Title: The mechanisms, dynamics, and implications of self-sealing and CO₂ resistance in wellbore cements

Abstract

Here, this study analyzes the dynamics and mechanisms of the interactions of carbonated brine with hydrated-Portland-cement; in particular, the study focuses on self-sealing, a process whereby hydrated-Portland cement reacts with carbonated brine to for silica and calcium carbonate in sufficient quantities to seal the flow pathway. The analysis is based on a comprehensive set of reactive-transport simulations that explore the complex coupled dynamics between the fluid flow and mineral reactions that underlie self-sealing, and it relies heavily on the synthesis of the extensive body of work on wellbore integrity that has been conducted over the past decade. The analysis explores a large chemical and mineralogical diversity and a wide range in physical conditions and flow regimes, attempting to assess the robustness of the analysis. Self-sealing conditions arise over a wide range in cement properties and reservoir conditions. Although some properties and conditions promote a stronger self-sealing response, self-sealing occurs for a wide range of Ca:Si ratios in cement and for various reservoir fluid compositions. Self-sealing conditions move along a wellbore proportional to the flux of the leaking carbonated brine, and the reaction zone spreads out proportional to the fluid velocity, where volumetric flux and velocity are related by porosity (fluxmore » = velocity * porosity). However, self-sealing conditions can be maintained in a specific section of a wellbore by controlling the pressure drive and/or effective wellbore permeability, which in turn can limit the flux and velocity of any leaking fluid. Finally, the phases produced by hydrating Portland cement represent a carbonic cement that will react with a carbonated brine to produce end products (calcium carbonate and silica) that can maintain integrity in the presence of carbonic acid. Lastly, the attributes that make hydrated Portland cement phases a carbonic cement are required for self-sealing.« less

Authors:

Guthrie, George Drake Jr. ^[1]; Pawar, Rajesh J.  ^[1];

• Search DOE PAGES for author "Pawar, Rajesh J."
• Search DOE PAGES for ORCID "0000-0003-1422-7532"

Carey, James William  ^[1];

• Search DOE PAGES for author "Carey, James William"
• Search DOE PAGES for ORCID "0000-0001-8488-2925"

Karra, Satish  ^[1];

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• Search DOE PAGES for ORCID "0000-0001-7847-6293"

Harp, Dylan Robert  ^[1];

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• Search DOE PAGES for ORCID "0000-0001-9777-8000"

Viswanathan, Hari S.  ^[1]

• Search DOE PAGES for author "Viswanathan, Hari S."
• Search DOE PAGES for ORCID "0000-0002-1178-9647"

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+ Show Author Affiliations

1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Publication Date:

Thu Jun 14 00:00:00 EDT 2018

Research Org.:

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:

USDOE Office of Fossil Energy (FE). Clean Coal (FE-20); USDOE National Nuclear Security Administration (NNSA); USDOE Office of Fossil Energy (FE)

OSTI Identifier:

1483500

Alternate Identifier(s):

OSTI ID: 1601502

Report Number(s):

LA-UR-17-29117
Journal ID: ISSN 1750-5836

Grant/Contract Number:  

89233218CNA000001; AC52-06NA25396

Resource Type:

Accepted Manuscript

Journal Name:

International Journal of Greenhouse Gas Control

Additional Journal Information:

Journal Volume: 75; Journal Issue: C; Journal ID: ISSN 1750-5836

Publisher:

Elsevier

Country of Publication:

United States

Language:

English

Subject:

58 GEOSCIENCES; wellbore integrity; Portland cement; self-sealing; CO2 resistance