Coordination chemistry of lanthanides in a AOT–CMPO solvent extraction system: UV-Vis and XAFS studies

Moon, Jisue; Nilsson, Mikael

doi:10.1039/C8DT02957A

Title: Coordination chemistry of lanthanides in a AOT–CMPO solvent extraction system: UV-Vis and XAFS studies

Abstract

Synergistic extraction systems using AOT and CMPO were investigated at the molecular level for improved understanding of the lanthanide coordination environment.

Authors:

Moon, Jisue ^[1];

^[2]

Department of Chemical engineering and Materials Science, University of California, Irvine, USA
Department of Chemical engineering and Materials Science, University of California, Irvine, USA, Department of Chemistry

Publication Date:: Tue Nov 06 00:00:00 EST 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1477898

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Dalton Transactions

Additional Journal Information:: Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 43; Journal ID: ISSN 1477-9226

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Moon, Jisue, and Nilsson, Mikael. Coordination chemistry of lanthanides in a AOT–CMPO solvent extraction system: UV-Vis and XAFS studies.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C8DT02957A.

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                    Moon, Jisue, & Nilsson, Mikael. Coordination chemistry of lanthanides in a AOT–CMPO solvent extraction system: UV-Vis and XAFS studies.  United Kingdom.  https://doi.org/10.1039/C8DT02957A

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                    Moon, Jisue, and Nilsson, Mikael. Tue .  
"Coordination chemistry of lanthanides in a AOT–CMPO solvent extraction system: UV-Vis and XAFS studies".  United Kingdom.  https://doi.org/10.1039/C8DT02957A.

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@article{osti_1477898,

  title        = {Coordination chemistry of lanthanides in a AOT–CMPO solvent extraction system: UV-Vis and XAFS studies},

  author       = {Moon, Jisue and Nilsson, Mikael},

  abstractNote = {Synergistic extraction systems using AOT and CMPO were investigated at the molecular level for improved understanding of the lanthanide coordination environment.},

  doi          = {10.1039/C8DT02957A},

  journal      = {Dalton Transactions},

  number       = 43,

  volume       = 47,

  place        = {United Kingdom},

  year         = {Tue Nov 06 00:00:00 EST 2018},

  month        = {Tue Nov 06 00:00:00 EST 2018}

}

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Title: Coordination chemistry of lanthanides in a AOT–CMPO solvent extraction system: UV-Vis and XAFS studies

Abstract

Citation Formats

Nanoparticle and polymer synthesis in microemulsions journal, December 1996

An europium( iii ) diglycolamide complex: insights into the coordination chemistry of lanthanides in solvent extraction journal, January 2015

Characterization and Comparison of Cm(III) and Eu(III) Complexed with 2,6-Di(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine Using EXAFS, TRFLS, and Quantum-Chemical Methods journal, November 2005

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal, June 2005

Coordination Chemistry of Trivalent Lanthanide and Actinide Ions in Dilute and Concentrated Chloride Solutions journal, February 2000

Extraction of Americium(Iii) from Chloride Media by Octyl(Phenyl)-N,N-Diisobutylcarbamoylmethylphosphine Oxide∗ journal, July 1987

The coordination chemistry of Cm III , Am III , and Ac III in nitrate solutions: an actinide L 3 -edge EXAFS study journal, January 2018

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Complexation Behavior of Eu(III) and Am(III) with CMPO and Ph 2 CMPO Ligands: Insights from Density Functional Theory journal, September 2013

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Cooperative effect of carbamoylmethylene phosphine oxide on the extraction of lanthanides(III) to water-in-oil microemulsion from concentrated nitric acid medium journal, January 2000

A Wavelet Transform and its Application to Spectroscopic Analysis journal, January 2002

Reversed-Micellar Extraction of Strontium(II) from Model Solutions of Seawater journal, January 2011

Extraction of Water and Speciation of Trivalent Lanthanides and Americium in Organophosphorus Extractants journal, November 2016

Reverse Micelle Synthesis and Characterization of Superparamagnetic MnFe 2 O 4 Spinel Ferrite Nanocrystallites journal, February 2000

Reverse-Micelle Formation in the Partitioning of Trivalent f-Element Cations by Biphasic Systems Containing a Tetraalkyldiglycolamide journal, April 2007

EXAFS and time-resolved laser fluorescence spectroscopy (TRLFS) investigations of the structure of Cm(iii)/Eu(iii) complexed with di(chlorophenyl)dithiophosphinic acid and different synergistic agents journal, January 2005

