The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting

Zhai, Shang; Rojas, Jimmy; Ahlborg, Nadia; Lim, Kipil; Toney, Michael F.; Jin, Hyungyu; Chueh, William C.; Majumdar, Arun

doi:10.1039/c8ee00050f

Title: The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting

Abstract

We report the discovery of a new class of oxides – poly-cation oxides (PCOs) – that consist of multiple cations and can thermochemically split water in a two-step cycle to produce hydrogen (H ₂ ) and oxygen (O ₂ ).

Authors:

Zhai, Shang ^[1]; Rojas, Jimmy ^[1]; Ahlborg, Nadia ^[1]; Lim, Kipil ^[2];

^[3];

^[4];

^[2];

^[1]

Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Stanford Univ., Stanford, CA (United States); Pohang Univ. of Science and Technology (POSTECH), Pohang (South Korea)

Publication Date:: Fri Jun 08 00:00:00 EDT 2018

Research Org.:: SLAC National Accelerator Lab., Menlo Park, CA (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office

OSTI Identifier:: 1476172

Alternate Identifier(s):: OSTI ID: 1441058

Grant/Contract Number:: AC02-76SF00515; N00014-17-1-2918

Resource Type:: Accepted Manuscript

Journal Name:: Energy & Environmental Science

Additional Journal Information:: Journal Volume: 11; Journal Issue: 8; Journal ID: ISSN 1754-5692

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Zhai, Shang, Rojas, Jimmy, Ahlborg, Nadia, Lim, Kipil, Toney, Michael F., Jin, Hyungyu, Chueh, William C., and Majumdar, Arun. The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting.  United States: N. p., 2018. 
Web.  doi:10.1039/c8ee00050f.

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                    Zhai, Shang, Rojas, Jimmy, Ahlborg, Nadia, Lim, Kipil, Toney, Michael F., Jin, Hyungyu, Chueh, William C., & Majumdar, Arun. The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting.  United States.  https://doi.org/10.1039/c8ee00050f

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                    Zhai, Shang, Rojas, Jimmy, Ahlborg, Nadia, Lim, Kipil, Toney, Michael F., Jin, Hyungyu, Chueh, William C., and Majumdar, Arun. Fri .  
"The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting".  United States.  https://doi.org/10.1039/c8ee00050f.  https://www.osti.gov/servlets/purl/1476172.

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@article{osti_1476172,

  title        = {The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting},

  author       = {Zhai, Shang and Rojas, Jimmy and Ahlborg, Nadia and Lim, Kipil and Toney, Michael F. and Jin, Hyungyu and Chueh, William C. and Majumdar, Arun},

  abstractNote = {We report the discovery of a new class of oxides – poly-cation oxides (PCOs) – that consist of multiple cations and can thermochemically split water in a two-step cycle to produce hydrogen (H 2 ) and oxygen (O 2 ).},

  doi          = {10.1039/c8ee00050f},

  journal      = {Energy & Environmental Science},

  number       = 8,

  volume       = 11,

  place        = {United States},

  year         = {Fri Jun 08 00:00:00 EDT 2018},

  month        = {Fri Jun 08 00:00:00 EDT 2018}

}

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Figures / Tables:

Fig. 1: Schematic of two-step thermochemical water splitting (TWS) using a poly-cation oxide (PCO). In a typical two-step TWS, a metal oxide (MO_xl becomes thermally-reduced at a higher temperature, $T$_H, and releases 0₂ to produce MO_$z$, (z < x). The reduced oxide is cooled to a lower temperature, $T$_L, wheremore »

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Title: The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting

Abstract

Citation Formats

Figures / Tables:

Production of solar hydrogen by a novel, 2-step, water-splitting thermochemical cycle journal, April 1995

Dopant Incorporation in Ceria for Enhanced Water-Splitting Activity during Solar Thermochemical Hydrogen Generation journal, June 2012

Oxygen nonstoichiometry of Ce1−ySmyO2−0.5y−x (y=0.1, 0.2) journal, November 1999

Solar hydrogen generation with H2O/ZnO/MnFe2O4 system journal, January 2004

Oxygen nonstoichiometry and defect equilibrium in La2−xSrxNiO4+δ journal, April 2009

Catalytic Function of IrO x in the Two-Step Thermochemical CO 2 -Splitting Reaction at High Temperatures journal, January 2016

A review on solar thermal syngas production via redox pair-based water/carbon dioxide splitting thermochemical cycles journal, February 2015

Lanthanum–Strontium–Manganese Perovskites as Redox Materials for Solar Thermochemical Splitting of H 2 O and CO 2 journal, March 2013

