Processing of novel pseudomorphic Cu–Mo hierarchies in thin films
Abstract
A new processing route has been discovered through which far-from-equilibrium, metastable architectures with unprecedented properties are synthesized. This novel architecture contains many orders of hierarchy with multiple concentration modulation wavelengths. At one length scale, the matrix is comprised of lateral modulations of BCC Mo and pseudomorphic BCC Cu with a wavelength of 10 nm. FCC, Cu-rich islands of approximate 250 nm diameter are woven in-between the Mo-Cu matrix and contain ordered arrays of pseudomorphic, FCC, Mo-rich, coherent precipitates of approximately 1.0 nm diameter spacing. The resulting material exhibits unprecedented mechanical behavior of extensive plastic deformability at room temperature.
- Authors:
-
- Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI, USA
- Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, NM, USA
- Department of Materials Science and Engineering, Texas A&,M University, College Station, TX, USA, Department of Mechanical Engineering, Texas A&,M University, College Station, TX, USA
- Department of Materials Science and Engineering, Texas A&,M University, College Station, TX, USA
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1483334
- Alternate Identifier(s):
- OSTI ID: 1571606
- Report Number(s):
- LA-UR-19-29913
Journal ID: ISSN 2166-3831; 1
- Grant/Contract Number:
- DMREF-1534534; AC52-06NA25396; NA0003525; DMR-0723032; 89233218CNA000001
- Resource Type:
- Published Article
- Journal Name:
- Materials Research Letters
- Additional Journal Information:
- Journal Name: Materials Research Letters Journal Volume: 7 Journal Issue: 1; Journal ID: ISSN 2166-3831
- Publisher:
- Taylor and Francis
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Material Science; Synthesis; hierarchical; pseudormorphic; self-assembly; immiscible; high-strength; deformable
Citation Formats
Derby, Benjamin, Cui, Yuchi, Baldwin, JonKevin, Arróyave, Raymundo, Demkowicz, Michael J., and Misra, Amit. Processing of novel pseudomorphic Cu–Mo hierarchies in thin films. United Kingdom: N. p., 2018.
Web. doi:10.1080/21663831.2018.1546237.
Derby, Benjamin, Cui, Yuchi, Baldwin, JonKevin, Arróyave, Raymundo, Demkowicz, Michael J., & Misra, Amit. Processing of novel pseudomorphic Cu–Mo hierarchies in thin films. United Kingdom. https://doi.org/10.1080/21663831.2018.1546237
Derby, Benjamin, Cui, Yuchi, Baldwin, JonKevin, Arróyave, Raymundo, Demkowicz, Michael J., and Misra, Amit. Fri .
"Processing of novel pseudomorphic Cu–Mo hierarchies in thin films". United Kingdom. https://doi.org/10.1080/21663831.2018.1546237.
@article{osti_1483334,
title = {Processing of novel pseudomorphic Cu–Mo hierarchies in thin films},
author = {Derby, Benjamin and Cui, Yuchi and Baldwin, JonKevin and Arróyave, Raymundo and Demkowicz, Michael J. and Misra, Amit},
abstractNote = {A new processing route has been discovered through which far-from-equilibrium, metastable architectures with unprecedented properties are synthesized. This novel architecture contains many orders of hierarchy with multiple concentration modulation wavelengths. At one length scale, the matrix is comprised of lateral modulations of BCC Mo and pseudomorphic BCC Cu with a wavelength of 10 nm. FCC, Cu-rich islands of approximate 250 nm diameter are woven in-between the Mo-Cu matrix and contain ordered arrays of pseudomorphic, FCC, Mo-rich, coherent precipitates of approximately 1.0 nm diameter spacing. The resulting material exhibits unprecedented mechanical behavior of extensive plastic deformability at room temperature.},
doi = {10.1080/21663831.2018.1546237},
journal = {Materials Research Letters},
number = 1,
volume = 7,
place = {United Kingdom},
year = {Fri Nov 16 00:00:00 EST 2018},
month = {Fri Nov 16 00:00:00 EST 2018}
}
https://doi.org/10.1080/21663831.2018.1546237
Web of Science
Figures / Tables:
Works referenced in this record:
Monte Carlo simulation of phase separation during thin‐film codeposition
journal, August 1993
- Adams, C. D.; Srolovitz, D. J.; Atzmon, M.
- Journal of Applied Physics, Vol. 74, Issue 3
Crystallization of Cu50W50 and Cu66W34 amorphous alloys
journal, May 1994
- Gržeta, B.; Radić, N.; Gracin, D.
- Journal of Non-Crystalline Solids, Vol. 170, Issue 1
Thermodynamic states and phase diagrams for bulk-incoherent, bulk-coherent, and epitaxially-coherent semiconductor alloys: Application to cubic (Ga,In)N
journal, May 2008
- Liu, Jefferson Z.; Zunger, Alex
- Physical Review B, Vol. 77, Issue 20
Early Stages of Crystallization in Phase-Separated Amorphous Copper-Niobium Alloy Thin Films
journal, December 2007
- Puthucode, Anantha; Kaufman, Michael J.; Banerjee, Rajarshi
- Metallurgical and Materials Transactions A, Vol. 39, Issue 7
Self-diffusion in molybdenum
journal, June 1963
- Askill, J.; Tomlin, D. H.
