Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures
Abstract
Transition metal dichalcogenides combining multiple principal elements in their structures are synthesized via mechanochemical exfoliation and spontaneous reassembly of binary precursors into 3D-heterostructures that are converted into single-phase layered materials by high-temperature reactive fusion. As a result, physical and chemical events enabling these transformations are summarized in the form of a conceivable reaction mechanism.
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1477202
- Alternate Identifier(s):
- OSTI ID: 1475079
- Report Number(s):
- IS-J-9760
Journal ID: ISSN 1359-7345
- Grant/Contract Number:
- AC02-07CH11358; Laboratory Directed Research and Development (LDRD) program
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 89; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., and Balema, Viktor P. Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures. United States: N. p., 2018.
Web. doi:10.1039/C8CC06766J.
Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., & Balema, Viktor P. Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures. United States. https://doi.org/10.1039/C8CC06766J
Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., and Balema, Viktor P. Mon .
"Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures". United States. https://doi.org/10.1039/C8CC06766J. https://www.osti.gov/servlets/purl/1477202.
@article{osti_1477202,
title = {Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures},
author = {Hlova, Ihor Z. and Dolotko, Oleksandr and Boote, Brett W. and Pathak, Arjun K. and Smith, Emily A. and Pecharsky, Vitalij K. and Balema, Viktor P.},
abstractNote = {Transition metal dichalcogenides combining multiple principal elements in their structures are synthesized via mechanochemical exfoliation and spontaneous reassembly of binary precursors into 3D-heterostructures that are converted into single-phase layered materials by high-temperature reactive fusion. As a result, physical and chemical events enabling these transformations are summarized in the form of a conceivable reaction mechanism.},
doi = {10.1039/C8CC06766J},
journal = {ChemComm},
number = 89,
volume = 54,
place = {United States},
year = {Mon Sep 24 00:00:00 EDT 2018},
month = {Mon Sep 24 00:00:00 EDT 2018}
}
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Cited by: 7 works
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Figures / Tables:
Fig. 1: (Mo0.5W0.5)S2. (a) XRD patterns and (b) Raman spectra of as-milled and milled then fused equimolar mixtures of MoS2 and WS2. Vertical bars in (a) indicate the Bragg peak positions of starting materials. Chart (b) also shows the Raman spectra of MoS2 and WS2.
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Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.