An Obscured or Nonexistent Binary Intermetallic, Co 7 Pr 17 , Its Existent Neighbor Co 2 Pr 5 , and Two New Ternaries in the System Co/Sn/Pr, CoSn 3 Pr 1–x , and Co 2–x Sn 7 Pr 3
Abstract
Four compounds are reported in this study. Co7Pr17 (10, cP96, P213, a = 13.4147(8) Å, Z = 4), either non-existent or obscured in the Co/Pr phase diagram has been obtained from a PrBr3 flux. With 29.2 mol% Co, it is close to Co2Pr5 (28.6 mol% Co, 2, C2Mn5 type of structure, mC28, C2/c, a = 16.5471(7) Å, b = 6.5107(3) Å, c = 7.1067(3) Å, β = 96.230(3)', Z = 4), existent in the Co/Pr phase diagram, produced by arc-melting of a stoichiometric mixture of the metals. The addition of the reactive metal tin to Co/Pr mixtures yielded two new ternary polar intermetallics, CoSn3Pr1-x (x = 0.04, 11, RuSn3La type, cP40, Pm3-n, a = 9.587(3) Å, Z = 8) and Co2–xSn7Pr3 (x = 0.78, 12, Ni2–xSn7–yCe3 type, oC24, Cmmm, a = 4.5043(4) Å, b = 27.227(2) Å, c = 4.5444(3) Å, Z = 2). Electronic structure calculations reveal extensive heteroatomic Co-Pr interactions in the binaries with little homoatomic contributions. With tin as the third component in the ternaries, heteroatomic Co–Sn and Sn–Pr bonding interactions are dominant, following the sequence of coordination spheres around Co.
- Authors:
-
[3];
[4];
[5]
- Ames Lab., Ames, IA (United States)
- Univ. zu Koln (Germany)
- Ames Lab., Ames, IA (United States); Stockholm Univ. (Sweden)
- Ames Lab., Ames, IA (United States); Stockholm Univ. (Sweden); Iowa State Univ., Ames, IA (United States)
- Ames Lab., Ames, IA (United States); Univ. zu Koln (Germany)
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1477240
- Report Number(s):
- IS-J-9755
Journal ID: ISSN 1528-7483
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Crystal Growth and Design
- Additional Journal Information:
- Journal Volume: 18; Journal Issue: 10; Journal ID: ISSN 1528-7483
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Rhodehouse, Melissa L., Bell, Thomas, Smetana, Volodymyr, Mudring, Anja-Verena, and Meyer, Gerd H. An Obscured or Nonexistent Binary Intermetallic, Co 7 Pr 17 , Its Existent Neighbor Co 2 Pr 5 , and Two New Ternaries in the System Co/Sn/Pr, CoSn 3 Pr 1–x , and Co 2–x Sn 7 Pr 3. United States: N. p., 2018.
Web. doi:10.1021/acs.cgd.8b01141.
Rhodehouse, Melissa L., Bell, Thomas, Smetana, Volodymyr, Mudring, Anja-Verena, & Meyer, Gerd H. An Obscured or Nonexistent Binary Intermetallic, Co 7 Pr 17 , Its Existent Neighbor Co 2 Pr 5 , and Two New Ternaries in the System Co/Sn/Pr, CoSn 3 Pr 1–x , and Co 2–x Sn 7 Pr 3. United States. https://doi.org/10.1021/acs.cgd.8b01141
Rhodehouse, Melissa L., Bell, Thomas, Smetana, Volodymyr, Mudring, Anja-Verena, and Meyer, Gerd H. Thu .
"An Obscured or Nonexistent Binary Intermetallic, Co 7 Pr 17 , Its Existent Neighbor Co 2 Pr 5 , and Two New Ternaries in the System Co/Sn/Pr, CoSn 3 Pr 1–x , and Co 2–x Sn 7 Pr 3". United States. https://doi.org/10.1021/acs.cgd.8b01141. https://www.osti.gov/servlets/purl/1477240.