The Hydrogen Economy journal, December 2004

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A thermodynamic study of nonstoichiometric cerium dioxide journal, November 1975

Critical limitations on the efficiency of two-step thermochemical cycles journal, January 2016

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A thermochemical study of ceria: exploiting an old material for new modes of energy conversion and CO 2 mitigation journal, July 2010

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Progress of international hydrogen production network for the thermochemical Cu–Cl cycle journal, January 2013

CO 2 utilization: an enabling element to move to a resource- and energy-efficient chemical and fuel production journal, March 2015

Tunable thermodynamic activity of La x Sr 1−x Mn y Al 1−y O 3−δ (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) perovskites for solar thermochemical fuel synthesis journal, January 2017

Thermochemical hydrogen production by a redox system of ZrO2-supported Co(II)-ferrite journal, May 2005

Solar thermochemical production of hydrogen––a review journal, May 2005

Oxygen exchange materials for solar thermochemical splitting of H2O and CO2: a review journal, September 2014

A Structural and Magnetic Investigation of the Inversion Degree in Ferrite Nanocrystals MFe 2 O 4 (M = Mn, Co, Ni) journal, May 2009

Catalysis for CO2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries journal, January 2013

High-Flux Solar-Driven Thermochemical Dissociation of CO2 and H2O Using Nonstoichiometric Ceria journal, December 2010

The electrical conductivity and thermodynamic behavior of SrO-doped nonstoichiometric cerium dioxide journal, January 1976

Thermochemical Cycles for High-Temperature Solar Hydrogen Production journal, December 2007

Oxygen Nonstoichiometry and Defect Equilibrium in La 2-x Sr x NiO 4+δ journal, August 2009

Solar Thermochemical Water-Splitting Ferrite-Cycle Heat Engines conference, October 2008

Design principles of perovskites for solar-driven thermochemical splitting of CO2 text, January 2017

The hydrogen economy journal, January 2006

Charge-Induced Disorder Controls the Thermal Conductivity of Entropy-Stabilized Oxides journal, October 2018

Modifying La 0.6 Sr 0.4 MnO 3 Perovskites with Cr Incorporation for Fast Isothermal CO 2 ‐Splitting Kinetics in Solar‐Driven Thermochemical Cycles journal, June 2019

High-entropy ceramics journal, February 2020

Sr- and Co-doped LaGaO 3−δ with high O 2 and H 2 yields in solar thermochemical water splitting journal, January 2019

Production of solar hydrogen by a novel, 2-step, water-splitting thermochemical cycle
journal, April 1995

Dopant Incorporation in Ceria for Enhanced Water-Splitting Activity during Solar Thermochemical Hydrogen Generation
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Oxygen nonstoichiometry of Ce1−ySmyO2−0.5y−x (y=0.1, 0.2)
journal, November 1999

Solar hydrogen generation with H2O/ZnO/MnFe2O4 system
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Oxygen nonstoichiometry and defect equilibrium in La2−xSrxNiO4+δ
journal, April 2009

Catalytic Function of IrO _x in the Two-Step Thermochemical CO ₂ -Splitting Reaction at High Temperatures
journal, January 2016

A review on solar thermal syngas production via redox pair-based water/carbon dioxide splitting thermochemical cycles
journal, February 2015

Lanthanum–Strontium–Manganese Perovskites as Redox Materials for Solar Thermochemical Splitting of H ₂ O and CO ₂
journal, March 2013

The Hydrogen Economy
journal, December 2004

Low-temperature, manganese oxide-based, thermochemical water splitting cycle
journal, May 2012

A thermodynamic study of nonstoichiometric cerium dioxide
journal, November 1975

Critical limitations on the efficiency of two-step thermochemical cycles
journal, January 2016

Giant onsite electronic entropy enhances the performance of ceria for water splitting
journal, August 2017

Thermodynamic Investigation of the Redox Properties of Ceria−Zirconia Solid Solutions
journal, August 2006

Clean hydrogen production with the Cu–Cl cycle – Progress of international consortium, II: Simulations, thermochemical data and materials
journal, December 2011

Opportunities and challenges for a sustainable energy future
journal, August 2012

Evidence for Entropy Effects in the Reduction of Ceria−Zirconia Solutions
journal, October 2006

Entropy-stabilized oxides
journal, September 2015

Significant reduction in the operating temperature of the Mn( ii )/Mn( iii ) oxide-based thermochemical water splitting cycle brought about by the use of nanoparticles
journal, January 2016

