In-situ observation of oxygen mobility and abnormal lattice expansion in ceria during flash sintering
Abstract
Flash sintering has been shown to be an effective method of sintering for many types of ceramics. However, the characteristics of flash sintering for each type of ceramic varies. When ionically conducting ceramics are sintered under a DC electric field, a strong dependence of densification with respect to position is observed. Microstructural analysis of the effect of electric field on oxygen ion conductors shows non-stoichiometry (oxygen deficiency) at the cathode which continues to build up over time under flash. In oxygen ion conductors, dominant charge carriers during flash are oxygen ions and the final density of the specimen is related to the availability of oxygen. This effect is no longer evident when using an AC power supply. In conclusion, use of AC instead of DC electric field is preferable for flash sintering of ionically conducting ceramics.
- Authors:
-
- Rutgers Univ., Piscataway, NJ (United States)
- Purdue Univ., West Lafayette, IN (United States)
- Rutgers Univ., Piscataway, NJ (United States); Cornell Univ., Ithaca, NY (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- Argonne National Laboratory, Advanced Photon Source; USDOE Office of Science (SC); US Department of the Navy, Office of Naval Research (ONR)
- OSTI Identifier:
- 1473696
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Ceramics International
- Additional Journal Information:
- Journal Volume: 44; Journal Issue: 13; Journal ID: ISSN 0272-8842
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Jha, Shikhar Krishn, Charalambous, Harry, Wang, Han, Phuah, Xin Li, Mead, Christopher, Okasinski, John, Wang, Haiyan, and Tsakalakos, Thomas. In-situ observation of oxygen mobility and abnormal lattice expansion in ceria during flash sintering. United States: N. p., 2018.
Web. doi:10.1016/j.ceramint.2018.05.186.
Jha, Shikhar Krishn, Charalambous, Harry, Wang, Han, Phuah, Xin Li, Mead, Christopher, Okasinski, John, Wang, Haiyan, & Tsakalakos, Thomas. In-situ observation of oxygen mobility and abnormal lattice expansion in ceria during flash sintering. United States. https://doi.org/10.1016/j.ceramint.2018.05.186
Jha, Shikhar Krishn, Charalambous, Harry, Wang, Han, Phuah, Xin Li, Mead, Christopher, Okasinski, John, Wang, Haiyan, and Tsakalakos, Thomas. Tue .
"In-situ observation of oxygen mobility and abnormal lattice expansion in ceria during flash sintering". United States. https://doi.org/10.1016/j.ceramint.2018.05.186. https://www.osti.gov/servlets/purl/1473696.
@article{osti_1473696,
title = {In-situ observation of oxygen mobility and abnormal lattice expansion in ceria during flash sintering},
author = {Jha, Shikhar Krishn and Charalambous, Harry and Wang, Han and Phuah, Xin Li and Mead, Christopher and Okasinski, John and Wang, Haiyan and Tsakalakos, Thomas},
abstractNote = {Flash sintering has been shown to be an effective method of sintering for many types of ceramics. However, the characteristics of flash sintering for each type of ceramic varies. When ionically conducting ceramics are sintered under a DC electric field, a strong dependence of densification with respect to position is observed. Microstructural analysis of the effect of electric field on oxygen ion conductors shows non-stoichiometry (oxygen deficiency) at the cathode which continues to build up over time under flash. In oxygen ion conductors, dominant charge carriers during flash are oxygen ions and the final density of the specimen is related to the availability of oxygen. This effect is no longer evident when using an AC power supply. In conclusion, use of AC instead of DC electric field is preferable for flash sintering of ionically conducting ceramics.},
doi = {10.1016/j.ceramint.2018.05.186},
journal = {Ceramics International},
number = 13,
volume = 44,
place = {United States},
year = {Tue May 22 00:00:00 EDT 2018},
month = {Tue May 22 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
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