@article{osti_1477240,
title = {An Obscured or Nonexistent Binary Intermetallic, Co 7 Pr 17 , Its Existent Neighbor Co 2 Pr 5 , and Two New Ternaries in the System Co/Sn/Pr, CoSn 3 Pr 1–x , and Co 2–x Sn 7 Pr 3},
author = {Rhodehouse, Melissa L. and Bell, Thomas and Smetana, Volodymyr and Mudring, Anja-Verena and Meyer, Gerd H.},
abstractNote = {Four compounds are reported in this study. Co7Pr17 (10, cP96, P213, a = 13.4147(8) Å, Z = 4), either non-existent or obscured in the Co/Pr phase diagram has been obtained from a PrBr3 flux. With 29.2 mol% Co, it is close to Co2Pr5 (28.6 mol% Co, 2, C2Mn5 type of structure, mC28, C2/c, a = 16.5471(7) Å, b = 6.5107(3) Å, c = 7.1067(3) Å, β = 96.230(3)', Z = 4), existent in the Co/Pr phase diagram, produced by arc-melting of a stoichiometric mixture of the metals. The addition of the reactive metal tin to Co/Pr mixtures yielded two new ternary polar intermetallics, CoSn3Pr1-x (x = 0.04, 11, RuSn3La type, cP40, Pm3-n, a = 9.587(3) Å, Z = 8) and Co2–xSn7Pr3 (x = 0.78, 12, Ni2–xSn7–yCe3 type, oC24, Cmmm, a = 4.5043(4) Å, b = 27.227(2) Å, c = 4.5444(3) Å, Z = 2). Electronic structure calculations reveal extensive heteroatomic Co-Pr interactions in the binaries with little homoatomic contributions. With tin as the third component in the ternaries, heteroatomic Co–Sn and Sn–Pr bonding interactions are dominant, following the sequence of coordination spheres around Co.},
doi = {10.1021/acs.cgd.8b01141},
journal = {Crystal Growth and Design},
number = 10,
volume = 18,
place = {United States},
year = {Thu Sep 06 00:00:00 EDT 2018},
month = {Thu Sep 06 00:00:00 EDT 2018}
}
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Figures / Tables:
Figure 1: The Co/Sn/Pr compositional triangle. Blue: binaries; red: new intermetallics; green: reported ternaries.
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Works referenced in this record:
Non-existent compounds
journal, March 1963
- Dasent, W. E.
- Journal of Chemical Education, Vol. 40, Issue 3
Crystal structure of R3Co8Sn4 compounds (R=Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y)
journal, February 2000
- Canepa, F.; Cirafici, S.; Fornasini, M. L.
- Journal of Alloys and Compounds, Vol. 297, Issue 1-2
Crystal-structure and magnetic properties of the new ternary compound Pr117Co57Sn112
journal, February 2010
- He, Wei; Zhang, Jiliang; Yan, Jialin
- Journal of Alloys and Compounds, Vol. 491, Issue 1-2
Structural disorder and magnetism in rare-earth (R) R117Co54+xSn112±y
journal, April 2013
- Mudryk, Y.; Manfrinetti, P.; Smetana, V.
- Journal of Alloys and Compounds, Vol. 557
Nouveaux isotypes de CeNiSi2 dans les systemes R-M-X (R ≡ La-Lu, M ≡ metaux des groupes 7 A 11 ET X ≡ Ge, Sn). I Compositions et parametres cristallins
journal, May 1990
- François, M.; Venturini, G.; Malaman, B.
- Journal of the Less Common Metals, Vol. 160, Issue 2
The ammonium-bromide route to anhydrous rare earth bromides MBr3
journal, January 1987
- Meyer, Gerd; Dötsch, Siegfried; Staffel, Thomas
- Journal of the Less Common Metals, Vol. 127
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015
- Krause, Lennard; Herbst-Irmer, Regine; Sheldrick, George M.
- Journal of Applied Crystallography, Vol. 48, Issue 1
SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015
- Sheldrick, George M.
- Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
Crystal structure refinement with SHELXL
journal, January 2015
- Sheldrick, George M.
- Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
Explicit, First-Principles Tight-Binding Theory
journal, December 1984
- Andersen, O. K.; Jepsen, O.
- Physical Review Letters, Vol. 53, Issue 27
Minimal basis sets in the linear muffin-tin orbital method: Application to the diamond-structure crystals C, Si, and Ge
journal, August 1986
- Lambrecht, Walter R. L.; Andersen, O. K.
- Physical Review B, Vol. 34, Issue 4
Crystal orbital Hamilton populations (COHP): energy-resolved visualization of chemical bonding in solids based on density-functional calculations
journal, August 1993
- Dronskowski, Richard; Bloechl, Peter E.
- The Journal of Physical Chemistry, Vol. 97, Issue 33
A Section Through the Compositional Triangle Pr-Co-I at 600 °C: Pr7CoI12 and Pr2Co2I
journal, September 2006
- Palasyuk, Andriy; Pantenburg, Ingo; Meyer, Gerd
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 632, Issue 12-13
Reduced Praseodymium Cluster Bromides Stabilized by Transition Metals
journal, March 1994
- Llusar, Rosa; Corbett, John D.
- Inorganic Chemistry, Vol. 33, Issue 5
Crystal structure of the so-called R.E.5Pd2 compounds
journal, October 1974
- Fornasini, M. L.; Palenzona, A.
- Journal of the Less Common Metals, Vol. 38, Issue 1
The crystal structure of Ti2Ni
journal, November 1959
- Yurko, G. A.; Barton, J. W.; Parr, J. G.
- Acta Crystallographica, Vol. 12, Issue 11
IX. A comparison of the crystal structures of Cu 5 Zn 8 and Cu 5 Cd 8
journal, July 1931
- Bradley, A. J.; Gregory, C. H.
- The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 12, Issue 75
From the Nonexistent Polar Intermetallic Pt 3 Pr 4 via Pt 2– x Pr 3 to Pt/Sn/Pr Ternaries
journal, April 2018
- Rhodehouse, Melissa L.; Bell, Thomas; Smetana, Volodymyr
- Inorganic Chemistry, Vol. 57, Issue 16
R 3 T 2 compounds ( R = rare earth or Y; T = Rh, Pd, Pt) with the rhombohedral Er 3 Ni 2 structure type
journal, August 1977
- Le Roy, J.; Moreau, J. -M.; Paccard, D.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 33, Issue 8
Crystal structure and magnetic properties of some 7:3 binary phases between lanthanides and metals of the 8th group
journal, October 1973
- Olcese, G. L.
- Journal of the Less Common Metals, Vol. 33, Issue 1
On phase equilibria and crystal structures in the systems Ce–Pd–B and Yb–Pd–B. Physical properties of R2Pd13.6B5 (R=Yb, Lu)
journal, May 2010
- Sologub, Oksana; Rogl, Peter; Salamakha, Leonid
- Journal of Solid State Chemistry, Vol. 183, Issue 5
The europium-palladium system
journal, October 1974
- Iandelli, A.; Palenzona, A.
- Journal of the Less Common Metals, Vol. 38, Issue 1
The monoclinic crystal structure of R 5 Co 2 ( R = Pr, Nd, Sm) with the Mn 5 C 2 structure type
journal, June 1976
- Moreau, J. -M.; Paccard, D.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 32, Issue 6
Structural consequences of the range of the interatomic potential A menagerie of clusters
journal, January 1997
- Doye, Jonathan P. K.; Wales, David J.
- Journal of the Chemical Society, Faraday Transactions, Vol. 93, Issue 24
New refinements of the γ brass type structures Cu5Zn8, Cu5Cd8 and Fe3Zn10
journal, June 1974
- Brandon, J. K.; Brizard, R. Y.; Chieh, P. C.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 30, Issue 6
Double-Icosahedral Li Clusters in a New Binary Compound Ba 19 Li 44 : A Reinvestigation of the Ba−Li Phase Diagram
journal, May 2007
- Smetana, Volodymyr; Babizhetskyy, Volodymyr; Vajenine, Grigori V.