Solar Thermochemical Water-Splitting Ferrite-Cycle Heat Engines
journal, January 2008

Perovskite La _0.6 Sr _0.4 Cr _1−x Co _x O _3−δ solid solutions for solar-thermochemical fuel production: strategies to lower the operation temperature
journal, January 2015

Oxygen nonstoichiometry, defect equilibria, and thermodynamic characterization of LaMnO3 perovskites with Ca/Sr A-site and Al B-site doping
journal, January 2016

Modeling Thermochemical Solar-to-Fuel Conversion: CALPHAD for Thermodynamic Assessment Studies of Perovskites, Exemplified for (La,Sr)MnO ₃
journal, September 2016

Thermodynamic evaluation and modeling of the Fe–Co–O system
journal, January 2004

Ceria–Zirconia Solid Solutions (Ce _{1– x} Zr _x O _2−δ , x ≤ 0.2) for Solar Thermochemical Water Splitting: A Thermodynamic Study
journal, October 2014

Thermodynamic modeling of the cerium–yttrium–oxygen system
journal, October 2008

A thermochemical study of ceria: exploiting an old material for new modes of energy conversion and CO ₂ mitigation
journal, July 2010

Oxygen nonstoichiometry and defect structure analysis of B-site mixed perovskite-type oxide (La, Sr)(Cr, M)O3−δ (M=Ti, Mn and Fe)
journal, November 2008

Design principles of perovskites for solar-driven thermochemical splitting of CO ₂
journal, January 2017

Thermodynamic Investigation of the Redox Properties for Ceria−Hafnia, Ceria−Terbia, and Ceria−Praseodymia Solid Solutions
journal, August 2008

Sr- and Mn-doped LaAlO3−δ for solar thermochemical H2 and CO production
journal, January 2013

Screening of water-splitting thermochemical cycles potentially attractive for hydrogen production by concentrated solar energy
journal, November 2006

Considerations in the Design of Materials for Solar-Driven Fuel Production Using Metal-Oxide Thermochemical Cycles
journal, October 2013

Thermochemical Cycles for High-Temperature Solar Hydrogen Production
journal, October 2007

Thermodynamic modelling of the cerium–oxygen system
journal, April 2006

Ce _0.67 Cr _0.33 O _2.11 : A New Low-Temperature O ₂ Evolution Material and H ₂ Generation Catalyst by Thermochemical Splitting of Water ^†
journal, February 2010

Progress of international hydrogen production network for the thermochemical Cu–Cl cycle
journal, January 2013

CO ₂ utilization: an enabling element to move to a resource- and energy-efficient chemical and fuel production
journal, March 2015

Tunable thermodynamic activity of La _x Sr _1−x Mn _y Al _1−y O _3−δ (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) perovskites for solar thermochemical fuel synthesis
journal, January 2017

Thermochemical hydrogen production by a redox system of ZrO₂-supported Co(II)-ferrite
journal, May 2005

Solar thermochemical production of hydrogen––a review
journal, May 2005

Oxygen exchange materials for solar thermochemical splitting of H2O and CO2: a review
journal, September 2014

A Structural and Magnetic Investigation of the Inversion Degree in Ferrite Nanocrystals MFe ₂ O ₄ (M = Mn, Co, Ni)
journal, May 2009

Catalysis for CO2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries
journal, January 2013

High-Flux Solar-Driven Thermochemical Dissociation of CO2 and H2O Using Nonstoichiometric Ceria
journal, December 2010

The electrical conductivity and thermodynamic behavior of SrO-doped nonstoichiometric cerium dioxide
journal, January 1976

Thermochemical Cycles for High-Temperature Solar Hydrogen Production
journal, December 2007

Oxygen Nonstoichiometry and Defect Equilibrium in La _2-x Sr _x NiO _4+δ
journal, August 2009

Solar Thermochemical Water-Splitting Ferrite-Cycle Heat Engines
conference, October 2008

Design principles of perovskites for solar-driven thermochemical splitting of CO2
text, January 2017

The hydrogen economy
journal, January 2006

Charge-Induced Disorder Controls the Thermal Conductivity of Entropy-Stabilized Oxides
journal, October 2018

Modifying La _0.6 Sr _0.4 MnO ₃ Perovskites with Cr Incorporation for Fast Isothermal CO ₂ ‐Splitting Kinetics in Solar‐Driven Thermochemical Cycles
journal, June 2019

High-entropy ceramics
journal, February 2020

Sr- and Co-doped LaGaO _3−δ with high O ₂ and H ₂ yields in solar thermochemical water splitting
journal, January 2019