.
- The American Physical Society
Analysis of strain and stacking faults in single nanowires using Bragg coherent diffraction imaging
text, January 2009
- Favre-Nicolin, V.; Mastropietro, F.; Eymery, J.
- arXiv
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journal, October 2019
- Yang, David; Phillips, Nicholas W.; Hofmann, Felix
- Journal of Synchrotron Radiation, Vol. 26, Issue 6
Nano-scale imaging of the full strain tensor of specific dislocations extracted from a bulk sample
text, January 2019
- Hofmann, Felix; Phillips, Nicholas W.; Das, Suchandrima
- arXiv