- Inorganic Chemistry, Vol. 46, Issue 13
Icosahedral Li clusters in the structures of Li33.3Ba13.1Ca3 and Li18.9Na8.3Ba15.3
journal, November 2007
- Smetana, Volodymyr; Babizhetskyy, Volodymyr; Hoch, Constantin
- Journal of Solid State Chemistry, Vol. 180, Issue 11
Synthesis, Crystal Structure, and TEM Analysis of Sr 19 Li 44 and Sr 3 Li 2 : A Reinvestigation of the Sr–Li Phase Diagram
journal, June 2014
- Smetana, Volodymyr; Kienle, Lorenz; Duppel, Viola
- Inorganic Chemistry, Vol. 54, Issue 3
Li26 Clusters in the Compound Li13Na29Ba19
journal, September 2006
- Smetana, Volodymyr; Babizhetskyy, Volodymyr; Vajenine, Grigori V.
- Angewandte Chemie International Edition, Vol. 45, Issue 36
The crystal structure of Mn 3 Al 10
journal, May 1959
- Taylor, M. A.
- Acta Crystallographica, Vol. 12, Issue 5
Anti-Mackay Polyicosahedral Clusters in La−Ni−Mg Ternary Compounds: Synthesis and Crystal Structure of the La 43 Ni 17 Mg 5 New Intermetallic Phase
journal, November 2009
- Solokha, Pavlo; De Negri, Serena; Pavlyuk, Volodymyr
- Inorganic Chemistry, Vol. 48, Issue 24
The crystal structure of the metallic phase Mg32(Al, Zn)49
journal, April 1957
- Bergman, G.; Waugh, J. L. T.; Pauling, L.
- Acta Crystallographica, Vol. 10, Issue 4
Kristallstruktur und Ferromagnetismus der Mangan-Aluminium-Kupferlegierungen
journal, January 1934
- Heusler, Otto
- Annalen der Physik, Vol. 411, Issue 2
Die ternären systeme (Titan, Zirkonium, Hafnium)-kupfer-Silizium
journal, January 1974
- Sprenger, Heinz
- Journal of the Less Common Metals, Vol. 34, Issue 1
Käfigstrukturen in intermetallischen Verbindungen: zur Kenntnis von LaRuSn3, CeRuSn3, PrRuSn3 UND NdRuSn3
journal, September 1986
- Eisenmann, Brigitte; Schäfer, Herbert
- Journal of the Less Common Metals, Vol. 123, Issue 1-2
Mixed valent stannide EuRuSn3 – Structure, magnetic properties, and Mössbauer spectroscopic investigation
journal, February 2010
- Harmening, Thomas; Hermes, Wilfried; Eul, Matthias
- Solid State Sciences, Vol. 12, Issue 2
Single Crystal X-ray Structure Investigation and Electronic Structure Studies of La-Deficient Nickel Stannide La4.87Ni12Sn24 Grown from Sn Flux
journal, February 2003
- Zhuravleva, Marina A.; Bilc, Daniel; Mahanti, S. D.
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 629, Issue 2
Crystallographic, magnetic and electrical characteristics of some R5−xNi12Sn24+x intermetallics
journal, March 2010
- Romaka, V. V.; Hlil, E. K.; Romaka, L.
- Journal of Alloys and Compounds, Vol. 493, Issue 1-2
Ca7Co8Sn25Ca3Co4Sn13 revised
journal, July 2006
- Schreyer, Martin; Fässler, Thomas F.
- Solid State Sciences, Vol. 8, Issue 7
Physical properties and superconductivity of skutterudite-related Yb 3 Co 4.3 Sn 12.7 and Yb 3 Co 4 Ge 13
journal, August 2001
- Mudryk, Ya; Grytsiv, A.; Rogl, P.
- Journal of Physics: Condensed Matter, Vol. 13, Issue 33
Magnetic ordering of CeNi0.78Sn2 and Ce3Ni2Sn7 compounds by neutron diffraction
journal, July 2001
- Schobinger-Papamantellos, P.; André, G.; Rodrı́guez-Carvajal, J.