Effect of Nitric Acid Distribution on Extraction Behavior of Trivalent F‐Elements in a TRUEX System journal, July 2006

Synergistic Extraction of Rare Earth Elements from Phosphoric Acid Medium using a Mixture of Surfactant AOT and DEHCNPB journal, July 2017

Extraction of nitric acid from aqueous media with O? D(iB)CMPO–n-dodecane journal, February 1997

Effect of drying methods and solvent extraction on the phenolic compounds of Gynura pseudochina (L.) DC. leaf extracts and their anti-psoriatic property journal, September 2018

Solvent extraction and separation of light rare earth elements (La, Pr and Nd) in the presence of lactic acid as a complexing agent by Cyanex 272 in kerosene and the effect of citric acid, acetic acid and Titriplex III as auxiliary agents journal, March 2018

The New MRCAT (Sector 10) Bending Magnet Beamline at the Advanced Photon Source conference, January 2010

Extraction of Europium(III) into W/O Microemulsion Containing Aerosol OT and a Bulky Diamide. I. Cooperative Effect journal, January 2003

Supercritical fluid extraction of rare earth elements from luminescent material in waste fluorescent lamps journal, March 2005

Temperature dependence of the f←f hypersensitive transitions of Ho3+ and Nd3+ in molten salt solvents and the structure of the LaCl3–KCl melts journal, January 2006

Acid-switched Eu(III) coordination inside reverse aggregates: Insights into a synergistic liquid-liquid extraction system journal, April 2017

Erbium(III) Coordination at the Surface of an Aqueous Electrolyte journal, May 2015

THE TRUEX PROCESS - A PROCESS FOR THE EXTRACTION OF THE TKANSURANIC ELEMENTS EROM NITRIC AC In WASTES UTILIZING MODIFIED PUREX SOLVENT* journal, February 1985

Ab initio theory and calculations of X-ray spectra journal, July 2009

Microemulsion-based media as novel drug delivery systems journal, December 2012

Structural study of complexes formed by acidic and neutral organophosphorus reagents journal, January 2017

Trivalent f -Element Intra-group Separation by Solvent Extraction with CMPO-complexant System journal, February 1998

Hypersensitive transitions of six-, seven-, and eight-coordinate neodymium, holmium, and erbium chelates journal, October 1967

Hypersensitive Transitions in Rare‐Earth Ions journal, January 1966

Extraction of Zirconium Nitrate by TBP in n -Octane: Influence of Cation Type on Third Phase Formation According to the “Sticky Spheres” Model journal, December 2004

Physicochemical characterization of colloidal drug delivery systems such as reverse micelles, vesicles, liquid crystals and nanoparticles for topical administration journal, September 2004

The formation of molecular aggregation structures in ternary system: Aerosol OT/water/iso-octane journal, February 1980

Study of the Interaction between HDEHP and CMPO and Its Effect on the Extraction of Selected Lanthanides journal, July 2012

Nanoparticle and polymer synthesis in microemulsions
journal, December 1996

An europium( iii ) diglycolamide complex: insights into the coordination chemistry of lanthanides in solvent extraction
journal, January 2015

Characterization and Comparison of Cm(III) and Eu(III) Complexed with 2,6-Di(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine Using EXAFS, TRFLS, and Quantum-Chemical Methods
journal, November 2005

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Coordination Chemistry of Trivalent Lanthanide and Actinide Ions in Dilute and Concentrated Chloride Solutions
journal, February 2000

Extraction of Americium(Iii) from Chloride Media by Octyl(Phenyl)-N,N-Diisobutylcarbamoylmethylphosphine Oxide∗
journal, July 1987

The coordination chemistry of Cm ^III , Am ^III , and Ac ^III in nitrate solutions: an actinide L ₃ -edge EXAFS study
journal, January 2018

Wavelet analysis of extended x-ray absorption fine structure data
journal, March 2005

Thermodynamic Modeling of Chemical Equilibria in Metal Extraction
journal, October 1988

Atomic cobalt on nitrogen-doped graphene for hydrogen generation
journal, October 2015

Hypersensitive transitions of hydrated neodymium-(III)holmium-(III) and erbium-(III) ions
journal, March 1968

Complexation Behavior of Eu(III) and Am(III) with CMPO and Ph ₂ CMPO Ligands: Insights from Density Functional Theory
journal, September 2013

Extraction of Trivalent Lanthanides and Actinides by “Cmpo-Like” Calixarenes
journal, January 1999

Recovery of light and heavy rare earth elements from apatite ore using sulphuric acid leaching, solvent extraction and precipitation
journal, August 2018