- Philosophical Magazine, Vol. 8, Issue 90
Oscillations in exchange coupling and magnetoresistance in metallic superlattice structures: Co/Ru, Co/Cr, and Fe/Cr
journal, May 1990
- Parkin, S. S. P.; More, N.; Roche, K. P.
- Physical Review Letters, Vol. 64, Issue 19
Structure Evolution During Processing of Polycrystalline Films
journal, August 2000
- Thompson, C. V.
- Annual Review of Materials Science, Vol. 30, Issue 1
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Formation of metastable phases by spinodal decomposition
journal, October 2016
- Alert, Ricard; Tierno, Pietro; Casademunt, Jaume
- Nature Communications, Vol. 7, Issue 1
Obtaining ultimate functionalities in nanocomposites: Design, control, and fabrication
journal, September 2015
- Nan, Ce-Wen; Jia, Quanxi
- MRS Bulletin, Vol. 40, Issue 9
Rolling textures in nanoscale Cu/Nb multilayers
journal, December 2003
- Anderson, Peter M.; Bingert, John F.; Misra, Amit
- Acta Materialia, Vol. 51, Issue 20
Microstructure and electronic properties of Cu/Mo multilayers and three-dimensional arrays of nanocrystalline Cu precipitates embedded in a Mo matrix
journal, April 2004
- Zhang, X.; Hundley, M. F.; Malinowski, A.
- Journal of Applied Physics, Vol. 95, Issue 7
Damage Mechanisms in Nanolayered Metallic Composites
journal, October 2003
- Misra, A.; Kung, H.; Hammon, D.
- International Journal of Damage Mechanics, Vol. 12, Issue 4
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Phase separation during co-deposition of Al–Ge thin films
journal, March 1992
- Adams, C. D.; Atzmon, M.; Cheng, Y-T.
- Journal of Materials Research, Vol. 7, Issue 3
On spinodal decomposition in Cu–34 at.% Ta thin films – An atom probe tomography and transmission electron microscopy study
journal, May 2015
- Müller, Claudia M.; Sologubenko, Alla S.; Gerstl, Stephan S. A.
- Acta Materialia, Vol. 89
Effects of substrate temperature and deposition rate on the phase separated morphology of co-sputtered, Cu-Mo thin films
journal, February 2018
- Derby, B.; Cui, Y.; Baldwin, J. K.
- Thin Solid Films, Vol. 647
The alloy theoretic automated toolkit: A user guide
journal, December 2002
- van de Walle, A.; Asta, M.; Ceder, G.
- Calphad, Vol. 26, Issue 4
The Self-Diffusion of Copper
journal, July 1939
- Steigman, J.; Shockley, W.; Nix, F. C.
- Physical Review, Vol. 56, Issue 1
High strength Mg/Nb nanolayer composites
journal, February 2011
- Ham, B.; Zhang, X.
- Materials Science and Engineering: A, Vol. 528, Issue 4-5
fcc titanium in Ti-Al multilayers
journal, August 1994
- Shechtman, D.; van Heerden, D.; Josell, D.
- Materials Letters, Vol. 20, Issue 5-6
Suppression of shear banding in high-strength Cu/Mo nanocomposites with hierarchical bicontinuous intertwined structures
journal, December 2017
- Cui, Yuchi; Derby, Benjamin; Li, Nan
- Materials Research Letters, Vol. 6, Issue 3
Deformation-induced structural transition in body-centred cubic molybdenum
journal, March 2014
- Wang, S. J.; Wang, H.; Du, K.
- Nature Communications, Vol. 5, Issue 1
Phase-separated Al–Si thin films
journal, August 2005
- Fukutani, Kazuhiko; Tanji, Koichi; Saito, Tatsuya
- Journal of Applied Physics, Vol. 98, Issue 3
Three-dimensional binary superlattices of magnetic nanocrystals and semiconductor quantum dots
journal, June 2003
- Redl, F. X.; Cho, K.-S.; Murray, C. B.
- Nature, Vol. 423, Issue 6943, p. 968-971
Stabilization of bcc Mg in Thin Films at Ambient Pressure: Experimental Evidence and ab initio Calculations
journal, September 2013
- Junkaew, A.; Ham, B.; Zhang, X.
- Materials Research Letters, Vol. 1, Issue 3
Deformability of ultrahigh strength 5nm Cu∕Nb nanolayered composites
journal, June 2008
- Mara, N. A.; Bhattacharyya, D.; Dickerson, P.
- Applied Physics Letters, Vol. 92, Issue 23
Microstructure Map for Self-Organized Phase Separation during Film Deposition
journal, August 2012
- Lu, Yong; Wang, Cuiping; Gao, Yipeng
- Physical Review Letters, Vol. 109, Issue 8
In-situ tracking the structural and chemical evolution of nanostructured CuCr alloys
journal, October 2017
- Zhang, Zaoli; Guo, Jinming; Dehm, Gerhard
- Acta Materialia, Vol. 138
An in situ X-ray diffraction study of phase separation in Cu–Ta alloy thin films
journal, January 2016
- Müller, Claudia M.; Spolenak, Ralph
- Thin Solid Films, Vol. 598
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