- Journal of Alloys and Compounds, Vol. 325, Issue 1-2
Crystal chemistry and magnetism of neodymium stannides including compounds of the structural series REnSn3n−2
journal, June 1992
- Weitzer, F.; Hiebl, K.; Rogl, P.
- Journal of Solid State Chemistry, Vol. 98, Issue 2
Gold Polar Intermetallics: Structural Versatility through Exclusive Bonding Motifs
journal, October 2017
- Smetana, Volodymyr; Rhodehouse, Melissa; Meyer, Gerd
- Accounts of Chemical Research, Vol. 50, Issue 11
Cs2Pt: A Platinide(-II) Exhibiting Complete Charge Separation
journal, October 2003
- Karpov, Andrey; Nuss, Jürgen; Wedig, Ulrich
- Angewandte Chemie International Edition, Vol. 42, Issue 39
Cesium Platinide Hydride 4Cs 2 Pt⋅CsH: An Intermetallic Double Salt Featuring Metal Anions
journal, October 2016
- Smetana, Volodymyr; Mudring, Anja-Verena
- Angewandte Chemie International Edition, Vol. 55, Issue 47
Synthesis, Structure, and Bonding Analysis of the Polar Intermetallic Phase Ca 2 Pt 2 Cd
journal, August 2012
- Samal, Saroj L.; Corbett, John D.
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 638, Issue 12-13
Substantial Cd–Cd Bonding in Ca 6 PtCd 11 : A Condensed Intermetallic Phase Built of Pentagonal Cd 7 and Rectangular Cd 4/2 Pt Pyramids
journal, August 2013
- Gulo, Fakhili; Samal, Saroj L.; Corbett, John D.
- Inorganic Chemistry, Vol. 52, Issue 17
Cluster Chemistry in Electron-Poor Ae–Pt–Cd Systems (Ae = Ca, Sr, Ba): (Sr,Ba)Pt 2 Cd 4 , Ca 6 Pt 8 Cd 16 , and Its Known Antitype Er 6 Pd 16 Sb 8
journal, February 2013
- Samal, Saroj L.; Gulo, Fakhili; Corbett, John D.
- Inorganic Chemistry, Vol. 52, Issue 5
Layered Structures and Disordered Polyanionic Nets in the Cation-Poor Polar Intermetallics CsAu 1.4 Ga 2.8 and CsAu 2 Ga 2.6
journal, January 2017
- Smetana, Volodymyr; Steinberg, Simon; Mudring, Anja-Verena
- Crystal Growth & Design, Vol. 17, Issue 2
Na8Au9.8(4)Ga7.2 and Na17Au5.87(2)Ga46.63: The diversity of pseudo 5-fold symmetries in the Na–Au–Ga system
journal, November 2013
- Smetana, Volodymyr; Corbett, John D.; Miller, Gordon J.
- Journal of Solid State Chemistry, Vol. 207
Gold-rich R 3 Au 7 Sn 3 : establishing the interdependence between electronic features and physical properties
journal, January 2015
- Provino, Alessia; Steinberg, Simon; Smetana, Volodymyr
- J. Mater. Chem. C, Vol. 3, Issue 32
Gold in the Layered Structures of R 3 Au 7 Sn 3 : From Relativity to Versatility
journal, September 2016
- Provino, Alessia; Steinberg, Simon; Smetana, Volodymyr
- Crystal Growth & Design, Vol. 16, Issue 10
Conventional and Stuffed Bergman-Type Phases in the Na–Au–T (T = Ga, Ge, Sn) Systems: Syntheses, Structures, Coloring of Cluster Centers, and Fermi Sphere–Brillouin Zone Interactions
journal, August 2012
- Lin, Qisheng; Smetana, Volodymyr; Miller, Gordon J.
- Inorganic Chemistry, Vol. 51, Issue 16
A Sodium-Containing Quasicrystal: Using Gold To Enhance Sodium’s Covalency in Intermetallic Compounds
journal, November 2012
- Smetana, Volodymyr; Lin, Qisheng; Pratt, Daniel K.
- Angewandte Chemie International Edition, Vol. 51, Issue 51
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