Liquid-Liquid Extraction of Low Molecular-Weight Proteins by Selective Solubilization in Reversed Micelles
journal, February 1987

Selective recovery of rare earth elements from ion-adsorption rare earth element ores by stepwise extraction with HEH(EHP) and HDEHP
journal, January 2017

Structural study of holmium (III) and uranium (VI) organic ligand complexes by extended X-ray absorbtion fine-structure spectroscopy
journal, June 1998

Cooperative effect of carbamoylmethylene phosphine oxide on the extraction of lanthanides(III) to water-in-oil microemulsion from concentrated nitric acid medium
journal, January 2000

A Wavelet Transform and its Application to Spectroscopic Analysis
journal, January 2002

Reversed-Micellar Extraction of Strontium(II) from Model Solutions of Seawater
journal, January 2011

Extraction of Water and Speciation of Trivalent Lanthanides and Americium in Organophosphorus Extractants
journal, November 2016

Reverse Micelle Synthesis and Characterization of Superparamagnetic MnFe ₂ O ₄ Spinel Ferrite Nanocrystallites
journal, February 2000

Reverse-Micelle Formation in the Partitioning of Trivalent f-Element Cations by Biphasic Systems Containing a Tetraalkyldiglycolamide
journal, April 2007

EXAFS and time-resolved laser fluorescence spectroscopy (TRLFS) investigations of the structure of Cm(iii)/Eu(iii) complexed with di(chlorophenyl)dithiophosphinic acid and different synergistic agents
journal, January 2005

Effect of Nitric Acid Distribution on Extraction Behavior of Trivalent F‐Elements in a TRUEX System
journal, July 2006

Synergistic Extraction of Rare Earth Elements from Phosphoric Acid Medium using a Mixture of Surfactant AOT and DEHCNPB
journal, July 2017

Extraction of nitric acid from aqueous media with O? D(iB)CMPO–n-dodecane
journal, February 1997

Effect of drying methods and solvent extraction on the phenolic compounds of Gynura pseudochina (L.) DC. leaf extracts and their anti-psoriatic property
journal, September 2018

Solvent extraction and separation of light rare earth elements (La, Pr and Nd) in the presence of lactic acid as a complexing agent by Cyanex 272 in kerosene and the effect of citric acid, acetic acid and Titriplex III as auxiliary agents
journal, March 2018

The New MRCAT (Sector 10) Bending Magnet Beamline at the Advanced Photon Source
conference, January 2010

Extraction of Europium(III) into W/O Microemulsion Containing Aerosol OT and a Bulky Diamide. I. Cooperative Effect
journal, January 2003

Supercritical fluid extraction of rare earth elements from luminescent material in waste fluorescent lamps
journal, March 2005

Temperature dependence of the f←f hypersensitive transitions of Ho3+ and Nd3+ in molten salt solvents and the structure of the LaCl3–KCl melts
journal, January 2006

Acid-switched Eu(III) coordination inside reverse aggregates: Insights into a synergistic liquid-liquid extraction system
journal, April 2017

Erbium(III) Coordination at the Surface of an Aqueous Electrolyte
journal, May 2015

THE TRUEX PROCESS - A PROCESS FOR THE EXTRACTION OF THE TKANSURANIC ELEMENTS EROM NITRIC AC In WASTES UTILIZING MODIFIED PUREX SOLVENT*
journal, February 1985

Ab initio theory and calculations of X-ray spectra
journal, July 2009

Microemulsion-based media as novel drug delivery systems
journal, December 2012

Structural study of complexes formed by acidic and neutral organophosphorus reagents
journal, January 2017

Trivalent f -Element Intra-group Separation by Solvent Extraction with CMPO-complexant System
journal, February 1998

Hypersensitive transitions of six-, seven-, and eight-coordinate neodymium, holmium, and erbium chelates
journal, October 1967

Hypersensitive Transitions in Rare‐Earth Ions
journal, January 1966

Extraction of Zirconium Nitrate by TBP in n -Octane: Influence of Cation Type on Third Phase Formation According to the “Sticky Spheres” Model
journal, December 2004

Physicochemical characterization of colloidal drug delivery systems such as reverse micelles, vesicles, liquid crystals and nanoparticles for topical administration
journal, September 2004

The formation of molecular aggregation structures in ternary system: Aerosol OT/water/iso-octane
journal, February 1980

Study of the Interaction between HDEHP and CMPO and Its Effect on the Extraction of Selected Lanthanides
journal, July 2012